-------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 1 converged, 1 successes so far. Misfit function evaluations this try => 323 Misfit this try = 3.710637E-02 Best Misfit so far = 3.710637E-02 obtained on Try 1 Prior probability, PP = 6.349672E-07 Bayes score, PP * exp(-Misfit) = 6.118377E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13000.0 1150.00 0.500000 0.500000 0.500000 Final coordinates: 13104.8 1155.86 0.310263 0.478632 0.521368 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.708149E-02 Extraneous predicted phases: 2.487597E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 36.881 0.0102 0.1854 0.0150 0.2103 0.0786 0.0010 0.0002 0.4942 0.0050 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0024 -0.0077 0.0113 0.0196 -0.0029 0.0024 0.0001 -0.0154 -0.0050 Composition Misfit: 0.177864E-01 Gt predicted* 63.114 0.0000 0.1373 0.1243 0.1168 0.1930 0.0024 0.0005 0.4194 0.0063 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0017 0.0145 -0.0368 0.0295 -0.0019 -0.0001 0.0028 -0.0063 Composition Misfit: 0.192951E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.002 0.0000 0.0000 0.0000 0.0000 0.6523 0.2462 0.0000 0.0000 0.1015 Sp 0.003 0.0000 0.0373 0.0236 0.0000 0.7962 0.0101 0.0013 0.0000 0.1314 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.750 -814695. MgO 155.767 -642540. Al2O3 84.933 -0.167482E+07 CaO 151.757 -755358. FeO 152.256 -335915. TiO2 1.884 -957008. Cr2O3 0.388 -0.123744E+07 SiO2 449.266 -907725. O2 5.905 -420133. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 2 converged, 2 successes so far. Misfit function evaluations this try => 404 Misfit this try = 8.419386E-02 Best Misfit so far = 3.710637E-02 obtained on Try 1 Prior probability, PP = 2.325802E-07 Bayes score, PP * exp(-Misfit) = 2.138000E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8474.26 971.932 0.292163 5.850630E-02 0.941494 Final coordinates: 14578.6 1022.91 0.173183 9.704654E-02 0.902953 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.707726E-02 Extraneous predicted phases: 7.116603E-03 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 3.023 0.0255 0.1666 0.0085 0.1907 0.0874 0.0006 0.0004 0.5115 0.0087 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0177 0.0111 0.0178 0.0392 -0.0117 0.0028 -0.0000 -0.0328 -0.0087 Composition Misfit: 0.744675E-01 Gt predicted* 96.843 0.0000 0.1384 0.1310 0.0913 0.2111 0.0008 0.0004 0.4227 0.0043 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0028 0.0077 -0.0113 0.0114 -0.0003 0.0000 -0.0005 -0.0043 Composition Misfit: 0.260980E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.013 0.0000 0.0000 0.0000 0.0000 0.7269 0.1219 0.0000 0.0000 0.1512 q 0.120 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.760 -790939. MgO 139.701 -633930. Al2O3 127.839 -0.164514E+07 CaO 94.568 -746663. FeO 208.272 -321735. TiO2 0.773 -936774. Cr2O3 0.421 -0.118943E+07 SiO2 427.667 -883490. O2 4.509 -383489. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 3 converged, 3 successes so far. Misfit function evaluations this try => 258 Misfit this try = 3.492218E-02 Best Misfit so far = 3.492218E-02 obtained on Try 3 Prior probability, PP = 9.597624E-08 Bayes score, PP * exp(-Misfit) = 9.268239E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16838.8 1058.53 0.923576 0.119607 0.880393 Final coordinates: 13219.7 1344.33 0.314324 0.486525 0.513475 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.487945E-02 Extraneous predicted phases: 4.273431E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 45.647 0.0084 0.1704 0.0320 0.2005 0.1010 0.0011 0.0003 0.4802 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0006 0.0073 -0.0057 0.0294 -0.0253 0.0023 0.0001 -0.0014 -0.0061 Composition Misfit: 0.166132E-01 Gt predicted* 54.348 0.0000 0.1428 0.1256 0.1125 0.1902 0.0025 0.0005 0.4201 0.0057 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0072 0.0132 -0.0325 0.0323 -0.0020 -0.0001 0.0021 -0.0057 Composition Misfit: 0.182662E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.005 0.0000 0.0463 0.0697 0.0000 0.7539 0.0112 0.0011 0.0000 0.1178 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.812 -837153. MgO 156.100 -657385. Al2O3 84.045 -0.171444E+07 CaO 152.940 -770526. FeO 151.097 -356829. TiO2 1.907 -998497. Cr2O3 0.387 -0.130355E+07 SiO2 449.712 -936602. O2 5.937 -463240. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 4 converged, 4 successes so far. Misfit function evaluations this try => 273 Misfit this try = 2.381851E-02 Best Misfit so far = 2.381851E-02 obtained on Try 4 Prior probability, PP = 3.289393E-07 Bayes score, PP * exp(-Misfit) = 3.211970E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10829.8 1311.06 7.867482E-02 0.230432 0.769568 Final coordinates: 10381.4 1197.27 0.320495 0.497020 0.502980 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.372160E-02 Extraneous predicted phases: 9.690264E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 43.928 0.0089 0.1754 0.0254 0.2084 0.0904 0.0015 0.0003 0.4835 0.0062 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0011 0.0023 0.0009 0.0215 -0.0147 0.0019 0.0001 -0.0047 -0.0062 Composition Misfit: 0.735361E-02 Gt predicted* 56.058 0.0000 0.1405 0.1259 0.1118 0.1931 0.0023 0.0005 0.4202 0.0057 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0049 0.0129 -0.0317 0.0294 -0.0018 -0.0000 0.0020 -0.0057 Composition Misfit: 0.163680E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.001 0.0000 0.0000 0.0000 0.0000 0.6427 0.2621 0.0000 0.0000 0.0952 Fsp 0.013 0.0172 0.0000 0.2328 0.2156 0.0000 0.0000 0.0000 0.5344 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.894 -838149. MgO 156.542 -652016. Al2O3 82.865 -0.168849E+07 CaO 154.513 -766179. FeO 149.556 -346746. TiO2 1.937 -966324. Cr2O3 0.386 -0.125854E+07 SiO2 450.306 -916369. O2 5.991 -419423. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 5 converged, 5 successes so far. Misfit function evaluations this try => 227 Misfit this try = 2.192255E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 2.613288E-07 Bayes score, PP * exp(-Misfit) = 2.556621E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16033.4 1042.67 6.287349E-02 0.917892 8.210769E-02 Final coordinates: 9758.75 1181.60 0.274444 0.404993 0.595007 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.192146E-02 Extraneous predicted phases: 1.094903E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 34.151 0.0094 0.1748 0.0239 0.2065 0.0923 0.0012 0.0003 0.4854 0.0062 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0016 0.0029 0.0024 0.0234 -0.0166 0.0022 0.0001 -0.0066 -0.0062 Composition Misfit: 0.100913E-01 Gt predicted* 65.848 0.0000 0.1402 0.1275 0.1063 0.1975 0.0019 0.0005 0.4210 0.0053 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0046 0.0113 -0.0262 0.0250 -0.0014 -0.0000 0.0012 -0.0053 Composition Misfit: 0.118301E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.001 0.0000 0.0353 0.0303 0.0000 0.7941 0.0089 0.0014 0.0000 0.1300 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.173 -831198. MgO 152.667 -650225. Al2O3 93.213 -0.168679E+07 CaO 140.721 -764794. FeO 163.066 -344096. TiO2 1.669 -967978. Cr2O3 0.394 -0.125520E+07 SiO2 445.097 -916573. O2 5.594 -424276. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 6 converged, 6 successes so far. Misfit function evaluations this try => 460 Misfit this try = 5.710385E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 1.903528E-07 Bayes score, PP * exp(-Misfit) = 1.797875E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8596.30 980.629 0.587327 0.927315 7.268520E-02 Final coordinates: 10513.1 1269.37 0.624353 0.859780 0.140220 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.733625E-02 Extraneous predicted phases: 1.976760E-02 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 96.735 0.0069 0.1714 0.0390 0.2107 0.0920 0.0027 0.0003 0.4696 0.0074 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual 0.0009 0.0063 -0.0127 0.0192 -0.0163 0.0008 -0.0000 0.0092 -0.0074 Composition Misfit: 0.952009E-02 Gt predicted* 3.114 0.0000 0.1521 0.1244 0.1163 0.1782 0.0029 0.0005 0.4196 0.0060 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0165 0.0143 -0.0363 0.0443 -0.0024 -0.0001 0.0026 -0.0060 Composition Misfit: 0.278162E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.092 0.0000 0.0000 0.0000 0.0000 0.6327 0.2788 0.0000 0.0000 0.0885 Sp 0.027 0.0000 0.0517 0.0453 0.0000 0.7590 0.0231 0.0012 0.0000 0.1197 Fsp 0.032 0.0148 0.0000 0.2352 0.2204 0.0000 0.0000 0.0000 0.5296 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 6.736 -846726. MgO 171.815 -656316. Al2O3 42.075 -0.170193E+07 CaO 208.881 -770882. FeO 96.304 -355123. TiO2 2.994 -978024. Cr2O3 0.354 -0.128067E+07 SiO2 470.840 -928165. O2 7.516 -430259. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 7 converged, 7 successes so far. Misfit function evaluations this try => 230 Misfit this try = 3.795939E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 8.294184E-08 Bayes score, PP * exp(-Misfit) = 7.985243E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17220.6 981.803 0.695635 0.906661 9.333873E-02 Final coordinates: 10888.0 1333.37 0.407338 0.636096 0.363904 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.795309E-02 Extraneous predicted phases: 6.296245E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 70.975 0.0071 0.1666 0.0416 0.2017 0.1036 0.0022 0.0003 0.4700 0.0070 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual 0.0008 0.0112 -0.0153 0.0282 -0.0279 0.0012 0.0000 0.0088 -0.0070 Composition Misfit: 0.187855E-01 Gt predicted* 29.024 0.0000 0.1490 0.1261 0.1094 0.1864 0.0027 0.0005 0.4204 0.0055 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0134 0.0127 -0.0294 0.0361 -0.0022 -0.0001 0.0018 -0.0055 Composition Misfit: 0.191676E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.002 0.0000 0.0523 0.0719 0.0000 0.7412 0.0201 0.0011 0.0000 0.1134 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.984 -850568. MgO 162.397 -660862. Al2O3 67.227 -0.171580E+07 CaO 175.357 -775432. FeO 129.140 -360657. TiO2 2.342 -994338. Cr2O3 0.374 -0.130382E+07 SiO2 458.179 -937869. O2 6.575 -452603. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 8 converged, 8 successes so far. Misfit function evaluations this try => 356 Misfit this try = 3.527133E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 8.603212E-08 Bayes score, PP * exp(-Misfit) = 8.305054E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17510.8 1286.60 5.305008E-02 4.887126E-02 0.951129 Final coordinates: 13230.4 1349.86 0.308062 0.474387 0.525613 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.525678E-02 Extraneous predicted phases: 1.455194E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.512 0.0084 0.1698 0.0324 0.1998 0.1021 0.0011 0.0003 0.4801 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0006 0.0079 -0.0061 0.0301 -0.0264 0.0023 0.0001 -0.0013 -0.0061 Composition Misfit: 0.177083E-01 Gt predicted* 55.486 0.0000 0.1429 0.1258 0.1117 0.1908 0.0024 0.0005 0.4202 0.0057 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0073 0.0130 -0.0317 0.0317 -0.0020 -0.0000 0.0019 -0.0057 Composition Misfit: 0.175485E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.003 0.0000 0.0467 0.0736 0.0000 0.7511 0.0106 0.0010 0.0000 0.1170 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.717 -837373. MgO 155.589 -657799. Al2O3 85.410 -0.171565E+07 CaO 151.121 -770936. FeO 152.879 -357349. TiO2 1.871 -0.100055E+07 Cr2O3 0.388 -0.130548E+07 SiO2 449.025 -937523. O2 5.887 -465228. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 9 converged, 9 successes so far. Misfit function evaluations this try => 311 Misfit this try = 2.213907E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 2.492387E-07 Bayes score, PP * exp(-Misfit) = 2.437814E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16208.6 1012.20 0.722271 0.529869 0.470131 Final coordinates: 9608.78 1168.83 0.252177 0.353830 0.646170 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.213881E-02 Extraneous predicted phases: 2.677186E-07 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 28.548 0.0098 0.1752 0.0222 0.2058 0.0923 0.0011 0.0003 0.4873 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0020 0.0025 0.0041 0.0241 -0.0165 0.0023 0.0001 -0.0086 -0.0060 Composition Misfit: 0.123037E-01 Gt predicted* 71.452 0.0000 0.1398 0.1282 0.1037 0.1998 0.0017 0.0004 0.4213 0.0051 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0042 0.0106 -0.0237 0.0227 -0.0012 -0.0000 0.0009 -0.0051 Composition Misfit: 0.983506E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.000 0.0000 0.0338 0.0288 0.0000 0.7977 0.0071 0.0015 0.0000 0.1312 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.772 -829382. MgO 150.513 -649459. Al2O3 98.966 -0.168469E+07 CaO 133.053 -764127. FeO 170.576 -342698. TiO2 1.520 -966964. Cr2O3 0.398 -0.125117E+07 SiO2 442.201 -914934. O2 5.377 -422828. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 10 converged, 10 successes so far. Misfit function evaluations this try => 236 Misfit this try = 0.608075 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 7.941271E-08 Bayes score, PP * exp(-Misfit) = 4.323210E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16844.6 971.925 0.949612 0.167645 0.832355 Final coordinates: 17987.6 1192.77 0.895399 0.999995 4.907029E-06 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.187237 Extraneous predicted phases: 0.420838 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 91.028 0.0086 0.1858 0.0206 0.2284 0.0643 0.0008 0.0003 0.4842 0.0069 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0007 -0.0081 0.0057 0.0015 0.0114 0.0026 0.0000 -0.0055 -0.0069 Composition Misfit: 0.123249E-01 Gt predicted* 8.219 0.0000 0.0895 0.0873 0.2277 0.1679 0.0069 0.0007 0.4007 0.0194 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 0.0461 0.0515 -0.1477 0.0546 -0.0064 -0.0003 0.0215 -0.0194 Composition Misfit: 0.174913 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.300 0.0000 0.0000 0.0000 0.0000 0.6930 0.1783 0.0000 0.0000 0.1287 sph 0.453 0.0000 0.0000 0.0000 0.3333 0.0000 0.3333 0.0000 0.3333 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 7.835 -834042. MgO 177.719 -647000. Al2O3 26.309 -0.167100E+07 CaO 229.895 -752372. FeO 75.721 -344443. TiO2 3.402 -947652. Cr2O3 0.342 -0.122917E+07 SiO2 478.776 -898359. O2 8.475 -369146. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 11 converged, 11 successes so far. Misfit function evaluations this try => 191 Misfit this try = 3.323839E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 1.343775E-07 Bayes score, PP * exp(-Misfit) = 1.299844E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12179.7 1261.41 0.854104 0.851635 0.148365 Final coordinates: 12580.8 1325.58 0.320515 0.498019 0.501981 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.320314E-02 Extraneous predicted phases: 3.524779E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 47.144 0.0084 0.1701 0.0322 0.2017 0.1003 0.0013 0.0003 0.4796 0.0062 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0005 0.0076 -0.0059 0.0282 -0.0246 0.0021 0.0001 -0.0008 -0.0062 Composition Misfit: 0.150472E-01 Gt predicted* 52.851 0.0000 0.1431 0.1256 0.1122 0.1902 0.0025 0.0005 0.4201 0.0057 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0075 0.0131 -0.0322 0.0324 -0.0020 -0.0001 0.0020 -0.0057 Composition Misfit: 0.181559E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0453 0.0632 0.0000 0.7587 0.0127 0.0011 0.0000 0.1190 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.902 -837599. MgO 156.584 -656903. Al2O3 82.753 -0.171146E+07 CaO 154.663 -770272. FeO 149.410 -355799. TiO2 1.940 -994704. Cr2O3 0.386 -0.129816E+07 SiO2 450.363 -934613. O2 5.986 -457949. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 12 converged, 12 successes so far. Misfit function evaluations this try => 622 Misfit this try = 3.789261E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 2.215290E-07 Bayes score, PP * exp(-Misfit) = 2.132917E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16000.6 1241.98 0.791245 0.759601 0.240399 Final coordinates: 15173.4 1266.42 0.308528 0.474513 0.525487 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.788905E-02 Extraneous predicted phases: 3.566627E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 37.780 0.0099 0.1807 0.0190 0.2056 0.0869 0.0008 0.0002 0.4919 0.0050 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0021 -0.0030 0.0073 0.0243 -0.0112 0.0026 0.0001 -0.0131 -0.0050 Composition Misfit: 0.171998E-01 Gt predicted* 62.217 0.0000 0.1392 0.1241 0.1174 0.1906 0.0025 0.0005 0.4193 0.0063 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0036 0.0147 -0.0373 0.0319 -0.0020 -0.0001 0.0028 -0.0063 Composition Misfit: 0.206892E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.003 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.718 -854748. MgO 155.594 -656675. Al2O3 85.396 -0.169394E+07 CaO 151.140 -768530. FeO 152.860 -353545. TiO2 1.872 -971797. Cr2O3 0.388 -0.127280E+07 SiO2 449.032 -912380. O2 5.895 -411891. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 13 converged, 13 successes so far. Misfit function evaluations this try => 248 Misfit this try = 3.427975E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 2.035414E-07 Bayes score, PP * exp(-Misfit) = 1.966823E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9943.38 1277.85 0.574141 0.313015 0.686985 Final coordinates: 12370.6 1298.90 0.247835 0.341576 0.658424 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.424763E-02 Extraneous predicted phases: 3.211882E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 28.228 0.0096 0.1712 0.0267 0.1976 0.1022 0.0007 0.0003 0.4860 0.0057 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0018 0.0066 -0.0003 0.0323 -0.0265 0.0027 0.0001 -0.0073 -0.0057 Composition Misfit: 0.232798E-01 Gt predicted* 71.764 0.0000 0.1408 0.1278 0.1048 0.1980 0.0018 0.0005 0.4212 0.0052 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0052 0.0109 -0.0248 0.0245 -0.0013 -0.0000 0.0010 -0.0052 Composition Misfit: 0.109678E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.008 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.676 -862312. MgO 149.997 -662536. Al2O3 100.344 -0.170683E+07 CaO 131.216 -776173. FeO 172.375 -359734. TiO2 1.485 -988019. Cr2O3 0.399 -0.129052E+07 SiO2 441.508 -923229. O2 5.340 -427346. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 14 converged, 14 successes so far. Misfit function evaluations this try => 727 Misfit this try = 6.042344E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 1.860870E-07 Bayes score, PP * exp(-Misfit) = 1.751759E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12921.8 1132.46 9.407108E-02 0.862363 0.137637 Final coordinates: 10456.6 1269.37 0.647095 0.880171 0.119829 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.796414E-02 Extraneous predicted phases: 2.245931E-02 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 99.777 0.0069 0.1717 0.0394 0.2108 0.0915 0.0028 0.0003 0.4693 0.0073 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual 0.0010 0.0061 -0.0131 0.0191 -0.0158 0.0006 -0.0000 0.0094 -0.0073 Composition Misfit: 0.950978E-02 Gt predicted* 0.069 0.0000 0.1532 0.1248 0.1159 0.1770 0.0029 0.0005 0.4198 0.0059 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0176 0.0140 -0.0359 0.0455 -0.0024 -0.0001 0.0024 -0.0059 Composition Misfit: 0.284544E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.075 0.0000 0.0000 0.0000 0.0000 0.6308 0.2821 0.0000 0.0000 0.0872 Sp 0.072 0.0000 0.0536 0.0467 0.0000 0.7552 0.0247 0.0011 0.0000 0.1186 Fsp 0.006 0.0147 0.0000 0.2353 0.2206 0.0000 0.0000 0.0000 0.5294 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 6.896 -846103. MgO 172.674 -656164. Al2O3 39.782 -0.170197E+07 CaO 211.937 -770793. FeO 93.311 -355057. TiO2 3.053 -978115. Cr2O3 0.353 -0.128073E+07 SiO2 471.994 -928470. O2 7.548 -431373. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 15 converged, 15 successes so far. Misfit function evaluations this try => 287 Misfit this try = 0.102827 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 1.089098E-07 Bayes score, PP * exp(-Misfit) = 9.826738E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17430.8 1202.29 5.243804E-02 0.420720 0.579280 Final coordinates: 17582.3 1108.57 0.185934 0.169975 0.830025 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.102798 Extraneous predicted phases: 2.972841E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 9.054 0.0148 0.1861 0.0067 0.2024 0.0778 0.0003 0.0002 0.5071 0.0046 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0070 -0.0084 0.0196 0.0275 -0.0021 0.0031 0.0001 -0.0283 -0.0046 Composition Misfit: 0.984345E-01 Gt predicted* 90.942 0.0000 0.1378 0.1301 0.0954 0.2083 0.0010 0.0004 0.4223 0.0046 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0022 0.0086 -0.0154 0.0142 -0.0006 -0.0000 -0.0001 -0.0046 Composition Misfit: 0.436319E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0296 0.0188 0.0000 0.8127 0.0008 0.0014 0.0000 0.1368 Effective Bulk* Chemical Potentials (J/mol) Na2O 1.332 -778433. MgO 142.772 -630256. Al2O3 119.639 -0.165754E+07 CaO 105.498 -741798. FeO 197.566 -320479. TiO2 0.985 -956502. Cr2O3 0.414 -0.121281E+07 SiO2 431.795 -895343. O2 4.592 -431034. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 16 converged, 16 successes so far. Misfit function evaluations this try => 249 Misfit this try = 7.498755E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 7.510198E-08 Bayes score, PP * exp(-Misfit) = 6.967624E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15422.5 970.887 0.196856 0.116634 0.883366 Final coordinates: 17432.2 1043.63 0.160995 8.448455E-02 0.915515 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.495964E-02 Extraneous predicted phases: 2.791522E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.457 0.0274 0.1631 0.0093 0.1876 0.0892 0.0006 0.0004 0.5136 0.0088 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0195 0.0146 0.0170 0.0423 -0.0135 0.0028 -0.0000 -0.0349 -0.0088 Composition Misfit: 0.728528E-01 Gt predicted* 97.539 0.0000 0.1380 0.1317 0.0899 0.2122 0.0007 0.0004 0.4230 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0024 0.0071 -0.0099 0.0104 -0.0002 0.0000 -0.0008 -0.0041 Composition Misfit: 0.210685E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0283 0.0135 0.0000 0.8177 0.0003 0.0018 0.0000 0.1384 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.662 -767916. MgO 139.172 -628009. Al2O3 129.252 -0.164336E+07 CaO 92.685 -739561. FeO 210.116 -316076. TiO2 0.736 -941863. Cr2O3 0.422 -0.118922E+07 SiO2 426.956 -884821. O2 4.228 -405305. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 17 converged, 17 successes so far. Misfit function evaluations this try => 433 Misfit this try = 4.476480E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 3.842308E-07 Bayes score, PP * exp(-Misfit) = 3.674101E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9643.40 1220.89 6.138385E-02 0.134924 0.865076 Final coordinates: 10490.4 1154.66 0.177635 0.144522 0.855478 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.416732E-02 Extraneous predicted phases: 5.974772E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 7.959 0.0145 0.1719 0.0162 0.1969 0.0957 0.0004 0.0003 0.4982 0.0059 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0066 0.0058 0.0101 0.0330 -0.0200 0.0030 0.0001 -0.0194 -0.0059 Composition Misfit: 0.407064E-01 Gt predicted* 92.022 0.0000 0.1385 0.1309 0.0932 0.2091 0.0009 0.0004 0.4226 0.0043 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0029 0.0078 -0.0131 0.0134 -0.0005 0.0000 -0.0005 -0.0043 Composition Misfit: 0.346090E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.019 0.0000 0.0297 0.0278 0.0000 0.8055 0.0014 0.0017 0.0000 0.1338 Effective Bulk* Chemical Potentials (J/mol) Na2O 1.132 -814591. MgO 141.700 -646384. Al2O3 122.501 -0.168059E+07 CaO 101.683 -760973. FeO 201.302 -338307. TiO2 0.911 -972761. Cr2O3 0.417 -0.124501E+07 SiO2 430.354 -912079. O2 4.470 -428533. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 18 converged, 18 successes so far. Misfit function evaluations this try => 480 Misfit this try = 3.468858E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 1.027628E-07 Bayes score, PP * exp(-Misfit) = 9.925926E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10671.2 1315.22 0.771516 0.809315 0.190685 Final coordinates: 12738.6 1340.70 0.306684 0.472403 0.527597 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.451739E-02 Extraneous predicted phases: 1.711903E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.679 0.0084 0.1693 0.0328 0.1999 0.1025 0.0012 0.0003 0.4795 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0005 0.0084 -0.0065 0.0300 -0.0268 0.0022 0.0001 -0.0007 -0.0061 Composition Misfit: 0.176172E-01 Gt predicted* 55.311 0.0000 0.1431 0.1261 0.1108 0.1912 0.0024 0.0005 0.4204 0.0056 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0075 0.0127 -0.0308 0.0314 -0.0019 -0.0000 0.0018 -0.0056 Composition Misfit: 0.169002E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.010 0.0000 0.0461 0.0724 0.0000 0.7523 0.0109 0.0011 0.0000 0.1172 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.701 -837889. MgO 155.505 -657761. Al2O3 85.633 -0.171455E+07 CaO 150.824 -771129. FeO 153.170 -357004. TiO2 1.866 -999086. Cr2O3 0.388 -0.130326E+07 SiO2 448.913 -936917. O2 5.872 -463435. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 19 converged, 19 successes so far. Misfit function evaluations this try => 713 Misfit this try = 4.938868E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 2.637904E-08 Bayes score, PP * exp(-Misfit) = 2.510786E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15364.9 1236.82 0.931673 0.498572 0.501428 Final coordinates: 17999.9 1303.86 0.346821 0.540819 0.459181 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.922563E-02 Extraneous predicted phases: 1.630478E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 42.788 0.0100 0.1837 0.0175 0.2065 0.0832 0.0007 0.0002 0.4934 0.0048 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0021 -0.0060 0.0088 0.0234 -0.0075 0.0027 0.0001 -0.0146 -0.0048 Composition Misfit: 0.203024E-01 Gt predicted* 57.195 0.0000 0.1381 0.1214 0.1261 0.1856 0.0031 0.0005 0.4180 0.0072 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0025 0.0173 -0.0461 0.0370 -0.0026 -0.0001 0.0041 -0.0072 Composition Misfit: 0.289232E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.018 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.237 -860521. MgO 158.386 -658011. Al2O3 77.940 -0.169637E+07 CaO 161.077 -768497. FeO 143.127 -356468. TiO2 2.065 -972049. Cr2O3 0.382 -0.127728E+07 SiO2 452.786 -910843. O2 6.205 -407918. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 20 converged, 20 successes so far. Misfit function evaluations this try => 554 Misfit this try = 7.394193E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 3.163746E-07 Bayes score, PP * exp(-Misfit) = 2.938252E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 11962.3 1050.10 0.650697 7.184188E-02 0.928158 Final coordinates: 14492.2 1047.91 0.160864 8.334779E-02 0.916652 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.394181E-02 Extraneous predicted phases: 1.207920E-07 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.376 0.0280 0.1593 0.0100 0.1856 0.0938 0.0006 0.0004 0.5131 0.0092 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0201 0.0184 0.0163 0.0443 -0.0181 0.0028 -0.0000 -0.0343 -0.0092 Composition Misfit: 0.718439E-01 Gt predicted* 97.623 0.0000 0.1380 0.1317 0.0899 0.2122 0.0007 0.0004 0.4230 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0024 0.0071 -0.0099 0.0104 -0.0002 0.0000 -0.0008 -0.0041 Composition Misfit: 0.209795E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.653 -793662. MgO 139.124 -636456. Al2O3 129.380 -0.164997E+07 CaO 92.515 -749242. FeO 210.283 -324826. TiO2 0.733 -942027. Cr2O3 0.422 -0.119769E+07 SiO2 426.891 -886594. O2 4.228 -388365. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 21 converged, 21 successes so far. Misfit function evaluations this try => 226 Misfit this try = 3.208648E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 1.830591E-07 Bayes score, PP * exp(-Misfit) = 1.772786E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13531.5 1172.58 0.596096 0.517855 0.482145 Final coordinates: 12858.7 1307.78 0.326207 0.507971 0.492029 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.208648E-02 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 46.661 0.0086 0.1723 0.0295 0.2034 0.0970 0.0012 0.0003 0.4816 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0008 0.0054 -0.0032 0.0265 -0.0213 0.0022 0.0001 -0.0028 -0.0061 Composition Misfit: 0.126072E-01 Gt predicted* 53.339 0.0000 0.1422 0.1250 0.1143 0.1896 0.0026 0.0005 0.4198 0.0059 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0066 0.0137 -0.0342 0.0329 -0.0021 -0.0001 0.0023 -0.0059 Composition Misfit: 0.194793E-01 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.980 -866464. MgO 157.003 -663019. Al2O3 81.634 -0.170710E+07 CaO 156.154 -776196. FeO 147.949 -361393. TiO2 1.969 -981800. Cr2O3 0.385 -0.129153E+07 SiO2 450.926 -923290. O2 6.033 -421383. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 22 converged, 22 successes so far. Misfit function evaluations this try => 595 Misfit this try = 2.754866E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 1.888792E-07 Bayes score, PP * exp(-Misfit) = 1.837469E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9365.52 1209.79 0.697280 0.185491 0.814509 Final coordinates: 9482.31 1217.10 0.215843 0.259741 0.740259 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.753725E-02 Extraneous predicted phases: 1.140133E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 20.203 0.0102 0.1696 0.0256 0.1991 0.1019 0.0008 0.0003 0.4863 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0024 0.0081 0.0007 0.0308 -0.0262 0.0026 0.0001 -0.0076 -0.0061 Composition Misfit: 0.209816E-01 Gt predicted* 79.794 0.0000 0.1400 0.1296 0.0985 0.2035 0.0013 0.0004 0.4220 0.0047 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0044 0.0092 -0.0184 0.0190 -0.0009 -0.0000 0.0002 -0.0047 Composition Misfit: 0.655568E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.003 0.0000 0.0334 0.0409 0.0000 0.7909 0.0042 0.0016 0.0000 0.1289 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.035 -830596. MgO 146.551 -652792. Al2O3 109.545 -0.169516E+07 CaO 118.951 -767697. FeO 184.388 -347082. TiO2 1.246 -983008. Cr2O3 0.407 -0.126861E+07 SiO2 436.876 -923095. O2 4.975 -440116. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 23 converged, 23 successes so far. Misfit function evaluations this try => 579 Misfit this try = 4.578434E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 1.345098E-08 Bayes score, PP * exp(-Misfit) = 1.284902E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15241.0 1328.11 0.911781 5.382711E-02 0.946173 Final coordinates: 17980.0 1343.55 0.344984 0.539497 0.460503 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.575520E-02 Extraneous predicted phases: 2.914388E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.193 0.0096 0.1809 0.0207 0.2049 0.0872 0.0007 0.0002 0.4908 0.0050 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0018 -0.0032 0.0056 0.0250 -0.0115 0.0027 0.0001 -0.0120 -0.0050 Composition Misfit: 0.173561E-01 Gt predicted* 55.800 0.0000 0.1391 0.1217 0.1250 0.1853 0.0031 0.0005 0.4182 0.0070 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0035 0.0170 -0.0450 0.0372 -0.0026 -0.0001 0.0040 -0.0070 Composition Misfit: 0.283991E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.007 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.227 -868599. MgO 158.330 -662219. Al2O3 78.089 -0.170510E+07 CaO 160.879 -772737. FeO 143.321 -361927. TiO2 2.061 -980581. Cr2O3 0.382 -0.128944E+07 SiO2 452.711 -916280. O2 6.180 -413793. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 24 converged, 24 successes so far. Misfit function evaluations this try => 583 Misfit this try = 4.954358E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 2.757470E-07 Bayes score, PP * exp(-Misfit) = 2.624184E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15035.5 1045.82 0.171670 6.683991E-02 0.933160 Final coordinates: 10123.7 1209.13 0.169790 0.116568 0.883432 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.938769E-02 Extraneous predicted phases: 1.558854E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 5.794 0.0161 0.1625 0.0217 0.1894 0.1069 0.0004 0.0003 0.4960 0.0067 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0083 0.0152 0.0047 0.0405 -0.0312 0.0030 0.0000 -0.0172 -0.0067 Composition Misfit: 0.465834E-01 Gt predicted* 94.196 0.0000 0.1386 0.1313 0.0916 0.2103 0.0009 0.0004 0.4228 0.0042 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0030 0.0074 -0.0115 0.0122 -0.0004 0.0000 -0.0007 -0.0042 Composition Misfit: 0.280426E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.010 0.0000 0.0304 0.0393 0.0000 0.7972 0.0009 0.0015 0.0000 0.1309 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.913 -818473. MgO 140.523 -651301. Al2O3 125.644 -0.169222E+07 CaO 97.494 -766221. FeO 205.406 -344732. TiO2 0.829 -988579. Cr2O3 0.419 -0.126545E+07 SiO2 428.772 -920866. O2 4.359 -441003. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 25 converged, 25 successes so far. Misfit function evaluations this try => 247 Misfit this try = 3.513223E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 1.757924E-07 Bayes score, PP * exp(-Misfit) = 1.697237E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9571.92 1246.93 0.571646 0.877287 0.122713 Final coordinates: 10508.0 1275.70 0.512844 0.760735 0.239265 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.512792E-02 Extraneous predicted phases: 4.307246E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 83.525 0.0071 0.1701 0.0382 0.2085 0.0952 0.0026 0.0003 0.4706 0.0073 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual 0.0007 0.0076 -0.0119 0.0214 -0.0195 0.0008 0.0000 0.0082 -0.0073 Composition Misfit: 0.107052E-01 Gt predicted* 16.474 0.0000 0.1487 0.1243 0.1153 0.1827 0.0030 0.0005 0.4195 0.0060 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0131 0.0145 -0.0352 0.0398 -0.0025 -0.0001 0.0027 -0.0060 Composition Misfit: 0.244227E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.001 0.0000 0.0500 0.0446 0.0000 0.7602 0.0251 0.0010 0.0000 0.1191 Effective Bulk* Chemical Potentials (J/mol) Na2O 5.960 -847721. MgO 167.645 -657135. Al2O3 53.212 -0.170373E+07 CaO 194.037 -771625. FeO 110.844 -355586. TiO2 2.705 -979312. Cr2O3 0.363 -0.128339E+07 SiO2 465.233 -928957. O2 7.106 -433132. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 26 converged, 26 successes so far. Misfit function evaluations this try => 316 Misfit this try = 4.125518E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 4.395787E-08 Bayes score, PP * exp(-Misfit) = 4.218128E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16872.6 1310.13 0.434370 0.314278 0.685722 Final coordinates: 16609.8 1330.58 0.358402 0.561261 0.438739 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.120241E-02 Extraneous predicted phases: 5.276714E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 47.746 0.0093 0.1790 0.0230 0.2060 0.0884 0.0009 0.0002 0.4879 0.0054 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0014 -0.0012 0.0033 0.0239 -0.0127 0.0025 0.0001 -0.0091 -0.0054 Composition Misfit: 0.124805E-01 Gt predicted* 52.244 0.0000 0.1398 0.1217 0.1249 0.1847 0.0032 0.0005 0.4182 0.0070 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0042 0.0170 -0.0449 0.0378 -0.0027 -0.0001 0.0040 -0.0070 Composition Misfit: 0.287220E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.010 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.398 -867684. MgO 159.247 -662087. Al2O3 75.642 -0.170468E+07 CaO 164.141 -773202. FeO 140.126 -361592. TiO2 2.124 -978484. Cr2O3 0.380 -0.128977E+07 SiO2 453.943 -917679. O2 6.278 -413223. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 27 converged, 27 successes so far. Misfit function evaluations this try => 229 Misfit this try = 2.304043E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 3.310321E-07 Bayes score, PP * exp(-Misfit) = 3.234922E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9347.55 981.581 0.775628 0.774138 0.225862 Final coordinates: 10216.2 1176.07 0.276659 0.410018 0.589982 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.302828E-02 Extraneous predicted phases: 1.214685E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 33.867 0.0096 0.1766 0.0222 0.2071 0.0901 0.0012 0.0003 0.4871 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0017 0.0011 0.0041 0.0228 -0.0144 0.0022 0.0001 -0.0083 -0.0060 Composition Misfit: 0.104443E-01 Gt predicted* 66.130 0.0000 0.1397 0.1271 0.1075 0.1971 0.0019 0.0005 0.4208 0.0054 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0041 0.0116 -0.0275 0.0255 -0.0014 -0.0000 0.0014 -0.0054 Composition Misfit: 0.125839E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.003 0.0000 0.0354 0.0289 0.0000 0.7950 0.0088 0.0014 0.0000 0.1304 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.213 -828577. MgO 152.879 -649010. Al2O3 92.648 -0.168480E+07 CaO 141.474 -763346. FeO 162.328 -342719. TiO2 1.684 -966339. Cr2O3 0.394 -0.125161E+07 SiO2 445.382 -915055. O2 5.614 -423449. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 28 converged, 28 successes so far. Misfit function evaluations this try => 528 Misfit this try = 0.607153 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 7.823888E-08 Bayes score, PP * exp(-Misfit) = 4.263236E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 11259.5 994.774 0.901179 0.865955 0.134045 Final coordinates: 17999.0 1194.09 0.897921 1.00000 1.681047E-07 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.187252 Extraneous predicted phases: 0.419902 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 91.056 0.0086 0.1857 0.0207 0.2283 0.0645 0.0008 0.0003 0.4841 0.0070 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0007 -0.0080 0.0056 0.0016 0.0112 0.0026 0.0000 -0.0053 -0.0070 Composition Misfit: 0.126408E-01 Gt predicted* 8.187 0.0000 0.0897 0.0869 0.2275 0.1683 0.0068 0.0007 0.4005 0.0195 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 0.0459 0.0518 -0.1475 0.0542 -0.0063 -0.0003 0.0217 -0.0195 Composition Misfit: 0.174611 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.274 0.0000 0.0000 0.0000 0.0000 0.6949 0.1751 0.0000 0.0000 0.1299 sph 0.484 0.0000 0.0000 0.0000 0.3333 0.0000 0.3333 0.0000 0.3333 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 7.835 -835680. MgO 177.719 -647416. Al2O3 26.308 -0.167133E+07 CaO 229.896 -752793. FeO 75.720 -344894. TiO2 3.402 -947815. Cr2O3 0.342 -0.122971E+07 SiO2 478.777 -898202. O2 8.499 -367674. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 29 converged, 29 successes so far. Misfit function evaluations this try => 390 Misfit this try = 1.17167 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 7.779156E-08 Bayes score, PP * exp(-Misfit) = 2.410365E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15374.7 1007.18 0.940542 0.194685 0.805315 Final coordinates: 17998.8 1195.41 0.999988 1.00000 1.015729E-07 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.205348 Extraneous predicted phases: 0.966321 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 91.653 0.0085 0.1857 0.0221 0.2293 0.0640 0.0007 0.0003 0.4819 0.0076 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0006 -0.0079 0.0042 0.0006 0.0117 0.0027 0.0000 -0.0031 -0.0076 Composition Misfit: 0.149138E-01 Gt predicted* 6.868 0.0000 0.0879 0.0832 0.2347 0.1671 0.0067 0.0007 0.3986 0.0211 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 0.0477 0.0555 -0.1547 0.0554 -0.0062 -0.0002 0.0236 -0.0211 Composition Misfit: 0.190434 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.513 0.0000 0.0000 0.0000 0.0000 0.7134 0.1443 0.0000 0.0000 0.1423 sph 0.441 0.0000 0.0000 0.0000 0.3333 0.0000 0.3333 0.0000 0.3333 0.0000 q 0.525 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 7.835 -843237. MgO 177.719 -649281. Al2O3 26.308 -0.167145E+07 CaO 229.896 -754593. FeO 75.720 -347669. TiO2 3.402 -948056. Cr2O3 0.342 -0.122995E+07 SiO2 478.777 -896651. O2 9.465 -354262. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 30 converged, 30 successes so far. Misfit function evaluations this try => 300 Misfit this try = 4.481481E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 1.833318E-07 Bayes score, PP * exp(-Misfit) = 1.752972E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17269.0 1067.16 0.946215 0.397569 0.602431 Final coordinates: 16123.1 1246.39 0.319464 0.496277 0.503723 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.473470E-02 Extraneous predicted phases: 8.010699E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 38.485 0.0102 0.1845 0.0161 0.2071 0.0821 0.0007 0.0002 0.4944 0.0048 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0023 -0.0068 0.0102 0.0228 -0.0064 0.0027 0.0001 -0.0156 -0.0048 Composition Misfit: 0.215783E-01 Gt predicted* 61.508 0.0000 0.1378 0.1232 0.1206 0.1896 0.0027 0.0005 0.4189 0.0066 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0022 0.0155 -0.0406 0.0329 -0.0022 -0.0001 0.0033 -0.0066 Composition Misfit: 0.231564E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.007 0.0000 0.0389 0.0338 0.0000 0.7885 0.0085 0.0010 0.0000 0.1293 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.888 -810306. MgO 156.510 -643920. Al2O3 82.949 -0.168786E+07 CaO 154.402 -755343. FeO 149.665 -340175. TiO2 1.935 -974970. Cr2O3 0.386 -0.126081E+07 SiO2 450.264 -917381. O2 5.977 -445972. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 31 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 32 converged, 31 successes so far. Misfit function evaluations this try => 727 Misfit this try = 7.659173E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 8.463518E-08 Bayes score, PP * exp(-Misfit) = 7.839485E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15215.5 1079.34 0.870461 5.248437E-02 0.947516 Final coordinates: 17347.5 1049.42 0.160726 8.267013E-02 0.917330 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.659107E-02 Extraneous predicted phases: 6.601462E-07 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.301 0.0286 0.1603 0.0098 0.1855 0.0914 0.0006 0.0004 0.5142 0.0092 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0208 0.0174 0.0165 0.0444 -0.0157 0.0028 -0.0001 -0.0355 -0.0092 Composition Misfit: 0.745075E-01 Gt predicted* 97.698 0.0000 0.1380 0.1317 0.0899 0.2122 0.0007 0.0004 0.4230 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0024 0.0071 -0.0098 0.0103 -0.0002 0.0000 -0.0008 -0.0041 Composition Misfit: 0.208356E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.648 -789797. MgO 139.096 -634064. Al2O3 129.456 -0.164449E+07 CaO 92.413 -745651. FeO 210.382 -322289. TiO2 0.731 -938388. Cr2O3 0.422 -0.119082E+07 SiO2 426.853 -880313. O2 4.227 -384590. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 33 converged, 32 successes so far. Misfit function evaluations this try => 296 Misfit this try = 4.507539E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 1.386958E-08 Bayes score, PP * exp(-Misfit) = 1.325828E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17291.8 1296.71 6.442385E-02 0.312629 0.687371 Final coordinates: 17816.2 1348.54 0.353250 0.554307 0.445693 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.507405E-02 Extraneous predicted phases: 1.333135E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 46.184 0.0095 0.1802 0.0217 0.2052 0.0878 0.0008 0.0002 0.4896 0.0051 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0016 -0.0025 0.0046 0.0247 -0.0120 0.0026 0.0001 -0.0109 -0.0051 Composition Misfit: 0.155015E-01 Gt predicted* 53.815 0.0000 0.1393 0.1215 0.1259 0.1843 0.0032 0.0005 0.4181 0.0071 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0037 0.0173 -0.0459 0.0382 -0.0027 -0.0001 0.0041 -0.0071 Composition Misfit: 0.295725E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.343 -870396. MgO 158.954 -662885. Al2O3 76.423 -0.170642E+07 CaO 163.099 -773458. FeO 141.147 -362923. TiO2 2.104 -980658. Cr2O3 0.381 -0.129245E+07 SiO2 453.549 -917342. O2 6.233 -413718. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 34 converged, 33 successes so far. Misfit function evaluations this try => 224 Misfit this try = 3.531218E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 1.738765E-07 Bayes score, PP * exp(-Misfit) = 1.678437E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8854.86 996.947 0.527823 0.801516 0.198484 Final coordinates: 10477.2 1275.59 0.519160 0.767269 0.232731 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.527322E-02 Extraneous predicted phases: 3.896142E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 84.520 0.0071 0.1701 0.0384 0.2085 0.0951 0.0026 0.0003 0.4705 0.0073 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual 0.0007 0.0076 -0.0121 0.0214 -0.0194 0.0008 0.0000 0.0083 -0.0073 Composition Misfit: 0.107575E-01 Gt predicted* 15.474 0.0000 0.1490 0.1243 0.1152 0.1825 0.0030 0.0005 0.4195 0.0060 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0134 0.0145 -0.0351 0.0400 -0.0025 -0.0001 0.0027 -0.0060 Composition Misfit: 0.245157E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.002 0.0000 0.0000 0.0000 0.0000 0.6295 0.2842 0.0000 0.0000 0.0863 Sp 0.004 0.0000 0.0506 0.0451 0.0000 0.7589 0.0258 0.0010 0.0000 0.1187 Effective Bulk* Chemical Potentials (J/mol) Na2O 6.012 -847848. MgO 167.920 -657164. Al2O3 52.477 -0.170374E+07 CaO 195.016 -771699. FeO 109.884 -355652. TiO2 2.724 -979213. Cr2O3 0.363 -0.128354E+07 SiO2 465.603 -928985. O2 7.131 -432955. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 35 converged, 34 successes so far. Misfit function evaluations this try => 604 Misfit this try = 0.120001 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 1.587472E-08 Bayes score, PP * exp(-Misfit) = 1.407959E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8702.25 971.303 0.862009 6.621580E-02 0.933784 Final coordinates: 17712.7 954.314 0.154471 7.286281E-02 0.927137 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 8.112582E-02 Extraneous predicted phases: 3.887549E-02 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.251 0.0257 0.1716 0.0075 0.1945 0.0787 0.0007 0.0004 0.5123 0.0086 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0178 0.0062 0.0188 0.0354 -0.0029 0.0027 -0.0001 -0.0336 -0.0086 Composition Misfit: 0.795589E-01 Gt predicted* 97.535 0.0000 0.1377 0.1332 0.0885 0.2124 0.0005 0.0004 0.4238 0.0036 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0021 0.0056 -0.0084 0.0101 -0.0001 0.0000 -0.0016 -0.0036 Composition Misfit: 0.156689E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.114 0.0000 0.0000 0.0000 0.0000 0.7359 0.1069 0.0000 0.0000 0.1573 Sp 0.100 0.0000 0.0282 0.0087 0.0000 0.8205 0.0002 0.0030 0.0000 0.1394 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.571 -758932. MgO 138.683 -621367. Al2O3 130.558 -0.162570E+07 CaO 90.943 -732353. FeO 211.822 -306798. TiO2 0.702 -923931. Cr2O3 0.423 -0.115766E+07 SiO2 426.298 -872458. O2 4.090 -387960. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 36 converged, 35 successes so far. Misfit function evaluations this try => 246 Misfit this try = 3.545843E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 8.595525E-08 Bayes score, PP * exp(-Misfit) = 8.296081E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15885.2 1174.15 0.838982 0.816258 0.183742 Final coordinates: 13202.0 1349.95 0.320672 0.497703 0.502297 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.544729E-02 Extraneous predicted phases: 1.114410E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 47.419 0.0083 0.1698 0.0330 0.2005 0.1016 0.0012 0.0003 0.4792 0.0062 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0005 0.0079 -0.0067 0.0294 -0.0258 0.0022 0.0001 -0.0004 -0.0062 Composition Misfit: 0.167448E-01 Gt predicted* 52.576 0.0000 0.1433 0.1254 0.1127 0.1897 0.0026 0.0005 0.4201 0.0058 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0076 0.0133 -0.0327 0.0328 -0.0021 -0.0001 0.0021 -0.0058 Composition Misfit: 0.187024E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Fsp 0.004 0.0211 0.0000 0.2289 0.2078 0.0000 0.0000 0.0000 0.5422 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.900 -874489. MgO 156.570 -666985. Al2O3 82.788 -0.171562E+07 CaO 154.615 -780114. FeO 149.456 -366675. TiO2 1.939 -990447. Cr2O3 0.386 -0.130564E+07 SiO2 450.345 -928447. O2 5.991 -427727. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 37 converged, 36 successes so far. Misfit function evaluations this try => 287 Misfit this try = 4.592860E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 1.227031E-08 Bayes score, PP * exp(-Misfit) = 1.171950E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14658.2 1069.36 0.158572 0.855513 0.144487 Final coordinates: 17997.7 1347.52 0.362553 0.568842 0.431158 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.591725E-02 Extraneous predicted phases: 1.135653E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 47.445 0.0094 0.1806 0.0215 0.2058 0.0868 0.0008 0.0002 0.4897 0.0051 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0016 -0.0029 0.0048 0.0241 -0.0111 0.0026 0.0001 -0.0109 -0.0051 Composition Misfit: 0.147243E-01 Gt predicted* 52.550 0.0000 0.1391 0.1209 0.1275 0.1835 0.0033 0.0005 0.4178 0.0072 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0035 0.0178 -0.0475 0.0390 -0.0028 -0.0001 0.0043 -0.0072 Composition Misfit: 0.311930E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.005 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.457 -870164. MgO 159.566 -662618. Al2O3 74.789 -0.170577E+07 CaO 165.277 -773068. FeO 139.013 -362738. TiO2 2.147 -979576. Cr2O3 0.380 -0.129209E+07 SiO2 454.372 -916784. O2 6.300 -412192. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 38 converged, 37 successes so far. Misfit function evaluations this try => 573 Misfit this try = 4.634458E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 2.773955E-08 Bayes score, PP * exp(-Misfit) = 2.648331E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17388.6 1309.92 0.761413 0.674317 0.325683 Final coordinates: 17683.6 1316.04 0.356051 0.558475 0.441525 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.633612E-02 Extraneous predicted phases: 8.463436E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 45.473 0.0097 0.1824 0.0195 0.2068 0.0844 0.0007 0.0002 0.4913 0.0050 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0018 -0.0047 0.0068 0.0231 -0.0086 0.0027 0.0001 -0.0126 -0.0050 Composition Misfit: 0.164848E-01 Gt predicted* 54.523 0.0000 0.1384 0.1212 0.1267 0.1848 0.0032 0.0005 0.4180 0.0072 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0027 0.0175 -0.0467 0.0377 -0.0027 -0.0001 0.0042 -0.0072 Composition Misfit: 0.298513E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.004 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.376 -863477. MgO 159.129 -659554. Al2O3 75.955 -0.169954E+07 CaO 163.723 -770204. FeO 140.535 -358542. TiO2 2.116 -974598. Cr2O3 0.381 -0.128175E+07 SiO2 453.785 -913219. O2 6.255 -409230. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 39 converged, 38 successes so far. Misfit function evaluations this try => 251 Misfit this try = 8.685832E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 1.179782E-07 Bayes score, PP * exp(-Misfit) = 1.081632E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17195.5 1086.00 0.564318 8.186689E-02 0.918133 Final coordinates: 17527.4 1180.30 0.164147 8.814603E-02 0.911854 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 8.648332E-02 Extraneous predicted phases: 3.750044E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.645 0.0266 0.1583 0.0126 0.1810 0.0993 0.0003 0.0003 0.5140 0.0077 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0188 0.0194 0.0138 0.0489 -0.0236 0.0031 0.0000 -0.0352 -0.0077 Composition Misfit: 0.841503E-01 Gt predicted* 97.326 0.0000 0.1382 0.1314 0.0905 0.2116 0.0008 0.0004 0.4229 0.0042 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0026 0.0074 -0.0105 0.0109 -0.0003 0.0000 -0.0007 -0.0042 Composition Misfit: 0.233297E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.028 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.691 -814064. MgO 139.326 -646449. Al2O3 128.840 -0.167083E+07 CaO 93.234 -758280. FeO 209.578 -338493. TiO2 0.747 -967740. Cr2O3 0.421 -0.123690E+07 SiO2 427.163 -895810. O2 4.300 -404788. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 40 converged, 39 successes so far. Misfit function evaluations this try => 629 Misfit this try = 7.568343E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 3.731468E-08 Bayes score, PP * exp(-Misfit) = 3.459480E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10656.0 994.536 0.878870 0.145919 0.854081 Final coordinates: 17840.3 1011.26 0.160213 8.163737E-02 0.918363 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.565435E-02 Extraneous predicted phases: 2.907888E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.236 0.0291 0.1620 0.0090 0.1866 0.0884 0.0008 0.0004 0.5142 0.0096 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0212 0.0157 0.0173 0.0433 -0.0127 0.0026 -0.0001 -0.0354 -0.0096 Composition Misfit: 0.736194E-01 Gt predicted* 97.760 0.0000 0.1379 0.1317 0.0898 0.2123 0.0007 0.0004 0.4230 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0023 0.0070 -0.0097 0.0102 -0.0002 0.0000 -0.0009 -0.0041 Composition Misfit: 0.203491E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0285 0.0112 0.0000 0.8189 0.0003 0.0022 0.0000 0.1389 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.640 -764968. MgO 139.052 -625649. Al2O3 129.572 -0.163604E+07 CaO 92.258 -736973. FeO 210.534 -312812. TiO2 0.728 -933597. Cr2O3 0.422 -0.117601E+07 SiO2 426.794 -879232. O2 4.216 -395202. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 41 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 42 converged, 40 successes so far. Misfit function evaluations this try => 151 Misfit this try = 3.351201E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 1.912642E-07 Bayes score, PP * exp(-Misfit) = 1.849608E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17121.5 1137.15 0.275834 0.295112 0.704888 Final coordinates: 13232.4 1304.80 0.361303 0.565744 0.434256 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.344691E-02 Extraneous predicted phases: 6.509357E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 52.618 0.0085 0.1736 0.0294 0.2057 0.0939 0.0014 0.0003 0.4811 0.0062 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0007 0.0041 -0.0031 0.0242 -0.0182 0.0020 0.0001 -0.0023 -0.0062 Composition Misfit: 0.985692E-02 Gt predicted* 47.371 0.0000 0.1421 0.1236 0.1186 0.1868 0.0029 0.0005 0.4191 0.0064 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0065 0.0152 -0.0386 0.0357 -0.0024 -0.0001 0.0030 -0.0064 Composition Misfit: 0.235900E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.011 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.433 -866249. MgO 159.435 -662373. Al2O3 75.137 -0.170549E+07 CaO 164.813 -775267. FeO 139.468 -360987. TiO2 2.138 -978448. Cr2O3 0.380 -0.128877E+07 SiO2 454.196 -922019. O2 6.299 -417459. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 43 converged, 41 successes so far. Misfit function evaluations this try => 569 Misfit this try = 8.879777E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 2.561943E-07 Bayes score, PP * exp(-Misfit) = 2.344256E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13056.7 1216.89 0.588713 9.767239E-02 0.902328 Final coordinates: 15439.3 1243.19 0.168486 0.101564 0.898436 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 8.817276E-02 Extraneous predicted phases: 6.250056E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 3.791 0.0214 0.1623 0.0147 0.1821 0.1043 0.0002 0.0003 0.5084 0.0064 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0135 0.0154 0.0116 0.0478 -0.0285 0.0032 0.0001 -0.0296 -0.0064 Composition Misfit: 0.854481E-01 Gt predicted* 96.172 0.0000 0.1384 0.1311 0.0915 0.2107 0.0008 0.0004 0.4227 0.0043 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0028 0.0076 -0.0115 0.0118 -0.0003 0.0000 -0.0006 -0.0043 Composition Misfit: 0.272469E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.037 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.796 -832227. MgO 139.891 -654417. Al2O3 127.331 -0.168887E+07 CaO 95.245 -767237. FeO 207.608 -348492. TiO2 0.786 -985063. Cr2O3 0.420 -0.126489E+07 SiO2 427.922 -908697. O2 4.372 -419024. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 44 converged, 42 successes so far. Misfit function evaluations this try => 610 Misfit this try = 0.293429 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 8.876476E-08 Bayes score, PP * exp(-Misfit) = 6.619205E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9490.14 989.602 0.191001 0.825769 0.174231 Final coordinates: 9896.98 1304.91 0.551927 0.836478 0.163522 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.801228E-02 Extraneous predicted phases: 0.255417 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 99.451 0.0065 0.1701 0.0435 0.2052 0.0961 0.0028 0.0003 0.4691 0.0064 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual 0.0013 0.0077 -0.0172 0.0247 -0.0204 0.0006 -0.0000 0.0097 -0.0064 Composition Misfit: 0.150146E-01 Gt predicted* 0.007 0.0000 0.1564 0.1290 0.1073 0.1782 0.0024 0.0005 0.4219 0.0044 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0208 0.0098 -0.0273 0.0443 -0.0019 -0.0000 0.0003 -0.0044 Composition Misfit: 0.229977E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.285 0.0000 0.0828 0.1377 0.0000 0.6592 0.0275 0.0015 0.0000 0.0913 Sp 0.257 0.0000 0.1293 0.2634 0.0000 0.5306 0.0138 0.0019 0.0000 0.0612 Effective Bulk* Chemical Potentials (J/mol) Na2O 6.554 -842005. MgO 170.834 -657624. Al2O3 44.695 -0.171079E+07 CaO 205.388 -772605. FeO 99.725 -357214. TiO2 2.926 -990585. Cr2O3 0.357 -0.129642E+07 SiO2 469.521 -937303. O2 6.880 -458977. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 45 converged, 43 successes so far. Misfit function evaluations this try => 307 Misfit this try = 3.538621E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 8.664159E-08 Bayes score, PP * exp(-Misfit) = 8.362928E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16902.5 1246.44 0.114132 0.335126 0.664874 Final coordinates: 13060.9 1349.70 0.314947 0.487672 0.512328 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.534859E-02 Extraneous predicted phases: 3.762397E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 46.477 0.0083 0.1694 0.0332 0.2001 0.1022 0.0012 0.0003 0.4791 0.0062 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0005 0.0083 -0.0069 0.0298 -0.0265 0.0022 0.0001 -0.0004 -0.0062 Composition Misfit: 0.173808E-01 Gt predicted* 53.519 0.0000 0.1433 0.1257 0.1119 0.1902 0.0025 0.0005 0.4202 0.0057 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0077 0.0130 -0.0319 0.0323 -0.0020 -0.0000 0.0020 -0.0057 Composition Misfit: 0.179678E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.005 0.0000 0.0474 0.0742 0.0000 0.7494 0.0117 0.0010 0.0000 0.1164 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.821 -838451. MgO 156.148 -658110. Al2O3 83.916 -0.171586E+07 CaO 153.112 -771337. FeO 150.929 -357740. TiO2 1.910 -999957. Cr2O3 0.387 -0.130582E+07 SiO2 449.777 -937715. O2 5.942 -464419. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 46 converged, 44 successes so far. Misfit function evaluations this try => 302 Misfit this try = 2.202136E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 2.532275E-07 Bayes score, PP * exp(-Misfit) = 2.477121E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 11778.0 1291.85 0.356277 0.720164 0.279836 Final coordinates: 9608.61 1155.93 0.256172 0.364691 0.635309 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.171280E-02 Extraneous predicted phases: 3.085609E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 29.330 0.0099 0.1764 0.0213 0.2069 0.0902 0.0011 0.0003 0.4880 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0020 0.0013 0.0050 0.0230 -0.0145 0.0023 0.0001 -0.0092 -0.0060 Composition Misfit: 0.114722E-01 Gt predicted* 70.657 0.0000 0.1395 0.1280 0.1044 0.1995 0.0017 0.0004 0.4213 0.0051 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0039 0.0107 -0.0244 0.0230 -0.0012 -0.0000 0.0009 -0.0051 Composition Misfit: 0.102406E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.013 0.0000 0.0339 0.0271 0.0000 0.7986 0.0075 0.0015 0.0000 0.1315 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.857 -827966. MgO 150.970 -648440. Al2O3 97.744 -0.168202E+07 CaO 134.680 -763058. FeO 168.982 -341315. TiO2 1.552 -963739. Cr2O3 0.397 -0.124671E+07 SiO2 442.816 -913052. O2 5.411 -420008. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 47 converged, 45 successes so far. Misfit function evaluations this try => 325 Misfit this try = 4.358178E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 2.234769E-08 Bayes score, PP * exp(-Misfit) = 2.139465E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16330.4 1007.58 0.827543 0.568228 0.431772 Final coordinates: 17357.8 1341.32 0.352072 0.552900 0.447100 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.356660E-02 Extraneous predicted phases: 1.518406E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 46.306 0.0094 0.1797 0.0220 0.2053 0.0881 0.0008 0.0002 0.4892 0.0052 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0016 -0.0020 0.0043 0.0246 -0.0124 0.0026 0.0001 -0.0104 -0.0052 Composition Misfit: 0.145852E-01 Gt predicted* 53.691 0.0000 0.1395 0.1217 0.1253 0.1846 0.0032 0.0005 0.4182 0.0070 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0039 0.0170 -0.0453 0.0379 -0.0027 -0.0001 0.0040 -0.0070 Composition Misfit: 0.289814E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.003 0.0000 0.0449 0.0530 0.0000 0.7673 0.0111 0.0010 0.0000 0.1227 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.332 -817976. MgO 158.894 -649712. Al2O3 76.582 -0.170575E+07 CaO 162.888 -760541. FeO 141.353 -349467. TiO2 2.100 -992861. Cr2O3 0.381 -0.129057E+07 SiO2 453.469 -930221. O2 6.221 -465475. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 48 converged, 46 successes so far. Misfit function evaluations this try => 501 Misfit this try = 2.276408E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 3.067502E-07 Bayes score, PP * exp(-Misfit) = 2.998462E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9411.00 1277.94 0.223991 0.309085 0.690915 Final coordinates: 9986.89 1158.76 0.258295 0.367791 0.632209 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.270002E-02 Extraneous predicted phases: 6.406194E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 29.292 0.0099 0.1774 0.0206 0.2068 0.0893 0.0011 0.0003 0.4887 0.0059 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0021 0.0003 0.0057 0.0231 -0.0136 0.0023 0.0001 -0.0099 -0.0059 Composition Misfit: 0.120638E-01 Gt predicted* 70.697 0.0000 0.1393 0.1277 0.1051 0.1993 0.0018 0.0004 0.4211 0.0052 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0037 0.0110 -0.0251 0.0232 -0.0013 -0.0000 0.0011 -0.0052 Composition Misfit: 0.106362E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Fsp 0.011 0.0186 0.0000 0.2314 0.2127 0.0000 0.0000 0.0000 0.5373 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.882 -831044. MgO 151.101 -649142. Al2O3 97.396 -0.168184E+07 CaO 135.145 -763595. FeO 168.527 -342135. TiO2 1.561 -962623. Cr2O3 0.397 -0.124735E+07 SiO2 442.992 -911758. O2 5.441 -416647. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 49 converged, 47 successes so far. Misfit function evaluations this try => 130 Misfit this try = 3.118906E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 1.899340E-07 Bayes score, PP * exp(-Misfit) = 1.841016E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10647.6 1282.15 0.392028 0.249395 0.750605 Final coordinates: 11925.6 1299.48 0.285591 0.429025 0.570975 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.118391E-02 Extraneous predicted phases: 5.157105E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 38.617 0.0088 0.1705 0.0298 0.2006 0.1009 0.0010 0.0003 0.4820 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0010 0.0072 -0.0035 0.0293 -0.0252 0.0024 0.0001 -0.0032 -0.0061 Composition Misfit: 0.167494E-01 Gt predicted* 61.381 0.0000 0.1420 0.1268 0.1086 0.1939 0.0021 0.0005 0.4207 0.0054 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0064 0.0120 -0.0286 0.0286 -0.0017 -0.0000 0.0015 -0.0054 Composition Misfit: 0.144345E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.002 0.0000 0.0411 0.0568 0.0000 0.7693 0.0093 0.0011 0.0000 0.1223 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.361 -834811. MgO 153.679 -655580. Al2O3 90.511 -0.170738E+07 CaO 144.322 -769324. FeO 159.538 -353255. TiO2 1.739 -992383. Cr2O3 0.392 -0.129071E+07 SiO2 446.458 -931757. O2 5.695 -455029. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 50 converged, 48 successes so far. Misfit function evaluations this try => 729 Misfit this try = 3.584033E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 8.031818E-08 Bayes score, PP * exp(-Misfit) = 7.749052E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17439.8 1296.70 0.114592 0.585552 0.414448 Final coordinates: 13992.6 1349.57 0.328175 0.511102 0.488898 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.583739E-02 Extraneous predicted phases: 2.939096E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 47.392 0.0085 0.1718 0.0307 0.2017 0.0988 0.0011 0.0003 0.4812 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0007 0.0059 -0.0044 0.0282 -0.0230 0.0023 0.0001 -0.0024 -0.0060 Composition Misfit: 0.150219E-01 Gt predicted* 52.606 0.0000 0.1426 0.1246 0.1155 0.1885 0.0027 0.0005 0.4197 0.0060 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0069 0.0141 -0.0354 0.0340 -0.0022 -0.0001 0.0025 -0.0060 Composition Misfit: 0.208155E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.005 -874628. MgO 157.135 -666433. Al2O3 81.282 -0.171406E+07 CaO 156.623 -779112. FeO 147.489 -366190. TiO2 1.978 -988402. Cr2O3 0.385 -0.130288E+07 SiO2 451.104 -926342. O2 6.050 -424328. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 51 converged, 49 successes so far. Misfit function evaluations this try => 253 Misfit this try = 4.615092E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 1.820103E-08 Bayes score, PP * exp(-Misfit) = 1.738013E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17131.3 1291.04 0.930996 0.833732 0.166268 Final coordinates: 17813.7 1334.44 0.353453 0.555236 0.444764 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.612720E-02 Extraneous predicted phases: 2.371759E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 45.662 0.0096 0.1812 0.0205 0.2058 0.0862 0.0007 0.0002 0.4907 0.0050 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0017 -0.0035 0.0058 0.0241 -0.0105 0.0027 0.0001 -0.0119 -0.0050 Composition Misfit: 0.162811E-01 Gt predicted* 54.335 0.0000 0.1389 0.1214 0.1264 0.1844 0.0032 0.0005 0.4180 0.0071 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0033 0.0174 -0.0464 0.0381 -0.0027 -0.0001 0.0041 -0.0071 Composition Misfit: 0.298461E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0443 0.0493 0.0000 0.7708 0.0110 0.0009 0.0000 0.1238 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.350 -815077. MgO 158.993 -648332. Al2O3 76.319 -0.170335E+07 CaO 163.238 -758878. FeO 141.010 -347875. TiO2 2.107 -990696. Cr2O3 0.381 -0.128753E+07 SiO2 453.602 -928489. O2 6.230 -464336. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 52 converged, 50 successes so far. Misfit function evaluations this try => 310 Misfit this try = 3.676697E-02 Best Misfit so far = 2.192255E-02 obtained on Try 5 Prior probability, PP = 7.305327E-08 Bayes score, PP * exp(-Misfit) = 7.041610E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12449.1 1043.01 0.369766 9.279562E-02 0.907204 Final coordinates: 15063.1 1341.02 0.321503 0.499272 0.500728 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.676664E-02 Extraneous predicted phases: 3.245128E-07 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 43.677 0.0090 0.1748 0.0265 0.2024 0.0952 0.0009 0.0002 0.4853 0.0056 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0012 0.0029 -0.0002 0.0275 -0.0195 0.0025 0.0001 -0.0065 -0.0056 Composition Misfit: 0.149856E-01 Gt predicted* 56.322 0.0000 0.1413 0.1241 0.1173 0.1885 0.0027 0.0005 0.4194 0.0062 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0056 0.0146 -0.0373 0.0340 -0.0022 -0.0001 0.0028 -0.0062 Composition Misfit: 0.217811E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.912 -870922. MgO 156.637 -664556. Al2O3 82.612 -0.171021E+07 CaO 154.851 -776645. FeO 149.226 -363994. TiO2 1.944 -985552. Cr2O3 0.386 -0.129759E+07 SiO2 450.434 -922687. O2 5.997 -421275. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 53 converged, 51 successes so far. Misfit function evaluations this try => 277 Misfit this try = 2.155725E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.625781E-07 Bayes score, PP * exp(-Misfit) = 2.569782E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17107.4 1257.89 0.228419 0.396785 0.603215 Final coordinates: 9709.51 1169.72 0.276988 0.410830 0.589170 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.153440E-02 Extraneous predicted phases: 2.284084E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 34.408 0.0095 0.1757 0.0231 0.2074 0.0907 0.0013 0.0003 0.4860 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0016 0.0020 0.0033 0.0225 -0.0150 0.0021 0.0001 -0.0072 -0.0061 Composition Misfit: 0.946155E-02 Gt predicted* 65.588 0.0000 0.1399 0.1273 0.1067 0.1974 0.0019 0.0005 0.4209 0.0053 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0043 0.0114 -0.0267 0.0251 -0.0014 -0.0000 0.0012 -0.0053 Composition Misfit: 0.120729E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0353 0.0284 0.0000 0.7952 0.0093 0.0014 0.0000 0.1303 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.219 -830234. MgO 152.913 -649424. Al2O3 92.556 -0.168444E+07 CaO 141.595 -763961. FeO 162.209 -342929. TiO2 1.686 -965174. Cr2O3 0.393 -0.125112E+07 SiO2 445.428 -914850. O2 5.616 -421393. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 54 converged, 52 successes so far. Misfit function evaluations this try => 215 Misfit this try = 2.842868E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 3.438990E-07 Bayes score, PP * exp(-Misfit) = 3.342601E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12461.5 1226.72 0.630594 0.710884 0.289116 Final coordinates: 11985.1 1253.29 0.310618 0.477585 0.522415 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.839822E-02 Extraneous predicted phases: 3.046250E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 41.722 0.0091 0.1746 0.0258 0.2052 0.0934 0.0012 0.0003 0.4845 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0012 0.0031 0.0005 0.0247 -0.0177 0.0022 0.0001 -0.0057 -0.0060 Composition Misfit: 0.109859E-01 Gt predicted* 58.270 0.0000 0.1410 0.1255 0.1127 0.1920 0.0024 0.0005 0.4201 0.0058 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0054 0.0132 -0.0327 0.0305 -0.0019 -0.0000 0.0021 -0.0058 Composition Misfit: 0.174123E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.008 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.742 -855242. MgO 155.723 -658126. Al2O3 85.050 -0.169723E+07 CaO 151.600 -771666. FeO 152.409 -354608. TiO2 1.881 -973667. Cr2O3 0.388 -0.127403E+07 SiO2 449.206 -918050. O2 5.918 -416490. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 55 converged, 53 successes so far. Misfit function evaluations this try => 225 Misfit this try = 2.214718E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.668809E-07 Bayes score, PP * exp(-Misfit) = 2.610352E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13844.4 1283.06 0.728486 0.607505 0.392495 Final coordinates: 9818.79 1184.57 0.300568 0.459960 0.540040 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.209441E-02 Extraneous predicted phases: 5.277668E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 40.166 0.0091 0.1749 0.0250 0.2079 0.0913 0.0014 0.0003 0.4839 0.0063 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0012 0.0028 0.0013 0.0220 -0.0155 0.0020 0.0001 -0.0051 -0.0063 Composition Misfit: 0.803567E-02 Gt predicted* 59.829 0.0000 0.1405 0.1267 0.1090 0.1951 0.0021 0.0005 0.4207 0.0055 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0049 0.0120 -0.0290 0.0274 -0.0016 -0.0000 0.0015 -0.0055 Composition Misfit: 0.140587E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.000 0.0000 0.0000 0.0000 0.0000 0.6462 0.2563 0.0000 0.0000 0.0975 Sp 0.005 0.0000 0.0370 0.0303 0.0000 0.7910 0.0116 0.0013 0.0000 0.1289 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.604 -832376. MgO 154.981 -650450. Al2O3 87.032 -0.168708E+07 CaO 148.959 -764915. FeO 154.997 -344618. TiO2 1.829 -966849. Cr2O3 0.389 -0.125556E+07 SiO2 448.209 -916844. O2 5.823 -423302. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 56 converged, 54 successes so far. Misfit function evaluations this try => 592 Misfit this try = 0.831976 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 7.160299E-08 Bayes score, PP * exp(-Misfit) = 3.116081E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17427.4 977.767 0.804195 0.930872 6.912845E-02 Final coordinates: 17999.3 1210.92 0.833882 1.00000 3.041754E-10 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.189445 Extraneous predicted phases: 0.642531 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 94.448 0.0083 0.1825 0.0228 0.2300 0.0648 0.0015 0.0003 0.4833 0.0064 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0004 -0.0048 0.0035 -0.0001 0.0109 0.0019 0.0000 -0.0045 -0.0064 Composition Misfit: 0.484148E-02 Gt predicted* 4.814 0.0000 0.0865 0.0918 0.2331 0.1598 0.0076 0.0007 0.4033 0.0171 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 0.0491 0.0469 -0.1531 0.0627 -0.0072 -0.0002 0.0189 -0.0171 Composition Misfit: 0.184603 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.494 0.0000 0.0000 0.0000 0.0000 0.6466 0.2556 0.0000 0.0000 0.0978 Sp 0.244 0.0000 0.0487 0.0248 0.0000 0.7813 0.0147 0.0015 0.0000 0.1291 Effective Bulk* Chemical Potentials (J/mol) Na2O 7.835 -794266. MgO 177.719 -638947. Al2O3 26.308 -0.167465E+07 CaO 229.896 -742777. FeO 75.720 -336303. TiO2 3.402 -956393. Cr2O3 0.342 -0.123729E+07 SiO2 478.777 -911273. O2 7.893 -421072. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 57 converged, 55 successes so far. Misfit function evaluations this try => 636 Misfit this try = 7.379720E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.119059E-07 Bayes score, PP * exp(-Misfit) = 1.968310E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16780.7 1099.65 6.466833E-02 0.765157 0.234843 Final coordinates: 15075.7 1027.09 0.161994 8.619018E-02 0.913810 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.378324E-02 Extraneous predicted phases: 1.395201E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.567 0.0267 0.1639 0.0089 0.1887 0.0892 0.0007 0.0004 0.5125 0.0089 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0189 0.0138 0.0174 0.0412 -0.0135 0.0027 -0.0000 -0.0338 -0.0089 Composition Misfit: 0.716342E-01 Gt predicted* 97.428 0.0000 0.1380 0.1316 0.0901 0.2121 0.0007 0.0004 0.4230 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0024 0.0071 -0.0100 0.0104 -0.0002 0.0000 -0.0008 -0.0041 Composition Misfit: 0.214901E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.005 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.675 -789979. MgO 139.244 -633944. Al2O3 129.060 -0.164484E+07 CaO 92.941 -746429. FeO 209.865 -321751. TiO2 0.741 -936210. Cr2O3 0.422 -0.118944E+07 SiO2 427.052 -882847. O2 4.250 -384787. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 58 converged, 56 successes so far. Misfit function evaluations this try => 334 Misfit this try = 0.606710 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 7.797241E-08 Bayes score, PP * exp(-Misfit) = 4.250601E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8922.21 1092.12 0.936424 0.356911 0.643089 Final coordinates: 17995.3 1195.51 0.895636 0.999997 2.927287E-06 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.186786 Extraneous predicted phases: 0.419923 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 91.288 0.0085 0.1855 0.0208 0.2284 0.0646 0.0008 0.0003 0.4840 0.0070 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0007 -0.0078 0.0055 0.0015 0.0111 0.0026 0.0000 -0.0052 -0.0070 Composition Misfit: 0.118862E-01 Gt predicted* 7.958 0.0000 0.0896 0.0871 0.2276 0.1680 0.0069 0.0007 0.4006 0.0194 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 0.0460 0.0517 -0.1476 0.0545 -0.0064 -0.0003 0.0216 -0.0194 Composition Misfit: 0.174900 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.297 0.0000 0.0000 0.0000 0.0000 0.6929 0.1785 0.0000 0.0000 0.1286 sph 0.456 0.0000 0.0000 0.0000 0.3333 0.0000 0.3333 0.0000 0.3333 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 7.835 -834695. MgO 177.719 -647273. Al2O3 26.309 -0.167157E+07 CaO 229.896 -752633. FeO 75.720 -344833. TiO2 3.402 -948036. Cr2O3 0.342 -0.122968E+07 SiO2 478.776 -898687. O2 8.477 -369122. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 59 converged, 57 successes so far. Misfit function evaluations this try => 221 Misfit this try = 3.072770E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.649520E-07 Bayes score, PP * exp(-Misfit) = 2.569344E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16074.3 1328.48 0.164692 0.760129 0.239871 Final coordinates: 12211.0 1278.59 0.265483 0.385297 0.614703 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.070088E-02 Extraneous predicted phases: 2.681920E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 32.419 0.0094 0.1728 0.0258 0.2006 0.0986 0.0008 0.0003 0.4859 0.0057 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0016 0.0049 0.0005 0.0292 -0.0228 0.0026 0.0001 -0.0071 -0.0057 Composition Misfit: 0.178568E-01 Gt predicted* 67.577 0.0000 0.1408 0.1272 0.1073 0.1961 0.0020 0.0005 0.4209 0.0053 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0052 0.0116 -0.0273 0.0264 -0.0015 -0.0000 0.0013 -0.0053 Composition Misfit: 0.128441E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0384 0.0502 0.0000 0.7780 0.0072 0.0012 0.0000 0.1251 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.019 -828825. MgO 151.838 -653021. Al2O3 95.427 -0.170258E+07 CaO 137.769 -766628. FeO 165.957 -349828. TiO2 1.612 -989550. Cr2O3 0.396 -0.128319E+07 SiO2 443.983 -928397. O2 5.507 -453693. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 60 converged, 58 successes so far. Misfit function evaluations this try => 206 Misfit this try = 8.261240E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.187381E-07 Bayes score, PP * exp(-Misfit) = 1.093231E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17420.1 1134.30 0.369566 8.539104E-02 0.914609 Final coordinates: 17581.2 1152.39 0.164521 9.119257E-02 0.908807 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 8.239315E-02 Extraneous predicted phases: 2.192544E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.895 0.0251 0.1626 0.0112 0.1849 0.0950 0.0003 0.0003 0.5132 0.0073 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0173 0.0151 0.0151 0.0450 -0.0193 0.0031 0.0000 -0.0344 -0.0073 Composition Misfit: 0.800234E-01 Gt predicted* 97.083 0.0000 0.1382 0.1314 0.0906 0.2116 0.0008 0.0004 0.4229 0.0042 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0026 0.0074 -0.0106 0.0109 -0.0003 0.0000 -0.0007 -0.0042 Composition Misfit: 0.236977E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.022 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.715 -809980. MgO 139.455 -643535. Al2O3 128.497 -0.166519E+07 CaO 93.690 -755304. FeO 209.131 -334794. TiO2 0.756 -960819. Cr2O3 0.421 -0.122732E+07 SiO2 427.335 -892197. O2 4.301 -400883. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 61 converged, 59 successes so far. Misfit function evaluations this try => 200 Misfit this try = 2.304721E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.446316E-07 Bayes score, PP * exp(-Misfit) = 2.390580E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8670.66 1305.05 0.257300 0.799078 0.200922 Final coordinates: 9553.90 1138.71 0.239054 0.322257 0.677743 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.293682E-02 Extraneous predicted phases: 1.103826E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 24.700 0.0103 0.1775 0.0193 0.2066 0.0891 0.0010 0.0003 0.4901 0.0059 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0025 0.0002 0.0070 0.0233 -0.0134 0.0024 0.0001 -0.0113 -0.0059 Composition Misfit: 0.142443E-01 Gt predicted* 75.292 0.0000 0.1391 0.1285 0.1024 0.2016 0.0016 0.0004 0.4215 0.0050 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0035 0.0102 -0.0223 0.0210 -0.0011 -0.0000 0.0007 -0.0050 Composition Misfit: 0.869256E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.008 0.0000 0.0325 0.0247 0.0000 0.8025 0.0059 0.0015 0.0000 0.1329 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.525 -826007. MgO 149.183 -647330. Al2O3 102.516 -0.167878E+07 CaO 128.321 -761992. FeO 175.211 -339522. TiO2 1.428 -961178. Cr2O3 0.401 -0.124143E+07 SiO2 440.414 -910495. O2 5.236 -416378. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 62 converged, 60 successes so far. Misfit function evaluations this try => 332 Misfit this try = 5.436003E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 7.982511E-08 Bayes score, PP * exp(-Misfit) = 7.560165E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17450.3 1323.93 0.903988 0.649601 0.350399 Final coordinates: 13996.5 1349.84 0.658363 0.884827 0.115173 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 5.089464E-02 Extraneous predicted phases: 3.465393E-03 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 99.848 0.0069 0.1717 0.0389 0.2112 0.0915 0.0029 0.0003 0.4690 0.0075 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual 0.0009 0.0060 -0.0126 0.0187 -0.0158 0.0005 -0.0000 0.0097 -0.0075 Composition Misfit: 0.907040E-02 Gt predicted* 0.101 0.0000 0.1460 0.1165 0.1319 0.1760 0.0049 0.0006 0.4158 0.0083 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0104 0.0222 -0.0519 0.0465 -0.0044 -0.0002 0.0064 -0.0083 Composition Misfit: 0.418242E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.039 0.0000 0.0000 0.0000 0.0000 0.6260 0.2900 0.0000 0.0000 0.0840 Sp 0.012 0.0000 0.0596 0.0445 0.0000 0.7445 0.0361 0.0008 0.0000 0.1145 Effective Bulk* Chemical Potentials (J/mol) Na2O 6.933 -851532. MgO 172.870 -659162. Al2O3 39.259 -0.171276E+07 CaO 212.635 -771802. FeO 92.627 -361028. TiO2 3.067 -984575. Cr2O3 0.352 -0.129647E+07 SiO2 472.257 -933560. O2 7.623 -436035. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 63 converged, 61 successes so far. Misfit function evaluations this try => 165 Misfit this try = 3.525103E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 8.963401E-08 Bayes score, PP * exp(-Misfit) = 8.652937E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16079.5 1168.03 0.597743 0.916786 8.321374E-02 Final coordinates: 13303.0 1347.64 0.321267 0.499499 0.500501 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.519862E-02 Extraneous predicted phases: 5.240891E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 47.279 0.0084 0.1702 0.0324 0.2008 0.1009 0.0012 0.0003 0.4797 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0005 0.0075 -0.0061 0.0291 -0.0252 0.0022 0.0001 -0.0009 -0.0061 Composition Misfit: 0.161747E-01 Gt predicted* 52.715 0.0000 0.1431 0.1253 0.1132 0.1895 0.0026 0.0005 0.4200 0.0058 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0075 0.0134 -0.0332 0.0330 -0.0021 -0.0001 0.0022 -0.0058 Composition Misfit: 0.190239E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.005 0.0000 0.0470 0.0707 0.0000 0.7521 0.0120 0.0010 0.0000 0.1172 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.914 -837552. MgO 156.646 -657538. Al2O3 82.586 -0.171494E+07 CaO 154.885 -770593. FeO 149.192 -357156. TiO2 1.945 -998913. Cr2O3 0.386 -0.130418E+07 SiO2 450.447 -937002. O2 5.991 -463649. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 64 converged, 62 successes so far. Misfit function evaluations this try => 310 Misfit this try = 8.807021E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.706860E-07 Bayes score, PP * exp(-Misfit) = 1.562966E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12352.4 1242.12 0.683446 0.101226 0.898774 Final coordinates: 14917.1 1292.99 0.167083 0.107375 0.892625 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 8.792725E-02 Extraneous predicted phases: 1.429560E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 4.570 0.0188 0.1628 0.0179 0.1806 0.1093 0.0002 0.0003 0.5044 0.0058 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0109 0.0149 0.0085 0.0493 -0.0336 0.0032 0.0001 -0.0257 -0.0058 Composition Misfit: 0.850988E-01 Gt predicted* 95.418 0.0000 0.1384 0.1312 0.0917 0.2104 0.0008 0.0004 0.4228 0.0042 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0028 0.0075 -0.0117 0.0122 -0.0003 0.0000 -0.0006 -0.0042 Composition Misfit: 0.282847E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ol 0.012 0.0000 0.3550 0.0000 0.0012 0.3105 0.0000 0.0000 0.3333 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.841 -801149. MgO 140.136 -649004. Al2O3 126.678 -0.170096E+07 CaO 96.116 -762199. FeO 206.755 -344593. TiO2 0.803 -0.100817E+07 Cr2O3 0.420 -0.128321E+07 SiO2 428.251 -927399. O2 4.318 -472855. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 65 converged, 63 successes so far. Misfit function evaluations this try => 162 Misfit this try = 3.531598E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.023638E-07 Bayes score, PP * exp(-Misfit) = 9.881184E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16030.5 1291.26 0.184147 0.923672 7.632803E-02 Final coordinates: 12377.0 1339.56 0.352897 0.554458 0.445542 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.526957E-02 Extraneous predicted phases: 4.640679E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 55.859 0.0078 0.1688 0.0357 0.2021 0.1012 0.0016 0.0003 0.4759 0.0065 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0000 0.0089 -0.0094 0.0278 -0.0255 0.0018 0.0001 0.0028 -0.0065 Composition Misfit: 0.153328E-01 Gt predicted* 44.135 0.0000 0.1447 0.1252 0.1132 0.1880 0.0027 0.0005 0.4200 0.0058 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0091 0.0136 -0.0331 0.0345 -0.0022 -0.0001 0.0022 -0.0058 Composition Misfit: 0.199368E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.005 0.0000 0.0489 0.0682 0.0000 0.7492 0.0166 0.0010 0.0000 0.1159 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.344 -842606. MgO 158.960 -658690. Al2O3 76.407 -0.171465E+07 CaO 163.121 -772270. FeO 141.125 -358354. TiO2 2.105 -995735. Cr2O3 0.381 -0.130263E+07 SiO2 453.558 -936827. O2 6.225 -457795. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 66 converged, 64 successes so far. Misfit function evaluations this try => 202 Misfit this try = 7.516310E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 6.486269E-08 Bayes score, PP * exp(-Misfit) = 6.016612E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16361.7 974.240 0.439143 8.833375E-02 0.911666 Final coordinates: 16919.4 1004.74 0.160456 8.364274E-02 0.916357 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.488855E-02 Extraneous predicted phases: 2.745492E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.421 0.0275 0.1650 0.0085 0.1891 0.0863 0.0008 0.0004 0.5133 0.0091 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0197 0.0127 0.0178 0.0408 -0.0105 0.0026 -0.0001 -0.0345 -0.0091 Composition Misfit: 0.728303E-01 Gt predicted* 97.567 0.0000 0.1379 0.1317 0.0898 0.2122 0.0007 0.0004 0.4230 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0023 0.0070 -0.0098 0.0103 -0.0002 0.0000 -0.0009 -0.0041 Composition Misfit: 0.205821E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.013 0.0000 0.0285 0.0110 0.0000 0.8189 0.0004 0.0023 0.0000 0.1389 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.655 -769297. MgO 139.137 -626791. Al2O3 129.346 -0.163680E+07 CaO 92.559 -738451. FeO 210.239 -313778. TiO2 0.734 -932381. Cr2O3 0.422 -0.117698E+07 SiO2 426.908 -879627. O2 4.217 -392601. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 67 converged, 65 successes so far. Misfit function evaluations this try => 224 Misfit this try = 6.822772E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 3.510115E-07 Bayes score, PP * exp(-Misfit) = 3.278615E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10323.5 1015.08 6.069587E-02 0.163685 0.836315 Final coordinates: 12869.6 1041.01 0.161853 8.766205E-02 0.912338 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 6.819363E-02 Extraneous predicted phases: 3.409243E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.753 0.0254 0.1638 0.0098 0.1895 0.0911 0.0006 0.0004 0.5108 0.0086 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0175 0.0139 0.0165 0.0404 -0.0153 0.0028 -0.0000 -0.0320 -0.0086 Composition Misfit: 0.660305E-01 Gt predicted* 97.242 0.0000 0.1380 0.1316 0.0901 0.2120 0.0007 0.0004 0.4230 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0024 0.0071 -0.0101 0.0105 -0.0003 0.0000 -0.0008 -0.0041 Composition Misfit: 0.216313E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.005 0.0000 0.0283 0.0143 0.0000 0.8167 0.0006 0.0022 0.0000 0.1379 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.687 -790766. MgO 139.306 -635946. Al2O3 128.894 -0.165208E+07 CaO 93.161 -749348. FeO 209.649 -324242. TiO2 0.745 -944027. Cr2O3 0.422 -0.119945E+07 SiO2 427.135 -890710. O2 4.242 -395885. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 68 converged, 66 successes so far. Misfit function evaluations this try => 259 Misfit this try = 2.878698E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.972550E-07 Bayes score, PP * exp(-Misfit) = 2.888199E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14412.5 1320.83 6.828439E-02 0.891115 0.108885 Final coordinates: 11792.8 1263.58 0.332824 0.519645 0.480355 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.877873E-02 Extraneous predicted phases: 8.252673E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 47.460 0.0087 0.1734 0.0283 0.2058 0.0943 0.0014 0.0003 0.4818 0.0062 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0008 0.0044 -0.0020 0.0241 -0.0185 0.0020 0.0001 -0.0031 -0.0062 Composition Misfit: 0.974427E-02 Gt predicted* 52.536 0.0000 0.1418 0.1251 0.1141 0.1902 0.0025 0.0005 0.4199 0.0059 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0062 0.0136 -0.0340 0.0323 -0.0020 -0.0000 0.0023 -0.0059 Composition Misfit: 0.190345E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Fsp 0.004 0.0190 0.0000 0.2310 0.2119 0.0000 0.0000 0.0000 0.5381 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.071 -855118. MgO 157.494 -658573. Al2O3 80.321 -0.169960E+07 CaO 157.904 -772196. FeO 146.235 -355569. TiO2 2.003 -975382. Cr2O3 0.384 -0.127781E+07 SiO2 451.587 -920645. O2 6.084 -420280. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 69 converged, 67 successes so far. Misfit function evaluations this try => 344 Misfit this try = 3.253388E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 3.051906E-07 Bayes score, PP * exp(-Misfit) = 2.954213E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13690.3 993.652 5.755566E-02 0.910691 8.930930E-02 Final coordinates: 10037.9 1124.19 0.224584 0.264368 0.735632 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.887164E-02 Extraneous predicted phases: 3.662237E-03 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 18.304 0.0115 0.1787 0.0164 0.2053 0.0878 0.0007 0.0002 0.4935 0.0058 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0036 -0.0010 0.0099 0.0246 -0.0120 0.0027 0.0001 -0.0147 -0.0058 Composition Misfit: 0.216799E-01 Gt predicted* 81.608 0.0000 0.1389 0.1288 0.1002 0.2038 0.0014 0.0004 0.4216 0.0050 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0033 0.0100 -0.0201 0.0187 -0.0009 -0.0000 0.0006 -0.0050 Composition Misfit: 0.719177E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.088 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.071 -827416. MgO 146.746 -646991. Al2O3 109.025 -0.167510E+07 CaO 119.645 -761551. FeO 183.709 -338571. TiO2 1.260 -957975. Cr2O3 0.406 -0.123491E+07 SiO2 437.138 -906048. O2 5.157 -407254. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 70 converged, 68 successes so far. Misfit function evaluations this try => 211 Misfit this try = 2.828871E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.366916E-07 Bayes score, PP * exp(-Misfit) = 2.300897E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10135.6 1116.27 9.071928E-02 0.892502 0.107498 Final coordinates: 10226.4 1236.48 0.398453 0.624160 0.375840 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.808841E-02 Extraneous predicted phases: 2.003051E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 62.151 0.0079 0.1717 0.0324 0.2089 0.0935 0.0021 0.0003 0.4764 0.0068 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0001 0.0060 -0.0061 0.0210 -0.0178 0.0013 0.0000 0.0023 -0.0068 Composition Misfit: 0.773499E-02 Gt predicted* 37.835 0.0000 0.1436 0.1251 0.1144 0.1880 0.0026 0.0005 0.4199 0.0059 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0080 0.0137 -0.0344 0.0345 -0.0021 -0.0001 0.0023 -0.0059 Composition Misfit: 0.203534E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.007 0.0000 0.0000 0.0000 0.0000 0.6354 0.2743 0.0000 0.0000 0.0903 Sp 0.008 0.0000 0.0434 0.0379 0.0000 0.7751 0.0187 0.0012 0.0000 0.1237 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.890 -840392. MgO 161.895 -654151. Al2O3 68.569 -0.169644E+07 CaO 173.568 -768487. FeO 130.892 -350676. TiO2 2.308 -973837. Cr2O3 0.375 -0.127132E+07 SiO2 457.503 -923756. O2 6.519 -429473. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 71 converged, 69 successes so far. Misfit function evaluations this try => 369 Misfit this try = 0.606560 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 8.019509E-08 Bayes score, PP * exp(-Misfit) = 4.372420E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8681.41 1009.36 0.899630 0.519440 0.480560 Final coordinates: 17989.0 1190.12 0.895913 0.999998 1.522615E-06 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.188616 Extraneous predicted phases: 0.417944 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 90.699 0.0086 0.1862 0.0204 0.2284 0.0639 0.0008 0.0003 0.4845 0.0069 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0008 -0.0085 0.0059 0.0015 0.0118 0.0026 0.0000 -0.0057 -0.0069 Composition Misfit: 0.129459E-01 Gt predicted* 8.548 0.0000 0.0892 0.0872 0.2281 0.1679 0.0068 0.0007 0.4007 0.0194 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 0.0464 0.0516 -0.1481 0.0546 -0.0063 -0.0003 0.0215 -0.0194 Composition Misfit: 0.175670 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.293 0.0000 0.0000 0.0000 0.0000 0.6937 0.1772 0.0000 0.0000 0.1291 sph 0.459 0.0000 0.0000 0.0000 0.3333 0.0000 0.3333 0.0000 0.3333 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 7.835 -833433. MgO 177.719 -646793. Al2O3 26.309 -0.167049E+07 CaO 229.896 -752101. FeO 75.720 -344091. TiO2 3.402 -947297. Cr2O3 0.342 -0.122877E+07 SiO2 478.777 -897996. O2 8.480 -368920. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 72 converged, 70 successes so far. Misfit function evaluations this try => 189 Misfit this try = 7.735058E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 9.520603E-08 Bayes score, PP * exp(-Misfit) = 8.811939E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17444.9 1092.50 0.144700 8.709379E-02 0.912906 Final coordinates: 17685.1 1096.32 0.161603 8.544394E-02 0.914556 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.734685E-02 Extraneous predicted phases: 3.730140E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.510 0.0271 0.1612 0.0105 0.1854 0.0926 0.0004 0.0004 0.5141 0.0083 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0193 0.0165 0.0158 0.0445 -0.0169 0.0030 -0.0000 -0.0353 -0.0083 Composition Misfit: 0.751794E-01 Gt predicted* 97.487 0.0000 0.1381 0.1316 0.0901 0.2120 0.0007 0.0004 0.4230 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0024 0.0072 -0.0101 0.0105 -0.0003 0.0000 -0.0008 -0.0041 Composition Misfit: 0.216744E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.003 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.669 -798313. MgO 139.213 -638120. Al2O3 129.144 -0.165333E+07 CaO 92.829 -749690. FeO 209.975 -327671. TiO2 0.739 -948363. Cr2O3 0.422 -0.120629E+07 SiO2 427.010 -885111. O2 4.242 -391823. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 73 converged, 71 successes so far. Misfit function evaluations this try => 562 Misfit this try = 8.572541E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.737420E-07 Bayes score, PP * exp(-Misfit) = 2.512531E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13911.6 1098.51 0.809612 5.592744E-02 0.944073 Final coordinates: 16019.7 1102.15 0.172722 0.120249 0.879751 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 8.551803E-02 Extraneous predicted phases: 2.073761E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 5.152 0.0185 0.1775 0.0081 0.1968 0.0840 0.0003 0.0003 0.5087 0.0058 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0107 0.0002 0.0182 0.0331 -0.0083 0.0031 0.0001 -0.0300 -0.0058 Composition Misfit: 0.825078E-01 Gt predicted* 94.827 0.0000 0.1381 0.1309 0.0923 0.2104 0.0009 0.0004 0.4226 0.0043 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0025 0.0078 -0.0123 0.0121 -0.0004 0.0000 -0.0005 -0.0043 Composition Misfit: 0.301021E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.021 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.942 -808267. MgO 140.678 -639773. Al2O3 125.230 -0.165892E+07 CaO 98.045 -752000. FeO 204.865 -329726. TiO2 0.840 -950748. Cr2O3 0.419 -0.121293E+07 SiO2 428.980 -889584. O2 4.423 -397978. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 74 converged, 72 successes so far. Misfit function evaluations this try => 474 Misfit this try = 2.945105E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 3.451687E-07 Bayes score, PP * exp(-Misfit) = 3.351514E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9171.30 1095.60 0.483875 0.125033 0.874967 Final coordinates: 12150.9 1255.30 0.276780 0.410483 0.589517 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.941364E-02 Extraneous predicted phases: 3.741536E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 34.260 0.0095 0.1747 0.0241 0.2028 0.0951 0.0009 0.0003 0.4869 0.0057 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0017 0.0030 0.0022 0.0271 -0.0194 0.0025 0.0001 -0.0081 -0.0057 Composition Misfit: 0.151786E-01 Gt predicted* 65.736 0.0000 0.1405 0.1266 0.1092 0.1950 0.0021 0.0005 0.4206 0.0055 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0049 0.0121 -0.0292 0.0275 -0.0016 -0.0000 0.0016 -0.0055 Composition Misfit: 0.142350E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.005 0.0000 0.0378 0.0428 0.0000 0.7833 0.0082 0.0011 0.0000 0.1268 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.216 -827404. MgO 152.898 -651462. Al2O3 92.595 -0.169767E+07 CaO 141.543 -764978. FeO 162.260 -347604. TiO2 1.685 -982928. Cr2O3 0.394 -0.127537E+07 SiO2 445.408 -924671. O2 5.614 -446412. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 75 converged, 73 successes so far. Misfit function evaluations this try => 192 Misfit this try = 3.303916E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.186964E-07 Bayes score, PP * exp(-Misfit) = 1.148388E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9848.23 1324.54 0.517804 0.302741 0.697259 Final coordinates: 11011.7 1315.13 0.308424 0.474870 0.525130 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.303834E-02 Extraneous predicted phases: 8.207657E-07 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 47.057 0.0080 0.1671 0.0358 0.2001 0.1046 0.0014 0.0003 0.4762 0.0065 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0002 0.0107 -0.0095 0.0298 -0.0289 0.0020 0.0000 0.0026 -0.0065 Composition Misfit: 0.184012E-01 Gt predicted* 52.942 0.0000 0.1441 0.1270 0.1075 0.1926 0.0022 0.0005 0.4208 0.0053 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0084 0.0117 -0.0275 0.0300 -0.0017 -0.0000 0.0013 -0.0053 Composition Misfit: 0.146371E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.001 0.0000 0.0448 0.0664 0.0000 0.7573 0.0120 0.0012 0.0000 0.1184 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.721 -843043. MgO 155.609 -658744. Al2O3 85.356 -0.171221E+07 CaO 151.193 -772972. FeO 152.808 -357107. TiO2 1.873 -994842. Cr2O3 0.388 -0.129860E+07 SiO2 449.053 -935334. O2 5.891 -455242. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 76 converged, 74 successes so far. Misfit function evaluations this try => 418 Misfit this try = 0.188787 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.081114E-07 Bayes score, PP * exp(-Misfit) = 8.951224E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8568.87 991.509 0.933693 0.105052 0.894948 Final coordinates: 9423.46 1272.45 0.154713 0.137466 0.862534 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.423274E-02 Extraneous predicted phases: 0.144554 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 10.259 0.0107 0.1644 0.0285 0.1883 0.1137 0.0005 0.0003 0.4885 0.0051 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0029 0.0133 -0.0022 0.0416 -0.0380 0.0029 0.0001 -0.0097 -0.0051 Composition Misfit: 0.415243E-01 Gt predicted* 89.177 0.0000 0.1382 0.1332 0.0911 0.2090 0.0009 0.0004 0.4238 0.0034 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0026 0.0056 -0.0110 0.0135 -0.0004 0.0000 -0.0017 -0.0034 Composition Misfit: 0.270847E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.204 0.0000 0.0792 0.2291 0.0000 0.6119 0.0012 0.0023 0.0000 0.0762 Sp 0.222 0.0000 0.0623 0.1759 0.0000 0.6667 0.0016 0.0022 0.0000 0.0913 Ol 0.138 0.0000 0.3468 0.0000 0.0014 0.3185 0.0000 0.0000 0.3333 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 1.077 -820911. MgO 141.403 -654365. Al2O3 123.294 -0.170732E+07 CaO 100.626 -769273. FeO 202.338 -349459. TiO2 0.890 -0.100516E+07 Cr2O3 0.417 -0.128968E+07 SiO2 429.955 -934896. O2 3.913 -478669. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 77 converged, 75 successes so far. Misfit function evaluations this try => 220 Misfit this try = 0.604493 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 7.665213E-08 Bayes score, PP * exp(-Misfit) = 4.187898E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9619.37 1204.18 0.889110 0.236941 0.763059 Final coordinates: 18000.0 1198.35 0.896451 1.00000 2.270915E-07 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.186367 Extraneous predicted phases: 0.418127 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 91.393 0.0085 0.1854 0.0209 0.2284 0.0648 0.0008 0.0003 0.4838 0.0070 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0007 -0.0077 0.0054 0.0015 0.0109 0.0026 0.0000 -0.0051 -0.0070 Composition Misfit: 0.118189E-01 Gt predicted* 7.853 0.0000 0.0898 0.0869 0.2274 0.1682 0.0069 0.0007 0.4005 0.0195 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 0.0458 0.0519 -0.1474 0.0543 -0.0064 -0.0003 0.0216 -0.0195 Composition Misfit: 0.174548 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.288 0.0000 0.0000 0.0000 0.0000 0.6932 0.1779 0.0000 0.0000 0.1288 sph 0.465 0.0000 0.0000 0.0000 0.3333 0.0000 0.3333 0.0000 0.3333 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 7.835 -836127. MgO 177.719 -647727. Al2O3 26.308 -0.167228E+07 CaO 229.896 -753056. FeO 75.720 -345285. TiO2 3.402 -948448. Cr2O3 0.342 -0.123072E+07 SiO2 478.777 -898880. O2 8.485 -368858. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 78 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 79 converged, 76 successes so far. Misfit function evaluations this try => 611 Misfit this try = 3.740610E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.057505E-07 Bayes score, PP * exp(-Misfit) = 1.018679E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16739.3 1307.70 0.491679 0.413852 0.586148 Final coordinates: 13568.8 1338.11 0.276846 0.399882 0.600118 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.605103E-02 Extraneous predicted phases: 1.355069E-03 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 34.419 0.0092 0.1711 0.0284 0.1984 0.1019 0.0008 0.0002 0.4843 0.0058 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0014 0.0066 -0.0021 0.0315 -0.0261 0.0026 0.0001 -0.0055 -0.0058 Composition Misfit: 0.215117E-01 Gt predicted* 65.529 0.0000 0.1417 0.1265 0.1090 0.1942 0.0021 0.0005 0.4205 0.0056 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0061 0.0123 -0.0290 0.0283 -0.0016 -0.0000 0.0017 -0.0056 Composition Misfit: 0.145393E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.052 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.133 -870270. MgO 152.452 -665577. Al2O3 93.788 -0.171269E+07 CaO 139.955 -778646. FeO 163.816 -364463. TiO2 1.654 -992101. Cr2O3 0.394 -0.130261E+07 SiO2 444.808 -925757. O2 5.669 -427448. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 80 converged, 77 successes so far. Misfit function evaluations this try => 237 Misfit this try = 9.888689E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 6.326435E-08 Bayes score, PP * exp(-Misfit) = 5.730770E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16568.6 1244.85 0.471353 0.132754 0.867246 Final coordinates: 17300.0 1278.81 0.178699 0.143535 0.856465 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 9.884911E-02 Extraneous predicted phases: 3.778403E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 7.271 0.0157 0.1744 0.0128 0.1877 0.0992 0.0002 0.0002 0.5052 0.0046 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0078 0.0034 0.0135 0.0422 -0.0235 0.0032 0.0001 -0.0264 -0.0046 Composition Misfit: 0.948792E-01 Gt predicted* 92.720 0.0000 0.1385 0.1305 0.0944 0.2084 0.0010 0.0004 0.4224 0.0045 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0029 0.0083 -0.0144 0.0142 -0.0005 -0.0000 -0.0002 -0.0045 Composition Misfit: 0.396990E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.009 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 1.125 -844266. MgO 141.658 -656070. Al2O3 122.612 -0.169373E+07 CaO 101.535 -768059. FeO 201.447 -351347. TiO2 0.908 -988248. Cr2O3 0.417 -0.127283E+07 SiO2 430.298 -909103. O2 4.500 -423867. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 81 converged, 78 successes so far. Misfit function evaluations this try => 321 Misfit this try = 0.147255 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 3.140436E-08 Bayes score, PP * exp(-Misfit) = 2.710428E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9677.51 983.518 0.777184 0.712137 0.287863 Final coordinates: 16589.8 951.089 0.152943 6.986200E-02 0.930138 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 8.323510E-02 Extraneous predicted phases: 6.402023E-02 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.218 0.0250 0.1724 0.0074 0.1956 0.0782 0.0006 0.0004 0.5120 0.0084 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0172 0.0053 0.0189 0.0343 -0.0025 0.0028 -0.0001 -0.0332 -0.0084 Composition Misfit: 0.817720E-01 Gt predicted* 97.509 0.0000 0.1377 0.1336 0.0881 0.2124 0.0005 0.0004 0.4240 0.0034 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0021 0.0052 -0.0081 0.0101 -0.0000 0.0000 -0.0018 -0.0034 Composition Misfit: 0.146309E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.152 0.0000 0.0000 0.0000 0.0000 0.7388 0.1020 0.0000 0.0000 0.1592 Sp 0.121 0.0000 0.0280 0.0089 0.0000 0.8204 0.0002 0.0032 0.0000 0.1393 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.547 -762516. MgO 138.557 -622792. Al2O3 130.896 -0.162736E+07 CaO 90.494 -734200. FeO 212.262 -308183. TiO2 0.693 -925765. Cr2O3 0.423 -0.116043E+07 SiO2 426.128 -873927. O2 4.058 -387373. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 82 converged, 79 successes so far. Misfit function evaluations this try => 416 Misfit this try = 5.801649E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 4.114384E-07 Bayes score, PP * exp(-Misfit) = 3.882474E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10951.3 1011.12 0.191315 0.842301 0.157699 Final coordinates: 11490.0 1078.71 0.172857 0.125691 0.874309 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 5.801601E-02 Extraneous predicted phases: 4.803192E-07 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 5.875 0.0170 0.1759 0.0104 0.1990 0.0866 0.0005 0.0003 0.5042 0.0062 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0091 0.0019 0.0159 0.0309 -0.0109 0.0029 0.0001 -0.0254 -0.0062 Composition Misfit: 0.550140E-01 Gt predicted* 94.124 0.0000 0.1381 0.1310 0.0923 0.2103 0.0009 0.0004 0.4227 0.0043 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0025 0.0077 -0.0122 0.0122 -0.0004 0.0000 -0.0005 -0.0043 Composition Misfit: 0.300199E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.985 -810278. MgO 140.907 -641578. Al2O3 124.618 -0.166316E+07 CaO 98.861 -755604. FeO 204.067 -331154. TiO2 0.856 -952330. Cr2O3 0.418 -0.121671E+07 SiO2 429.288 -897111. O2 4.409 -401458. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 83 converged, 80 successes so far. Misfit function evaluations this try => 448 Misfit this try = 2.544777E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.232795E-07 Bayes score, PP * exp(-Misfit) = 2.176692E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9322.82 1015.38 0.302481 0.741330 0.258670 Final coordinates: 9415.68 1169.98 0.219245 0.270507 0.729493 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.504131E-02 Extraneous predicted phases: 4.064650E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 20.388 0.0105 0.1736 0.0214 0.2029 0.0952 0.0008 0.0003 0.4892 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0027 0.0041 0.0049 0.0270 -0.0195 0.0026 0.0001 -0.0104 -0.0060 Composition Misfit: 0.181606E-01 Gt predicted* 79.594 0.0000 0.1395 0.1294 0.0993 0.2034 0.0014 0.0004 0.4219 0.0047 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0038 0.0093 -0.0192 0.0191 -0.0009 -0.0000 0.0002 -0.0047 Composition Misfit: 0.688067E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.015 0.0000 0.0322 0.0303 0.0000 0.7997 0.0044 0.0015 0.0000 0.1319 Fsp 0.003 0.0205 0.0000 0.2295 0.2090 0.0000 0.0000 0.0000 0.5410 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.119 -827429. MgO 147.005 -649582. Al2O3 108.335 -0.168557E+07 CaO 120.565 -764423. FeO 182.808 -342506. TiO2 1.278 -970884. Cr2O3 0.406 -0.125259E+07 SiO2 437.485 -915713. O2 5.010 -426682. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 84 converged, 81 successes so far. Misfit function evaluations this try => 532 Misfit this try = 7.883952E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.851742E-07 Bayes score, PP * exp(-Misfit) = 2.635546E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15668.0 1093.46 0.412409 0.122704 0.877296 Final coordinates: 16124.1 1128.91 0.168379 9.836253E-02 0.901637 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.777263E-02 Extraneous predicted phases: 1.066887E-03 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 3.365 0.0233 0.1663 0.0103 0.1883 0.0926 0.0004 0.0003 0.5115 0.0071 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0154 0.0114 0.0160 0.0416 -0.0169 0.0030 0.0000 -0.0327 -0.0071 Composition Misfit: 0.751933E-01 Gt predicted* 96.588 0.0000 0.1383 0.1312 0.0912 0.2112 0.0008 0.0004 0.4227 0.0043 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0027 0.0076 -0.0112 0.0114 -0.0003 0.0000 -0.0006 -0.0043 Composition Misfit: 0.257933E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.048 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.771 -808853. MgO 139.756 -642469. Al2O3 127.691 -0.166356E+07 CaO 94.765 -754795. FeO 208.078 -333123. TiO2 0.776 -957204. Cr2O3 0.421 -0.122153E+07 SiO2 427.741 -892607. O2 4.379 -399973. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 85 converged, 82 successes so far. Misfit function evaluations this try => 342 Misfit this try = 3.467869E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.002087E-07 Bayes score, PP * exp(-Misfit) = 9.679316E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16283.3 1241.51 0.906514 5.088935E-02 0.949111 Final coordinates: 13179.2 1342.16 0.317088 0.491453 0.508547 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.466982E-02 Extraneous predicted phases: 8.865920E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 46.191 0.0084 0.1703 0.0320 0.2009 0.1008 0.0012 0.0003 0.4801 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0006 0.0074 -0.0057 0.0290 -0.0251 0.0022 0.0001 -0.0013 -0.0061 Composition Misfit: 0.161806E-01 Gt predicted* 53.807 0.0000 0.1430 0.1255 0.1127 0.1900 0.0025 0.0005 0.4201 0.0058 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0073 0.0133 -0.0327 0.0325 -0.0020 -0.0000 0.0021 -0.0058 Composition Misfit: 0.184892E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.002 0.0000 0.0462 0.0687 0.0000 0.7544 0.0118 0.0010 0.0000 0.1179 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.851 -837035. MgO 156.307 -657267. Al2O3 83.491 -0.171401E+07 CaO 153.679 -770402. FeO 150.374 -356663. TiO2 1.921 -997959. Cr2O3 0.386 -0.130290E+07 SiO2 449.991 -936330. O2 5.960 -462599. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 86 converged, 83 successes so far. Misfit function evaluations this try => 315 Misfit this try = 3.597934E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 7.956681E-08 Bayes score, PP * exp(-Misfit) = 7.675494E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15171.8 1306.44 0.918365 0.853242 0.146758 Final coordinates: 14354.8 1346.61 0.305324 0.469212 0.530788 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.594701E-02 Extraneous predicted phases: 3.233596E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 41.677 0.0089 0.1728 0.0284 0.2006 0.0986 0.0009 0.0003 0.4839 0.0057 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0011 0.0049 -0.0021 0.0293 -0.0229 0.0025 0.0001 -0.0051 -0.0057 Composition Misfit: 0.170223E-01 Gt predicted* 58.319 0.0000 0.1417 0.1252 0.1140 0.1903 0.0025 0.0005 0.4199 0.0059 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0061 0.0136 -0.0339 0.0322 -0.0020 -0.0001 0.0023 -0.0059 Composition Misfit: 0.189247E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0453 0.0677 0.0000 0.7570 0.0102 0.0009 0.0000 0.1189 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.676 -830806. MgO 155.371 -655344. Al2O3 85.992 -0.171292E+07 CaO 150.345 -767880. FeO 153.639 -354761. TiO2 1.856 -999043. Cr2O3 0.388 -0.130178E+07 SiO2 448.732 -935540. O2 5.864 -467011. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 87 converged, 84 successes so far. Misfit function evaluations this try => 366 Misfit this try = 4.622107E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.202282E-08 Bayes score, PP * exp(-Misfit) = 1.147976E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15010.3 990.697 0.136600 0.697662 0.302338 Final coordinates: 17996.4 1348.61 0.373647 0.586594 0.413406 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.621835E-02 Extraneous predicted phases: 2.716817E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 49.394 0.0094 0.1805 0.0219 0.2064 0.0864 0.0008 0.0002 0.4891 0.0052 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0015 -0.0027 0.0044 0.0235 -0.0107 0.0026 0.0001 -0.0103 -0.0052 Composition Misfit: 0.132088E-01 Gt predicted* 50.604 0.0000 0.1391 0.1204 0.1291 0.1824 0.0035 0.0005 0.4176 0.0074 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0035 0.0183 -0.0491 0.0401 -0.0030 -0.0001 0.0046 -0.0074 Composition Misfit: 0.330096E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.596 -870590. MgO 160.313 -662767. Al2O3 72.793 -0.170591E+07 CaO 167.938 -773127. FeO 136.407 -363041. TiO2 2.198 -978482. Cr2O3 0.378 -0.129000E+07 SiO2 455.377 -916936. O2 6.371 -411456. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 88 converged, 85 successes so far. Misfit function evaluations this try => 230 Misfit this try = 0.456049 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 7.511654E-08 Bayes score, PP * exp(-Misfit) = 4.760755E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9158.67 970.886 0.496362 0.306367 0.693633 Final coordinates: 10303.1 973.632 0.201974 0.252226 0.747774 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 8.835820E-02 Extraneous predicted phases: 0.367691 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 17.944 0.0111 0.1941 0.0073 0.2158 0.0650 0.0003 0.0002 0.5018 0.0043 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0032 -0.0164 0.0190 0.0141 0.0107 0.0031 0.0001 -0.0230 -0.0043 Composition Misfit: 0.836671E-01 Gt predicted* 81.321 0.0000 0.1360 0.1334 0.0970 0.2052 0.0006 0.0004 0.4239 0.0034 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0004 0.0053 -0.0170 0.0173 -0.0001 0.0000 -0.0017 -0.0034 Composition Misfit: 0.469107E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Opx 0.099 0.0002 0.3313 0.0170 0.0079 0.1549 0.0001 0.0006 0.4858 0.0022 Ilm 0.355 0.0000 0.0000 0.0000 0.0000 0.7082 0.1530 0.0000 0.0000 0.1388 Sp 0.281 0.0000 0.0290 0.0131 0.0000 0.8154 0.0008 0.0040 0.0000 0.1376 Effective Bulk* Chemical Potentials (J/mol) Na2O 1.976 -794726. MgO 146.235 -632166. Al2O3 110.390 -0.164496E+07 CaO 117.825 -745657. FeO 185.492 -318886. TiO2 1.225 -937172. Cr2O3 0.407 -0.118426E+07 SiO2 436.450 -888561. O2 4.683 -398213. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 89 converged, 86 successes so far. Misfit function evaluations this try => 223 Misfit this try = 3.540766E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 8.550527E-08 Bayes score, PP * exp(-Misfit) = 8.253070E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17091.1 1305.59 0.680875 0.737388 0.262612 Final coordinates: 13326.4 1349.95 0.310976 0.479191 0.520809 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.540379E-02 Extraneous predicted phases: 3.874378E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.892 0.0085 0.1700 0.0322 0.2000 0.1018 0.0011 0.0003 0.4802 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0006 0.0078 -0.0059 0.0299 -0.0260 0.0023 0.0001 -0.0014 -0.0061 Composition Misfit: 0.174237E-01 Gt predicted* 55.106 0.0000 0.1430 0.1256 0.1122 0.1904 0.0025 0.0005 0.4201 0.0057 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0073 0.0131 -0.0321 0.0321 -0.0020 -0.0001 0.0020 -0.0057 Composition Misfit: 0.179801E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.003 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.755 -874739. MgO 155.791 -667087. Al2O3 84.870 -0.171547E+07 CaO 151.841 -780176. FeO 152.174 -366675. TiO2 1.885 -990770. Cr2O3 0.388 -0.130485E+07 SiO2 449.297 -927943. O2 5.915 -427397. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 90 converged, 87 successes so far. Misfit function evaluations this try => 615 Misfit this try = 0.613542 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 5.603224E-08 Bayes score, PP * exp(-Misfit) = 3.033753E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10333.6 987.890 0.919687 0.881788 0.118212 Final coordinates: 17518.1 1276.27 0.788117 0.978811 2.118918E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.120786 Extraneous predicted phases: 0.492756 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 99.322 0.0077 0.1767 0.0286 0.2268 0.0731 0.0020 0.0003 0.4778 0.0069 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual 0.0002 0.0010 -0.0023 0.0031 0.0026 0.0014 0.0000 0.0010 -0.0069 Composition Misfit: 0.139449E-02 Gt predicted* 0.003 0.0000 0.1072 0.1008 0.1982 0.1645 0.0070 0.0007 0.4079 0.0138 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 0.0285 0.0379 -0.1182 0.0580 -0.0065 -0.0003 0.0143 -0.0138 Composition Misfit: 0.119391 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.395 0.0000 0.0000 0.0000 0.0000 0.6354 0.2743 0.0000 0.0000 0.0903 Sp 0.281 0.0000 0.0540 0.0315 0.0000 0.7659 0.0243 0.0012 0.0000 0.1231 Effective Bulk* Chemical Potentials (J/mol) Na2O 7.669 -814341. MgO 176.827 -645991. Al2O3 28.691 -0.168903E+07 CaO 226.720 -752342. FeO 78.831 -345531. TiO2 3.340 -967149. Cr2O3 0.344 -0.126115E+07 SiO2 477.577 -919845. O2 7.766 -428536. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 91 converged, 88 successes so far. Misfit function evaluations this try => 147 Misfit this try = 3.453526E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.057728E-07 Bayes score, PP * exp(-Misfit) = 1.021823E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10082.6 1329.53 0.612671 0.366393 0.633607 Final coordinates: 12254.5 1337.11 0.295108 0.448741 0.551259 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.452421E-02 Extraneous predicted phases: 1.104556E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 42.527 0.0084 0.1682 0.0336 0.1989 0.1043 0.0011 0.0003 0.4790 0.0062 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0005 0.0095 -0.0073 0.0310 -0.0286 0.0023 0.0001 -0.0002 -0.0062 Composition Misfit: 0.193351E-01 Gt predicted* 57.471 0.0000 0.1431 0.1267 0.1088 0.1926 0.0023 0.0005 0.4207 0.0054 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0075 0.0121 -0.0288 0.0299 -0.0018 -0.0000 0.0015 -0.0054 Composition Misfit: 0.151891E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.003 0.0000 0.0454 0.0726 0.0000 0.7534 0.0101 0.0010 0.0000 0.1175 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.516 -839471. MgO 154.509 -658368. Al2O3 88.294 -0.171477E+07 CaO 147.277 -772036. FeO 156.644 -357361. TiO2 1.797 -999419. Cr2O3 0.390 -0.130326E+07 SiO2 447.574 -937003. O2 5.778 -462419. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 92 converged, 89 successes so far. Misfit function evaluations this try => 242 Misfit this try = 4.529571E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.322453E-08 Bayes score, PP * exp(-Misfit) = 1.263888E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16311.0 1306.38 0.690182 0.895842 0.104158 Final coordinates: 17909.9 1347.26 0.370403 0.580200 0.419800 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.523697E-02 Extraneous predicted phases: 5.874254E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 48.693 0.0094 0.1806 0.0219 0.2062 0.0864 0.0009 0.0002 0.4893 0.0052 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0016 -0.0029 0.0044 0.0237 -0.0107 0.0025 0.0001 -0.0105 -0.0052 Composition Misfit: 0.129622E-01 Gt predicted* 51.297 0.0000 0.1390 0.1205 0.1286 0.1829 0.0034 0.0005 0.4176 0.0074 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0034 0.0182 -0.0486 0.0396 -0.0029 -0.0001 0.0046 -0.0074 Composition Misfit: 0.322747E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.011 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.546 -870668. MgO 160.044 -662718. Al2O3 73.512 -0.170585E+07 CaO 166.979 -773091. FeO 137.346 -362863. TiO2 2.180 -979107. Cr2O3 0.379 -0.128924E+07 SiO2 455.015 -916951. O2 6.359 -411599. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 93 converged, 90 successes so far. Misfit function evaluations this try => 323 Misfit this try = 4.580237E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.166764E-08 Bayes score, PP * exp(-Misfit) = 1.114529E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17119.0 981.512 0.941450 5.790519E-02 0.942095 Final coordinates: 18000.0 1349.97 0.354247 0.556443 0.443557 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.579070E-02 Extraneous predicted phases: 1.166744E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 46.240 0.0095 0.1804 0.0214 0.2052 0.0875 0.0007 0.0002 0.4899 0.0051 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0016 -0.0027 0.0049 0.0247 -0.0117 0.0027 0.0001 -0.0111 -0.0051 Composition Misfit: 0.157802E-01 Gt predicted* 53.758 0.0000 0.1393 0.1214 0.1264 0.1841 0.0032 0.0005 0.4180 0.0071 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0037 0.0174 -0.0464 0.0384 -0.0027 -0.0001 0.0041 -0.0071 Composition Misfit: 0.300105E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.003 0.0000 0.0453 0.0537 0.0000 0.7666 0.0110 0.0009 0.0000 0.1225 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.360 -816351. MgO 159.044 -649351. Al2O3 76.183 -0.170635E+07 CaO 163.419 -759815. FeO 140.833 -349466. TiO2 2.110 -994031. Cr2O3 0.381 -0.129261E+07 SiO2 453.670 -930642. O2 6.236 -467499. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 94 converged, 91 successes so far. Misfit function evaluations this try => 200 Misfit this try = 3.132907E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.650292E-07 Bayes score, PP * exp(-Misfit) = 1.599391E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9357.96 1225.12 0.428359 7.759603E-02 0.922404 Final coordinates: 11401.2 1301.36 0.279861 0.417181 0.582819 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.128638E-02 Extraneous predicted phases: 4.269191E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 38.291 0.0086 0.1689 0.0316 0.1998 0.1031 0.0011 0.0003 0.4805 0.0062 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0008 0.0088 -0.0053 0.0301 -0.0273 0.0023 0.0001 -0.0017 -0.0062 Composition Misfit: 0.180911E-01 Gt predicted* 61.704 0.0000 0.1424 0.1273 0.1068 0.1948 0.0021 0.0005 0.4209 0.0052 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0067 0.0114 -0.0268 0.0277 -0.0016 -0.0000 0.0012 -0.0052 Composition Misfit: 0.131953E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.005 0.0000 0.0413 0.0602 0.0000 0.7669 0.0089 0.0012 0.0000 0.1215 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.269 -837367. MgO 153.180 -656648. Al2O3 91.842 -0.170879E+07 CaO 142.547 -770668. FeO 161.277 -354322. TiO2 1.705 -993661. Cr2O3 0.393 -0.129272E+07 SiO2 445.787 -932851. O2 5.642 -455346. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 95 converged, 92 successes so far. Misfit function evaluations this try => 346 Misfit this try = 2.350236E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.511299E-07 Bayes score, PP * exp(-Misfit) = 2.452966E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14410.3 974.530 7.877321E-02 0.347193 0.652807 Final coordinates: 9590.41 1148.13 0.234678 0.310872 0.689128 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.343413E-02 Extraneous predicted phases: 6.823155E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 23.744 0.0104 0.1767 0.0197 0.2056 0.0906 0.0009 0.0003 0.4900 0.0059 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0025 0.0011 0.0066 0.0243 -0.0149 0.0025 0.0001 -0.0112 -0.0059 Composition Misfit: 0.151067E-01 Gt predicted* 76.250 0.0000 0.1392 0.1287 0.1017 0.2019 0.0015 0.0004 0.4216 0.0049 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0036 0.0101 -0.0217 0.0206 -0.0010 -0.0000 0.0006 -0.0049 Composition Misfit: 0.832743E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.006 0.0000 0.0326 0.0262 0.0000 0.8017 0.0054 0.0015 0.0000 0.1326 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.436 -826348. MgO 148.704 -647901. Al2O3 103.796 -0.168066E+07 CaO 126.614 -762582. FeO 176.882 -340332. TiO2 1.395 -963800. Cr2O3 0.402 -0.124479E+07 SiO2 439.770 -911904. O2 5.189 -419236. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 96 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 97 converged, 93 successes so far. Misfit function evaluations this try => 331 Misfit this try = 3.891316E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 8.109458E-08 Bayes score, PP * exp(-Misfit) = 7.799954E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15682.3 1317.57 0.248407 0.917266 8.273436E-02 Final coordinates: 12066.5 1349.54 0.430267 0.666111 0.333889 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.886591E-02 Extraneous predicted phases: 4.725037E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 73.174 0.0072 0.1680 0.0403 0.2033 0.1009 0.0022 0.0003 0.4709 0.0069 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual 0.0007 0.0097 -0.0139 0.0266 -0.0252 0.0012 0.0000 0.0078 -0.0069 Composition Misfit: 0.160586E-01 Gt predicted* 26.817 0.0000 0.1483 0.1244 0.1138 0.1844 0.0030 0.0005 0.4196 0.0060 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0127 0.0144 -0.0338 0.0381 -0.0026 -0.0001 0.0026 -0.0060 Composition Misfit: 0.228073E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Fsp 0.009 0.0178 0.0000 0.2322 0.2143 0.0000 0.0000 0.0000 0.5357 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 5.219 -867677. MgO 163.661 -665106. Al2O3 63.852 -0.171699E+07 CaO 179.855 -779030. FeO 124.734 -365708. TiO2 2.430 -990251. Cr2O3 0.371 -0.130689E+07 SiO2 459.878 -933746. O2 6.709 -435344. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 98 converged, 94 successes so far. Misfit function evaluations this try => 236 Misfit this try = 7.587822E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 3.558610E-08 Bayes score, PP * exp(-Misfit) = 3.298579E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17412.6 979.795 0.317795 8.201736E-02 0.917983 Final coordinates: 17628.8 997.017 0.159710 8.066888E-02 0.919331 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.567887E-02 Extraneous predicted phases: 1.993480E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.185 0.0294 0.1619 0.0088 0.1868 0.0879 0.0009 0.0004 0.5141 0.0098 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0216 0.0158 0.0175 0.0431 -0.0122 0.0026 -0.0001 -0.0353 -0.0098 Composition Misfit: 0.736768E-01 Gt predicted* 97.804 0.0000 0.1379 0.1318 0.0897 0.2124 0.0007 0.0004 0.4231 0.0040 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0023 0.0070 -0.0096 0.0101 -0.0002 0.0000 -0.0009 -0.0040 Composition Misfit: 0.200202E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.011 0.0000 0.0283 0.0104 0.0000 0.8197 0.0004 0.0020 0.0000 0.1391 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.632 -765540. MgO 139.012 -625270. Al2O3 129.681 -0.163369E+07 CaO 92.113 -736635. FeO 210.676 -312033. TiO2 0.725 -929513. Cr2O3 0.422 -0.117302E+07 SiO2 426.740 -877385. O2 4.206 -390498. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 99 converged, 95 successes so far. Misfit function evaluations this try => 158 Misfit this try = 2.288278E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.866904E-07 Bayes score, PP * exp(-Misfit) = 2.802046E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12305.7 1300.77 0.254419 0.713736 0.286264 Final coordinates: 10012.9 1190.97 0.313893 0.485718 0.514282 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.279238E-02 Extraneous predicted phases: 9.039761E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 43.023 0.0089 0.1749 0.0256 0.2084 0.0909 0.0015 0.0003 0.4832 0.0063 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0011 0.0028 0.0007 0.0215 -0.0152 0.0019 0.0001 -0.0045 -0.0063 Composition Misfit: 0.748860E-02 Gt predicted* 56.967 0.0000 0.1406 0.1263 0.1104 0.1939 0.0022 0.0005 0.4205 0.0056 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0050 0.0124 -0.0304 0.0286 -0.0017 -0.0000 0.0017 -0.0056 Composition Misfit: 0.153038E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.005 0.0000 0.0000 0.0000 0.0000 0.6443 0.2594 0.0000 0.0000 0.0962 Sp 0.005 0.0000 0.0379 0.0311 0.0000 0.7890 0.0126 0.0012 0.0000 0.1282 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.806 -832538. MgO 156.066 -650615. Al2O3 84.136 -0.168791E+07 CaO 152.819 -764970. FeO 151.215 -345096. TiO2 1.904 -967460. Cr2O3 0.387 -0.125758E+07 SiO2 449.667 -917514. O2 5.933 -424288. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 100 converged, 96 successes so far. Misfit function evaluations this try => 295 Misfit this try = 4.406337E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.751013E-07 Bayes score, PP * exp(-Misfit) = 2.632426E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9300.38 1045.20 0.114589 9.967903E-02 0.900321 Final coordinates: 9870.25 1116.71 0.171870 0.121995 0.878005 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.401622E-02 Extraneous predicted phases: 4.714449E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 5.888 0.0165 0.1696 0.0152 0.1968 0.0947 0.0005 0.0003 0.4997 0.0067 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0086 0.0081 0.0111 0.0331 -0.0190 0.0029 0.0000 -0.0209 -0.0067 Composition Misfit: 0.411469E-01 Gt predicted* 94.103 0.0000 0.1383 0.1312 0.0918 0.2104 0.0009 0.0004 0.4228 0.0042 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0027 0.0076 -0.0118 0.0121 -0.0004 0.0000 -0.0006 -0.0042 Composition Misfit: 0.286930E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Fsp 0.010 0.0340 0.0000 0.2160 0.1820 0.0000 0.0000 0.0000 0.5680 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.956 -816220. MgO 140.752 -645998. Al2O3 125.034 -0.167381E+07 CaO 98.307 -760707. FeO 204.609 -336734. TiO2 0.845 -964230. Cr2O3 0.419 -0.123430E+07 SiO2 429.079 -906182. O2 4.396 -412434. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 101 converged, 97 successes so far. Misfit function evaluations this try => 205 Misfit this try = 2.259452E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.477202E-07 Bayes score, PP * exp(-Misfit) = 2.421858E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14066.2 1076.84 0.103304 0.474820 0.525180 Final coordinates: 9567.72 1155.34 0.243580 0.333466 0.666534 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.252132E-02 Extraneous predicted phases: 7.320179E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 26.196 0.0101 0.1760 0.0208 0.2060 0.0912 0.0010 0.0003 0.4887 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0023 0.0017 0.0055 0.0239 -0.0155 0.0024 0.0001 -0.0099 -0.0060 Composition Misfit: 0.134381E-01 Gt predicted* 73.798 0.0000 0.1395 0.1284 0.1027 0.2008 0.0016 0.0004 0.4215 0.0050 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0039 0.0103 -0.0227 0.0217 -0.0011 -0.0000 0.0007 -0.0050 Composition Misfit: 0.908319E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.006 0.0000 0.0330 0.0270 0.0000 0.8003 0.0060 0.0016 0.0000 0.1321 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.613 -827769. MgO 149.655 -648523. Al2O3 101.256 -0.168209E+07 CaO 130.001 -763207. FeO 173.566 -341265. TiO2 1.461 -964735. Cr2O3 0.400 -0.124665E+07 SiO2 441.049 -912967. O2 5.285 -420089. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 102 converged, 98 successes so far. Misfit function evaluations this try => 274 Misfit this try = 7.222171E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.975634E-07 Bayes score, PP * exp(-Misfit) = 2.768306E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13497.7 991.249 0.454664 8.966644E-02 0.910334 Final coordinates: 14005.3 1033.41 0.163396 8.591774E-02 0.914082 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.189543E-02 Extraneous predicted phases: 3.262826E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.482 0.0276 0.1608 0.0096 0.1869 0.0922 0.0007 0.0004 0.5125 0.0093 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0198 0.0169 0.0167 0.0430 -0.0165 0.0027 -0.0000 -0.0337 -0.0093 Composition Misfit: 0.697011E-01 Gt predicted* 97.492 0.0000 0.1381 0.1315 0.0902 0.2120 0.0007 0.0004 0.4229 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0025 0.0072 -0.0101 0.0106 -0.0002 0.0000 -0.0008 -0.0041 Composition Misfit: 0.219436E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.026 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.673 -792136. MgO 139.233 -635516. Al2O3 129.091 -0.164815E+07 CaO 92.900 -748482. FeO 209.905 -323541. TiO2 0.740 -939364. Cr2O3 0.422 -0.119445E+07 SiO2 427.037 -886007. O2 4.287 -386604. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 103 converged, 99 successes so far. Misfit function evaluations this try => 340 Misfit this try = 2.212526E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.436366E-07 Bayes score, PP * exp(-Misfit) = 2.383053E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15928.9 1283.39 0.189007 0.233136 0.766864 Final coordinates: 9641.83 1184.15 0.266511 0.388216 0.611784 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.196025E-02 Extraneous predicted phases: 1.650086E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 32.609 0.0094 0.1742 0.0241 0.2059 0.0933 0.0012 0.0003 0.4854 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0016 0.0035 0.0022 0.0240 -0.0176 0.0022 0.0001 -0.0067 -0.0061 Composition Misfit: 0.108899E-01 Gt predicted* 67.381 0.0000 0.1402 0.1278 0.1052 0.1982 0.0018 0.0004 0.4212 0.0052 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0046 0.0109 -0.0252 0.0244 -0.0013 -0.0000 0.0010 -0.0052 Composition Misfit: 0.110703E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.010 0.0000 0.0351 0.0313 0.0000 0.7938 0.0086 0.0014 0.0000 0.1298 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.042 -831041. MgO 151.961 -650462. Al2O3 95.099 -0.168761E+07 CaO 138.206 -765094. FeO 165.528 -344318. TiO2 1.621 -969360. Cr2O3 0.395 -0.125622E+07 SiO2 444.148 -917301. O2 5.514 -426270. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 104 converged, 100 successes so far. Misfit function evaluations this try => 193 Misfit this try = 2.265375E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.492642E-07 Bayes score, PP * exp(-Misfit) = 2.436809E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9207.54 1057.31 0.722067 0.608805 0.391195 Final coordinates: 9580.03 1143.74 0.244431 0.335400 0.664600 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.261323E-02 Extraneous predicted phases: 4.052438E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 26.075 0.0102 0.1772 0.0198 0.2067 0.0894 0.0010 0.0003 0.4895 0.0059 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0024 0.0005 0.0065 0.0232 -0.0137 0.0024 0.0001 -0.0107 -0.0059 Composition Misfit: 0.134300E-01 Gt predicted* 73.921 0.0000 0.1392 0.1283 0.1030 0.2009 0.0016 0.0004 0.4214 0.0050 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0036 0.0104 -0.0230 0.0216 -0.0011 -0.0000 0.0008 -0.0050 Composition Misfit: 0.918321E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.005 0.0000 0.0329 0.0252 0.0000 0.8017 0.0062 0.0014 0.0000 0.1326 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.628 -826803. MgO 149.737 -647691. Al2O3 101.038 -0.167972E+07 CaO 130.290 -762342. FeO 173.282 -340074. TiO2 1.467 -961978. Cr2O3 0.400 -0.124322E+07 SiO2 441.158 -911164. O2 5.294 -417131. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 105 converged, 101 successes so far. Misfit function evaluations this try => 346 Misfit this try = 4.606132E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.288903E-08 Bayes score, PP * exp(-Misfit) = 1.230881E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16786.9 1320.34 0.942820 0.196176 0.803824 Final coordinates: 17998.5 1344.99 0.353070 0.552451 0.447549 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.600201E-02 Extraneous predicted phases: 5.930647E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 45.578 0.0096 0.1808 0.0210 0.2053 0.0870 0.0007 0.0002 0.4903 0.0051 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0017 -0.0031 0.0053 0.0246 -0.0113 0.0027 0.0001 -0.0115 -0.0051 Composition Misfit: 0.163043E-01 Gt predicted* 54.412 0.0000 0.1391 0.1214 0.1262 0.1844 0.0032 0.0005 0.4180 0.0071 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0035 0.0174 -0.0462 0.0381 -0.0027 -0.0001 0.0041 -0.0071 Composition Misfit: 0.296977E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.011 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.329 -869416. MgO 158.876 -662324. Al2O3 76.632 -0.170532E+07 CaO 162.821 -772848. FeO 141.419 -362248. TiO2 2.099 -979683. Cr2O3 0.381 -0.129048E+07 SiO2 453.444 -916435. O2 6.241 -412764. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 106 converged, 102 successes so far. Misfit function evaluations this try => 144 Misfit this try = 3.261916E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.637791E-07 Bayes score, PP * exp(-Misfit) = 1.585230E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17413.3 1177.20 0.148594 0.396011 0.603989 Final coordinates: 13164.9 1314.65 0.314986 0.487069 0.512931 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.261834E-02 Extraneous predicted phases: 8.175030E-07 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.067 0.0087 0.1723 0.0289 0.2025 0.0976 0.0011 0.0003 0.4825 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0009 0.0054 -0.0026 0.0274 -0.0219 0.0023 0.0001 -0.0037 -0.0060 Composition Misfit: 0.139318E-01 Gt predicted* 55.932 0.0000 0.1421 0.1253 0.1135 0.1903 0.0025 0.0005 0.4200 0.0059 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0065 0.0135 -0.0335 0.0322 -0.0020 -0.0001 0.0022 -0.0059 Composition Misfit: 0.186866E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.816 -867321. MgO 156.123 -663465. Al2O3 83.984 -0.170814E+07 CaO 153.022 -776536. FeO 151.017 -361931. TiO2 1.908 -983540. Cr2O3 0.387 -0.129249E+07 SiO2 449.743 -923506. O2 5.946 -422287. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 107 converged, 103 successes so far. Misfit function evaluations this try => 245 Misfit this try = 7.819297E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.360533E-07 Bayes score, PP * exp(-Misfit) = 2.182988E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16026.5 987.718 0.284882 0.507890 0.492110 Final coordinates: 16445.6 1120.90 0.163737 9.164124E-02 0.908359 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.815668E-02 Extraneous predicted phases: 3.628309E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.981 0.0245 0.1647 0.0105 0.1872 0.0925 0.0004 0.0003 0.5125 0.0074 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0166 0.0131 0.0158 0.0426 -0.0168 0.0030 0.0000 -0.0337 -0.0074 Composition Misfit: 0.758268E-01 Gt predicted* 97.010 0.0000 0.1381 0.1314 0.0905 0.2117 0.0008 0.0004 0.4229 0.0042 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0025 0.0073 -0.0105 0.0108 -0.0003 0.0000 -0.0007 -0.0042 Composition Misfit: 0.232992E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.009 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.718 -805815. MgO 139.474 -641510. Al2O3 128.447 -0.166103E+07 CaO 93.758 -753577. FeO 209.065 -331875. TiO2 0.757 -956156. Cr2O3 0.421 -0.121729E+07 SiO2 427.361 -890897. O2 4.279 -399100. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 108 converged, 104 successes so far. Misfit function evaluations this try => 320 Misfit this try = 4.611180E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.318376E-08 Bayes score, PP * exp(-Misfit) = 1.258963E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16771.5 981.580 0.895024 0.660824 0.339176 Final coordinates: 17967.0 1345.12 0.347521 0.543124 0.456876 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.604618E-02 Extraneous predicted phases: 6.562136E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.658 0.0096 0.1806 0.0209 0.2049 0.0876 0.0007 0.0002 0.4905 0.0051 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0018 -0.0028 0.0054 0.0249 -0.0119 0.0027 0.0001 -0.0117 -0.0051 Composition Misfit: 0.172266E-01 Gt predicted* 55.331 0.0000 0.1393 0.1217 0.1253 0.1848 0.0031 0.0005 0.4182 0.0070 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0037 0.0171 -0.0453 0.0377 -0.0026 -0.0001 0.0040 -0.0070 Composition Misfit: 0.288196E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.011 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.255 -869203. MgO 158.483 -662399. Al2O3 77.681 -0.170541E+07 CaO 161.423 -772894. FeO 142.788 -362241. TiO2 2.072 -980300. Cr2O3 0.382 -0.129161E+07 SiO2 452.916 -916525. O2 6.203 -413411. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 109 converged, 105 successes so far. Misfit function evaluations this try => 226 Misfit this try = 2.347848E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 3.317163E-07 Bayes score, PP * exp(-Misfit) = 3.240189E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 11497.0 1083.73 0.435420 0.179986 0.820014 Final coordinates: 10334.9 1190.91 0.312076 0.481829 0.518171 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.347827E-02 Extraneous predicted phases: 2.182239E-07 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 42.009 0.0091 0.1758 0.0246 0.2083 0.0901 0.0014 0.0003 0.4843 0.0062 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0012 0.0019 0.0017 0.0216 -0.0144 0.0020 0.0001 -0.0055 -0.0062 Composition Misfit: 0.772811E-02 Gt predicted* 57.991 0.0000 0.1403 0.1261 0.1112 0.1938 0.0022 0.0005 0.4203 0.0057 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0047 0.0127 -0.0311 0.0287 -0.0017 -0.0000 0.0018 -0.0057 Composition Misfit: 0.157502E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.000 0.0000 0.0376 0.0305 0.0000 0.7899 0.0121 0.0013 0.0000 0.1286 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.775 -831316. MgO 155.902 -650115. Al2O3 84.573 -0.168731E+07 CaO 152.236 -764305. FeO 151.786 -344587. TiO2 1.893 -967052. Cr2O3 0.387 -0.125649E+07 SiO2 449.447 -916966. O2 5.921 -424263. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 110 converged, 106 successes so far. Misfit function evaluations this try => 570 Misfit this try = 7.614825E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 6.127111E-08 Bayes score, PP * exp(-Misfit) = 5.677864E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17369.5 1071.23 5.198769E-02 0.283432 0.716568 Final coordinates: 17035.3 1005.91 0.160515 8.135917E-02 0.918641 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.614319E-02 Extraneous predicted phases: 5.059405E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.191 0.0296 0.1608 0.0090 0.1859 0.0894 0.0008 0.0004 0.5142 0.0099 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0217 0.0169 0.0173 0.0440 -0.0137 0.0026 -0.0001 -0.0354 -0.0099 Composition Misfit: 0.741024E-01 Gt predicted* 97.805 0.0000 0.1380 0.1317 0.0898 0.2123 0.0007 0.0004 0.4230 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0024 0.0071 -0.0097 0.0102 -0.0002 0.0000 -0.0008 -0.0041 Composition Misfit: 0.204079E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.003 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.637 -782503. MgO 139.041 -630368. Al2O3 129.603 -0.163651E+07 CaO 92.217 -741984. FeO 210.574 -317423. TiO2 0.727 -929014. Cr2O3 0.422 -0.117727E+07 SiO2 426.779 -875995. O2 4.225 -377660. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 111 converged, 107 successes so far. Misfit function evaluations this try => 310 Misfit this try = 7.497755E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 9.933483E-08 Bayes score, PP * exp(-Misfit) = 9.215931E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15382.0 979.073 0.116226 0.664264 0.335736 Final coordinates: 16398.7 1013.36 0.159868 8.150369E-02 0.918496 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.470009E-02 Extraneous predicted phases: 2.774574E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.261 0.0287 0.1616 0.0091 0.1868 0.0892 0.0008 0.0004 0.5138 0.0095 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0209 0.0161 0.0172 0.0431 -0.0135 0.0026 -0.0001 -0.0351 -0.0095 Composition Misfit: 0.726749E-01 Gt predicted* 97.727 0.0000 0.1380 0.1318 0.0897 0.2123 0.0007 0.0004 0.4231 0.0040 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0023 0.0070 -0.0097 0.0102 -0.0002 0.0000 -0.0009 -0.0040 Composition Misfit: 0.202522E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.013 0.0000 0.0284 0.0117 0.0000 0.8189 0.0004 0.0017 0.0000 0.1389 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.639 -771286. MgO 139.047 -628203. Al2O3 129.587 -0.163940E+07 CaO 92.238 -740107. FeO 210.553 -315435. TiO2 0.727 -934395. Cr2O3 0.422 -0.118276E+07 SiO2 426.787 -881666. O2 4.208 -394236. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 112 converged, 108 successes so far. Misfit function evaluations this try => 209 Misfit this try = 7.716881E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.034544E-07 Bayes score, PP * exp(-Misfit) = 1.883446E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14056.5 1162.04 0.606465 0.167691 0.832309 Final coordinates: 16602.5 1104.73 0.164518 8.820538E-02 0.911795 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.664890E-02 Extraneous predicted phases: 5.199048E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.619 0.0268 0.1606 0.0107 0.1849 0.0943 0.0005 0.0004 0.5136 0.0083 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0190 0.0171 0.0156 0.0450 -0.0186 0.0030 -0.0000 -0.0348 -0.0083 Composition Misfit: 0.743483E-01 Gt predicted* 97.347 0.0000 0.1382 0.1314 0.0904 0.2117 0.0008 0.0004 0.4229 0.0042 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0026 0.0073 -0.0104 0.0108 -0.0003 0.0000 -0.0007 -0.0042 Composition Misfit: 0.230057E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.033 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.691 -801308. MgO 139.329 -639910. Al2O3 128.833 -0.165716E+07 CaO 93.243 -751929. FeO 209.569 -329777. TiO2 0.747 -951610. Cr2O3 0.421 -0.121238E+07 SiO2 427.166 -888575. O2 4.310 -394518. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 113 converged, 109 successes so far. Misfit function evaluations this try => 338 Misfit this try = 4.593335E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.219083E-08 Bayes score, PP * exp(-Misfit) = 1.164353E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16914.5 1015.69 0.941025 0.804992 0.195008 Final coordinates: 17978.1 1348.64 0.342548 0.535599 0.464401 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.591402E-02 Extraneous predicted phases: 1.933358E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.019 0.0096 0.1804 0.0210 0.2045 0.0881 0.0007 0.0002 0.4905 0.0050 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0018 -0.0027 0.0053 0.0254 -0.0123 0.0027 0.0001 -0.0117 -0.0050 Composition Misfit: 0.178629E-01 Gt predicted* 55.975 0.0000 0.1394 0.1219 0.1246 0.1853 0.0031 0.0005 0.4183 0.0070 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0038 0.0168 -0.0445 0.0372 -0.0026 -0.0001 0.0039 -0.0070 Composition Misfit: 0.280512E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.006 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.196 -869952. MgO 158.166 -662712. Al2O3 78.527 -0.170625E+07 CaO 160.295 -773318. FeO 143.893 -362648. TiO2 2.050 -981461. Cr2O3 0.383 -0.129296E+07 SiO2 452.490 -916983. O2 6.161 -414204. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 114 converged, 110 successes so far. Misfit function evaluations this try => 649 Misfit this try = 4.701940E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.937824E-08 Bayes score, PP * exp(-Misfit) = 1.848818E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13638.5 1016.12 0.786912 0.342976 0.657024 Final coordinates: 17962.0 1324.49 0.358720 0.561126 0.438874 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.691891E-02 Extraneous predicted phases: 1.004903E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 45.667 0.0097 0.1822 0.0196 0.2065 0.0847 0.0007 0.0002 0.4914 0.0050 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0018 -0.0045 0.0067 0.0234 -0.0090 0.0027 0.0001 -0.0126 -0.0050 Composition Misfit: 0.162726E-01 Gt predicted* 54.320 0.0000 0.1386 0.1210 0.1274 0.1842 0.0032 0.0005 0.4178 0.0073 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0030 0.0178 -0.0474 0.0383 -0.0027 -0.0001 0.0043 -0.0073 Composition Misfit: 0.306463E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.014 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.396 -865079. MgO 159.241 -660232. Al2O3 75.657 -0.170082E+07 CaO 164.121 -770664. FeO 140.146 -359506. TiO2 2.124 -975279. Cr2O3 0.380 -0.128363E+07 SiO2 453.935 -913722. O2 6.284 -409668. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 115 converged, 111 successes so far. Misfit function evaluations this try => 347 Misfit this try = 3.878939E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 4.516233E-08 Bayes score, PP * exp(-Misfit) = 4.344405E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14078.7 1230.86 0.848437 0.406930 0.593070 Final coordinates: 15896.0 1348.74 0.314958 0.487623 0.512377 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.876199E-02 Extraneous predicted phases: 2.740008E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 41.581 0.0093 0.1759 0.0248 0.2020 0.0945 0.0008 0.0002 0.4871 0.0054 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0014 0.0018 0.0015 0.0279 -0.0187 0.0026 0.0001 -0.0084 -0.0054 Composition Misfit: 0.169011E-01 Gt predicted* 58.415 0.0000 0.1409 0.1241 0.1176 0.1886 0.0027 0.0005 0.4194 0.0063 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0053 0.0147 -0.0376 0.0339 -0.0022 -0.0001 0.0028 -0.0063 Composition Misfit: 0.218609E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0442 0.0616 0.0000 0.7632 0.0090 0.0009 0.0000 0.1212 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.821 -824174. MgO 156.146 -652824. Al2O3 83.922 -0.171046E+07 CaO 153.105 -764505. FeO 150.936 -352360. TiO2 1.910 -998182. Cr2O3 0.387 -0.129839E+07 SiO2 449.775 -933630. O2 5.942 -468743. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 116 converged, 112 successes so far. Misfit function evaluations this try => 158 Misfit this try = 3.341434E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.346088E-07 Bayes score, PP * exp(-Misfit) = 1.301853E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8915.55 1322.99 0.864193 0.440926 0.559074 Final coordinates: 12811.3 1326.12 0.299072 0.456287 0.543713 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.340531E-02 Extraneous predicted phases: 9.030531E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 41.683 0.0087 0.1706 0.0306 0.2004 0.1010 0.0011 0.0003 0.4815 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0008 0.0071 -0.0042 0.0295 -0.0252 0.0023 0.0001 -0.0027 -0.0060 Composition Misfit: 0.168776E-01 Gt predicted* 58.313 0.0000 0.1423 0.1261 0.1109 0.1919 0.0023 0.0005 0.4204 0.0056 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0067 0.0127 -0.0309 0.0306 -0.0018 -0.0000 0.0018 -0.0056 Composition Misfit: 0.165277E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Fsp 0.004 0.0215 0.0000 0.2285 0.2070 0.0000 0.0000 0.0000 0.5430 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.575 -869021. MgO 154.827 -664799. Al2O3 87.445 -0.171134E+07 CaO 148.408 -778135. FeO 155.536 -363520. TiO2 1.819 -987729. Cr2O3 0.390 -0.129785E+07 SiO2 448.001 -926081. O2 5.815 -426742. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 117 converged, 113 successes so far. Misfit function evaluations this try => 362 Misfit this try = 3.206224E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.026442E-07 Bayes score, PP * exp(-Misfit) = 1.962500E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15968.3 1192.68 0.495496 0.155406 0.844594 Final coordinates: 13027.5 1301.30 0.286981 0.432048 0.567952 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.204833E-02 Extraneous predicted phases: 1.390254E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 37.330 0.0092 0.1730 0.0267 0.2013 0.0979 0.0009 0.0002 0.4850 0.0057 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0013 0.0047 -0.0004 0.0286 -0.0222 0.0025 0.0001 -0.0062 -0.0057 Composition Misfit: 0.162279E-01 Gt predicted* 62.667 0.0000 0.1413 0.1262 0.1107 0.1931 0.0022 0.0005 0.4204 0.0056 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0057 0.0126 -0.0307 0.0294 -0.0017 -0.0000 0.0018 -0.0056 Composition Misfit: 0.158205E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.003 0.0000 0.0405 0.0536 0.0000 0.7724 0.0089 0.0012 0.0000 0.1234 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.385 -829557. MgO 153.806 -653637. Al2O3 90.171 -0.170574E+07 CaO 144.775 -766812. FeO 159.094 -351396. TiO2 1.748 -991825. Cr2O3 0.392 -0.128882E+07 SiO2 446.629 -930563. O2 5.707 -457499. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 118 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 119 converged, 114 successes so far. Misfit function evaluations this try => 229 Misfit this try = 4.585967E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 3.344318E-08 Bayes score, PP * exp(-Misfit) = 3.194412E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14782.3 1158.92 0.679573 0.846675 0.153325 Final coordinates: 17508.8 1312.48 0.335472 0.524271 0.475729 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.585914E-02 Extraneous predicted phases: 5.314012E-07 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 41.968 0.0098 0.1822 0.0187 0.2054 0.0857 0.0007 0.0002 0.4924 0.0049 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0020 -0.0045 0.0076 0.0245 -0.0100 0.0027 0.0001 -0.0136 -0.0049 Composition Misfit: 0.190088E-01 Gt predicted* 58.031 0.0000 0.1387 0.1222 0.1238 0.1865 0.0029 0.0005 0.4184 0.0069 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0031 0.0165 -0.0438 0.0360 -0.0025 -0.0001 0.0037 -0.0069 Composition Misfit: 0.268503E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.108 -862350. MgO 157.689 -659348. Al2O3 79.801 -0.169928E+07 CaO 158.597 -770125. FeO 145.556 -357948. TiO2 2.017 -975407. Cr2O3 0.384 -0.127994E+07 SiO2 451.849 -913142. O2 6.104 -411250. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 120 converged, 115 successes so far. Misfit function evaluations this try => 244 Misfit this try = 5.707084E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 3.522299E-07 Bayes score, PP * exp(-Misfit) = 3.326907E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10090.1 1084.77 4.885566E-02 0.114401 0.885599 Final coordinates: 10977.5 1077.25 0.166242 9.963975E-02 0.900360 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 5.699618E-02 Extraneous predicted phases: 7.465361E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 3.750 0.0212 0.1665 0.0119 0.1930 0.0928 0.0005 0.0003 0.5060 0.0076 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0133 0.0112 0.0144 0.0369 -0.0171 0.0029 0.0000 -0.0272 -0.0076 Composition Misfit: 0.545557E-01 Gt predicted* 96.238 0.0000 0.1382 0.1314 0.0908 0.2114 0.0008 0.0004 0.4229 0.0042 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0026 0.0074 -0.0108 0.0111 -0.0003 0.0000 -0.0007 -0.0042 Composition Misfit: 0.244045E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.013 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.781 -806935. MgO 139.810 -642092. Al2O3 127.548 -0.166338E+07 CaO 94.956 -756353. FeO 207.891 -331570. TiO2 0.780 -953991. Cr2O3 0.420 -0.121655E+07 SiO2 427.813 -898116. O2 4.320 -400336. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 121 converged, 116 successes so far. Misfit function evaluations this try => 290 Misfit this try = 2.408355E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.454267E-07 Bayes score, PP * exp(-Misfit) = 2.395865E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8848.30 1299.03 0.369321 0.291669 0.708331 Final coordinates: 9911.15 1211.63 0.332532 0.520054 0.479946 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.395411E-02 Extraneous predicted phases: 1.294394E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 48.303 0.0085 0.1728 0.0287 0.2080 0.0932 0.0017 0.0003 0.4803 0.0065 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0007 0.0049 -0.0024 0.0219 -0.0175 0.0017 0.0001 -0.0016 -0.0065 Composition Misfit: 0.779442E-02 Gt predicted* 51.689 0.0000 0.1418 0.1262 0.1108 0.1925 0.0023 0.0005 0.4204 0.0056 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0062 0.0125 -0.0307 0.0301 -0.0018 -0.0000 0.0018 -0.0056 Composition Misfit: 0.161597E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.008 0.0000 0.0389 0.0350 0.0000 0.7846 0.0134 0.0013 0.0000 0.1267 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.075 -836126. MgO 157.512 -652409. Al2O3 80.275 -0.169223E+07 CaO 157.965 -766842. FeO 146.175 -347689. TiO2 2.004 -971553. Cr2O3 0.384 -0.126394E+07 SiO2 451.610 -920782. O2 6.076 -427983. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 122 converged, 117 successes so far. Misfit function evaluations this try => 408 Misfit this try = 3.173453E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 3.050164E-07 Bayes score, PP * exp(-Misfit) = 2.954889E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8716.35 1056.31 0.939003 0.295384 0.704616 Final coordinates: 13478.8 1269.79 0.317015 0.491079 0.508921 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.173452E-02 Extraneous predicted phases: 9.684257E-09 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 41.736 0.0093 0.1770 0.0236 0.2053 0.0911 0.0010 0.0002 0.4869 0.0056 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0015 0.0008 0.0027 0.0246 -0.0153 0.0024 0.0001 -0.0082 -0.0056 Composition Misfit: 0.117516E-01 Gt predicted* 58.264 0.0000 0.1403 0.1246 0.1160 0.1904 0.0025 0.0005 0.4196 0.0061 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0047 0.0142 -0.0360 0.0321 -0.0020 -0.0001 0.0026 -0.0061 Composition Misfit: 0.199830E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.848 -857161. MgO 156.292 -658481. Al2O3 83.533 -0.169787E+07 CaO 153.623 -771291. FeO 150.429 -355571. TiO2 1.920 -974107. Cr2O3 0.387 -0.127578E+07 SiO2 449.970 -916761. O2 5.961 -415215. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 123 converged, 118 successes so far. Misfit function evaluations this try => 381 Misfit this try = 3.367409E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.250401E-07 Bayes score, PP * exp(-Misfit) = 1.208995E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 11938.0 1326.72 9.184474E-02 0.114500 0.885500 Final coordinates: 12762.7 1330.17 0.288866 0.436068 0.563932 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.364964E-02 Extraneous predicted phases: 2.445602E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 39.663 0.0087 0.1702 0.0308 0.1994 0.1021 0.0010 0.0003 0.4816 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0009 0.0076 -0.0045 0.0305 -0.0264 0.0024 0.0001 -0.0028 -0.0060 Composition Misfit: 0.183113E-01 Gt predicted* 60.334 0.0000 0.1422 0.1265 0.1096 0.1930 0.0022 0.0005 0.4206 0.0055 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0066 0.0122 -0.0295 0.0295 -0.0017 -0.0000 0.0016 -0.0055 Composition Misfit: 0.153383E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0441 0.0671 0.0000 0.7591 0.0092 0.0010 0.0000 0.1194 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.417 -835236. MgO 153.975 -656728. Al2O3 89.719 -0.171239E+07 CaO 145.378 -770081. FeO 158.504 -355426. TiO2 1.760 -998196. Cr2O3 0.391 -0.129978E+07 SiO2 446.856 -935322. O2 5.723 -462663. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 124 converged, 119 successes so far. Misfit function evaluations this try => 190 Misfit this try = 4.591738E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.231226E-08 Bayes score, PP * exp(-Misfit) = 1.175970E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14915.3 1157.38 0.787317 0.948463 5.153725E-02 Final coordinates: 17984.0 1347.91 0.351100 0.549928 0.450072 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.589587E-02 Extraneous predicted phases: 2.150447E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 45.476 0.0095 0.1805 0.0212 0.2051 0.0875 0.0007 0.0002 0.4901 0.0051 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0017 -0.0028 0.0051 0.0248 -0.0118 0.0027 0.0001 -0.0114 -0.0051 Composition Misfit: 0.165018E-01 Gt predicted* 54.517 0.0000 0.1392 0.1215 0.1259 0.1845 0.0032 0.0005 0.4181 0.0071 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0036 0.0172 -0.0458 0.0380 -0.0027 -0.0001 0.0041 -0.0071 Composition Misfit: 0.293941E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.006 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.309 -869933. MgO 158.769 -662667. Al2O3 76.916 -0.170597E+07 CaO 162.442 -773164. FeO 141.790 -362661. TiO2 2.091 -980327. Cr2O3 0.381 -0.129198E+07 SiO2 453.301 -916868. O2 6.223 -413579. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 125 converged, 120 successes so far. Misfit function evaluations this try => 731 Misfit this try = 0.607265 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 7.799338E-08 Bayes score, PP * exp(-Misfit) = 4.249382E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 11235.7 1070.79 0.830197 0.504360 0.495640 Final coordinates: 17999.4 1194.73 0.895315 1.00000 4.350838E-07 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.186891 Extraneous predicted phases: 0.420374 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 91.207 0.0085 0.1856 0.0208 0.2284 0.0645 0.0008 0.0003 0.4841 0.0070 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0007 -0.0079 0.0055 0.0015 0.0112 0.0026 0.0000 -0.0053 -0.0070 Composition Misfit: 0.120045E-01 Gt predicted* 8.041 0.0000 0.0896 0.0872 0.2277 0.1679 0.0069 0.0007 0.4007 0.0194 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 0.0460 0.0515 -0.1477 0.0546 -0.0064 -0.0003 0.0215 -0.0194 Composition Misfit: 0.174886 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.301 0.0000 0.0000 0.0000 0.0000 0.6926 0.1789 0.0000 0.0000 0.1284 sph 0.452 0.0000 0.0000 0.0000 0.3333 0.0000 0.3333 0.0000 0.3333 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 7.835 -834274. MgO 177.719 -647163. Al2O3 26.309 -0.167142E+07 CaO 229.896 -752485. FeO 75.720 -344656. TiO2 3.402 -947932. Cr2O3 0.342 -0.123008E+07 SiO2 478.777 -898625. O2 8.474 -369408. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 126 converged, 121 successes so far. Misfit function evaluations this try => 201 Misfit this try = 0.106712 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 3.177569E-08 Bayes score, PP * exp(-Misfit) = 2.855948E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17447.0 1286.07 0.331256 7.689500E-02 0.923105 Final coordinates: 17704.0 1306.67 0.164073 9.215323E-02 0.907847 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.106650 Extraneous predicted phases: 6.231029E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 3.113 0.0237 0.1572 0.0163 0.1753 0.1097 0.0002 0.0003 0.5110 0.0064 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0158 0.0206 0.0100 0.0546 -0.0340 0.0032 0.0001 -0.0322 -0.0064 Composition Misfit: 0.104172 Gt predicted* 96.875 0.0000 0.1383 0.1313 0.0909 0.2112 0.0008 0.0004 0.4228 0.0042 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0027 0.0074 -0.0109 0.0113 -0.0003 0.0000 -0.0007 -0.0042 Composition Misfit: 0.247811E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.012 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.722 -839892. MgO 139.495 -659071. Al2O3 128.389 -0.169784E+07 CaO 93.834 -771133. FeO 208.990 -354881. TiO2 0.758 -996705. Cr2O3 0.421 -0.128163E+07 SiO2 427.390 -911906. O2 4.286 -424542. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 127 converged, 122 successes so far. Misfit function evaluations this try => 400 Misfit this try = 4.664107E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.521212E-08 Bayes score, PP * exp(-Misfit) = 2.406320E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17486.5 1118.55 0.816740 0.209513 0.790487 Final coordinates: 17754.5 1318.55 0.344542 0.540435 0.459565 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.660880E-02 Extraneous predicted phases: 3.226983E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 43.613 0.0098 0.1822 0.0191 0.2059 0.0852 0.0007 0.0002 0.4920 0.0049 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0019 -0.0045 0.0072 0.0240 -0.0095 0.0027 0.0001 -0.0132 -0.0049 Composition Misfit: 0.182105E-01 Gt predicted* 56.383 0.0000 0.1386 0.1218 0.1253 0.1855 0.0031 0.0005 0.4182 0.0070 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0030 0.0170 -0.0452 0.0370 -0.0026 -0.0001 0.0040 -0.0070 Composition Misfit: 0.283983E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0428 0.0461 0.0000 0.7751 0.0098 0.0010 0.0000 0.1252 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.234 -812418. MgO 158.370 -646923. Al2O3 77.983 -0.170005E+07 CaO 161.020 -757531. FeO 143.183 -345845. TiO2 2.064 -988061. Cr2O3 0.382 -0.128210E+07 SiO2 452.764 -926240. O2 6.167 -462376. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 128 converged, 123 successes so far. Misfit function evaluations this try => 139 Misfit this try = 2.193279E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.632081E-07 Bayes score, PP * exp(-Misfit) = 2.574981E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8941.34 1139.86 0.286801 0.238863 0.761137 Final coordinates: 9702.89 1166.46 0.264647 0.383947 0.616053 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.177848E-02 Extraneous predicted phases: 1.543070E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 31.506 0.0097 0.1759 0.0223 0.2068 0.0909 0.0012 0.0003 0.4870 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0018 0.0018 0.0040 0.0231 -0.0152 0.0022 0.0001 -0.0082 -0.0060 Composition Misfit: 0.107399E-01 Gt predicted* 68.485 0.0000 0.1398 0.1278 0.1054 0.1985 0.0018 0.0004 0.4211 0.0052 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0041 0.0110 -0.0254 0.0240 -0.0013 -0.0000 0.0010 -0.0052 Composition Misfit: 0.110385E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.009 0.0000 0.0346 0.0282 0.0000 0.7966 0.0083 0.0014 0.0000 0.1308 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.008 -829206. MgO 151.781 -649134. Al2O3 95.579 -0.168389E+07 CaO 137.566 -763698. FeO 166.155 -342422. TiO2 1.608 -965309. Cr2O3 0.396 -0.125016E+07 SiO2 443.906 -914428. O2 5.497 -421627. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 129 converged, 124 successes so far. Misfit function evaluations this try => 205 Misfit this try = 2.993935E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.292738E-07 Bayes score, PP * exp(-Misfit) = 2.225113E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14562.9 1167.15 0.724435 0.357211 0.642789 Final coordinates: 11967.5 1286.82 0.317203 0.491703 0.508297 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.992701E-02 Extraneous predicted phases: 1.234495E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 45.202 0.0086 0.1718 0.0296 0.2036 0.0973 0.0013 0.0003 0.4813 0.0062 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0008 0.0059 -0.0033 0.0263 -0.0216 0.0021 0.0001 -0.0025 -0.0062 Composition Misfit: 0.124102E-01 Gt predicted* 54.796 0.0000 0.1422 0.1257 0.1121 0.1912 0.0024 0.0005 0.4202 0.0057 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0066 0.0130 -0.0321 0.0313 -0.0019 -0.0000 0.0020 -0.0057 Composition Misfit: 0.175168E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.003 0.0000 0.0421 0.0503 0.0000 0.7710 0.0127 0.0011 0.0000 0.1227 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.853 -834811. MgO 156.318 -654651. Al2O3 83.463 -0.170431E+07 CaO 153.716 -768267. FeO 150.337 -352266. TiO2 1.922 -986915. Cr2O3 0.386 -0.128587E+07 SiO2 450.005 -929515. O2 5.961 -449034. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 130 converged, 125 successes so far. Misfit function evaluations this try => 247 Misfit this try = 7.686673E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 7.339100E-08 Bayes score, PP * exp(-Misfit) = 6.796104E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9758.56 1187.74 0.948310 0.145369 0.854631 Final coordinates: 16910.4 1013.10 0.161575 8.291086E-02 0.917089 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.679581E-02 Extraneous predicted phases: 7.091689E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.278 0.0290 0.1613 0.0090 0.1864 0.0896 0.0007 0.0004 0.5139 0.0096 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0212 0.0164 0.0173 0.0435 -0.0138 0.0027 -0.0001 -0.0352 -0.0096 Composition Misfit: 0.747013E-01 Gt predicted* 97.710 0.0000 0.1380 0.1316 0.0899 0.2122 0.0007 0.0004 0.4230 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0024 0.0071 -0.0099 0.0103 -0.0002 0.0000 -0.0008 -0.0041 Composition Misfit: 0.209455E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.012 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.650 -784258. MgO 139.106 -631097. Al2O3 129.429 -0.163828E+07 CaO 92.449 -742807. FeO 210.347 -318346. TiO2 0.731 -930770. Cr2O3 0.422 -0.118050E+07 SiO2 426.867 -877097. O2 4.248 -379057. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 131 converged, 126 successes so far. Misfit function evaluations this try => 609 Misfit this try = 4.539595E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.532626E-08 Bayes score, PP * exp(-Misfit) = 1.464607E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17448.1 1139.56 0.578993 0.703335 0.296665 Final coordinates: 17815.6 1343.46 0.354417 0.554936 0.445064 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.535281E-02 Extraneous predicted phases: 4.314952E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 46.009 0.0095 0.1805 0.0213 0.2055 0.0872 0.0007 0.0002 0.4900 0.0051 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0017 -0.0028 0.0050 0.0244 -0.0115 0.0027 0.0001 -0.0112 -0.0051 Composition Misfit: 0.156687E-01 Gt predicted* 53.982 0.0000 0.1393 0.1214 0.1261 0.1844 0.0032 0.0005 0.4180 0.0071 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0037 0.0174 -0.0461 0.0382 -0.0027 -0.0001 0.0041 -0.0071 Composition Misfit: 0.296841E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.009 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.348 -869185. MgO 158.980 -662368. Al2O3 76.353 -0.170532E+07 CaO 163.193 -772902. FeO 141.054 -362209. TiO2 2.106 -978839. Cr2O3 0.381 -0.129108E+07 SiO2 453.585 -916648. O2 6.249 -413154. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 132 converged, 127 successes so far. Misfit function evaluations this try => 300 Misfit this try = 2.790446E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 4.170284E-07 Bayes score, PP * exp(-Misfit) = 4.055523E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13163.0 1172.76 0.245147 0.657703 0.342297 Final coordinates: 11736.0 1226.84 0.351133 0.551331 0.448669 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.789084E-02 Extraneous predicted phases: 1.361697E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 49.199 0.0088 0.1766 0.0255 0.2087 0.0889 0.0015 0.0003 0.4836 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0010 0.0011 0.0008 0.0212 -0.0131 0.0019 0.0001 -0.0048 -0.0061 Composition Misfit: 0.675000E-02 Gt predicted* 50.798 0.0000 0.1402 0.1242 0.1172 0.1896 0.0026 0.0005 0.4194 0.0062 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0046 0.0145 -0.0372 0.0329 -0.0021 -0.0001 0.0027 -0.0062 Composition Misfit: 0.211408E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.003 0.0000 0.0407 0.0341 0.0000 0.7826 0.0150 0.0012 0.0000 0.1263 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.320 -830554. MgO 158.828 -650608. Al2O3 76.758 -0.169179E+07 CaO 162.653 -764079. FeO 141.584 -346592. TiO2 2.096 -971519. Cr2O3 0.381 -0.126476E+07 SiO2 453.381 -920234. O2 6.214 -431079. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 133 converged, 128 successes so far. Misfit function evaluations this try => 288 Misfit this try = 4.282429E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 3.487292E-07 Bayes score, PP * exp(-Misfit) = 3.341104E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10987.6 1059.38 0.767645 0.198292 0.801708 Final coordinates: 10286.4 1166.00 0.180227 0.149867 0.850133 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.267687E-02 Extraneous predicted phases: 1.474245E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 8.468 0.0141 0.1709 0.0174 0.1964 0.0978 0.0004 0.0003 0.4967 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0062 0.0068 0.0089 0.0335 -0.0221 0.0030 0.0001 -0.0180 -0.0060 Composition Misfit: 0.390527E-01 Gt predicted* 91.515 0.0000 0.1386 0.1307 0.0935 0.2088 0.0010 0.0004 0.4226 0.0044 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0030 0.0080 -0.0135 0.0137 -0.0005 0.0000 -0.0004 -0.0044 Composition Misfit: 0.362414E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Fsp 0.017 0.0307 0.0000 0.2193 0.1885 0.0000 0.0000 0.0000 0.5615 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 1.174 -827999. MgO 141.925 -650349. Al2O3 121.900 -0.168330E+07 CaO 102.484 -765044. FeO 200.518 -342638. TiO2 0.926 -972901. Cr2O3 0.416 -0.124950E+07 SiO2 430.656 -911316. O2 4.517 -419350. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 134 converged, 129 successes so far. Misfit function evaluations this try => 360 Misfit this try = 9.269391E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 8.659278E-08 Bayes score, PP * exp(-Misfit) = 7.892694E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16061.9 1324.67 6.183050E-02 0.224965 0.775035 Final coordinates: 16321.8 1299.15 0.179263 0.146336 0.853664 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 9.268116E-02 Extraneous predicted phases: 1.274380E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 7.716 0.0151 0.1718 0.0152 0.1863 0.1036 0.0002 0.0002 0.5028 0.0048 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0072 0.0059 0.0111 0.0436 -0.0279 0.0032 0.0001 -0.0240 -0.0048 Composition Misfit: 0.886134E-01 Gt predicted* 92.279 0.0000 0.1386 0.1305 0.0946 0.2081 0.0010 0.0004 0.4224 0.0045 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0030 0.0083 -0.0145 0.0145 -0.0005 -0.0000 -0.0002 -0.0045 Composition Misfit: 0.406775E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.005 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 1.147 -849804. MgO 141.776 -659089. Al2O3 122.297 -0.170003E+07 CaO 101.955 -771458. FeO 201.036 -355015. TiO2 0.916 -994687. Cr2O3 0.416 -0.128202E+07 SiO2 430.457 -914090. O2 4.505 -427888. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 135 converged, 130 successes so far. Misfit function evaluations this try => 189 Misfit this try = 3.126796E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.755581E-07 Bayes score, PP * exp(-Misfit) = 2.670753E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16883.8 1211.55 0.168914 0.856436 0.143564 Final coordinates: 13123.6 1279.32 0.319037 0.494716 0.505284 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.126762E-02 Extraneous predicted phases: 3.419833E-07 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 43.092 0.0091 0.1754 0.0255 0.2047 0.0930 0.0011 0.0003 0.4852 0.0058 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0012 0.0023 0.0008 0.0252 -0.0173 0.0023 0.0001 -0.0064 -0.0058 Composition Misfit: 0.116137E-01 Gt predicted* 56.907 0.0000 0.1409 0.1248 0.1153 0.1903 0.0025 0.0005 0.4197 0.0060 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0052 0.0140 -0.0352 0.0322 -0.0020 -0.0001 0.0025 -0.0060 Composition Misfit: 0.196539E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.876 -859725. MgO 156.445 -659811. Al2O3 83.124 -0.170053E+07 CaO 154.168 -772765. FeO 149.895 -357212. TiO2 1.931 -976341. Cr2O3 0.386 -0.128058E+07 SiO2 450.176 -918855. O2 5.978 -417299. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 136 converged, 131 successes so far. Misfit function evaluations this try => 299 Misfit this try = 4.600093E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 4.268265E-08 Bayes score, PP * exp(-Misfit) = 4.076369E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10136.7 1314.75 0.850523 6.595662E-02 0.934043 Final coordinates: 17319.0 1305.57 0.368613 0.579181 0.420819 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.600093E-02 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 47.524 0.0096 0.1825 0.0196 0.2077 0.0835 0.0008 0.0002 0.4909 0.0051 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0018 -0.0048 0.0067 0.0222 -0.0078 0.0026 0.0001 -0.0122 -0.0051 Composition Misfit: 0.141726E-01 Gt predicted* 52.476 0.0000 0.1381 0.1206 0.1286 0.1837 0.0033 0.0005 0.4177 0.0074 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0025 0.0181 -0.0486 0.0388 -0.0029 -0.0001 0.0045 -0.0074 Composition Misfit: 0.318284E-01 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.538 -861946. MgO 160.001 -658852. Al2O3 73.627 -0.169784E+07 CaO 166.827 -769505. FeO 137.495 -357589. TiO2 2.177 -971761. Cr2O3 0.379 -0.127831E+07 SiO2 454.957 -912648. O2 6.335 -407742. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 137 converged, 132 successes so far. Misfit function evaluations this try => 213 Misfit this try = 4.026657E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 8.913491E-08 Bayes score, PP * exp(-Misfit) = 8.561706E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12289.3 1330.30 0.627940 0.897022 0.102978 Final coordinates: 10723.8 1326.15 0.512829 0.760784 0.239216 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.025562E-02 Extraneous predicted phases: 1.095726E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 88.669 0.0067 0.1682 0.0432 0.2036 0.1005 0.0027 0.0003 0.4675 0.0072 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual 0.0011 0.0095 -0.0169 0.0263 -0.0248 0.0007 -0.0000 0.0113 -0.0072 Composition Misfit: 0.173190E-01 Gt predicted* 11.329 0.0000 0.1533 0.1255 0.1104 0.1818 0.0029 0.0005 0.4201 0.0056 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0177 0.0133 -0.0303 0.0408 -0.0024 -0.0001 0.0020 -0.0056 Composition Misfit: 0.229366E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.002 0.0000 0.0557 0.0648 0.0000 0.7402 0.0249 0.0011 0.0000 0.1134 Effective Bulk* Chemical Potentials (J/mol) Na2O 5.961 -853194. MgO 167.647 -660750. Al2O3 53.207 -0.171415E+07 CaO 194.044 -775591. FeO 110.836 -360954. TiO2 2.705 -990519. Cr2O3 0.363 -0.130048E+07 SiO2 465.236 -936611. O2 7.105 -445752. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 138 converged, 133 successes so far. Misfit function evaluations this try => 671 Misfit this try = 3.499675E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 8.977875E-08 Bayes score, PP * exp(-Misfit) = 8.669113E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17363.5 1074.43 0.899432 0.697350 0.302650 Final coordinates: 13490.9 1346.95 0.307640 0.473283 0.526717 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.499675E-02 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 43.661 0.0086 0.1709 0.0312 0.2001 0.1008 0.0011 0.0003 0.4812 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0008 0.0068 -0.0048 0.0298 -0.0251 0.0023 0.0001 -0.0024 -0.0060 Composition Misfit: 0.170623E-01 Gt predicted* 56.339 0.0000 0.1424 0.1256 0.1125 0.1908 0.0025 0.0005 0.4201 0.0058 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0068 0.0132 -0.0324 0.0317 -0.0020 -0.0000 0.0021 -0.0058 Composition Misfit: 0.179345E-01 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.708 -873832. MgO 155.542 -666617. Al2O3 85.534 -0.171452E+07 CaO 150.955 -779599. FeO 153.041 -366098. TiO2 1.868 -990014. Cr2O3 0.388 -0.130288E+07 SiO2 448.963 -927149. O2 5.885 -426810. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 139 converged, 134 successes so far. Misfit function evaluations this try => 461 Misfit this try = 4.566889E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.826240E-08 Bayes score, PP * exp(-Misfit) = 2.700072E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8668.02 978.357 0.925708 0.944272 5.572761E-02 Final coordinates: 17576.1 1319.67 0.357097 0.558871 0.441129 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.559794E-02 Extraneous predicted phases: 7.094745E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 45.681 0.0096 0.1820 0.0199 0.2065 0.0849 0.0008 0.0002 0.4910 0.0050 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0018 -0.0042 0.0064 0.0234 -0.0092 0.0026 0.0001 -0.0123 -0.0050 Composition Misfit: 0.156010E-01 Gt predicted* 54.308 0.0000 0.1386 0.1212 0.1268 0.1846 0.0032 0.0005 0.4179 0.0072 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0030 0.0176 -0.0468 0.0379 -0.0027 -0.0001 0.0042 -0.0072 Composition Misfit: 0.299969E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.012 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.379 -864438. MgO 159.146 -660057. Al2O3 75.910 -0.170051E+07 CaO 163.783 -770703. FeO 140.477 -359179. TiO2 2.117 -975135. Cr2O3 0.381 -0.128237E+07 SiO2 453.807 -913960. O2 6.270 -409911. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 140 converged, 135 successes so far. Misfit function evaluations this try => 630 Misfit this try = 4.593838E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.301206E-08 Bayes score, PP * exp(-Misfit) = 1.242783E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8645.01 972.676 7.268786E-02 0.480363 0.519637 Final coordinates: 17976.1 1345.42 0.345387 0.540608 0.459392 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.592524E-02 Extraneous predicted phases: 1.314148E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.385 0.0096 0.1807 0.0208 0.2048 0.0876 0.0007 0.0002 0.4906 0.0050 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0018 -0.0030 0.0055 0.0251 -0.0119 0.0027 0.0001 -0.0119 -0.0050 Composition Misfit: 0.173129E-01 Gt predicted* 55.610 0.0000 0.1392 0.1218 0.1252 0.1850 0.0031 0.0005 0.4182 0.0070 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0036 0.0170 -0.0451 0.0375 -0.0026 -0.0001 0.0040 -0.0070 Composition Misfit: 0.286124E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.005 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.236 -869219. MgO 158.377 -662445. Al2O3 77.964 -0.170549E+07 CaO 161.046 -772896. FeO 143.158 -362230. TiO2 2.064 -980269. Cr2O3 0.382 -0.129126E+07 SiO2 452.774 -916545. O2 6.181 -414114. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 141 converged, 136 successes so far. Misfit function evaluations this try => 240 Misfit this try = 2.447980E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.277942E-07 Bayes score, PP * exp(-Misfit) = 2.222855E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14089.0 981.335 0.675328 0.189677 0.810323 Final coordinates: 9682.85 1204.30 0.243504 0.333568 0.666432 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.433431E-02 Extraneous predicted phases: 1.454856E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 27.428 0.0097 0.1721 0.0250 0.2028 0.0975 0.0010 0.0003 0.4856 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0018 0.0056 0.0014 0.0270 -0.0218 0.0024 0.0001 -0.0068 -0.0061 Composition Misfit: 0.152479E-01 Gt predicted* 72.563 0.0000 0.1403 0.1286 0.1023 0.2002 0.0016 0.0004 0.4216 0.0049 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0047 0.0101 -0.0223 0.0223 -0.0011 -0.0000 0.0006 -0.0049 Composition Misfit: 0.908641E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.009 0.0000 0.0345 0.0361 0.0000 0.7921 0.0066 0.0014 0.0000 0.1293 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.614 -831458. MgO 149.660 -651759. Al2O3 101.244 -0.169192E+07 CaO 130.016 -766482. FeO 173.551 -345987. TiO2 1.461 -975963. Cr2O3 0.400 -0.126328E+07 SiO2 441.055 -920487. O2 5.283 -433513. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 142 converged, 137 successes so far. Misfit function evaluations this try => 209 Misfit this try = 2.179265E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.702498E-07 Bayes score, PP * exp(-Misfit) = 2.644241E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8610.87 1198.51 0.150342 0.665151 0.334849 Final coordinates: 9782.03 1173.83 0.286527 0.431113 0.568887 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.177320E-02 Extraneous predicted phases: 1.944393E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 36.626 0.0093 0.1757 0.0236 0.2077 0.0906 0.0013 0.0003 0.4853 0.0062 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0015 0.0020 0.0027 0.0222 -0.0149 0.0021 0.0001 -0.0066 -0.0062 Composition Misfit: 0.882743E-02 Gt predicted* 63.369 0.0000 0.1400 0.1271 0.1078 0.1965 0.0020 0.0005 0.4208 0.0054 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0044 0.0117 -0.0278 0.0261 -0.0015 -0.0000 0.0014 -0.0054 Composition Misfit: 0.129458E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.001 0.0000 0.0000 0.0000 0.0000 0.6495 0.2509 0.0000 0.0000 0.0996 Sp 0.003 0.0000 0.0359 0.0287 0.0000 0.7940 0.0101 0.0014 0.0000 0.1299 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.378 -830903. MgO 153.767 -649684. Al2O3 90.276 -0.168507E+07 CaO 144.635 -764175. FeO 159.231 -343396. TiO2 1.745 -965333. Cr2O3 0.392 -0.125208E+07 SiO2 446.576 -915290. O2 5.703 -421529. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 143 converged, 138 successes so far. Misfit function evaluations this try => 278 Misfit this try = 4.350720E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 3.200317E-08 Bayes score, PP * exp(-Misfit) = 3.064066E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14021.2 1084.63 0.799579 0.948302 5.169840E-02 Final coordinates: 17156.7 1329.34 0.351205 0.548872 0.451128 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.341164E-02 Extraneous predicted phases: 9.556383E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 45.547 0.0095 0.1803 0.0214 0.2056 0.0873 0.0008 0.0002 0.4897 0.0052 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0017 -0.0026 0.0049 0.0243 -0.0116 0.0026 0.0001 -0.0109 -0.0052 Composition Misfit: 0.148685E-01 Gt predicted* 54.440 0.0000 0.1393 0.1217 0.1251 0.1851 0.0031 0.0005 0.4182 0.0070 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0037 0.0170 -0.0450 0.0374 -0.0026 -0.0001 0.0040 -0.0070 Composition Misfit: 0.285431E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.014 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.300 -866577. MgO 158.725 -661471. Al2O3 77.035 -0.170343E+07 CaO 162.284 -772321. FeO 141.945 -360833. TiO2 2.088 -978200. Cr2O3 0.381 -0.128706E+07 SiO2 453.241 -916244. O2 6.231 -412616. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 144 converged, 139 successes so far. Misfit function evaluations this try => 322 Misfit this try = 7.580269E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.665968E-07 Bayes score, PP * exp(-Misfit) = 1.544350E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15747.5 991.147 6.828160E-02 4.904610E-02 0.950954 Final coordinates: 15450.3 1018.83 0.162413 8.453546E-02 0.915465 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.565346E-02 Extraneous predicted phases: 1.492316E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.390 0.0282 0.1615 0.0090 0.1871 0.0903 0.0007 0.0004 0.5132 0.0094 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0203 0.0162 0.0173 0.0428 -0.0146 0.0027 -0.0001 -0.0345 -0.0094 Composition Misfit: 0.735118E-01 Gt predicted* 97.592 0.0000 0.1381 0.1316 0.0900 0.2121 0.0007 0.0004 0.4230 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0024 0.0072 -0.0100 0.0104 -0.0002 0.0000 -0.0008 -0.0041 Composition Misfit: 0.214167E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.018 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.662 -787678. MgO 139.174 -632899. Al2O3 129.246 -0.164242E+07 CaO 92.693 -745230. FeO 210.108 -320408. TiO2 0.736 -933894. Cr2O3 0.422 -0.118574E+07 SiO2 426.959 -881047. O2 4.266 -381886. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 145 converged, 140 successes so far. Misfit function evaluations this try => 196 Misfit this try = 2.952408E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 1.594297E-07 Bayes score, PP * exp(-Misfit) = 1.547915E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14966.6 1282.71 6.185043E-02 8.125766E-02 0.918742 Final coordinates: 10507.2 1283.22 0.282266 0.421434 0.578566 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.948281E-02 Extraneous predicted phases: 4.127226E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 39.498 0.0085 0.1680 0.0328 0.2008 0.1031 0.0012 0.0003 0.4789 0.0064 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0006 0.0097 -0.0064 0.0291 -0.0274 0.0022 0.0000 -0.0002 -0.0064 Composition Misfit: 0.171922E-01 Gt predicted* 60.494 0.0000 0.1427 0.1276 0.1054 0.1956 0.0020 0.0005 0.4211 0.0051 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0071 0.0111 -0.0254 0.0269 -0.0015 -0.0000 0.0011 -0.0051 Composition Misfit: 0.122906E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Fsp 0.009 0.0199 0.0000 0.2301 0.2103 0.0000 0.0000 0.0000 0.5397 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.302 -847899. MgO 153.359 -658912. Al2O3 91.364 -0.170656E+07 CaO 143.185 -773364. FeO 160.652 -356011. TiO2 1.717 -987889. Cr2O3 0.393 -0.128844E+07 SiO2 446.028 -929141. O2 5.668 -441313. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 146 converged, 141 successes so far. Misfit function evaluations this try => 175 Misfit this try = 3.314304E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.304767E-07 Bayes score, PP * exp(-Misfit) = 2.229632E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10638.2 1311.86 0.485458 0.117649 0.882351 Final coordinates: 13702.3 1289.75 0.342724 0.536898 0.463102 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.314296E-02 Extraneous predicted phases: 8.074779E-08 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 47.441 0.0089 0.1760 0.0259 0.2059 0.0915 0.0012 0.0003 0.4846 0.0058 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0011 0.0017 0.0004 0.0240 -0.0158 0.0022 0.0001 -0.0058 -0.0058 Composition Misfit: 0.101764E-01 Gt predicted* 52.559 0.0000 0.1408 0.1237 0.1187 0.1880 0.0028 0.0005 0.4192 0.0064 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0052 0.0151 -0.0387 0.0346 -0.0023 -0.0001 0.0030 -0.0064 Composition Misfit: 0.229665E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.207 -861923. MgO 158.221 -660388. Al2O3 78.381 -0.170148E+07 CaO 160.490 -773006. FeO 143.702 -358378. TiO2 2.054 -976012. Cr2O3 0.383 -0.128125E+07 SiO2 452.564 -918905. O2 6.156 -415078. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 147 converged, 142 successes so far. Misfit function evaluations this try => 178 Misfit this try = 2.186428E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 2.563267E-07 Bayes score, PP * exp(-Misfit) = 2.507831E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8771.76 1095.25 0.689714 0.372262 0.627738 Final coordinates: 9706.58 1178.98 0.275737 0.408215 0.591785 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.182541E-02 Extraneous predicted phases: 3.886910E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 34.478 0.0094 0.1749 0.0239 0.2068 0.0920 0.0012 0.0003 0.4854 0.0062 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0015 0.0028 0.0024 0.0231 -0.0163 0.0022 0.0001 -0.0066 -0.0062 Composition Misfit: 0.991520E-02 Gt predicted* 65.517 0.0000 0.1402 0.1275 0.1064 0.1974 0.0019 0.0005 0.4210 0.0053 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0046 0.0113 -0.0263 0.0251 -0.0014 -0.0000 0.0012 -0.0053 Composition Misfit: 0.119102E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.005 0.0000 0.0354 0.0299 0.0000 0.7940 0.0092 0.0014 0.0000 0.1299 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.198 -831394. MgO 152.803 -650171. Al2O3 92.850 -0.168636E+07 CaO 141.204 -764741. FeO 162.593 -343949. TiO2 1.679 -967213. Cr2O3 0.394 -0.125412E+07 SiO2 445.280 -916209. O2 5.604 -423352. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 148 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 149 converged, 143 successes so far. Misfit function evaluations this try => 263 Misfit this try = 2.391939E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 3.057593E-07 Bayes score, PP * exp(-Misfit) = 2.985325E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8961.67 1206.14 0.433033 0.814088 0.185912 Final coordinates: 10274.7 1202.76 0.322222 0.500782 0.499218 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.391894E-02 Extraneous predicted phases: 4.474078E-07 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.803 0.0088 0.1746 0.0263 0.2081 0.0914 0.0015 0.0003 0.4827 0.0063 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0010 0.0031 0.0001 0.0218 -0.0157 0.0019 0.0001 -0.0039 -0.0063 Composition Misfit: 0.756997E-02 Gt predicted* 55.196 0.0000 0.1409 0.1260 0.1115 0.1929 0.0023 0.0005 0.4203 0.0057 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0052 0.0128 -0.0315 0.0296 -0.0018 -0.0000 0.0019 -0.0057 Composition Misfit: 0.163490E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.000 0.0000 0.0387 0.0325 0.0000 0.7866 0.0135 0.0012 0.0000 0.1274 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.924 -833268. MgO 156.700 -651139. Al2O3 82.442 -0.168980E+07 CaO 155.077 -765384. FeO 149.004 -346063. TiO2 1.948 -969229. Cr2O3 0.386 -0.126045E+07 SiO2 450.519 -918840. O2 6.002 -426445. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 150 converged, 144 successes so far. Misfit function evaluations this try => 313 Misfit this try = 4.143037E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 3.524411E-08 Bayes score, PP * exp(-Misfit) = 3.381377E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16479.9 1330.56 0.120197 0.165524 0.834476 Final coordinates: 16894.6 1333.33 0.335786 0.524195 0.475805 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.141970E-02 Extraneous predicted phases: 1.067040E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 43.527 0.0095 0.1795 0.0219 0.2045 0.0890 0.0008 0.0002 0.4895 0.0052 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0017 -0.0018 0.0044 0.0254 -0.0132 0.0026 0.0001 -0.0107 -0.0052 Composition Misfit: 0.156181E-01 Gt predicted* 56.469 0.0000 0.1396 0.1226 0.1223 0.1867 0.0029 0.0005 0.4186 0.0067 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0040 0.0161 -0.0423 0.0358 -0.0024 -0.0001 0.0035 -0.0067 Composition Misfit: 0.258016E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.005 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.107 -867646. MgO 157.686 -662113. Al2O3 79.809 -0.170490E+07 CaO 158.586 -773152. FeO 145.567 -361486. TiO2 2.017 -980999. Cr2O3 0.384 -0.128981E+07 SiO2 451.845 -917393. O2 6.110 -414503. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 151 converged, 145 successes so far. Misfit function evaluations this try => 345 Misfit this try = 7.563286E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 5.281749E-07 Bayes score, PP * exp(-Misfit) = 4.897008E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10487.4 1210.09 0.229845 6.011125E-02 0.939889 Final coordinates: 12427.0 1206.65 0.161580 8.845454E-02 0.911545 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.509138E-02 Extraneous predicted phases: 5.414828E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 3.047 0.0233 0.1549 0.0179 0.1815 0.1077 0.0003 0.0003 0.5064 0.0076 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0154 0.0228 0.0084 0.0484 -0.0320 0.0031 -0.0000 -0.0277 -0.0076 Composition Misfit: 0.728499E-01 Gt predicted* 96.935 0.0000 0.1383 0.1317 0.0902 0.2116 0.0008 0.0004 0.4230 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0027 0.0071 -0.0102 0.0109 -0.0003 0.0000 -0.0008 -0.0041 Composition Misfit: 0.224151E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.018 0.0000 0.0301 0.0375 0.0000 0.7990 0.0005 0.0015 0.0000 0.1315 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.693 -801506. MgO 139.339 -647408. Al2O3 128.805 -0.168657E+07 CaO 93.280 -761344. FeO 209.533 -340409. TiO2 0.748 -987985. Cr2O3 0.421 -0.125791E+07 SiO2 427.180 -917116. O2 4.232 -443389. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 152 converged, 146 successes so far. Misfit function evaluations this try => 581 Misfit this try = 7.338518E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 3.886913E-07 Bayes score, PP * exp(-Misfit) = 3.611886E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14291.3 976.157 0.411255 0.523625 0.476375 Final coordinates: 15034.1 1093.01 0.162538 8.792173E-02 0.912078 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.336601E-02 Extraneous predicted phases: 1.917015E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.714 0.0258 0.1617 0.0105 0.1865 0.0940 0.0005 0.0004 0.5124 0.0082 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0180 0.0160 0.0158 0.0434 -0.0183 0.0029 -0.0000 -0.0336 -0.0082 Composition Misfit: 0.711392E-01 Gt predicted* 97.280 0.0000 0.1381 0.1315 0.0903 0.2119 0.0007 0.0004 0.4229 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0025 0.0072 -0.0102 0.0107 -0.0003 0.0000 -0.0008 -0.0041 Composition Misfit: 0.222684E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.006 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.689 -801862. MgO 139.317 -640142. Al2O3 128.865 -0.165809E+07 CaO 93.200 -752797. FeO 209.611 -329763. TiO2 0.746 -951001. Cr2O3 0.422 -0.121218E+07 SiO2 427.150 -890722. O2 4.259 -395645. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 153 converged, 147 successes so far. Misfit function evaluations this try => 535 Misfit this try = 4.097362E-02 Best Misfit so far = 2.155725E-02 obtained on Try 53 Prior probability, PP = 4.347944E-08 Bayes score, PP * exp(-Misfit) = 4.173393E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17225.4 1327.07 0.782256 0.913027 8.697336E-02 Final coordinates: 16578.8 1332.17 0.336739 0.526022 0.473978 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.096689E-02 Extraneous predicted phases: 6.730101E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.009 0.0094 0.1789 0.0224 0.2044 0.0896 0.0008 0.0002 0.4889 0.0052 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0016 -0.0012 0.0039 0.0254 -0.0139 0.0026 0.0001 -0.0102 -0.0052 Composition Misfit: 0.151758E-01 Gt predicted* 55.987 0.0000 0.1398 0.1227 0.1221 0.1865 0.0029 0.0005 0.4187 0.0067 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0042 0.0161 -0.0421 0.0360 -0.0025 -0.0001 0.0035 -0.0067 Composition Misfit: 0.257911E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.004 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.121 -867787. MgO 157.763 -662224. Al2O3 79.604 -0.170530E+07 CaO 158.860 -773509. FeO 145.299 -361582. TiO2 2.022 -980251. Cr2O3 0.383 -0.129087E+07 SiO2 451.948 -917967. O2 6.116 -415501. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 154 converged, 148 successes so far. Misfit function evaluations this try => 439 Misfit this try = 2.129366E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.565235E-07 Bayes score, PP * exp(-Misfit) = 2.511189E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10363.0 1215.39 0.338340 0.915158 8.484157E-02 Final coordinates: 9690.01 1175.48 0.273902 0.404159 0.595841 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.126074E-02 Extraneous predicted phases: 3.291769E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 33.926 0.0094 0.1755 0.0235 0.2069 0.0913 0.0013 0.0003 0.4858 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0016 0.0022 0.0028 0.0230 -0.0156 0.0021 0.0001 -0.0070 -0.0061 Composition Misfit: 0.956301E-02 Gt predicted* 66.069 0.0000 0.1399 0.1275 0.1062 0.1978 0.0019 0.0005 0.4210 0.0053 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0043 0.0113 -0.0262 0.0247 -0.0014 -0.0000 0.0012 -0.0053 Composition Misfit: 0.116977E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0355 0.0298 0.0000 0.7940 0.0095 0.0014 0.0000 0.1299 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.167 -831037. MgO 152.632 -649864. Al2O3 93.307 -0.168570E+07 CaO 140.596 -764518. FeO 163.188 -343580. TiO2 1.667 -966292. Cr2O3 0.394 -0.125234E+07 SiO2 445.050 -915728. O2 5.587 -422705. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 155 converged, 149 successes so far. Misfit function evaluations this try => 212 Misfit this try = 3.469561E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.003404E-07 Bayes score, PP * exp(-Misfit) = 9.691872E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8505.69 1329.66 0.749164 5.927880E-02 0.940721 Final coordinates: 12953.6 1342.22 0.314115 0.485919 0.514081 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.468273E-02 Extraneous predicted phases: 1.288481E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 45.973 0.0084 0.1698 0.0326 0.2004 0.1017 0.0012 0.0003 0.4796 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0005 0.0079 -0.0063 0.0295 -0.0259 0.0022 0.0001 -0.0008 -0.0061 Composition Misfit: 0.168098E-01 Gt predicted* 54.025 0.0000 0.1431 0.1257 0.1119 0.1904 0.0025 0.0005 0.4202 0.0057 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0075 0.0130 -0.0319 0.0321 -0.0020 -0.0000 0.0020 -0.0057 Composition Misfit: 0.178729E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.003 0.0000 0.0465 0.0711 0.0000 0.7526 0.0115 0.0011 0.0000 0.1173 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.807 -837696. MgO 156.074 -657608. Al2O3 84.113 -0.171443E+07 CaO 152.849 -770863. FeO 151.186 -356990. TiO2 1.905 -998680. Cr2O3 0.387 -0.130288E+07 SiO2 449.678 -936737. O2 5.936 -462875. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 156 converged, 150 successes so far. Misfit function evaluations this try => 264 Misfit this try = 4.855343E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 3.462409E-07 Bayes score, PP * exp(-Misfit) = 3.298313E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10559.5 1046.53 0.487408 5.733564E-02 0.942664 Final coordinates: 10666.5 1091.11 0.177179 0.142885 0.857115 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.797984E-02 Extraneous predicted phases: 5.735885E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 7.495 0.0151 0.1766 0.0119 0.2007 0.0876 0.0005 0.0003 0.5013 0.0059 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0073 0.0011 0.0144 0.0292 -0.0119 0.0029 0.0001 -0.0225 -0.0059 Composition Misfit: 0.446089E-01 Gt predicted* 92.482 0.0000 0.1382 0.1309 0.0931 0.2095 0.0009 0.0004 0.4226 0.0043 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0026 0.0078 -0.0131 0.0130 -0.0004 0.0000 -0.0005 -0.0043 Composition Misfit: 0.337092E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Opx 0.005 0.0004 0.3052 0.0233 0.0122 0.1748 0.0002 0.0005 0.4801 0.0034 Sp 0.018 0.0000 0.0289 0.0198 0.0000 0.8121 0.0013 0.0018 0.0000 0.1361 Effective Bulk* Chemical Potentials (J/mol) Na2O 1.120 -809285. MgO 141.631 -641912. Al2O3 122.685 -0.166738E+07 CaO 101.438 -756233. FeO 201.543 -331925. TiO2 0.906 -957018. Cr2O3 0.417 -0.122317E+07 SiO2 430.261 -902033. O2 4.464 -411263. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 157 converged, 151 successes so far. Misfit function evaluations this try => 219 Misfit this try = 2.166218E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.598289E-07 Bayes score, PP * exp(-Misfit) = 2.542610E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9241.96 1012.36 0.563121 0.438685 0.561315 Final coordinates: 9677.07 1166.00 0.268949 0.392935 0.607065 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.155660E-02 Extraneous predicted phases: 1.055804E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 32.434 0.0096 0.1760 0.0224 0.2070 0.0907 0.0012 0.0003 0.4867 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0018 0.0017 0.0039 0.0229 -0.0150 0.0022 0.0001 -0.0079 -0.0061 Composition Misfit: 0.101812E-01 Gt predicted* 67.551 0.0000 0.1398 0.1276 0.1059 0.1982 0.0018 0.0005 0.4211 0.0052 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0042 0.0112 -0.0259 0.0243 -0.0013 -0.0000 0.0011 -0.0052 Composition Misfit: 0.113754E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.006 0.0000 0.0348 0.0277 0.0000 0.7966 0.0089 0.0013 0.0000 0.1308 Fsp 0.009 0.0177 0.0000 0.2323 0.2146 0.0000 0.0000 0.0000 0.5354 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.079 -829838. MgO 152.159 -649228. Al2O3 94.569 -0.168381E+07 CaO 138.913 -763788. FeO 164.836 -342546. TiO2 1.634 -964797. Cr2O3 0.395 -0.125036E+07 SiO2 444.415 -914315. O2 5.542 -420722. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 158 converged, 152 successes so far. Misfit function evaluations this try => 187 Misfit this try = 2.338800E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.726240E-07 Bayes score, PP * exp(-Misfit) = 2.663219E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13215.8 1208.93 0.145616 0.780241 0.219759 Final coordinates: 10067.5 1206.59 0.279091 0.415287 0.584713 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.337551E-02 Extraneous predicted phases: 1.249582E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 35.793 0.0092 0.1734 0.0256 0.2054 0.0945 0.0012 0.0003 0.4842 0.0062 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0014 0.0043 0.0007 0.0244 -0.0187 0.0022 0.0001 -0.0054 -0.0062 Composition Misfit: 0.109581E-01 Gt predicted* 64.204 0.0000 0.1407 0.1273 0.1067 0.1966 0.0019 0.0005 0.4209 0.0053 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0051 0.0114 -0.0267 0.0260 -0.0015 -0.0000 0.0012 -0.0053 Composition Misfit: 0.124174E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.003 0.0000 0.0363 0.0346 0.0000 0.7898 0.0095 0.0013 0.0000 0.1285 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.254 -832423. MgO 153.100 -651519. Al2O3 92.055 -0.169133E+07 CaO 142.263 -765968. FeO 161.555 -346195. TiO2 1.699 -973159. Cr2O3 0.393 -0.126324E+07 SiO2 445.680 -920003. O2 5.636 -430809. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 159 converged, 153 successes so far. Misfit function evaluations this try => 612 Misfit this try = 0.659785 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.726192E-07 Bayes score, PP * exp(-Misfit) = 1.409340E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8776.47 1017.61 0.766387 0.859957 0.140043 Final coordinates: 9750.01 1142.13 0.740944 0.953912 4.608837E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.451171E-02 Extraneous predicted phases: 0.615273 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 99.179 0.0075 0.1759 0.0313 0.2234 0.0761 0.0018 0.0003 0.4770 0.0067 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual 0.0003 0.0018 -0.0050 0.0065 -0.0004 0.0016 0.0000 0.0018 -0.0067 Composition Misfit: 0.244855E-02 Gt predicted* 0.073 0.0000 0.1339 0.1260 0.1391 0.1725 0.0020 0.0005 0.4203 0.0058 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 0.0017 0.0127 -0.0591 0.0500 -0.0015 -0.0000 0.0019 -0.0058 Composition Misfit: 0.420632E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.448 0.0000 0.0000 0.0000 0.0000 0.6431 0.2614 0.0000 0.0000 0.0954 Sp 0.300 0.0000 0.0443 0.0363 0.0000 0.7788 0.0119 0.0018 0.0000 0.1269 Effective Bulk* Chemical Potentials (J/mol) Na2O 7.474 -816587. MgO 175.779 -644674. Al2O3 31.491 -0.167579E+07 CaO 222.989 -757192. FeO 82.486 -338932. TiO2 3.268 -960271. Cr2O3 0.346 -0.124043E+07 SiO2 476.168 -914082. O2 7.640 -422700. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 160 converged, 154 successes so far. Misfit function evaluations this try => 137 Misfit this try = 3.428804E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.248834E-07 Bayes score, PP * exp(-Misfit) = 1.206740E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10159.1 1329.89 0.723231 0.481030 0.518970 Final coordinates: 13916.5 1326.73 0.314486 0.485455 0.514545 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.427572E-02 Extraneous predicted phases: 1.231893E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 43.190 0.0089 0.1733 0.0279 0.2021 0.0970 0.0010 0.0003 0.4837 0.0058 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0011 0.0044 -0.0016 0.0278 -0.0213 0.0024 0.0001 -0.0050 -0.0058 Composition Misfit: 0.146953E-01 Gt predicted* 56.805 0.0000 0.1417 0.1249 0.1147 0.1899 0.0026 0.0005 0.4198 0.0060 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0061 0.0138 -0.0347 0.0326 -0.0021 -0.0001 0.0024 -0.0060 Composition Misfit: 0.195805E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.005 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.804 -868874. MgO 156.055 -664055. Al2O3 84.165 -0.170929E+07 CaO 152.780 -776769. FeO 151.254 -362970. TiO2 1.904 -984870. Cr2O3 0.387 -0.129538E+07 SiO2 449.652 -923398. O2 5.946 -422315. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 161 converged, 155 successes so far. Misfit function evaluations this try => 288 Misfit this try = 4.068420E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.767019E-07 Bayes score, PP * exp(-Misfit) = 1.696572E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15568.8 1210.33 7.063689E-02 0.942282 5.771764E-02 Final coordinates: 10482.1 1274.46 0.572512 0.818406 0.181594 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.662249E-02 Extraneous predicted phases: 4.061705E-03 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 91.583 0.0070 0.1707 0.0390 0.2095 0.0937 0.0027 0.0003 0.4698 0.0073 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual 0.0009 0.0070 -0.0127 0.0204 -0.0180 0.0007 0.0000 0.0090 -0.0073 Composition Misfit: 0.103605E-01 Gt predicted* 8.353 0.0000 0.1507 0.1244 0.1157 0.1801 0.0030 0.0005 0.4196 0.0060 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0151 0.0144 -0.0357 0.0424 -0.0025 -0.0001 0.0026 -0.0060 Composition Misfit: 0.262620E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.036 0.0000 0.0000 0.0000 0.0000 0.6302 0.2829 0.0000 0.0000 0.0868 Sp 0.027 0.0000 0.0516 0.0457 0.0000 0.7577 0.0251 0.0011 0.0000 0.1187 Fsp 0.001 0.0151 0.0000 0.2349 0.2198 0.0000 0.0000 0.0000 0.5302 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 6.412 -847663. MgO 170.073 -656907. Al2O3 46.727 -0.170329E+07 CaO 202.680 -771481. FeO 102.378 -355620. TiO2 2.873 -978948. Cr2O3 0.358 -0.128213E+07 SiO2 468.498 -928912. O2 7.327 -432184. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 162 converged, 156 successes so far. Misfit function evaluations this try => 724 Misfit this try = 8.094617E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.163879E-07 Bayes score, PP * exp(-Misfit) = 1.073379E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17033.4 1039.83 0.599869 6.448187E-02 0.935518 Final coordinates: 17510.7 1112.18 0.161629 8.254538E-02 0.917455 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 8.084785E-02 Extraneous predicted phases: 9.831836E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.249 0.0293 0.1558 0.0116 0.1812 0.0971 0.0004 0.0004 0.5152 0.0089 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0215 0.0219 0.0147 0.0487 -0.0214 0.0030 -0.0000 -0.0364 -0.0089 Composition Misfit: 0.787042E-01 Gt predicted* 97.737 0.0000 0.1381 0.1316 0.0900 0.2121 0.0007 0.0004 0.4229 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0025 0.0072 -0.0100 0.0105 -0.0002 0.0000 -0.0008 -0.0041 Composition Misfit: 0.214367E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.014 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.647 -800329. MgO 139.091 -639894. Al2O3 129.470 -0.165655E+07 CaO 92.394 -751595. FeO 210.400 -329941. TiO2 0.730 -952398. Cr2O3 0.422 -0.121179E+07 SiO2 426.846 -887422. O2 4.251 -392955. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 163 converged, 157 successes so far. Misfit function evaluations this try => 138 Misfit this try = 3.494565E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.535091E-07 Bayes score, PP * exp(-Misfit) = 1.482373E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9233.18 1300.69 0.558313 0.717705 0.282295 Final coordinates: 10417.1 1283.32 0.488132 0.734661 0.265339 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.494456E-02 Extraneous predicted phases: 1.085367E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 80.941 0.0071 0.1693 0.0389 0.2072 0.0969 0.0025 0.0003 0.4705 0.0072 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual 0.0007 0.0084 -0.0126 0.0227 -0.0211 0.0009 0.0000 0.0083 -0.0072 Composition Misfit: 0.121057E-01 Gt predicted* 19.057 0.0000 0.1493 0.1248 0.1133 0.1836 0.0029 0.0005 0.4198 0.0059 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0136 0.0140 -0.0333 0.0389 -0.0024 -0.0001 0.0024 -0.0059 Composition Misfit: 0.228389E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Fsp 0.001 0.0158 0.0000 0.2342 0.2183 0.0000 0.0000 0.0000 0.5317 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 5.756 -848636. MgO 166.547 -657863. Al2O3 56.144 -0.170564E+07 CaO 190.129 -772481. FeO 114.671 -356436. TiO2 2.629 -981595. Cr2O3 0.365 -0.128610E+07 SiO2 463.758 -930319. O2 6.997 -435881. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 164 converged, 158 successes so far. Misfit function evaluations this try => 318 Misfit this try = 6.976645E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 6.343736E-07 Bayes score, PP * exp(-Misfit) = 5.916242E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10782.8 1295.66 0.198509 6.827448E-02 0.931726 Final coordinates: 12823.2 1154.54 0.174387 0.115673 0.884327 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 6.792972E-02 Extraneous predicted phases: 1.836728E-03 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 4.862 0.0189 0.1685 0.0129 0.1915 0.0957 0.0003 0.0003 0.5054 0.0065 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0111 0.0092 0.0135 0.0384 -0.0200 0.0031 0.0001 -0.0266 -0.0065 Composition Misfit: 0.649001E-01 Gt predicted* 95.075 0.0000 0.1385 0.1309 0.0922 0.2102 0.0008 0.0004 0.4226 0.0044 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0029 0.0079 -0.0122 0.0123 -0.0004 0.0000 -0.0004 -0.0044 Composition Misfit: 0.302959E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.064 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.906 -820928. MgO 140.485 -647759. Al2O3 125.745 -0.167567E+07 CaO 97.359 -761442. FeO 205.537 -339469. TiO2 0.827 -968160. Cr2O3 0.419 -0.123940E+07 SiO2 428.721 -903358. O2 4.480 -409501. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 165 converged, 159 successes so far. Misfit function evaluations this try => 243 Misfit this try = 4.449421E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.440463E-08 Bayes score, PP * exp(-Misfit) = 1.377775E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17355.1 1318.35 0.871375 0.636494 0.363506 Final coordinates: 17733.4 1349.81 0.343424 0.538349 0.461651 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.448633E-02 Extraneous predicted phases: 7.874790E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.663 0.0095 0.1796 0.0217 0.2046 0.0887 0.0007 0.0002 0.4899 0.0051 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0017 -0.0019 0.0046 0.0253 -0.0130 0.0027 0.0001 -0.0111 -0.0051 Composition Misfit: 0.164933E-01 Gt predicted* 55.335 0.0000 0.1397 0.1220 0.1243 0.1851 0.0031 0.0005 0.4183 0.0069 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0041 0.0168 -0.0443 0.0374 -0.0026 -0.0001 0.0038 -0.0069 Composition Misfit: 0.279931E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.002 0.0000 0.0451 0.0558 0.0000 0.7653 0.0108 0.0010 0.0000 0.1220 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.218 -816518. MgO 158.282 -649633. Al2O3 78.218 -0.170695E+07 CaO 160.707 -760310. FeO 143.489 -349582. TiO2 2.058 -995131. Cr2O3 0.382 -0.129362E+07 SiO2 452.646 -931158. O2 6.160 -469194. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 166 converged, 160 successes so far. Misfit function evaluations this try => 171 Misfit this try = 3.939970E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 5.719400E-08 Bayes score, PP * exp(-Misfit) = 5.498438E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9248.81 1322.81 0.315875 0.181175 0.818825 Final coordinates: 10127.4 1337.06 0.263367 0.380201 0.619799 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.939656E-02 Extraneous predicted phases: 3.137513E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 38.574 0.0079 0.1624 0.0404 0.1940 0.1136 0.0012 0.0003 0.4736 0.0066 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0000 0.0153 -0.0141 0.0359 -0.0378 0.0022 0.0000 0.0052 -0.0066 Composition Misfit: 0.295572E-01 Gt predicted* 61.424 0.0000 0.1438 0.1288 0.1013 0.1974 0.0018 0.0004 0.4217 0.0047 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0082 0.0099 -0.0213 0.0251 -0.0013 -0.0000 0.0005 -0.0047 Composition Misfit: 0.983934E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.001 0.0000 0.0471 0.0931 0.0000 0.7386 0.0071 0.0012 0.0000 0.1129 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.979 -848553. MgO 151.623 -662122. Al2O3 96.000 -0.171889E+07 CaO 137.005 -777010. FeO 166.705 -360680. TiO2 1.597 -0.100437E+07 Cr2O3 0.396 -0.130984E+07 SiO2 443.694 -940198. O2 5.488 -462816. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 167 converged, 161 successes so far. Misfit function evaluations this try => 211 Misfit this try = 0.103787 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.193862E-07 Bayes score, PP * exp(-Misfit) = 1.076169E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17182.4 1070.41 0.370004 0.164141 0.835859 Final coordinates: 17490.5 1115.17 0.183878 0.158939 0.841061 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.103666 Extraneous predicted phases: 1.207670E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 8.136 0.0154 0.1845 0.0070 0.2009 0.0795 0.0003 0.0002 0.5074 0.0048 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0076 -0.0068 0.0193 0.0290 -0.0038 0.0031 0.0001 -0.0286 -0.0048 Composition Misfit: 0.995674E-01 Gt predicted* 91.848 0.0000 0.1379 0.1302 0.0949 0.2087 0.0010 0.0004 0.4223 0.0045 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0023 0.0085 -0.0148 0.0138 -0.0005 -0.0000 -0.0001 -0.0045 Composition Misfit: 0.409837E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.016 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 1.245 -813086. MgO 142.307 -639526. Al2O3 120.880 -0.165899E+07 CaO 103.844 -751124. FeO 199.186 -329941. TiO2 0.953 -950636. Cr2O3 0.415 -0.121504E+07 SiO2 431.170 -887831. O2 4.578 -397369. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 168 converged, 162 successes so far. Misfit function evaluations this try => 268 Misfit this try = 3.852668E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 4.879108E-08 Bayes score, PP * exp(-Misfit) = 4.694707E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8994.26 1132.12 0.736481 5.707588E-02 0.942924 Final coordinates: 15689.3 1349.50 0.327222 0.510175 0.489825 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.850052E-02 Extraneous predicted phases: 2.615626E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.363 0.0091 0.1755 0.0259 0.2027 0.0943 0.0009 0.0002 0.4859 0.0055 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0013 0.0022 0.0004 0.0272 -0.0186 0.0025 0.0001 -0.0072 -0.0055 Composition Misfit: 0.151955E-01 Gt predicted* 55.633 0.0000 0.1411 0.1237 0.1189 0.1874 0.0028 0.0005 0.4192 0.0064 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0055 0.0151 -0.0389 0.0351 -0.0023 -0.0001 0.0030 -0.0064 Composition Misfit: 0.233050E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0452 0.0610 0.0000 0.7618 0.0103 0.0010 0.0000 0.1207 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.997 -826570. MgO 157.096 -653427. Al2O3 81.386 -0.171091E+07 CaO 156.485 -765216. FeO 147.625 -353181. TiO2 1.976 -997317. Cr2O3 0.385 -0.129888E+07 SiO2 451.051 -933852. O2 6.038 -466478. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 169 converged, 163 successes so far. Misfit function evaluations this try => 227 Misfit this try = 2.184248E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.575592E-07 Bayes score, PP * exp(-Misfit) = 2.519944E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8686.63 1058.98 0.179647 0.789788 0.210212 Final coordinates: 9653.65 1163.47 0.257759 0.367818 0.632182 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.174509E-02 Extraneous predicted phases: 9.738744E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 29.814 0.0098 0.1759 0.0219 0.2066 0.0910 0.0011 0.0003 0.4874 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0019 0.0018 0.0044 0.0233 -0.0153 0.0023 0.0001 -0.0087 -0.0060 Composition Misfit: 0.113819E-01 Gt predicted* 70.178 0.0000 0.1397 0.1280 0.1045 0.1993 0.0017 0.0004 0.4212 0.0051 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0041 0.0108 -0.0245 0.0232 -0.0012 -0.0000 0.0009 -0.0051 Composition Misfit: 0.103632E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.007 0.0000 0.0342 0.0279 0.0000 0.7976 0.0077 0.0014 0.0000 0.1312 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.882 -828668. MgO 151.102 -648941. Al2O3 97.393 -0.168344E+07 CaO 135.149 -763537. FeO 168.523 -342070. TiO2 1.561 -965204. Cr2O3 0.397 -0.124937E+07 SiO2 442.993 -914107. O2 5.430 -421582. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 170 converged, 164 successes so far. Misfit function evaluations this try => 736 Misfit this try = 3.523517E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 9.410138E-08 Bayes score, PP * exp(-Misfit) = 9.084344E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17454.9 1187.66 0.942253 0.423637 0.576363 Final coordinates: 13597.3 1344.08 0.307670 0.471856 0.528144 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.520247E-02 Extraneous predicted phases: 3.269590E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 43.111 0.0087 0.1711 0.0305 0.2003 0.1005 0.0010 0.0003 0.4817 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0008 0.0066 -0.0042 0.0296 -0.0247 0.0024 0.0001 -0.0030 -0.0060 Composition Misfit: 0.170376E-01 Gt predicted* 56.881 0.0000 0.1424 0.1255 0.1127 0.1906 0.0025 0.0005 0.4201 0.0058 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0068 0.0133 -0.0327 0.0319 -0.0020 -0.0000 0.0021 -0.0058 Composition Misfit: 0.181648E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.008 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.697 -873036. MgO 155.482 -666200. Al2O3 85.694 -0.171373E+07 CaO 150.742 -779142. FeO 153.250 -365575. TiO2 1.864 -989662. Cr2O3 0.388 -0.130276E+07 SiO2 448.882 -926507. O2 5.894 -426166. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 171 converged, 165 successes so far. Misfit function evaluations this try => 246 Misfit this try = 0.611245 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.516746E-07 Bayes score, PP * exp(-Misfit) = 8.230997E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10644.2 1133.46 0.112950 0.881387 0.118613 Final coordinates: 9176.54 1077.21 0.390042 0.639951 0.360049 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.084633E-02 Extraneous predicted phases: 0.580399 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 57.003 0.0088 0.1838 0.0197 0.2189 0.0735 0.0010 0.0003 0.4885 0.0055 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0010 -0.0060 0.0066 0.0110 0.0022 0.0024 0.0000 -0.0098 -0.0055 Composition Misfit: 0.921088E-02 Gt predicted* 42.224 0.0000 0.1353 0.1295 0.1203 0.1865 0.0013 0.0005 0.4219 0.0047 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 0.0003 0.0093 -0.0403 0.0360 -0.0008 -0.0000 0.0002 -0.0047 Composition Misfit: 0.216355E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.429 0.0000 0.0000 0.0000 0.0000 0.6607 0.2322 0.0000 0.0000 0.1071 Sp 0.344 0.0000 0.0358 0.0251 0.0000 0.7984 0.0056 0.0026 0.0000 0.1325 Effective Bulk* Chemical Potentials (J/mol) Na2O 5.014 -809732. MgO 162.560 -640691. Al2O3 66.793 -0.166544E+07 CaO 175.934 -754116. FeO 128.574 -331837. TiO2 2.354 -952160. Cr2O3 0.374 -0.122030E+07 SiO2 458.397 -905383. O2 6.269 -415062. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 172 converged, 166 successes so far. Misfit function evaluations this try => 311 Misfit this try = 4.009194E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 5.508552E-08 Bayes score, PP * exp(-Misfit) = 5.292072E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12270.4 1329.94 0.463689 5.175858E-02 0.948241 Final coordinates: 16335.1 1326.49 0.330454 0.514999 0.485001 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.008608E-02 Extraneous predicted phases: 5.864501E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 42.939 0.0095 0.1788 0.0223 0.2043 0.0899 0.0008 0.0002 0.4890 0.0053 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0016 -0.0010 0.0040 0.0256 -0.0142 0.0026 0.0001 -0.0102 -0.0053 Composition Misfit: 0.154731E-01 Gt predicted* 57.058 0.0000 0.1399 0.1231 0.1210 0.1873 0.0029 0.0005 0.4189 0.0066 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0043 0.0157 -0.0409 0.0352 -0.0024 -0.0001 0.0033 -0.0066 Composition Misfit: 0.246130E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.003 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.035 -866541. MgO 157.299 -661850. Al2O3 80.843 -0.170459E+07 CaO 157.208 -773270. FeO 146.917 -360920. TiO2 1.990 -980105. Cr2O3 0.384 -0.128931E+07 SiO2 451.324 -917758. O2 6.069 -415714. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 173 converged, 167 successes so far. Misfit function evaluations this try => 734 Misfit this try = 3.143288E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.974150E-07 Bayes score, PP * exp(-Misfit) = 1.913062E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16734.6 1325.39 9.450888E-02 0.141192 0.858808 Final coordinates: 11359.4 1288.24 0.368849 0.580658 0.419342 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.113368E-02 Extraneous predicted phases: 2.992001E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 57.745 0.0079 0.1704 0.0337 0.2055 0.0972 0.0018 0.0003 0.4767 0.0066 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0001 0.0073 -0.0073 0.0244 -0.0215 0.0016 0.0001 0.0021 -0.0066 Composition Misfit: 0.110733E-01 Gt predicted* 42.242 0.0000 0.1441 0.1251 0.1137 0.1881 0.0027 0.0005 0.4199 0.0058 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0085 0.0136 -0.0337 0.0344 -0.0022 -0.0001 0.0023 -0.0058 Composition Misfit: 0.200604E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.013 0.0000 0.0455 0.0502 0.0000 0.7646 0.0183 0.0011 0.0000 0.1204 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.550 -840541. MgO 160.063 -656201. Al2O3 73.461 -0.170539E+07 CaO 167.048 -770083. FeO 137.278 -354246. TiO2 2.181 -984833. Cr2O3 0.379 -0.128679E+07 SiO2 455.041 -930270. O2 6.329 -444386. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 174 converged, 168 successes so far. Misfit function evaluations this try => 172 Misfit this try = 2.939300E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.161792E-07 Bayes score, PP * exp(-Misfit) = 2.099175E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13088.3 1287.66 0.101379 0.682526 0.317474 Final coordinates: 11361.8 1281.56 0.298518 0.456147 0.543853 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.927666E-02 Extraneous predicted phases: 1.163465E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 41.849 0.0086 0.1706 0.0302 0.2025 0.0995 0.0012 0.0003 0.4810 0.0062 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0008 0.0072 -0.0039 0.0274 -0.0237 0.0022 0.0001 -0.0022 -0.0062 Composition Misfit: 0.141999E-01 Gt predicted* 58.143 0.0000 0.1423 0.1266 0.1092 0.1931 0.0022 0.0005 0.4206 0.0054 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0067 0.0121 -0.0291 0.0294 -0.0017 -0.0000 0.0016 -0.0054 Composition Misfit: 0.150768E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.008 0.0000 0.0413 0.0512 0.0000 0.7717 0.0117 0.0012 0.0000 0.1229 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.574 -835758. MgO 154.821 -655131. Al2O3 87.461 -0.170450E+07 CaO 148.387 -769100. FeO 155.556 -352364. TiO2 1.818 -987519. Cr2O3 0.390 -0.128567E+07 SiO2 447.993 -929740. O2 5.805 -449311. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 175 converged, 169 successes so far. Misfit function evaluations this try => 260 Misfit this try = 3.269661E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.867944E-07 Bayes score, PP * exp(-Misfit) = 1.807856E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 11011.3 1324.63 8.880096E-02 6.511062E-02 0.934889 Final coordinates: 13499.7 1305.32 0.298535 0.455348 0.544652 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.269658E-02 Extraneous predicted phases: 2.392272E-08 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 39.409 0.0091 0.1739 0.0263 0.2022 0.0964 0.0009 0.0002 0.4853 0.0057 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0013 0.0038 0.0000 0.0277 -0.0207 0.0025 0.0001 -0.0065 -0.0057 Composition Misfit: 0.151703E-01 Gt predicted* 60.590 0.0000 0.1412 0.1255 0.1127 0.1918 0.0024 0.0005 0.4201 0.0058 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0056 0.0132 -0.0327 0.0307 -0.0019 -0.0000 0.0021 -0.0058 Composition Misfit: 0.175263E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.568 -864209. MgO 154.787 -662174. Al2O3 87.551 -0.170558E+07 CaO 148.267 -775085. FeO 155.674 -360216. TiO2 1.816 -982430. Cr2O3 0.390 -0.128886E+07 SiO2 447.948 -921467. O2 5.809 -421623. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 176 converged, 170 successes so far. Misfit function evaluations this try => 343 Misfit this try = 2.473106E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.459853E-07 Bayes score, PP * exp(-Misfit) = 2.399764E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8586.99 1003.79 0.197986 0.423516 0.576484 Final coordinates: 9552.51 1151.30 0.220467 0.273503 0.726497 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.453328E-02 Extraneous predicted phases: 1.977818E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 20.226 0.0107 0.1755 0.0197 0.2046 0.0918 0.0008 0.0003 0.4908 0.0058 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0029 0.0022 0.0067 0.0253 -0.0161 0.0026 0.0001 -0.0120 -0.0058 Composition Misfit: 0.175480E-01 Gt predicted* 79.763 0.0000 0.1392 0.1292 0.0996 0.2036 0.0014 0.0004 0.4218 0.0048 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0036 0.0095 -0.0196 0.0190 -0.0009 -0.0000 0.0003 -0.0048 Composition Misfit: 0.698530E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.011 0.0000 0.0323 0.0276 0.0000 0.8013 0.0050 0.0014 0.0000 0.1324 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.143 -825624. MgO 147.131 -648106. Al2O3 107.998 -0.168144E+07 CaO 121.014 -762802. FeO 182.368 -340509. TiO2 1.286 -965350. Cr2O3 0.405 -0.124632E+07 SiO2 437.655 -912561. O2 5.026 -421239. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 177 converged, 171 successes so far. Misfit function evaluations this try => 140 Misfit this try = 3.443429E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.112358E-07 Bayes score, PP * exp(-Misfit) = 1.074707E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 11565.0 1326.55 0.731970 0.242699 0.757301 Final coordinates: 13166.6 1336.67 0.306897 0.472377 0.527623 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.438290E-02 Extraneous predicted phases: 5.138448E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 43.558 0.0086 0.1707 0.0310 0.2005 0.1007 0.0011 0.0003 0.4812 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0008 0.0070 -0.0047 0.0294 -0.0250 0.0023 0.0001 -0.0024 -0.0060 Composition Misfit: 0.167326E-01 Gt predicted* 56.437 0.0000 0.1425 0.1257 0.1120 0.1909 0.0024 0.0005 0.4202 0.0057 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0069 0.0130 -0.0320 0.0316 -0.0020 -0.0000 0.0020 -0.0057 Composition Misfit: 0.176503E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.005 0.0000 0.0453 0.0670 0.0000 0.7571 0.0109 0.0010 0.0000 0.1187 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.701 -835449. MgO 155.504 -656681. Al2O3 85.636 -0.171292E+07 CaO 150.820 -769826. FeO 153.174 -355804. TiO2 1.866 -997653. Cr2O3 0.388 -0.130089E+07 SiO2 448.912 -935618. O2 5.876 -462706. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 178 converged, 172 successes so far. Misfit function evaluations this try => 199 Misfit this try = 3.594380E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 9.370022E-08 Bayes score, PP * exp(-Misfit) = 9.039208E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10559.2 1153.47 0.713273 0.879446 0.120554 Final coordinates: 10274.5 1312.59 0.399689 0.625636 0.374364 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.591084E-02 Extraneous predicted phases: 3.295171E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 69.267 0.0071 0.1665 0.0410 0.2023 0.1033 0.0022 0.0003 0.4703 0.0070 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual 0.0007 0.0112 -0.0147 0.0276 -0.0275 0.0012 0.0000 0.0085 -0.0070 Composition Misfit: 0.180247E-01 Gt predicted* 30.729 0.0000 0.1488 0.1266 0.1082 0.1875 0.0025 0.0005 0.4207 0.0053 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0131 0.0122 -0.0282 0.0351 -0.0020 -0.0001 0.0015 -0.0053 Composition Misfit: 0.178862E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0501 0.0656 0.0000 0.7482 0.0197 0.0011 0.0000 0.1154 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.902 -849450. MgO 161.957 -659948. Al2O3 68.403 -0.171253E+07 CaO 173.789 -774765. FeO 130.676 -358958. TiO2 2.312 -991210. Cr2O3 0.375 -0.129845E+07 SiO2 457.586 -935746. O2 6.529 -449197. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 179 converged, 173 successes so far. Misfit function evaluations this try => 235 Misfit this try = 4.574322E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.178770E-08 Bayes score, PP * exp(-Misfit) = 1.126064E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16685.5 972.467 0.567499 0.793211 0.206789 Final coordinates: 17999.9 1349.46 0.344469 0.540185 0.459815 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.572911E-02 Extraneous predicted phases: 1.410970E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.521 0.0096 0.1804 0.0211 0.2046 0.0880 0.0007 0.0002 0.4904 0.0050 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0017 -0.0027 0.0052 0.0253 -0.0122 0.0027 0.0001 -0.0116 -0.0050 Composition Misfit: 0.172570E-01 Gt predicted* 55.476 0.0000 0.1393 0.1218 0.1250 0.1850 0.0031 0.0005 0.4183 0.0070 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0037 0.0169 -0.0449 0.0375 -0.0026 -0.0001 0.0039 -0.0070 Composition Misfit: 0.284721E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.003 0.0000 0.0448 0.0544 0.0000 0.7670 0.0102 0.0009 0.0000 0.1227 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.232 -815642. MgO 158.359 -649210. Al2O3 78.011 -0.170636E+07 CaO 160.982 -759702. FeO 143.220 -349138. TiO2 2.063 -994767. Cr2O3 0.382 -0.129302E+07 SiO2 452.750 -930664. O2 6.167 -468968. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 180 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 181 converged, 174 successes so far. Misfit function evaluations this try => 169 Misfit this try = 2.576971E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 3.575390E-07 Bayes score, PP * exp(-Misfit) = 3.484431E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10082.8 1047.71 0.906925 0.298864 0.701136 Final coordinates: 10844.0 1214.04 0.259399 0.371679 0.628321 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.566708E-02 Extraneous predicted phases: 1.026295E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 30.383 0.0097 0.1747 0.0232 0.2038 0.0943 0.0010 0.0003 0.4873 0.0058 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0019 0.0030 0.0031 0.0261 -0.0186 0.0024 0.0001 -0.0085 -0.0058 Composition Misfit: 0.142801E-01 Gt predicted* 69.609 0.0000 0.1401 0.1276 0.1057 0.1979 0.0018 0.0005 0.4211 0.0052 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0045 0.0111 -0.0257 0.0246 -0.0013 -0.0000 0.0011 -0.0052 Composition Misfit: 0.113870E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.008 0.0000 0.0355 0.0356 0.0000 0.7910 0.0074 0.0013 0.0000 0.1291 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.912 -827966. MgO 151.264 -650483. Al2O3 96.959 -0.169160E+07 CaO 135.728 -764656. FeO 167.956 -345220. TiO2 1.572 -975928. Cr2O3 0.397 -0.126400E+07 SiO2 443.212 -920228. O2 5.446 -435950. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 182 converged, 175 successes so far. Misfit function evaluations this try => 342 Misfit this try = 4.553075E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.635229E-08 Bayes score, PP * exp(-Misfit) = 1.562445E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17444.0 1317.50 0.912037 9.832949E-02 0.901671 Final coordinates: 17768.2 1341.99 0.354201 0.555175 0.444825 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.551415E-02 Extraneous predicted phases: 1.660246E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 46.021 0.0095 0.1805 0.0212 0.2054 0.0872 0.0007 0.0002 0.4900 0.0051 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0017 -0.0028 0.0051 0.0245 -0.0115 0.0027 0.0001 -0.0112 -0.0051 Composition Misfit: 0.157389E-01 Gt predicted* 53.974 0.0000 0.1392 0.1214 0.1262 0.1843 0.0032 0.0005 0.4181 0.0071 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0036 0.0173 -0.0462 0.0383 -0.0027 -0.0001 0.0041 -0.0071 Composition Misfit: 0.297752E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.006 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.350 -869059. MgO 158.990 -662241. Al2O3 76.326 -0.170507E+07 CaO 163.229 -772814. FeO 141.019 -362048. TiO2 2.107 -979387. Cr2O3 0.381 -0.129062E+07 SiO2 453.598 -916556. O2 6.244 -413002. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 183 converged, 176 successes so far. Misfit function evaluations this try => 326 Misfit this try = 2.428701E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 3.561970E-07 Bayes score, PP * exp(-Misfit) = 3.476502E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8623.10 978.006 6.522573E-02 0.933432 6.656794E-02 Final coordinates: 10317.5 1160.00 0.283221 0.424539 0.575461 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.365376E-02 Extraneous predicted phases: 6.332422E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 34.743 0.0097 0.1785 0.0207 0.2084 0.0873 0.0011 0.0003 0.4882 0.0059 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0018 -0.0007 0.0056 0.0215 -0.0116 0.0023 0.0001 -0.0095 -0.0059 Composition Misfit: 0.103052E-01 Gt predicted* 65.233 0.0000 0.1392 0.1269 0.1088 0.1965 0.0019 0.0005 0.4207 0.0055 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0036 0.0119 -0.0288 0.0260 -0.0014 -0.0000 0.0015 -0.0055 Composition Misfit: 0.133486E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.018 0.0000 0.0000 0.0000 0.0000 0.6532 0.2446 0.0000 0.0000 0.1022 Sp 0.007 0.0000 0.0352 0.0264 0.0000 0.7971 0.0086 0.0014 0.0000 0.1312 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.326 -826690. MgO 153.490 -647671. Al2O3 91.015 -0.168126E+07 CaO 143.650 -761859. FeO 160.196 -340907. TiO2 1.726 -962390. Cr2O3 0.392 -0.124604E+07 SiO2 446.204 -912470. O2 5.671 -419458. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 184 converged, 177 successes so far. Misfit function evaluations this try => 765 Misfit this try = 3.250768E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.865788E-07 Bayes score, PP * exp(-Misfit) = 1.806111E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16245.0 1061.32 0.850278 0.804690 0.195310 Final coordinates: 13658.5 1304.44 0.321135 0.499791 0.500209 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.228406E-02 Extraneous predicted phases: 2.236276E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.210 0.0089 0.1743 0.0268 0.2041 0.0944 0.0011 0.0003 0.4843 0.0058 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0011 0.0034 -0.0005 0.0258 -0.0187 0.0023 0.0001 -0.0055 -0.0058 Composition Misfit: 0.122115E-01 Gt predicted* 55.779 0.0000 0.1414 0.1247 0.1154 0.1897 0.0026 0.0005 0.4197 0.0060 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0058 0.0140 -0.0354 0.0329 -0.0021 -0.0001 0.0025 -0.0060 Composition Misfit: 0.200726E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.011 0.0000 0.0431 0.0514 0.0000 0.7692 0.0131 0.0010 0.0000 0.1223 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.916 -827922. MgO 156.658 -652883. Al2O3 82.553 -0.170479E+07 CaO 154.928 -765597. FeO 149.150 -351182. TiO2 1.945 -989399. Cr2O3 0.386 -0.128854E+07 SiO2 450.463 -930058. O2 5.987 -455937. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 185 converged, 178 successes so far. Misfit function evaluations this try => 323 Misfit this try = 4.470901E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.008727E-08 Bayes score, PP * exp(-Misfit) = 1.920897E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17092.5 1026.07 0.880741 0.142723 0.857277 Final coordinates: 17593.8 1338.03 0.343069 0.537816 0.462184 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.469402E-02 Extraneous predicted phases: 1.499493E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.274 0.0096 0.1804 0.0209 0.2049 0.0877 0.0007 0.0002 0.4904 0.0051 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0017 -0.0027 0.0054 0.0250 -0.0120 0.0027 0.0001 -0.0116 -0.0051 Composition Misfit: 0.167665E-01 Gt predicted* 55.723 0.0000 0.1393 0.1220 0.1245 0.1854 0.0031 0.0005 0.4183 0.0069 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0037 0.0168 -0.0444 0.0371 -0.0026 -0.0001 0.0038 -0.0069 Composition Misfit: 0.279275E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.003 0.0000 0.0439 0.0513 0.0000 0.7703 0.0098 0.0010 0.0000 0.1237 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.214 -816478. MgO 158.259 -649033. Al2O3 78.278 -0.170463E+07 CaO 160.627 -759786. FeO 143.568 -348628. TiO2 2.056 -992503. Cr2O3 0.382 -0.128963E+07 SiO2 452.616 -929330. O2 6.157 -465141. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 186 converged, 179 successes so far. Misfit function evaluations this try => 268 Misfit this try = 0.610483 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 7.999656E-08 Bayes score, PP * exp(-Misfit) = 4.344523E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16858.9 1155.67 0.903380 0.321334 0.678666 Final coordinates: 17975.6 1193.28 0.894862 0.999931 6.851020E-05 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.186522 Extraneous predicted phases: 0.423960 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 91.131 0.0085 0.1857 0.0207 0.2285 0.0644 0.0008 0.0003 0.4842 0.0069 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0007 -0.0080 0.0056 0.0014 0.0114 0.0026 0.0000 -0.0054 -0.0069 Composition Misfit: 0.120822E-01 Gt predicted* 8.114 0.0000 0.0896 0.0874 0.2276 0.1678 0.0068 0.0007 0.4008 0.0193 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 0.0460 0.0514 -0.1475 0.0547 -0.0064 -0.0003 0.0214 -0.0193 Composition Misfit: 0.174440 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.306 0.0000 0.0000 0.0000 0.0000 0.6930 0.1784 0.0000 0.0000 0.1287 sph 0.448 0.0000 0.0000 0.0000 0.3333 0.0000 0.3333 0.0000 0.3333 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 7.835 -834167. MgO 177.716 -647082. Al2O3 26.316 -0.167114E+07 CaO 229.886 -752440. FeO 75.730 -344524. TiO2 3.402 -947756. Cr2O3 0.342 -0.122950E+07 SiO2 478.773 -898441. O2 8.471 -369190. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 187 converged, 180 successes so far. Misfit function evaluations this try => 253 Misfit this try = 2.945498E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.421072E-07 Bayes score, PP * exp(-Misfit) = 2.350800E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16605.3 1169.93 0.328947 0.477711 0.522289 Final coordinates: 11693.0 1278.85 0.276324 0.408482 0.591518 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.937538E-02 Extraneous predicted phases: 7.959546E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 35.673 0.0091 0.1715 0.0279 0.2012 0.0995 0.0010 0.0003 0.4836 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0012 0.0062 -0.0016 0.0287 -0.0237 0.0024 0.0001 -0.0048 -0.0060 Composition Misfit: 0.159721E-01 Gt predicted* 64.315 0.0000 0.1414 0.1270 0.1077 0.1952 0.0020 0.0005 0.4208 0.0054 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0058 0.0117 -0.0276 0.0273 -0.0015 -0.0000 0.0014 -0.0054 Composition Misfit: 0.134033E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Fsp 0.012 0.0212 0.0000 0.2288 0.2076 0.0000 0.0000 0.0000 0.5424 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.201 -855923. MgO 152.814 -660041. Al2O3 92.821 -0.170352E+07 CaO 141.243 -773882. FeO 162.554 -356951. TiO2 1.680 -982769. Cr2O3 0.394 -0.128418E+07 SiO2 445.295 -923121. O2 5.615 -427619. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 188 converged, 181 successes so far. Misfit function evaluations this try => 741 Misfit this try = 7.124757E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 3.781544E-07 Bayes score, PP * exp(-Misfit) = 3.521492E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9581.78 979.591 0.674309 0.122413 0.877587 Final coordinates: 13418.2 1049.31 0.161142 8.581212E-02 0.914188 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.107304E-02 Extraneous predicted phases: 1.745284E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.619 0.0261 0.1621 0.0100 0.1881 0.0924 0.0006 0.0004 0.5116 0.0087 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0183 0.0156 0.0163 0.0418 -0.0167 0.0028 -0.0000 -0.0328 -0.0087 Composition Misfit: 0.689429E-01 Gt predicted* 97.370 0.0000 0.1380 0.1317 0.0900 0.2120 0.0007 0.0004 0.4230 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0024 0.0071 -0.0100 0.0105 -0.0003 0.0000 -0.0008 -0.0041 Composition Misfit: 0.213016E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.010 0.0000 0.0282 0.0149 0.0000 0.8166 0.0005 0.0020 0.0000 0.1378 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.672 -788297. MgO 139.228 -635551. Al2O3 129.102 -0.165259E+07 CaO 92.884 -748724. FeO 209.921 -323991. TiO2 0.740 -946018. Cr2O3 0.422 -0.120105E+07 SiO2 427.031 -891154. O2 4.228 -399106. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 189 converged, 182 successes so far. Misfit function evaluations this try => 668 Misfit this try = 2.431109E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 3.516495E-07 Bayes score, PP * exp(-Misfit) = 3.432036E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10130.5 1053.89 0.288785 0.491043 0.508957 Final coordinates: 10595.2 1201.17 0.330250 0.515756 0.484244 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.425269E-02 Extraneous predicted phases: 5.839343E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 45.979 0.0089 0.1755 0.0256 0.2089 0.0899 0.0015 0.0003 0.4831 0.0063 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0010 0.0022 0.0007 0.0210 -0.0142 0.0019 0.0001 -0.0044 -0.0063 Composition Misfit: 0.690838E-02 Gt predicted* 54.016 0.0000 0.1405 0.1256 0.1128 0.1923 0.0024 0.0005 0.4201 0.0058 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0049 0.0132 -0.0328 0.0302 -0.0019 -0.0000 0.0021 -0.0058 Composition Misfit: 0.173443E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.006 0.0000 0.0387 0.0310 0.0000 0.7882 0.0124 0.0014 0.0000 0.1283 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.041 -831723. MgO 157.331 -650478. Al2O3 80.758 -0.168879E+07 CaO 157.321 -764486. FeO 146.806 -345392. TiO2 1.992 -968820. Cr2O3 0.384 -0.125912E+07 SiO2 451.367 -918132. O2 6.060 -426049. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 190 converged, 183 successes so far. Misfit function evaluations this try => 604 Misfit this try = 3.174177E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.595560E-07 Bayes score, PP * exp(-Misfit) = 2.514466E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8893.90 1210.00 0.911440 0.259242 0.740758 Final coordinates: 13426.6 1282.86 0.308437 0.474031 0.525969 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.173238E-02 Extraneous predicted phases: 9.390038E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 40.535 0.0092 0.1757 0.0246 0.2040 0.0933 0.0010 0.0002 0.4863 0.0057 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0014 0.0020 0.0017 0.0259 -0.0175 0.0024 0.0001 -0.0075 -0.0057 Composition Misfit: 0.129773E-01 Gt predicted* 59.460 0.0000 0.1407 0.1250 0.1144 0.1911 0.0024 0.0005 0.4198 0.0060 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0051 0.0137 -0.0344 0.0314 -0.0019 -0.0001 0.0023 -0.0060 Composition Misfit: 0.187550E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.004 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.714 -859767. MgO 155.574 -659900. Al2O3 85.450 -0.170085E+07 CaO 151.068 -772760. FeO 152.931 -357287. TiO2 1.870 -977364. Cr2O3 0.388 -0.128065E+07 SiO2 449.005 -918624. O2 5.896 -417860. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 191 converged, 184 successes so far. Misfit function evaluations this try => 117 Misfit this try = 3.799184E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 7.812403E-08 Bayes score, PP * exp(-Misfit) = 7.521163E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16843.4 1324.76 0.162128 0.196790 0.803210 Final coordinates: 11716.4 1348.30 0.260854 0.374666 0.625334 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.796757E-02 Extraneous predicted phases: 2.427104E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 35.192 0.0085 0.1656 0.0354 0.1948 0.1099 0.0009 0.0003 0.4785 0.0062 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0006 0.0121 -0.0091 0.0351 -0.0341 0.0025 0.0001 0.0003 -0.0062 Composition Misfit: 0.265773E-01 Gt predicted* 64.805 0.0000 0.1427 0.1280 0.1042 0.1964 0.0019 0.0005 0.4213 0.0050 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0071 0.0107 -0.0242 0.0261 -0.0014 -0.0000 0.0009 -0.0050 Composition Misfit: 0.113903E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0460 0.0885 0.0000 0.7434 0.0065 0.0011 0.0000 0.1145 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.936 -841630. MgO 151.390 -660149. Al2O3 96.623 -0.171850E+07 CaO 136.175 -774198. FeO 167.518 -359052. TiO2 1.581 -0.100591E+07 Cr2O3 0.397 -0.130963E+07 SiO2 443.381 -939744. O2 5.462 -467953. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 192 converged, 185 successes so far. Misfit function evaluations this try => 248 Misfit this try = 0.124501 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.285783E-08 Bayes score, PP * exp(-Misfit) = 1.135265E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14438.9 975.156 4.821374E-02 0.688539 0.311461 Final coordinates: 17900.9 950.966 0.154391 7.375111E-02 0.926249 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 8.214977E-02 Extraneous predicted phases: 4.235145E-02 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.351 0.0249 0.1733 0.0073 0.1960 0.0772 0.0007 0.0004 0.5120 0.0083 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0170 0.0044 0.0191 0.0339 -0.0014 0.0027 -0.0001 -0.0332 -0.0083 Composition Misfit: 0.805838E-01 Gt predicted* 97.425 0.0000 0.1377 0.1332 0.0885 0.2124 0.0005 0.0004 0.4238 0.0035 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0021 0.0055 -0.0084 0.0102 -0.0000 0.0000 -0.0016 -0.0035 Composition Misfit: 0.156595E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.115 0.0000 0.0000 0.0000 0.0000 0.7343 0.1094 0.0000 0.0000 0.1562 Sp 0.109 0.0000 0.0281 0.0086 0.0000 0.8208 0.0002 0.0028 0.0000 0.1395 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.578 -757484. MgO 138.720 -620677. Al2O3 130.459 -0.162479E+07 CaO 91.076 -731600. FeO 211.691 -305978. TiO2 0.705 -922993. Cr2O3 0.423 -0.115718E+07 SiO2 426.348 -871869. O2 4.085 -388581. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 193 converged, 186 successes so far. Misfit function evaluations this try => 179 Misfit this try = 2.458425E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 3.049496E-07 Bayes score, PP * exp(-Misfit) = 2.975441E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9178.23 1090.06 0.832856 0.272802 0.727198 Final coordinates: 10396.6 1212.26 0.266651 0.387755 0.612245 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.457661E-02 Extraneous predicted phases: 7.640962E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 32.541 0.0094 0.1737 0.0246 0.2043 0.0950 0.0011 0.0003 0.4856 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0016 0.0040 0.0017 0.0256 -0.0192 0.0023 0.0001 -0.0068 -0.0060 Composition Misfit: 0.128839E-01 Gt predicted* 67.457 0.0000 0.1405 0.1276 0.1059 0.1974 0.0019 0.0005 0.4210 0.0052 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0049 0.0112 -0.0259 0.0251 -0.0014 -0.0000 0.0011 -0.0052 Composition Misfit: 0.116927E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.002 0.0000 0.0360 0.0358 0.0000 0.7900 0.0081 0.0013 0.0000 0.1288 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.038 -830530. MgO 151.941 -651246. Al2O3 95.151 -0.169201E+07 CaO 138.137 -765554. FeO 165.596 -345957. TiO2 1.619 -975288. Cr2O3 0.395 -0.126391E+07 SiO2 444.122 -920530. O2 5.520 -434144. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 194 converged, 187 successes so far. Misfit function evaluations this try => 265 Misfit this try = 2.189771E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.574889E-07 Bayes score, PP * exp(-Misfit) = 2.519117E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 11980.0 976.693 0.695432 0.897103 0.102897 Final coordinates: 9637.08 1153.03 0.259503 0.371492 0.628508 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.187527E-02 Extraneous predicted phases: 2.244266E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 29.868 0.0099 0.1769 0.0210 0.2072 0.0896 0.0011 0.0003 0.4881 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0020 0.0008 0.0053 0.0227 -0.0139 0.0023 0.0001 -0.0093 -0.0060 Composition Misfit: 0.113026E-01 Gt predicted* 70.129 0.0000 0.1394 0.1278 0.1049 0.1993 0.0018 0.0004 0.4212 0.0052 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0038 0.0109 -0.0249 0.0233 -0.0013 -0.0000 0.0010 -0.0052 Composition Misfit: 0.105727E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0340 0.0263 0.0000 0.7990 0.0076 0.0015 0.0000 0.1317 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.911 -828413. MgO 151.256 -648335. Al2O3 96.980 -0.168136E+07 CaO 135.700 -762938. FeO 167.984 -341156. TiO2 1.572 -962697. Cr2O3 0.397 -0.124548E+07 SiO2 443.201 -912408. O2 5.449 -418166. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 195 converged, 188 successes so far. Misfit function evaluations this try => 542 Misfit this try = 2.173950E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.613741E-07 Bayes score, PP * exp(-Misfit) = 2.557533E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9661.85 996.710 5.576989E-02 0.243700 0.756300 Final coordinates: 9689.98 1166.57 0.267290 0.389812 0.610188 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.162463E-02 Extraneous predicted phases: 1.148710E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 32.143 0.0096 0.1759 0.0224 0.2070 0.0908 0.0012 0.0003 0.4867 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0018 0.0018 0.0039 0.0229 -0.0151 0.0022 0.0001 -0.0079 -0.0061 Composition Misfit: 0.103939E-01 Gt predicted* 67.849 0.0000 0.1398 0.1277 0.1057 0.1983 0.0018 0.0005 0.4211 0.0052 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0042 0.0111 -0.0256 0.0242 -0.0013 -0.0000 0.0011 -0.0052 Composition Misfit: 0.112308E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.008 0.0000 0.0348 0.0282 0.0000 0.7964 0.0085 0.0014 0.0000 0.1308 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.054 -829440. MgO 152.028 -649168. Al2O3 94.920 -0.168391E+07 CaO 138.445 -763728. FeO 165.294 -342494. TiO2 1.625 -965171. Cr2O3 0.395 -0.125016E+07 SiO2 444.238 -914459. O2 5.523 -421417. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 196 converged, 189 successes so far. Misfit function evaluations this try => 270 Misfit this try = 4.208470E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 3.924853E-07 Bayes score, PP * exp(-Misfit) = 3.763104E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13417.0 1249.33 0.286202 0.130618 0.869382 Final coordinates: 10645.7 1121.62 0.187831 0.176205 0.823795 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.203575E-02 Extraneous predicted phases: 4.894614E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 10.446 0.0134 0.1773 0.0138 0.2013 0.0893 0.0005 0.0002 0.4985 0.0056 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0056 0.0004 0.0125 0.0286 -0.0136 0.0029 0.0001 -0.0198 -0.0056 Composition Misfit: 0.377326E-01 Gt predicted* 89.549 0.0000 0.1384 0.1304 0.0950 0.2079 0.0011 0.0004 0.4224 0.0045 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0028 0.0084 -0.0150 0.0146 -0.0006 -0.0000 -0.0002 -0.0045 Composition Misfit: 0.430313E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.005 0.0000 0.0297 0.0229 0.0000 0.8089 0.0018 0.0016 0.0000 0.1351 Effective Bulk* Chemical Potentials (J/mol) Na2O 1.381 -813680. MgO 143.034 -643913. Al2O3 118.938 -0.167362E+07 CaO 106.431 -758272. FeO 196.651 -334958. TiO2 1.003 -963035. Cr2O3 0.414 -0.123349E+07 SiO2 432.147 -906683. O2 4.617 -418936. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 197 converged, 190 successes so far. Misfit function evaluations this try => 351 Misfit this try = 2.977254E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.587910E-07 Bayes score, PP * exp(-Misfit) = 2.511997E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8565.38 1274.71 6.936394E-02 0.651345 0.348655 Final coordinates: 11299.6 1265.66 0.247572 0.343131 0.656869 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.973412E-02 Extraneous predicted phases: 3.841965E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 28.610 0.0095 0.1712 0.0266 0.1998 0.1006 0.0008 0.0003 0.4853 0.0059 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0017 0.0065 -0.0003 0.0301 -0.0249 0.0026 0.0001 -0.0065 -0.0059 Composition Misfit: 0.194736E-01 Gt predicted* 71.385 0.0000 0.1407 0.1281 0.1038 0.1987 0.0017 0.0004 0.4213 0.0051 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0051 0.0106 -0.0238 0.0238 -0.0012 -0.0000 0.0008 -0.0051 Composition Misfit: 0.102605E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.005 0.0000 0.0365 0.0459 0.0000 0.7838 0.0059 0.0010 0.0000 0.1269 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.688 -832057. MgO 150.062 -653900. Al2O3 100.169 -0.170175E+07 CaO 131.449 -768021. FeO 172.147 -350078. TiO2 1.489 -988597. Cr2O3 0.399 -0.128134E+07 SiO2 441.596 -927403. O2 5.327 -448723. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 198 converged, 191 successes so far. Misfit function evaluations this try => 252 Misfit this try = 1.16643 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 7.843078E-08 Bayes score, PP * exp(-Misfit) = 2.442947E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16902.6 1004.27 0.942592 0.279818 0.720182 Final coordinates: 17955.3 1200.91 0.996620 0.999362 6.381738E-04 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.201746 Extraneous predicted phases: 0.964680 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 92.382 0.0084 0.1848 0.0226 0.2294 0.0649 0.0007 0.0003 0.4812 0.0077 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0006 -0.0071 0.0037 0.0005 0.0108 0.0027 0.0000 -0.0024 -0.0077 Composition Misfit: 0.137014E-01 Gt predicted* 6.147 0.0000 0.0886 0.0834 0.2335 0.1675 0.0068 0.0007 0.3986 0.0210 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 0.0470 0.0554 -0.1534 0.0551 -0.0063 -0.0003 0.0235 -0.0210 Composition Misfit: 0.188045 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.515 0.0000 0.0000 0.0000 0.0000 0.7118 0.1470 0.0000 0.0000 0.1412 sph 0.440 0.0000 0.0000 0.0000 0.3333 0.0000 0.3333 0.0000 0.3333 0.0000 q 0.516 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 7.830 -844660. MgO 177.692 -649863. Al2O3 26.380 -0.167274E+07 CaO 229.800 -755218. FeO 75.814 -348347. TiO2 3.400 -948915. Cr2O3 0.342 -0.123190E+07 SiO2 478.741 -897449. O2 9.445 -355195. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 199 converged, 192 successes so far. Misfit function evaluations this try => 142 Misfit this try = 3.509837E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 9.410955E-08 Bayes score, PP * exp(-Misfit) = 9.086375E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14471.9 1283.84 0.727886 0.385923 0.614077 Final coordinates: 13425.5 1344.79 0.328505 0.511628 0.488372 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.509448E-02 Extraneous predicted phases: 3.895649E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 48.304 0.0084 0.1708 0.0320 0.2016 0.0997 0.0012 0.0003 0.4799 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0005 0.0069 -0.0057 0.0283 -0.0240 0.0022 0.0001 -0.0012 -0.0061 Composition Misfit: 0.151900E-01 Gt predicted* 51.694 0.0000 0.1430 0.1249 0.1142 0.1890 0.0027 0.0005 0.4198 0.0059 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0074 0.0138 -0.0342 0.0336 -0.0022 -0.0001 0.0024 -0.0059 Composition Misfit: 0.199045E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.003 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.009 -874146. MgO 157.157 -666436. Al2O3 81.222 -0.171401E+07 CaO 156.702 -779416. FeO 147.412 -366073. TiO2 1.980 -988155. Cr2O3 0.385 -0.130250E+07 SiO2 451.133 -927005. O2 6.053 -424778. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 200 converged, 193 successes so far. Misfit function evaluations this try => 314 Misfit this try = 3.781051E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 8.710641E-08 Bayes score, PP * exp(-Misfit) = 8.387436E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17449.8 1042.22 0.935501 8.469715E-02 0.915303 Final coordinates: 11516.1 1340.41 0.408571 0.637944 0.362056 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.778500E-02 Extraneous predicted phases: 2.551296E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 69.974 0.0072 0.1673 0.0404 0.2025 0.1023 0.0021 0.0003 0.4710 0.0069 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual 0.0007 0.0104 -0.0141 0.0274 -0.0265 0.0013 0.0000 0.0078 -0.0069 Composition Misfit: 0.171741E-01 Gt predicted* 30.022 0.0000 0.1481 0.1254 0.1116 0.1859 0.0028 0.0005 0.4201 0.0057 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0125 0.0134 -0.0316 0.0367 -0.0023 -0.0001 0.0021 -0.0057 Composition Misfit: 0.206109E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0525 0.0695 0.0000 0.7422 0.0210 0.0011 0.0000 0.1137 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.998 -849657. MgO 162.475 -660583. Al2O3 67.019 -0.171618E+07 CaO 175.634 -774772. FeO 128.869 -360638. TiO2 2.348 -994533. Cr2O3 0.374 -0.130492E+07 SiO2 458.283 -937849. O2 6.582 -453230. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 201 converged, 194 successes so far. Misfit function evaluations this try => 255 Misfit this try = 3.516685E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.032329E-07 Bayes score, PP * exp(-Misfit) = 9.966563E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15736.7 985.606 0.810231 0.773535 0.226465 Final coordinates: 14136.6 1335.25 0.318614 0.493660 0.506340 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.516412E-02 Extraneous predicted phases: 2.731290E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.194 0.0088 0.1733 0.0283 0.2019 0.0972 0.0010 0.0003 0.4835 0.0058 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0010 0.0045 -0.0020 0.0280 -0.0215 0.0024 0.0001 -0.0047 -0.0058 Composition Misfit: 0.148137E-01 Gt predicted* 55.804 0.0000 0.1418 0.1247 0.1155 0.1892 0.0026 0.0005 0.4197 0.0060 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0062 0.0140 -0.0355 0.0333 -0.0021 -0.0001 0.0025 -0.0060 Composition Misfit: 0.203504E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.868 -870736. MgO 156.400 -664772. Al2O3 83.243 -0.171072E+07 CaO 154.009 -777359. FeO 150.050 -363977. TiO2 1.928 -985908. Cr2O3 0.386 -0.129753E+07 SiO2 450.116 -924048. O2 5.976 -422878. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 202 converged, 195 successes so far. Misfit function evaluations this try => 528 Misfit this try = 4.620449E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.576544E-07 Bayes score, PP * exp(-Misfit) = 1.505358E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15219.6 1031.07 0.736668 0.210190 0.789810 Final coordinates: 11321.6 1303.00 0.197051 0.204277 0.795723 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.620273E-02 Extraneous predicted phases: 1.762365E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 14.878 0.0110 0.1661 0.0280 0.1899 0.1113 0.0005 0.0003 0.4873 0.0058 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0031 0.0116 -0.0016 0.0400 -0.0355 0.0029 0.0001 -0.0085 -0.0058 Composition Misfit: 0.408121E-01 Gt predicted* 85.120 0.0000 0.1397 0.1301 0.0966 0.2053 0.0012 0.0004 0.4222 0.0045 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0041 0.0087 -0.0165 0.0172 -0.0007 -0.0000 -0.0001 -0.0045 Composition Misfit: 0.539058E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Fsp 0.002 0.0286 0.0000 0.2214 0.1927 0.0000 0.0000 0.0000 0.5573 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 1.601 -852344. MgO 144.216 -662005. Al2O3 115.782 -0.171010E+07 CaO 110.639 -776427. FeO 192.530 -358615. TiO2 1.085 -999982. Cr2O3 0.411 -0.129578E+07 SiO2 433.736 -928211. O2 4.742 -442514. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 203 converged, 196 successes so far. Misfit function evaluations this try => 633 Misfit this try = 0.878682 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.065358E-07 Bayes score, PP * exp(-Misfit) = 8.578052E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14903.5 983.167 0.349111 0.952474 4.752579E-02 Final coordinates: 16365.0 1216.31 0.812463 0.992814 7.186390E-03 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.140381 Extraneous predicted phases: 0.738301 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 99.106 0.0078 0.1777 0.0270 0.2293 0.0699 0.0017 0.0003 0.4795 0.0067 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual 0.0000 0.0000 -0.0007 0.0006 0.0058 0.0017 0.0000 -0.0007 -0.0067 Composition Misfit: 0.215712E-02 Gt predicted* 0.082 0.0000 0.0968 0.1018 0.2108 0.1621 0.0059 0.0006 0.4082 0.0139 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 0.0388 0.0370 -0.1308 0.0604 -0.0054 -0.0002 0.0140 -0.0139 Composition Misfit: 0.138224 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.502 0.0000 0.0000 0.0000 0.0000 0.6415 0.2642 0.0000 0.0000 0.0943 Sp 0.310 0.0000 0.0481 0.0293 0.0000 0.7775 0.0166 0.0016 0.0000 0.1269 Effective Bulk* Chemical Potentials (J/mol) Na2O 7.779 -803555. MgO 177.417 -641976. Al2O3 27.117 -0.167829E+07 CaO 228.819 -747780. FeO 76.775 -339109. TiO2 3.381 -960015. Cr2O3 0.343 -0.124414E+07 SiO2 478.370 -914148. O2 7.797 -424311. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 204 converged, 197 successes so far. Misfit function evaluations this try => 598 Misfit this try = 7.392069E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 9.655193E-08 Bayes score, PP * exp(-Misfit) = 8.967215E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16104.9 971.522 6.944946E-02 0.165541 0.834459 Final coordinates: 16948.9 1036.99 0.160537 8.285502E-02 0.917145 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.388800E-02 Extraneous predicted phases: 3.269373E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.335 0.0283 0.1616 0.0095 0.1866 0.0899 0.0007 0.0004 0.5139 0.0091 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0204 0.0161 0.0168 0.0433 -0.0142 0.0027 -0.0001 -0.0352 -0.0091 Composition Misfit: 0.718171E-01 Gt predicted* 97.660 0.0000 0.1380 0.1317 0.0898 0.2122 0.0007 0.0004 0.4230 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0024 0.0071 -0.0098 0.0103 -0.0002 0.0000 -0.0008 -0.0041 Composition Misfit: 0.207089E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0284 0.0132 0.0000 0.8175 0.0004 0.0021 0.0000 0.1383 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.649 -768634. MgO 139.104 -628321. Al2O3 129.435 -0.164288E+07 CaO 92.441 -740035. FeO 210.355 -316239. TiO2 0.731 -940908. Cr2O3 0.422 -0.118753E+07 SiO2 426.863 -884688. O2 4.221 -403412. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 205 converged, 198 successes so far. Misfit function evaluations this try => 214 Misfit this try = 2.487386E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 4.068625E-07 Bayes score, PP * exp(-Misfit) = 3.968671E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9865.47 1150.76 0.373719 0.863287 0.136713 Final coordinates: 10889.1 1192.72 0.307873 0.474083 0.525917 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.485048E-02 Extraneous predicted phases: 2.337615E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 40.351 0.0093 0.1770 0.0230 0.2081 0.0890 0.0013 0.0003 0.4861 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0015 0.0007 0.0033 0.0218 -0.0133 0.0021 0.0001 -0.0073 -0.0060 Composition Misfit: 0.858350E-02 Gt predicted* 59.646 0.0000 0.1399 0.1258 0.1120 0.1936 0.0022 0.0005 0.4202 0.0058 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0043 0.0129 -0.0319 0.0289 -0.0017 -0.0000 0.0020 -0.0058 Composition Misfit: 0.162670E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0376 0.0304 0.0000 0.7902 0.0117 0.0013 0.0000 0.1288 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.714 -828769. MgO 155.576 -649241. Al2O3 85.444 -0.168669E+07 CaO 151.075 -763179. FeO 152.923 -343736. TiO2 1.871 -967098. Cr2O3 0.388 -0.125554E+07 SiO2 449.008 -916460. O2 5.885 -425779. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 206 converged, 199 successes so far. Misfit function evaluations this try => 577 Misfit this try = 4.773998E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.110734E-08 Bayes score, PP * exp(-Misfit) = 2.012335E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17444.4 972.930 0.841707 0.315768 0.684232 Final coordinates: 17998.4 1317.80 0.353743 0.553528 0.446472 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.767864E-02 Extraneous predicted phases: 6.133307E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.562 0.0098 0.1828 0.0187 0.2063 0.0844 0.0007 0.0002 0.4922 0.0049 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0019 -0.0051 0.0076 0.0236 -0.0086 0.0027 0.0001 -0.0134 -0.0049 Composition Misfit: 0.175155E-01 Gt predicted* 55.428 0.0000 0.1384 0.1212 0.1271 0.1845 0.0032 0.0005 0.4179 0.0072 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0028 0.0176 -0.0471 0.0380 -0.0027 -0.0001 0.0042 -0.0072 Composition Misfit: 0.301632E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.011 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.337 -863453. MgO 158.921 -659468. Al2O3 76.511 -0.169934E+07 CaO 162.982 -769949. FeO 141.261 -358476. TiO2 2.102 -974183. Cr2O3 0.381 -0.128215E+07 SiO2 453.505 -912731. O2 6.246 -409312. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 207 converged, 200 successes so far. Misfit function evaluations this try => 241 Misfit this try = 3.534844E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 9.893311E-08 Bayes score, PP * exp(-Misfit) = 9.549707E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12305.9 1296.48 0.734828 0.116148 0.883852 Final coordinates: 14317.2 1335.63 0.325754 0.506522 0.493478 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.534184E-02 Extraneous predicted phases: 6.595905E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 45.426 0.0088 0.1735 0.0282 0.2026 0.0964 0.0010 0.0002 0.4835 0.0058 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0010 0.0042 -0.0019 0.0273 -0.0206 0.0024 0.0001 -0.0047 -0.0058 Composition Misfit: 0.140423E-01 Gt predicted* 54.570 0.0000 0.1418 0.1243 0.1164 0.1885 0.0027 0.0005 0.4195 0.0061 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0062 0.0144 -0.0364 0.0340 -0.0022 -0.0001 0.0027 -0.0061 Composition Misfit: 0.212995E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.004 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.969 -870824. MgO 156.942 -664655. Al2O3 81.797 -0.171038E+07 CaO 155.937 -777118. FeO 148.161 -363977. TiO2 1.965 -985082. Cr2O3 0.385 -0.129673E+07 SiO2 450.844 -923681. O2 6.033 -421522. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 208 converged, 201 successes so far. Misfit function evaluations this try => 734 Misfit this try = 3.408815E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.158816E-07 Bayes score, PP * exp(-Misfit) = 1.119980E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16632.3 1196.22 0.351545 0.215441 0.784559 Final coordinates: 12960.8 1334.58 0.306428 0.471472 0.528528 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.403603E-02 Extraneous predicted phases: 5.212074E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 43.743 0.0085 0.1703 0.0314 0.2005 0.1012 0.0011 0.0003 0.4807 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0007 0.0075 -0.0051 0.0294 -0.0254 0.0023 0.0001 -0.0019 -0.0061 Composition Misfit: 0.167258E-01 Gt predicted* 56.252 0.0000 0.1427 0.1259 0.1115 0.1910 0.0024 0.0005 0.4203 0.0057 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0071 0.0129 -0.0315 0.0315 -0.0019 -0.0000 0.0019 -0.0057 Composition Misfit: 0.173103E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.005 0.0000 0.0449 0.0674 0.0000 0.7573 0.0105 0.0011 0.0000 0.1188 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.694 -836106. MgO 155.466 -656881. Al2O3 85.738 -0.171284E+07 CaO 150.684 -770113. FeO 153.307 -355913. TiO2 1.863 -997654. Cr2O3 0.388 -0.130088E+07 SiO2 448.860 -935587. O2 5.872 -462021. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 209 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 210 converged, 202 successes so far. Misfit function evaluations this try => 390 Misfit this try = 3.531346E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 8.654496E-08 Bayes score, PP * exp(-Misfit) = 8.354209E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16103.3 1105.56 0.918141 0.429795 0.570205 Final coordinates: 13379.8 1349.20 0.321707 0.500192 0.499808 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.528184E-02 Extraneous predicted phases: 3.161254E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 47.309 0.0084 0.1703 0.0324 0.2009 0.1007 0.0012 0.0003 0.4798 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0005 0.0074 -0.0061 0.0290 -0.0250 0.0022 0.0001 -0.0010 -0.0061 Composition Misfit: 0.161930E-01 Gt predicted* 52.687 0.0000 0.1431 0.1253 0.1133 0.1895 0.0026 0.0005 0.4200 0.0058 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0074 0.0135 -0.0333 0.0330 -0.0021 -0.0001 0.0022 -0.0058 Composition Misfit: 0.190889E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0464 0.0681 0.0000 0.7544 0.0122 0.0009 0.0000 0.1179 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.919 -837841. MgO 156.675 -657651. Al2O3 82.508 -0.171513E+07 CaO 154.988 -770711. FeO 149.091 -357354. TiO2 1.947 -998890. Cr2O3 0.386 -0.130415E+07 SiO2 450.486 -937004. O2 5.995 -463123. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 211 converged, 203 successes so far. Misfit function evaluations this try => 319 Misfit this try = 3.499532E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 8.931148E-08 Bayes score, PP * exp(-Misfit) = 8.624005E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17042.5 1296.32 0.616967 0.420808 0.579192 Final coordinates: 13345.5 1347.71 0.312251 0.482163 0.517837 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.499510E-02 Extraneous predicted phases: 2.198266E-07 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 45.113 0.0085 0.1703 0.0320 0.2005 0.1010 0.0011 0.0003 0.4803 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0006 0.0074 -0.0057 0.0294 -0.0253 0.0023 0.0001 -0.0016 -0.0061 Composition Misfit: 0.169933E-01 Gt predicted* 54.887 0.0000 0.1428 0.1255 0.1122 0.1906 0.0025 0.0005 0.4201 0.0058 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0072 0.0132 -0.0322 0.0319 -0.0020 -0.0001 0.0021 -0.0058 Composition Misfit: 0.180018E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.000 0.0000 0.0462 0.0706 0.0000 0.7533 0.0114 0.0010 0.0000 0.1175 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.778 -836590. MgO 155.916 -657388. Al2O3 84.536 -0.171491E+07 CaO 152.286 -770450. FeO 151.737 -356956. TiO2 1.894 -999161. Cr2O3 0.387 -0.130465E+07 SiO2 449.465 -937028. O2 5.923 -464537. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 212 converged, 204 successes so far. Misfit function evaluations this try => 333 Misfit this try = 7.485924E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 9.434983E-08 Bayes score, PP * exp(-Misfit) = 8.754476E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15398.1 1053.42 0.203005 9.771807E-02 0.902282 Final coordinates: 16371.0 1008.57 0.159608 8.093425E-02 0.919066 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.443813E-02 Extraneous predicted phases: 4.211116E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.227 0.0290 0.1610 0.0091 0.1867 0.0894 0.0008 0.0004 0.5140 0.0096 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0211 0.0167 0.0172 0.0432 -0.0137 0.0026 -0.0001 -0.0352 -0.0096 Composition Misfit: 0.724284E-01 Gt predicted* 97.757 0.0000 0.1380 0.1318 0.0897 0.2123 0.0007 0.0004 0.4231 0.0040 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0023 0.0069 -0.0096 0.0102 -0.0002 0.0000 -0.0009 -0.0040 Composition Misfit: 0.200969E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.016 0.0000 0.0279 0.0113 0.0000 0.8196 0.0003 0.0020 0.0000 0.1389 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.634 -770656. MgO 139.023 -627915. Al2O3 129.651 -0.163847E+07 CaO 92.153 -739796. FeO 210.637 -315003. TiO2 0.726 -933619. Cr2O3 0.422 -0.118035E+07 SiO2 426.755 -881086. O2 4.202 -393296. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 213 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 214 converged, 205 successes so far. Misfit function evaluations this try => 288 Misfit this try = 3.127536E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.652664E-07 Bayes score, PP * exp(-Misfit) = 1.601776E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14398.7 1325.03 0.880572 9.808367E-02 0.901916 Final coordinates: 11524.3 1303.26 0.317359 0.492262 0.507738 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.122261E-02 Extraneous predicted phases: 5.275666E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 47.235 0.0083 0.1693 0.0330 0.2021 0.1008 0.0014 0.0003 0.4784 0.0064 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0004 0.0084 -0.0066 0.0277 -0.0251 0.0020 0.0001 0.0003 -0.0064 Composition Misfit: 0.147843E-01 Gt predicted* 52.759 0.0000 0.1433 0.1263 0.1102 0.1914 0.0024 0.0005 0.4205 0.0055 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0077 0.0125 -0.0301 0.0311 -0.0019 -0.0000 0.0017 -0.0055 Composition Misfit: 0.164383E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.005 0.0000 0.0439 0.0585 0.0000 0.7631 0.0132 0.0011 0.0000 0.1202 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.857 -839101. MgO 156.341 -656786. Al2O3 83.400 -0.170865E+07 CaO 153.800 -770705. FeO 150.255 -354915. TiO2 1.924 -990762. Cr2O3 0.386 -0.129258E+07 SiO2 450.037 -932743. O2 5.961 -452562. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 215 converged, 206 successes so far. Misfit function evaluations this try => 342 Misfit this try = 3.431419E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 9.507861E-08 Bayes score, PP * exp(-Misfit) = 9.187140E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 11135.4 1261.45 0.672103 6.762183E-02 0.932378 Final coordinates: 12135.4 1341.92 0.286894 0.431864 0.568136 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.430096E-02 Extraneous predicted phases: 1.323156E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 40.991 0.0084 0.1681 0.0341 0.1982 0.1050 0.0011 0.0003 0.4786 0.0063 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0005 0.0097 -0.0078 0.0317 -0.0293 0.0023 0.0001 0.0002 -0.0063 Composition Misfit: 0.204193E-01 Gt predicted* 59.006 0.0000 0.1427 0.1271 0.1074 0.1940 0.0022 0.0005 0.4209 0.0053 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0071 0.0116 -0.0273 0.0285 -0.0017 -0.0000 0.0013 -0.0053 Composition Misfit: 0.138817E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.003 0.0000 0.0460 0.0800 0.0000 0.7478 0.0093 0.0011 0.0000 0.1157 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.384 -839954. MgO 153.798 -658848. Al2O3 90.191 -0.171606E+07 CaO 144.748 -772589. FeO 159.121 -357934. TiO2 1.748 -0.100179E+07 Cr2O3 0.392 -0.130536E+07 SiO2 446.618 -938091. O2 5.706 -464726. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 216 converged, 207 successes so far. Misfit function evaluations this try => 259 Misfit this try = 8.782198E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 3.022089E-07 Bayes score, PP * exp(-Misfit) = 2.768004E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8878.37 1070.42 0.950696 0.171513 0.828487 Final coordinates: 13711.5 1031.29 0.179493 0.146306 0.853694 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 8.778825E-02 Extraneous predicted phases: 3.372565E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 7.251 0.0159 0.1852 0.0067 0.2043 0.0754 0.0005 0.0002 0.5063 0.0055 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0081 -0.0074 0.0196 0.0256 0.0003 0.0029 0.0001 -0.0275 -0.0055 Composition Misfit: 0.842912E-01 Gt predicted* 92.740 0.0000 0.1378 0.1306 0.0936 0.2098 0.0009 0.0004 0.4225 0.0044 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0021 0.0081 -0.0136 0.0128 -0.0005 0.0000 -0.0003 -0.0044 Composition Misfit: 0.349703E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.008 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 1.146 -800944. MgO 141.775 -635103. Al2O3 122.300 -0.164961E+07 CaO 101.950 -748100. FeO 201.040 -323255. TiO2 0.916 -937744. Cr2O3 0.416 -0.119523E+07 SiO2 430.455 -886429. O2 4.511 -390422. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 217 converged, 208 successes so far. Misfit function evaluations this try => 334 Misfit this try = 3.221393E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.011540E-07 Bayes score, PP * exp(-Misfit) = 1.947773E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10191.0 1320.95 0.929838 0.877647 0.122353 Final coordinates: 13177.2 1301.63 0.321490 0.499677 0.500323 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.219749E-02 Extraneous predicted phases: 1.644102E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.741 0.0088 0.1736 0.0277 0.2037 0.0955 0.0011 0.0003 0.4833 0.0059 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0010 0.0041 -0.0014 0.0262 -0.0198 0.0023 0.0001 -0.0046 -0.0059 Composition Misfit: 0.125144E-01 Gt predicted* 55.256 0.0000 0.1416 0.1249 0.1148 0.1898 0.0026 0.0005 0.4198 0.0060 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0060 0.0139 -0.0348 0.0327 -0.0021 -0.0001 0.0024 -0.0060 Composition Misfit: 0.196831E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.003 0.0000 0.0427 0.0515 0.0000 0.7700 0.0120 0.0011 0.0000 0.1227 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.915 -831385. MgO 156.654 -653783. Al2O3 82.566 -0.170522E+07 CaO 154.911 -766787. FeO 149.166 -351923. TiO2 1.945 -988921. Cr2O3 0.386 -0.128802E+07 SiO2 450.457 -930019. O2 5.994 -453272. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 218 converged, 209 successes so far. Misfit function evaluations this try => 734 Misfit this try = 0.608165 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 7.854189E-08 Bayes score, PP * exp(-Misfit) = 4.275418E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12807.6 1204.82 0.947778 0.367327 0.632673 Final coordinates: 17987.0 1195.36 0.895976 0.999977 2.309729E-05 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.186560 Extraneous predicted phases: 0.421605 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 91.297 0.0085 0.1855 0.0209 0.2284 0.0646 0.0008 0.0003 0.4840 0.0070 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0007 -0.0078 0.0055 0.0015 0.0111 0.0026 0.0000 -0.0052 -0.0070 Composition Misfit: 0.119673E-01 Gt predicted* 7.947 0.0000 0.0896 0.0871 0.2275 0.1682 0.0069 0.0007 0.4006 0.0194 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 0.0460 0.0516 -0.1475 0.0543 -0.0064 -0.0003 0.0215 -0.0194 Composition Misfit: 0.174593 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.295 0.0000 0.0000 0.0000 0.0000 0.6933 0.1779 0.0000 0.0000 0.1289 sph 0.460 0.0000 0.0000 0.0000 0.3333 0.0000 0.3333 0.0000 0.3333 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 7.835 -835096. MgO 177.718 -647361. Al2O3 26.311 -0.167158E+07 CaO 229.893 -752737. FeO 75.723 -344876. TiO2 3.402 -948023. Cr2O3 0.342 -0.123023E+07 SiO2 478.775 -898587. O2 8.481 -368852. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 219 converged, 210 successes so far. Misfit function evaluations this try => 182 Misfit this try = 3.465566E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.098870E-07 Bayes score, PP * exp(-Misfit) = 1.061441E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9090.21 1308.91 0.236292 5.493872E-02 0.945061 Final coordinates: 12743.3 1337.16 0.287654 0.433916 0.566084 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.456090E-02 Extraneous predicted phases: 9.475859E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 39.805 0.0086 0.1695 0.0316 0.1988 0.1032 0.0010 0.0003 0.4810 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0008 0.0082 -0.0053 0.0311 -0.0274 0.0024 0.0001 -0.0023 -0.0060 Composition Misfit: 0.193811E-01 Gt predicted* 60.188 0.0000 0.1424 0.1266 0.1092 0.1930 0.0022 0.0005 0.4206 0.0055 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0068 0.0122 -0.0292 0.0295 -0.0017 -0.0000 0.0016 -0.0055 Composition Misfit: 0.151798E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.007 0.0000 0.0449 0.0721 0.0000 0.7548 0.0091 0.0011 0.0000 0.1180 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.400 -836263. MgO 153.885 -657364. Al2O3 89.961 -0.171399E+07 CaO 145.055 -770808. FeO 158.820 -356266. TiO2 1.754 -999703. Cr2O3 0.391 -0.130299E+07 SiO2 446.735 -936425. O2 5.711 -464371. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 220 converged, 211 successes so far. Misfit function evaluations this try => 300 Misfit this try = 3.566251E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 8.317263E-08 Bayes score, PP * exp(-Misfit) = 8.025875E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9114.92 1216.54 0.915755 0.282590 0.717410 Final coordinates: 13665.0 1349.99 0.324204 0.503903 0.496097 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.565927E-02 Extraneous predicted phases: 3.240201E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 47.192 0.0084 0.1708 0.0316 0.2011 0.1001 0.0011 0.0003 0.4804 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0006 0.0069 -0.0053 0.0288 -0.0244 0.0023 0.0001 -0.0017 -0.0061 Composition Misfit: 0.157366E-01 Gt predicted* 52.805 0.0000 0.1429 0.1250 0.1143 0.1889 0.0026 0.0005 0.4198 0.0059 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0073 0.0138 -0.0343 0.0336 -0.0021 -0.0001 0.0023 -0.0059 Composition Misfit: 0.199227E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.948 -874795. MgO 156.831 -666777. Al2O3 82.091 -0.171475E+07 CaO 155.545 -779649. FeO 148.546 -366519. TiO2 1.957 -989179. Cr2O3 0.385 -0.130454E+07 SiO2 450.696 -927161. O2 6.020 -425677. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 221 converged, 212 successes so far. Misfit function evaluations this try => 166 Misfit this try = 3.147700E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.054386E-07 Bayes score, PP * exp(-Misfit) = 1.990728E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12876.8 1208.93 0.414022 0.157762 0.842238 Final coordinates: 12829.6 1300.25 0.311906 0.481842 0.518158 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.145036E-02 Extraneous predicted phases: 2.664491E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 43.220 0.0088 0.1727 0.0283 0.2031 0.0967 0.0011 0.0003 0.4830 0.0059 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0010 0.0050 -0.0020 0.0268 -0.0210 0.0023 0.0001 -0.0043 -0.0059 Composition Misfit: 0.133035E-01 Gt predicted* 56.776 0.0000 0.1419 0.1254 0.1130 0.1909 0.0025 0.0005 0.4200 0.0058 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0063 0.0134 -0.0330 0.0316 -0.0020 -0.0000 0.0022 -0.0058 Composition Misfit: 0.181469E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0422 0.0524 0.0000 0.7703 0.0114 0.0011 0.0000 0.1227 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.775 -831700. MgO 155.903 -654193. Al2O3 84.572 -0.170557E+07 CaO 152.238 -767308. FeO 151.784 -352151. TiO2 1.893 -990157. Cr2O3 0.387 -0.128930E+07 SiO2 449.447 -930453. O2 5.918 -453879. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 222 converged, 213 successes so far. Misfit function evaluations this try => 543 Misfit this try = 2.794320E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 3.508168E-07 Bayes score, PP * exp(-Misfit) = 3.411496E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10177.5 1323.67 5.202253E-02 0.921947 7.805271E-02 Final coordinates: 10647.7 1205.36 0.229278 0.296863 0.703137 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.785372E-02 Extraneous predicted phases: 8.948188E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 22.744 0.0104 0.1742 0.0216 0.2016 0.0960 0.0008 0.0003 0.4895 0.0057 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0025 0.0036 0.0047 0.0283 -0.0203 0.0026 0.0001 -0.0107 -0.0057 Composition Misfit: 0.195165E-01 Gt predicted* 77.249 0.0000 0.1397 0.1288 0.1015 0.2015 0.0015 0.0004 0.4216 0.0049 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0041 0.0100 -0.0215 0.0210 -0.0010 -0.0000 0.0006 -0.0049 Composition Misfit: 0.833719E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.007 0.0000 0.0333 0.0352 0.0000 0.7950 0.0047 0.0014 0.0000 0.1304 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.326 -826213. MgO 148.114 -650096. Al2O3 105.371 -0.169050E+07 CaO 124.515 -764432. FeO 178.939 -344173. TiO2 1.355 -977212. Cr2O3 0.403 -0.126174E+07 SiO2 438.977 -919270. O2 5.128 -436216. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 223 converged, 214 successes so far. Misfit function evaluations this try => 584 Misfit this try = 2.582735E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 3.232830E-07 Bayes score, PP * exp(-Misfit) = 3.150403E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10846.7 981.132 0.459640 0.186960 0.813040 Final coordinates: 10639.0 1218.07 0.252373 0.354288 0.645712 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.582722E-02 Extraneous predicted phases: 1.349967E-07 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 28.920 0.0097 0.1736 0.0239 0.2029 0.0960 0.0009 0.0003 0.4868 0.0059 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0019 0.0041 0.0025 0.0270 -0.0202 0.0025 0.0001 -0.0081 -0.0059 Composition Misfit: 0.153210E-01 Gt predicted* 71.079 0.0000 0.1402 0.1280 0.1044 0.1988 0.0017 0.0004 0.4212 0.0051 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0046 0.0108 -0.0244 0.0237 -0.0013 -0.0000 0.0009 -0.0051 Composition Misfit: 0.105062E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.000 0.0000 0.0350 0.0370 0.0000 0.7912 0.0063 0.0013 0.0000 0.1292 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.776 -829245. MgO 150.532 -651216. Al2O3 98.914 -0.169289E+07 CaO 133.121 -765473. FeO 170.509 -345962. TiO2 1.522 -977717. Cr2O3 0.398 -0.126680E+07 SiO2 442.227 -921118. O2 5.379 -436919. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 224 converged, 215 successes so far. Misfit function evaluations this try => 453 Misfit this try = 0.886546 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 7.300376E-08 Bayes score, PP * exp(-Misfit) = 3.008314E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9323.70 1268.90 0.885337 0.150028 0.849972 Final coordinates: 8040.74 1087.05 9.643197E-02 3.340093E-05 0.999967 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 5.295458E-02 Extraneous predicted phases: 0.833591 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 0.001 0.0280 0.1476 0.0195 0.1798 0.1029 0.0010 0.0005 0.5137 0.0069 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0202 0.0301 0.0068 0.0501 -0.0271 0.0024 -0.0002 -0.0350 -0.0069 Composition Misfit: 0.527727E-01 Gt predicted* 98.783 0.0000 0.1355 0.1375 0.0808 0.2175 0.0005 0.0004 0.4260 0.0018 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 0.0001 0.0013 -0.0008 0.0051 0.0000 0.0001 -0.0038 -0.0018 Composition Misfit: 0.181869E-03 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.654 0.0000 0.1446 0.3771 0.0000 0.4386 0.0004 0.0061 0.0000 0.0332 Sp 0.469 0.0000 0.0347 0.0677 0.0000 0.7687 0.0033 0.0050 0.0000 0.1207 Ol 0.093 0.0000 0.3608 0.0000 0.0005 0.3054 0.0000 0.0000 0.3333 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.000 -768877. MgO 135.616 -638291. Al2O3 138.748 -0.167023E+07 CaO 80.028 -753041. FeO 222.513 -327070. TiO2 0.490 -971488. Cr2O3 0.429 -0.122841E+07 SiO2 422.175 -914210. O2 2.682 -464139. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 225 converged, 216 successes so far. Misfit function evaluations this try => 603 Misfit this try = 7.549798E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 4.992586E-08 Bayes score, PP * exp(-Misfit) = 4.629533E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10187.8 1141.41 0.936700 4.892106E-02 0.951079 Final coordinates: 17449.8 1011.32 0.161615 8.232068E-02 0.917679 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.539019E-02 Extraneous predicted phases: 1.077833E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 2.220 0.0295 0.1606 0.0092 0.1859 0.0894 0.0008 0.0004 0.5143 0.0098 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0217 0.0171 0.0171 0.0440 -0.0137 0.0026 -0.0001 -0.0356 -0.0098 Composition Misfit: 0.733029E-01 Gt predicted* 97.765 0.0000 0.1380 0.1316 0.0899 0.2122 0.0007 0.0004 0.4230 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0024 0.0071 -0.0099 0.0103 -0.0002 0.0000 -0.0008 -0.0041 Composition Misfit: 0.208729E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.015 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.645 -783034. MgO 139.081 -630496. Al2O3 129.495 -0.163680E+07 CaO 92.361 -741944. FeO 210.433 -317618. TiO2 0.730 -929008. Cr2O3 0.422 -0.117807E+07 SiO2 426.833 -875681. O2 4.251 -377641. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 226 converged, 217 successes so far. Misfit function evaluations this try => 304 Misfit this try = 2.171252E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.630012E-07 Bayes score, PP * exp(-Misfit) = 2.573523E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8911.96 1221.16 0.453591 0.909027 9.097339E-02 Final coordinates: 9735.05 1174.99 0.284621 0.427130 0.572870 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.169401E-02 Extraneous predicted phases: 1.850914E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 36.307 0.0093 0.1754 0.0238 0.2076 0.0910 0.0013 0.0003 0.4852 0.0062 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0015 0.0023 0.0025 0.0223 -0.0153 0.0021 0.0001 -0.0064 -0.0062 Composition Misfit: 0.896501E-02 Gt predicted* 63.690 0.0000 0.1401 0.1272 0.1075 0.1966 0.0020 0.0005 0.4208 0.0054 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0045 0.0116 -0.0274 0.0259 -0.0015 -0.0000 0.0013 -0.0054 Composition Misfit: 0.127290E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.003 0.0000 0.0358 0.0289 0.0000 0.7938 0.0103 0.0013 0.0000 0.1298 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.347 -831054. MgO 153.599 -649815. Al2O3 90.724 -0.168540E+07 CaO 144.038 -764349. FeO 159.816 -343563. TiO2 1.734 -965660. Cr2O3 0.392 -0.125285E+07 SiO2 446.350 -915563. O2 5.686 -421980. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 227 converged, 218 successes so far. Misfit function evaluations this try => 318 Misfit this try = 0.235522 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.135309E-07 Bayes score, PP * exp(-Misfit) = 8.970739E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10325.5 1007.95 0.170524 0.805387 0.194613 Final coordinates: 9413.72 1032.09 0.222196 0.300527 0.699473 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.475393E-02 Extraneous predicted phases: 0.190768 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 22.319 0.0106 0.1876 0.0116 0.2133 0.0739 0.0005 0.0003 0.4973 0.0049 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0028 -0.0099 0.0147 0.0166 0.0018 0.0029 0.0001 -0.0185 -0.0049 Composition Misfit: 0.382528E-01 Gt predicted* 77.165 0.0000 0.1370 0.1317 0.1001 0.2029 0.0009 0.0004 0.4230 0.0040 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0014 0.0071 -0.0201 0.0197 -0.0004 -0.0000 -0.0009 -0.0040 Composition Misfit: 0.650118E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Opx 0.055 0.0002 0.3179 0.0225 0.0101 0.1645 0.0002 0.0006 0.4809 0.0030 Ilm 0.251 0.0000 0.0000 0.0000 0.0000 0.6890 0.1850 0.0000 0.0000 0.1260 Sp 0.210 0.0000 0.0301 0.0171 0.0000 0.8117 0.0019 0.0029 0.0000 0.1363 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.355 -807953. MgO 148.269 -638284. Al2O3 104.959 -0.165782E+07 CaO 125.064 -752402. FeO 178.401 -327004. TiO2 1.365 -946076. Cr2O3 0.403 -0.120554E+07 SiO2 439.184 -897165. O2 4.955 -404182. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 228 converged, 219 successes so far. Misfit function evaluations this try => 242 Misfit this try = 2.304639E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.475505E-07 Bayes score, PP * exp(-Misfit) = 2.419106E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9178.07 1066.11 0.807887 0.503198 0.496802 Final coordinates: 9581.69 1136.02 0.240854 0.326141 0.673859 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.304055E-02 Extraneous predicted phases: 5.838759E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 24.989 0.0103 0.1778 0.0190 0.2068 0.0887 0.0010 0.0003 0.4902 0.0059 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0025 -0.0001 0.0073 0.0231 -0.0130 0.0024 0.0001 -0.0114 -0.0059 Composition Misfit: 0.141809E-01 Gt predicted* 75.009 0.0000 0.1390 0.1284 0.1026 0.2014 0.0016 0.0004 0.4214 0.0050 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0034 0.0103 -0.0226 0.0211 -0.0011 -0.0000 0.0007 -0.0050 Composition Misfit: 0.885966E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.002 0.0000 0.0326 0.0241 0.0000 0.8028 0.0060 0.0016 0.0000 0.1330 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.555 -825985. MgO 149.347 -647146. Al2O3 102.079 -0.167818E+07 CaO 128.903 -761795. FeO 174.641 -339274. TiO2 1.440 -960324. Cr2O3 0.401 -0.124001E+07 SiO2 440.634 -909987. O2 5.258 -415311. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 229 converged, 220 successes so far. Misfit function evaluations this try => 738 Misfit this try = 5.021567E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 7.724265E-08 Bayes score, PP * exp(-Misfit) = 7.345964E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15769.5 1328.50 8.816114E-02 0.571326 0.428674 Final coordinates: 15723.1 1324.13 0.241507 0.326585 0.673415 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 5.020471E-02 Extraneous predicted phases: 1.096427E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 24.460 0.0106 0.1763 0.0200 0.1961 0.0982 0.0004 0.0002 0.4933 0.0048 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0027 0.0014 0.0063 0.0338 -0.0225 0.0030 0.0001 -0.0146 -0.0048 Composition Misfit: 0.382604E-01 Gt predicted* 75.536 0.0000 0.1398 0.1273 0.1068 0.1976 0.0018 0.0005 0.4209 0.0054 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0042 0.0114 -0.0268 0.0249 -0.0013 -0.0000 0.0013 -0.0054 Composition Misfit: 0.119444E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.005 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.559 -863489. MgO 149.366 -662134. Al2O3 102.029 -0.170618E+07 CaO 128.969 -774264. FeO 174.576 -359915. TiO2 1.441 -989737. Cr2O3 0.401 -0.129183E+07 SiO2 440.659 -918854. O2 5.270 -425946. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 230 converged, 221 successes so far. Misfit function evaluations this try => 289 Misfit this try = 3.480907E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 8.444192E-08 Bayes score, PP * exp(-Misfit) = 8.155314E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17478.7 1117.94 0.642840 0.822013 0.177987 Final coordinates: 13514.7 1349.95 0.314815 0.485800 0.514200 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.478806E-02 Extraneous predicted phases: 2.100551E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 45.368 0.0085 0.1704 0.0319 0.2007 0.1007 0.0011 0.0003 0.4805 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0006 0.0073 -0.0056 0.0292 -0.0250 0.0023 0.0001 -0.0017 -0.0060 Composition Misfit: 0.164461E-01 Gt predicted* 54.625 0.0000 0.1429 0.1253 0.1126 0.1903 0.0025 0.0005 0.4200 0.0058 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0073 0.0134 -0.0326 0.0322 -0.0020 -0.0001 0.0022 -0.0058 Composition Misfit: 0.183419E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.006 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.806 -874717. MgO 156.069 -666884. Al2O3 84.127 -0.171510E+07 CaO 152.831 -779904. FeO 151.203 -366556. TiO2 1.905 -990112. Cr2O3 0.387 -0.130361E+07 SiO2 449.671 -927504. O2 5.950 -426701. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 231 converged, 222 successes so far. Misfit function evaluations this try => 417 Misfit this try = 5.017591E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 3.091448E-07 Bayes score, PP * exp(-Misfit) = 2.940159E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15412.2 1159.70 8.453021E-02 0.181701 0.818299 Final coordinates: 10122.9 1115.31 0.163021 9.354686E-02 0.906453 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.956571E-02 Extraneous predicted phases: 6.101982E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 3.495 0.0214 0.1608 0.0158 0.1904 0.0992 0.0005 0.0004 0.5036 0.0079 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0135 0.0169 0.0106 0.0395 -0.0235 0.0029 -0.0000 -0.0248 -0.0079 Composition Misfit: 0.473115E-01 Gt predicted* 96.482 0.0000 0.1382 0.1317 0.0902 0.2116 0.0008 0.0004 0.4230 0.0041 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0026 0.0071 -0.0102 0.0109 -0.0003 0.0000 -0.0008 -0.0041 Composition Misfit: 0.225419E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.019 0.0000 0.0284 0.0223 0.0000 0.8108 0.0008 0.0022 0.0000 0.1355 Fsp 0.004 0.0495 0.0000 0.2005 0.1510 0.0000 0.0000 0.0000 0.5990 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.733 -808445. MgO 139.554 -645206. Al2O3 128.233 -0.167232E+07 CaO 94.043 -759881. FeO 208.785 -335909. TiO2 0.762 -965916. Cr2O3 0.421 -0.123077E+07 SiO2 427.469 -906063. O2 4.255 -412723. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 232 converged, 223 successes so far. Misfit function evaluations this try => 358 Misfit this try = 2.216108E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.626933E-07 Bayes score, PP * exp(-Misfit) = 2.569358E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8488.22 1125.60 0.370025 0.477827 0.522173 Final coordinates: 9673.93 1151.83 0.246815 0.340517 0.659483 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.214612E-02 Extraneous predicted phases: 1.495682E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 26.736 0.0101 0.1770 0.0204 0.2062 0.0902 0.0011 0.0002 0.4888 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0023 0.0008 0.0059 0.0237 -0.0145 0.0024 0.0001 -0.0100 -0.0060 Composition Misfit: 0.127785E-01 Gt predicted* 73.258 0.0000 0.1392 0.1283 0.1033 0.2007 0.0016 0.0005 0.4214 0.0050 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0036 0.0105 -0.0233 0.0219 -0.0011 -0.0000 0.0008 -0.0050 Composition Misfit: 0.936767E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Fsp 0.005 0.0185 0.0000 0.2315 0.2131 0.0000 0.0000 0.0000 0.5369 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.668 -828092. MgO 149.952 -648353. Al2O3 100.463 -0.168110E+07 CaO 131.057 -762933. FeO 172.531 -341025. TiO2 1.482 -963712. Cr2O3 0.400 -0.124559E+07 SiO2 441.448 -912028. O2 5.323 -417655. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 233 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 234 converged, 224 successes so far. Misfit function evaluations this try => 247 Misfit this try = 2.137816E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.618830E-07 Bayes score, PP * exp(-Misfit) = 2.563438E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9061.13 1181.84 0.298533 0.324445 0.675555 Final coordinates: 9682.82 1162.63 0.269577 0.394363 0.605637 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.136868E-02 Extraneous predicted phases: 9.485154E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 32.487 0.0096 0.1763 0.0222 0.2073 0.0901 0.0012 0.0003 0.4868 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0018 0.0014 0.0041 0.0226 -0.0144 0.0022 0.0001 -0.0080 -0.0061 Composition Misfit: 0.996537E-02 Gt predicted* 67.511 0.0000 0.1397 0.1276 0.1060 0.1982 0.0018 0.0005 0.4210 0.0053 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0040 0.0112 -0.0259 0.0243 -0.0013 -0.0000 0.0011 -0.0053 Composition Misfit: 0.114033E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.002 0.0000 0.0346 0.0273 0.0000 0.7972 0.0085 0.0015 0.0000 0.1310 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.090 -829045. MgO 152.219 -648896. Al2O3 94.408 -0.168306E+07 CaO 139.127 -763420. FeO 164.626 -342134. TiO2 1.638 -964313. Cr2O3 0.395 -0.124829E+07 SiO2 444.496 -913882. O2 5.547 -420249. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 235 converged, 225 successes so far. Misfit function evaluations this try => 626 Misfit this try = 4.548924E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.207098E-08 Bayes score, PP * exp(-Misfit) = 1.153419E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16001.7 1051.57 0.891390 0.910917 8.908261E-02 Final coordinates: 18000.0 1348.26 0.348951 0.547719 0.452281 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.547471E-02 Extraneous predicted phases: 1.453055E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 45.281 0.0095 0.1803 0.0212 0.2051 0.0876 0.0007 0.0002 0.4902 0.0051 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0017 -0.0026 0.0051 0.0248 -0.0119 0.0027 0.0001 -0.0115 -0.0051 Composition Misfit: 0.163832E-01 Gt predicted* 54.716 0.0000 0.1394 0.1216 0.1255 0.1846 0.0032 0.0005 0.4182 0.0070 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0038 0.0171 -0.0455 0.0379 -0.0027 -0.0001 0.0040 -0.0070 Composition Misfit: 0.290915E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.003 0.0000 0.0446 0.0538 0.0000 0.7678 0.0099 0.0009 0.0000 0.1230 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.291 -815829. MgO 158.676 -649134. Al2O3 77.164 -0.170606E+07 CaO 162.111 -759612. FeO 142.114 -349087. TiO2 2.085 -994171. Cr2O3 0.382 -0.129309E+07 SiO2 453.176 -930443. O2 6.199 -468158. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 236 converged, 226 successes so far. Misfit function evaluations this try => 196 Misfit this try = 3.367717E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.340246E-07 Bayes score, PP * exp(-Misfit) = 1.295862E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12568.1 1271.15 0.789961 0.289374 0.710626 Final coordinates: 13102.2 1326.48 0.294826 0.447130 0.552870 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.366854E-02 Extraneous predicted phases: 8.629410E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 40.139 0.0088 0.1711 0.0295 0.2003 0.1006 0.0010 0.0003 0.4826 0.0059 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0010 0.0066 -0.0032 0.0296 -0.0248 0.0024 0.0001 -0.0038 -0.0059 Composition Misfit: 0.172228E-01 Gt predicted* 59.857 0.0000 0.1421 0.1261 0.1110 0.1921 0.0023 0.0005 0.4203 0.0056 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0065 0.0127 -0.0309 0.0304 -0.0018 -0.0000 0.0018 -0.0056 Composition Misfit: 0.164457E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.004 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.503 -869338. MgO 154.441 -664778. Al2O3 88.475 -0.171096E+07 CaO 147.036 -777962. FeO 156.880 -363424. TiO2 1.792 -987673. Cr2O3 0.390 -0.129768E+07 SiO2 447.482 -925257. O2 5.782 -425814. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 237 converged, 227 successes so far. Misfit function evaluations this try => 598 Misfit this try = 4.961977E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 3.516988E-07 Bayes score, PP * exp(-Misfit) = 3.346735E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8804.01 1109.28 7.039809E-02 6.615259E-02 0.933847 Final coordinates: 10426.7 1114.33 0.167046 0.106841 0.893159 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.948354E-02 Extraneous predicted phases: 1.362244E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 4.538 0.0188 0.1671 0.0142 0.1936 0.0956 0.0005 0.0003 0.5028 0.0070 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0109 0.0106 0.0121 0.0363 -0.0199 0.0029 0.0000 -0.0240 -0.0070 Composition Misfit: 0.469238E-01 Gt predicted* 95.453 0.0000 0.1382 0.1314 0.0911 0.2110 0.0008 0.0004 0.4229 0.0042 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0026 0.0073 -0.0111 0.0115 -0.0003 0.0000 -0.0007 -0.0042 Composition Misfit: 0.255976E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.009 0.0000 0.0289 0.0231 0.0000 0.8099 0.0008 0.0018 0.0000 0.1354 Effective Bulk* Chemical Potentials (J/mol) Na2O 0.837 -808780. MgO 140.113 -644309. Al2O3 126.738 -0.167198E+07 CaO 96.036 -758776. FeO 206.834 -334932. TiO2 0.801 -964090. Cr2O3 0.420 -0.123055E+07 SiO2 428.221 -905661. O2 4.319 -414928. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 238 converged, 228 successes so far. Misfit function evaluations this try => 318 Misfit this try = 2.846713E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.868383E-07 Bayes score, PP * exp(-Misfit) = 2.787879E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13746.5 1323.81 0.887990 0.821070 0.178930 Final coordinates: 11856.1 1267.69 0.291595 0.442071 0.557929 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.836607E-02 Extraneous predicted phases: 1.010676E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 38.754 0.0090 0.1730 0.0270 0.2033 0.0964 0.0011 0.0003 0.4839 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0012 0.0047 -0.0007 0.0266 -0.0207 0.0023 0.0001 -0.0051 -0.0060 Composition Misfit: 0.132632E-01 Gt predicted* 61.239 0.0000 0.1413 0.1265 0.1098 0.1938 0.0022 0.0005 0.4205 0.0055 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0056 0.0123 -0.0298 0.0288 -0.0017 -0.0000 0.0017 -0.0055 Composition Misfit: 0.151028E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.008 0.0000 0.0394 0.0456 0.0000 0.7788 0.0096 0.0012 0.0000 0.1254 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.464 -831554. MgO 154.228 -653186. Al2O3 89.044 -0.170068E+07 CaO 146.278 -766798. FeO 157.623 -349879. TiO2 1.777 -984660. Cr2O3 0.391 -0.127900E+07 SiO2 447.196 -926841. O2 5.745 -446799. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 239 converged, 229 successes so far. Misfit function evaluations this try => 217 Misfit this try = 4.520008E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.998490E-08 Bayes score, PP * exp(-Misfit) = 1.910170E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17525.1 1313.34 0.775992 0.425940 0.574060 Final coordinates: 17687.4 1334.58 0.343914 0.539185 0.460815 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.519169E-02 Extraneous predicted phases: 8.388757E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.166 0.0096 0.1809 0.0205 0.2052 0.0870 0.0007 0.0002 0.4908 0.0050 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0018 -0.0032 0.0058 0.0247 -0.0113 0.0027 0.0001 -0.0120 -0.0050 Composition Misfit: 0.170539E-01 Gt predicted* 55.832 0.0000 0.1391 0.1219 0.1248 0.1854 0.0031 0.0005 0.4183 0.0070 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0035 0.0169 -0.0448 0.0371 -0.0026 -0.0001 0.0039 -0.0070 Composition Misfit: 0.281378E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.002 0.0000 0.0437 0.0505 0.0000 0.7708 0.0103 0.0010 0.0000 0.1237 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.225 -814972. MgO 158.317 -648431. Al2O3 78.124 -0.170367E+07 CaO 160.832 -759082. FeO 143.367 -347898. TiO2 2.060 -991833. Cr2O3 0.382 -0.128793E+07 SiO2 452.693 -928817. O2 6.163 -465505. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 240 converged, 230 successes so far. Misfit function evaluations this try => 195 Misfit this try = 2.711767E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 3.047107E-07 Bayes score, PP * exp(-Misfit) = 2.965587E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9150.57 1327.94 0.525189 0.650358 0.349642 Final coordinates: 10721.9 1230.20 0.367263 0.576859 0.423141 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.709995E-02 Extraneous predicted phases: 1.772056E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 54.494 0.0083 0.1735 0.0293 0.2086 0.0920 0.0018 0.0003 0.4797 0.0065 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0005 0.0042 -0.0029 0.0213 -0.0163 0.0016 0.0001 -0.0009 -0.0065 Composition Misfit: 0.698571E-02 Gt predicted* 45.500 0.0000 0.1419 0.1248 0.1151 0.1893 0.0026 0.0005 0.4197 0.0060 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0063 0.0139 -0.0351 0.0332 -0.0021 -0.0000 0.0024 -0.0060 Composition Misfit: 0.201142E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Fsp 0.005 0.0169 0.0000 0.2331 0.2162 0.0000 0.0000 0.0000 0.5338 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.520 -843918. MgO 159.903 -654586. Al2O3 73.888 -0.169436E+07 CaO 166.479 -768620. FeO 137.836 -350739. TiO2 2.170 -970742. Cr2O3 0.379 -0.126824E+07 SiO2 454.826 -920284. O2 6.328 -422360. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 241 converged, 231 successes so far. Misfit function evaluations this try => 339 Misfit this try = 2.196247E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.595780E-07 Bayes score, PP * exp(-Misfit) = 2.539392E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16624.5 987.745 0.647711 0.945507 5.449309E-02 Final coordinates: 9669.98 1164.14 0.266107 0.386262 0.613738 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.165482E-02 Extraneous predicted phases: 3.076445E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 31.711 0.0096 0.1762 0.0222 0.2070 0.0906 0.0012 0.0003 0.4869 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0018 0.0016 0.0041 0.0229 -0.0149 0.0022 0.0001 -0.0081 -0.0061 Composition Misfit: 0.105630E-01 Gt predicted* 68.262 0.0000 0.1397 0.1277 0.1055 0.1985 0.0018 0.0005 0.4211 0.0052 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0041 0.0111 -0.0255 0.0240 -0.0013 -0.0000 0.0011 -0.0052 Composition Misfit: 0.110918E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.008 0.0000 0.0346 0.0275 0.0000 0.7972 0.0083 0.0014 0.0000 0.1310 Fsp 0.019 0.0179 0.0000 0.2321 0.2142 0.0000 0.0000 0.0000 0.5358 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.026 -829715. MgO 151.878 -649139. Al2O3 95.319 -0.168350E+07 CaO 137.913 -763735. FeO 165.815 -342361. TiO2 1.615 -964540. Cr2O3 0.396 -0.124924E+07 SiO2 444.037 -913997. O2 5.516 -420259. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 242 converged, 232 successes so far. Misfit function evaluations this try => 275 Misfit this try = 2.549976E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.612834E-07 Bayes score, PP * exp(-Misfit) = 2.547050E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14635.3 1030.73 0.228874 0.748470 0.251530 Final coordinates: 9744.40 1120.79 0.228356 0.294858 0.705142 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.526991E-02 Extraneous predicted phases: 2.298484E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 21.626 0.0108 0.1793 0.0171 0.2068 0.0868 0.0009 0.0002 0.4924 0.0057 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0030 -0.0015 0.0092 0.0231 -0.0111 0.0025 0.0001 -0.0136 -0.0057 Composition Misfit: 0.175120E-01 Gt predicted* 78.361 0.0000 0.1387 0.1289 0.1011 0.2029 0.0015 0.0004 0.4217 0.0049 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0030 0.0099 -0.0211 0.0196 -0.0010 -0.0000 0.0005 -0.0049 Composition Misfit: 0.775792E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.003 0.0000 0.0000 0.0000 0.0000 0.6675 0.2209 0.0000 0.0000 0.1116 Sp 0.011 0.0000 0.0319 0.0224 0.0000 0.8053 0.0049 0.0017 0.0000 0.1339 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.310 -823095. MgO 148.030 -645738. Al2O3 105.597 -0.167490E+07 CaO 124.214 -760312. FeO 179.233 -337283. TiO2 1.349 -957788. Cr2O3 0.404 -0.123485E+07 SiO2 438.863 -907511. O2 5.116 -412741. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 243 converged, 233 successes so far. Misfit function evaluations this try => 443 Misfit this try = 0.174679 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 1.396323E-07 Bayes score, PP * exp(-Misfit) = 1.172529E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10444.0 1274.67 0.888721 0.299477 0.700523 Final coordinates: 16185.3 1268.78 0.696240 0.900837 9.916253E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 7.692059E-02 Extraneous predicted phases: 9.775867E-02 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 87.337 0.0080 0.1797 0.0271 0.2205 0.0765 0.0015 0.0003 0.4793 0.0070 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0002 -0.0020 -0.0008 0.0094 -0.0008 0.0019 0.0000 -0.0005 -0.0070 Composition Misfit: 0.273411E-02 Gt predicted* 12.301 0.0000 0.1255 0.1075 0.1661 0.1719 0.0054 0.0006 0.4111 0.0118 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 0.0101 0.0312 -0.0861 0.0506 -0.0049 -0.0002 0.0110 -0.0118 Composition Misfit: 0.741865E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Ilm 0.171 0.0000 0.0000 0.0000 0.0000 0.6539 0.2435 0.0000 0.0000 0.1026 sph 0.185 0.0000 0.0000 0.0000 0.3333 0.0000 0.3333 0.0000 0.3333 0.0000 q 0.005 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 7.058 -859927. MgO 173.544 -656671. Al2O3 37.459 -0.169045E+07 CaO 215.034 -766366. FeO 90.277 -356067. TiO2 3.113 -960342. Cr2O3 0.351 -0.126224E+07 SiO2 473.164 -910348. O2 7.857 -385746. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 244 converged, 234 successes so far. Misfit function evaluations this try => 262 Misfit this try = 4.224036E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 3.076154E-08 Bayes score, PP * exp(-Misfit) = 2.948922E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16121.6 1295.90 0.797128 0.881806 0.118194 Final coordinates: 16994.6 1337.26 0.334067 0.522221 0.477779 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 4.222897E-02 Extraneous predicted phases: 1.138178E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 43.342 0.0095 0.1794 0.0219 0.2042 0.0894 0.0007 0.0002 0.4896 0.0052 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0017 -0.0016 0.0044 0.0257 -0.0136 0.0027 0.0001 -0.0108 -0.0052 Composition Misfit: 0.163748E-01 Gt predicted* 56.656 0.0000 0.1397 0.1227 0.1223 0.1865 0.0029 0.0005 0.4187 0.0067 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0041 0.0161 -0.0423 0.0360 -0.0024 -0.0001 0.0035 -0.0067 Composition Misfit: 0.258542E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.003 0.0000 0.0438 0.0533 0.0000 0.7690 0.0099 0.0010 0.0000 0.1231 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.092 -818357. MgO 157.603 -649949. Al2O3 80.031 -0.170566E+07 CaO 158.290 -760956. FeO 145.857 -349371. TiO2 2.011 -993308. Cr2O3 0.384 -0.129144E+07 SiO2 451.733 -930190. O2 6.091 -465634. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 245 converged, 235 successes so far. Misfit function evaluations this try => 189 Misfit this try = 3.502029E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 9.379244E-08 Bayes score, PP * exp(-Misfit) = 9.056465E-08 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14286.0 1051.90 0.900543 0.110330 0.889670 Final coordinates: 13278.6 1345.39 0.319162 0.494869 0.505131 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.501949E-02 Extraneous predicted phases: 8.016482E-07 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 46.626 0.0084 0.1703 0.0322 0.2008 0.1008 0.0012 0.0003 0.4799 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0006 0.0074 -0.0058 0.0291 -0.0251 0.0022 0.0001 -0.0011 -0.0061 Composition Misfit: 0.162740E-01 Gt predicted* 53.373 0.0000 0.1430 0.1254 0.1130 0.1898 0.0026 0.0005 0.4200 0.0058 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0074 0.0134 -0.0329 0.0327 -0.0021 -0.0000 0.0021 -0.0058 Composition Misfit: 0.187455E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 q 0.001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.877 -874090. MgO 156.451 -666664. Al2O3 83.107 -0.171447E+07 CaO 154.191 -779698. FeO 149.872 -366182. TiO2 1.931 -989447. Cr2O3 0.386 -0.130348E+07 SiO2 450.185 -927428. O2 5.979 -426052. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 246 converged, 236 successes so far. Misfit function evaluations this try => 140 Misfit this try = 2.177303E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.684236E-07 Bayes score, PP * exp(-Misfit) = 2.626424E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8607.03 1304.70 9.655917E-02 0.528829 0.471171 Final coordinates: 9768.03 1173.64 0.277464 0.411609 0.588391 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.177104E-02 Extraneous predicted phases: 1.990569E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 34.547 0.0094 0.1756 0.0232 0.2072 0.0911 0.0012 0.0003 0.4858 0.0061 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0016 0.0021 0.0031 0.0227 -0.0153 0.0022 0.0001 -0.0071 -0.0061 Composition Misfit: 0.960943E-02 Gt predicted* 65.452 0.0000 0.1400 0.1273 0.1068 0.1973 0.0019 0.0005 0.4209 0.0053 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0044 0.0114 -0.0268 0.0252 -0.0014 -0.0000 0.0012 -0.0053 Composition Misfit: 0.121616E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.001 0.0000 0.0354 0.0289 0.0000 0.7948 0.0093 0.0014 0.0000 0.1302 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.225 -830445. MgO 152.946 -649638. Al2O3 92.469 -0.168514E+07 CaO 141.712 -764155. FeO 162.095 -343258. TiO2 1.689 -965938. Cr2O3 0.393 -0.125221E+07 SiO2 445.472 -915338. O2 5.622 -422291. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 247 converged, 237 successes so far. Misfit function evaluations this try => 245 Misfit this try = 3.222666E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 3.058036E-07 Bayes score, PP * exp(-Misfit) = 2.961057E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12295.1 1280.72 0.283929 0.244844 0.755156 Final coordinates: 13084.3 1271.05 0.270653 0.397715 0.602285 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 3.199343E-02 Extraneous predicted phases: 2.332304E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 32.453 0.0097 0.1755 0.0229 0.2019 0.0949 0.0008 0.0002 0.4886 0.0055 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0019 0.0022 0.0034 0.0280 -0.0192 0.0026 0.0001 -0.0098 -0.0055 Composition Misfit: 0.178009E-01 Gt predicted* 67.536 0.0000 0.1403 0.1266 0.1093 0.1951 0.0020 0.0005 0.4206 0.0055 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0047 0.0121 -0.0293 0.0274 -0.0016 -0.0000 0.0016 -0.0055 Composition Misfit: 0.141925E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.012 0.0000 0.0381 0.0461 0.0000 0.7813 0.0073 0.0010 0.0000 0.1263 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.116 -823921. MgO 152.361 -650883. Al2O3 94.031 -0.169927E+07 CaO 139.630 -763997. FeO 164.134 -347502. TiO2 1.648 -986501. Cr2O3 0.395 -0.127921E+07 SiO2 444.685 -925943. O2 5.553 -452571. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 248 converged, 238 successes so far. Misfit function evaluations this try => 212 Misfit this try = 2.661284E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 4.686805E-07 Bayes score, PP * exp(-Misfit) = 4.563721E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10705.2 1145.10 0.380554 0.899746 0.100254 Final coordinates: 11367.4 1193.13 0.331105 0.517167 0.482833 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.657618E-02 Extraneous predicted phases: 3.665978E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 44.306 0.0092 0.1784 0.0226 0.2094 0.0866 0.0014 0.0003 0.4862 0.0059 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0014 -0.0007 0.0037 0.0205 -0.0109 0.0020 0.0001 -0.0074 -0.0059 Composition Misfit: 0.735424E-02 Gt predicted* 55.690 0.0000 0.1394 0.1248 0.1156 0.1915 0.0025 0.0005 0.4197 0.0061 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0038 0.0140 -0.0356 0.0310 -0.0020 -0.0000 0.0025 -0.0061 Composition Misfit: 0.192219E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.004 0.0000 0.0387 0.0292 0.0000 0.7893 0.0131 0.0012 0.0000 0.1286 Effective Bulk* Chemical Potentials (J/mol) Na2O 4.052 -827793. MgO 157.390 -648595. Al2O3 80.600 -0.168566E+07 CaO 157.533 -762239. FeO 146.599 -343318. TiO2 1.996 -965466. Cr2O3 0.384 -0.125430E+07 SiO2 451.447 -915669. O2 6.067 -424264. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 249 converged, 239 successes so far. Misfit function evaluations this try => 293 Misfit this try = 2.188082E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.524757E-07 Bayes score, PP * exp(-Misfit) = 2.470113E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12106.7 1304.74 0.358275 0.433789 0.566211 Final coordinates: 9604.66 1157.19 0.251526 0.352958 0.647042 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.179596E-02 Extraneous predicted phases: 8.485830E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 28.179 0.0099 0.1765 0.0212 0.2064 0.0905 0.0011 0.0003 0.4881 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0021 0.0012 0.0051 0.0235 -0.0148 0.0023 0.0001 -0.0093 -0.0060 Composition Misfit: 0.120211E-01 Gt predicted* 71.814 0.0000 0.1394 0.1282 0.1038 0.2001 0.0017 0.0004 0.4213 0.0051 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0038 0.0106 -0.0238 0.0224 -0.0012 -0.0000 0.0008 -0.0051 Composition Misfit: 0.977481E-02 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Sp 0.007 0.0000 0.0334 0.0269 0.0000 0.7996 0.0067 0.0015 0.0000 0.1319 Effective Bulk* Chemical Potentials (J/mol) Na2O 2.765 -827966. MgO 150.476 -648568. Al2O3 99.064 -0.168228E+07 CaO 132.922 -763188. FeO 170.704 -341460. TiO2 1.518 -964563. Cr2O3 0.398 -0.124770E+07 SiO2 442.152 -913228. O2 5.367 -420220. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 250 converged, 240 successes so far. Misfit function evaluations this try => 405 Misfit this try = 2.858519E-02 Best Misfit so far = 2.129366E-02 obtained on Try 154 Prior probability, PP = 2.633038E-07 Bayes score, PP * exp(-Misfit) = 2.558838E-07 Best Bayes score so far = 6.118377E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9124.05 1144.81 0.539866 7.350141E-02 0.926499 Final coordinates: 11725.1 1272.71 0.285271 0.427973 0.572027 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 2.857315E-02 Extraneous predicted phases: 1.203308E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Cpx predicted* 37.569 0.0090 0.1724 0.0276 0.2022 0.0979 0.0011 0.0003 0.4835 0.0060 observed* 0.0078 0.1777 0.0263 0.2299 0.0757 0.0034 0.0003 0.4788 0.0000 residual -0.0012 0.0053 -0.0013 0.0277 -0.0222 0.0023 0.0001 -0.0047 -0.0060 Composition Misfit: 0.142679E-01 Gt predicted* 62.426 0.0000 0.1413 0.1267 0.1089 0.1944 0.0021 0.0005 0.4207 0.0055 observed* 0.0000 0.1356 0.1388 0.0800 0.2225 0.0005 0.0004 0.4222 0.0000 residual 0.0000 -0.0057 0.0120 -0.0288 0.0281 -0.0016 -0.0000 0.0015 -0.0055 Composition Misfit: 0.143053E-01 The following predicted phases are not observed: vol % Na2O MgO Al2O3 CaO FeO TiO2 Cr2O3 SiO2 O2 Fsp 0.005 0.0206 0.0000 0.2294 0.2089 0.0000 0.0000 0.0000 0.5411 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 3.353 -855518. MgO 153.634 -659504. Al2O3 90.629 -0.170202E+07 CaO 144.165 -773246. FeO 159.692 -356342. TiO2 1.736 -980744. Cr2O3 0.392 -0.128171E+07 SiO2 446.398 -922110. O2 5.694 -425236. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 2 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10276.7 1209.24 0.226069 0.416563 0.583437 2.232520E-02 Mean perturbed parameters: 9983.34 1192.36 0.249985 0.410361 0.589639 2.180943E-02 Parameter standard deviation: 586.661 33.7574 4.783359E-02 1.240489E-02 1.240489E-02 1.031539E-03 -------------------------------------------------------------------------------- After 3 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10510.7 1206.45 0.228557 0.455616 0.544384 2.416279E-02 Mean perturbed parameters: 10159.1 1197.06 0.242843 0.425446 0.574554 2.259388E-02 Parameter standard deviation: 713.362 32.3930 4.660578E-02 3.742826E-02 3.742826E-02 2.155921E-03 -------------------------------------------------------------------------------- After 4 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10275.7 1207.95 0.258728 0.416138 0.583862 2.092899E-02 Mean perturbed parameters: 10188.3 1199.78 0.246814 0.423119 0.576881 2.217766E-02 Parameter standard deviation: 673.501 32.4193 3.904888E-02 3.133289E-02 3.133289E-02 1.772848E-03 -------------------------------------------------------------------------------- After 5 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10078.6 1192.29 0.295364 0.379765 0.620235 2.327201E-02 Mean perturbed parameters: 10166.4 1198.28 0.256524 0.414448 0.585552 2.239653E-02 Parameter standard deviation: 614.786 29.3073 3.547905E-02 2.975027E-02 2.975027E-02 1.826392E-03 -------------------------------------------------------------------------------- After 6 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10451.3 1196.99 0.307750 0.371877 0.628123 2.703421E-02 Mean perturbed parameters: 10213.8 1198.07 0.265062 0.407353 0.592647 2.316948E-02 Parameter standard deviation: 646.746 27.9217 3.515878E-02 3.027354E-02 3.027354E-02 3.042919E-03 -------------------------------------------------------------------------------- After 7 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10059.8 1209.43 0.241742 0.416058 0.583942 1.919122E-02 Mean perturbed parameters: 10191.8 1199.69 0.261730 0.408596 0.591404 2.260116E-02 Parameter standard deviation: 609.387 29.0139 3.467702E-02 2.805955E-02 2.805955E-02 2.907377E-03 -------------------------------------------------------------------------------- After 8 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10173.9 1211.60 0.253420 0.403948 0.596052 2.234566E-02 Mean perturbed parameters: 10189.6 1201.18 0.260691 0.408015 0.591985 2.256922E-02 Parameter standard deviation: 593.082 30.1324 3.302490E-02 2.597822E-02 2.597822E-02 2.720917E-03 -------------------------------------------------------------------------------- After 9 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 11798.8 1267.85 0.376917 0.438847 0.561153 3.408495E-02 Mean perturbed parameters: 10368.4 1208.59 0.273605 0.411441 0.588559 2.384874E-02 Parameter standard deviation: 929.326 43.1400 4.775783E-02 2.721979E-02 2.721979E-02 5.189421E-03 -------------------------------------------------------------------------------- After 10 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9902.50 1169.74 0.277379 0.382888 0.617112 2.024033E-02 Mean perturbed parameters: 10321.8 1204.70 0.273983 0.408586 0.591414 2.348790E-02 Parameter standard deviation: 879.035 40.7178 4.504142E-02 2.662452E-02 2.662452E-02 4.905215E-03 -------------------------------------------------------------------------------- After 11 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10017.1 1189.90 0.281409 0.386580 0.613420 2.515947E-02 Mean perturbed parameters: 10294.1 1203.36 0.274658 0.406585 0.593415 2.363986E-02 Parameter standard deviation: 840.318 38.8962 4.279593E-02 2.586272E-02 2.586272E-02 4.811389E-03 -------------------------------------------------------------------------------- After 12 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10309.8 1206.59 0.200910 0.383899 0.616101 2.710097E-02 Mean perturbed parameters: 10295.4 1203.63 0.268512 0.404695 0.595305 2.392829E-02 Parameter standard deviation: 822.714 38.2535 4.636105E-02 2.540446E-02 2.540446E-02 4.910281E-03 -------------------------------------------------------------------------------- After 13 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9898.74 1183.85 0.232920 0.386132 0.613868 2.021462E-02 Mean perturbed parameters: 10264.9 1202.11 0.265774 0.403267 0.596733 2.364262E-02 Parameter standard deviation: 789.990 36.7046 4.593685E-02 2.487334E-02 2.487334E-02 4.711544E-03 -------------------------------------------------------------------------------- After 14 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10285.4 1192.42 0.333934 0.469530 0.530470 2.888696E-02 Mean perturbed parameters: 10266.4 1201.41 0.270643 0.408000 0.592000 2.401722E-02 Parameter standard deviation: 776.754 35.5763 4.717083E-02 2.999691E-02 2.999691E-02 4.992626E-03 -------------------------------------------------------------------------------- After 15 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9589.65 1162.04 0.270997 0.406580 0.593420 1.929966E-02 Mean perturbed parameters: 10221.2 1198.79 0.270666 0.407905 0.592095 2.370271E-02 Parameter standard deviation: 748.979 34.4698 4.546158E-02 2.891299E-02 2.891299E-02 4.840440E-03 -------------------------------------------------------------------------------- After 16 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9956.66 1185.87 0.294151 0.421453 0.578547 2.122814E-02 Mean perturbed parameters: 10204.7 1197.98 0.272134 0.408752 0.591248 2.354805E-02 Parameter standard deviation: 726.851 33.4087 4.423016E-02 2.828729E-02 2.828729E-02 4.676340E-03 -------------------------------------------------------------------------------- After 17 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10313.8 1181.66 0.307251 0.394247 0.605753 2.336014E-02 Mean perturbed parameters: 10211.1 1197.02 0.274200 0.407899 0.592101 2.353700E-02 Parameter standard deviation: 720.842 32.3847 4.362965E-02 2.750090E-02 2.750090E-02 4.557225E-03 -------------------------------------------------------------------------------- After 18 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10391.4 1171.69 0.349781 0.491192 0.508808 2.514520E-02 Mean perturbed parameters: 10221.1 1195.61 0.278399 0.412526 0.587474 2.362634E-02 Parameter standard deviation: 719.715 31.4313 4.615470E-02 3.402044E-02 3.402044E-02 4.518765E-03 -------------------------------------------------------------------------------- After 19 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9885.55 1169.60 0.278656 0.388732 0.611268 2.208437E-02 Mean perturbed parameters: 10203.5 1194.25 0.278412 0.411274 0.588726 2.354519E-02 Parameter standard deviation: 700.954 30.5771 4.486830E-02 3.326127E-02 3.326127E-02 4.395403E-03 -------------------------------------------------------------------------------- After 20 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9962.71 1175.77 0.280709 0.391428 0.608572 2.426790E-02 Mean perturbed parameters: 10191.4 1193.32 0.278527 0.410282 0.589718 2.358132E-02 Parameter standard deviation: 685.121 29.7617 4.369951E-02 3.250562E-02 3.250562E-02 4.332244E-03 -------------------------------------------------------------------------------- After 21 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9755.97 1173.01 0.274322 0.382629 0.617371 2.072175E-02 Mean perturbed parameters: 10170.7 1192.35 0.278327 0.408965 0.591035 2.344515E-02 Parameter standard deviation: 667.936 29.0133 4.259311E-02 3.204625E-02 3.204625E-02 4.224485E-03 -------------------------------------------------------------------------------- After 22 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9893.56 1183.78 0.281777 0.407245 0.592755 2.814589E-02 Mean perturbed parameters: 10158.1 1191.96 0.278484 0.408887 0.591113 2.365882E-02 Parameter standard deviation: 653.351 28.3720 4.160213E-02 3.128119E-02 3.128119E-02 4.385466E-03 -------------------------------------------------------------------------------- After 23 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10336.6 1195.18 0.328722 0.442889 0.557111 2.340259E-02 Mean perturbed parameters: 10165.9 1192.10 0.280668 0.410365 0.589635 2.364768E-02 Parameter standard deviation: 653.043 28.0361 4.229263E-02 3.165782E-02 3.165782E-02 4.308164E-03 -------------------------------------------------------------------------------- After 24 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9667.00 1166.65 0.273129 0.404937 0.595063 2.194997E-02 Mean perturbed parameters: 10145.1 1191.04 0.280354 0.410139 0.589861 2.357694E-02 Parameter standard deviation: 638.707 27.4816 4.136332E-02 3.096239E-02 3.096239E-02 4.215689E-03 -------------------------------------------------------------------------------- After 25 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9751.32 1172.47 0.267030 0.406933 0.593067 2.203961E-02 Mean perturbed parameters: 10129.3 1190.30 0.279821 0.410011 0.589989 2.351545E-02 Parameter standard deviation: 625.384 26.9100 4.051671E-02 3.031576E-02 3.031576E-02 4.129736E-03 -------------------------------------------------------------------------------- After 26 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10263.0 1211.58 0.238032 0.393431 0.606569 2.582155E-02 Mean perturbed parameters: 10134.5 1191.12 0.278214 0.409373 0.590627 2.360415E-02 Parameter standard deviation: 623.374 27.3369 4.034113E-02 2.978065E-02 2.978065E-02 4.146396E-03 -------------------------------------------------------------------------------- After 27 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9673.18 1167.36 0.273333 0.404110 0.595890 2.198555E-02 Mean perturbed parameters: 10117.4 1190.24 0.278033 0.409178 0.590822 2.354420E-02 Parameter standard deviation: 611.277 26.8533 3.955789E-02 2.920233E-02 2.920233E-02 4.068140E-03 -------------------------------------------------------------------------------- After 28 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10117.9 1196.29 0.316169 0.446944 0.553056 2.226612E-02 Mean perturbed parameters: 10117.4 1190.46 0.279395 0.410527 0.589473 2.349855E-02 Parameter standard deviation: 605.477 26.6539 3.966153E-02 2.981596E-02 2.981596E-02 3.996477E-03 -------------------------------------------------------------------------------- After 29 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9968.44 1212.45 0.300633 0.413342 0.586658 2.356375E-02 Mean perturbed parameters: 10112.3 1191.21 0.280127 0.410624 0.589376 2.350080E-02 Parameter standard deviation: 596.890 27.0902 3.927311E-02 2.933008E-02 2.933008E-02 3.947842E-03 -------------------------------------------------------------------------------- After 30 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10159.4 1213.22 0.245291 0.396820 0.603180 2.398564E-02 Mean perturbed parameters: 10113.8 1191.95 0.278966 0.410164 0.589836 2.351696E-02 Parameter standard deviation: 592.950 27.5258 3.895407E-02 2.885216E-02 2.885216E-02 3.911255E-03 -------------------------------------------------------------------------------- After 31 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10623.7 1203.91 0.189277 0.355500 0.644500 2.177966E-02 Mean perturbed parameters: 10130.3 1192.33 0.276073 0.408400 0.591600 2.346092E-02 Parameter standard deviation: 607.395 27.5562 4.129834E-02 2.972578E-02 2.972578E-02 3.846538E-03 -------------------------------------------------------------------------------- After 32 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9814.15 1191.92 0.259803 0.409262 0.590738 2.113638E-02 Mean perturbed parameters: 10120.4 1192.32 0.275564 0.408427 0.591573 2.338828E-02 Parameter standard deviation: 597.934 27.2684 4.070561E-02 2.925676E-02 2.925676E-02 3.784094E-03 -------------------------------------------------------------------------------- After 33 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9643.97 1183.33 0.269130 0.405886 0.594114 2.067289E-02 Mean perturbed parameters: 10106.0 1192.05 0.275369 0.408350 0.591650 2.330599E-02 Parameter standard deviation: 588.573 26.8748 4.007342E-02 2.879761E-02 2.879761E-02 3.726115E-03 -------------------------------------------------------------------------------- After 34 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10175.2 1191.77 0.192520 0.351170 0.648830 2.319269E-02 Mean perturbed parameters: 10108.0 1192.04 0.272933 0.406668 0.593332 2.330266E-02 Parameter standard deviation: 585.708 26.6158 4.192750E-02 2.982043E-02 2.982043E-02 3.684086E-03 -------------------------------------------------------------------------------- After 35 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10502.6 1183.50 0.330239 0.428051 0.571949 2.520296E-02 Mean perturbed parameters: 10119.3 1191.80 0.274570 0.407279 0.592721 2.335696E-02 Parameter standard deviation: 593.620 26.2575 4.242122E-02 2.966299E-02 2.966299E-02 3.690906E-03 -------------------------------------------------------------------------------- After 36 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10635.5 1168.20 0.270782 0.253054 0.746946 3.946061E-02 Mean perturbed parameters: 10133.6 1191.14 0.274465 0.402995 0.597005 2.380428E-02 Parameter standard deviation: 606.513 25.9089 4.181413E-02 3.882161E-02 3.882161E-02 4.760590E-03 -------------------------------------------------------------------------------- After 37 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10181.6 1196.53 0.304305 0.418582 0.581418 2.543972E-02 Mean perturbed parameters: 10134.9 1191.29 0.275271 0.403417 0.596583 2.384848E-02 Parameter standard deviation: 603.615 25.7862 4.153951E-02 3.835403E-02 3.835403E-02 4.744595E-03 -------------------------------------------------------------------------------- After 38 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10274.2 1198.21 0.278081 0.345408 0.654592 2.600362E-02 Mean perturbed parameters: 10138.6 1191.47 0.275345 0.401890 0.598110 2.390519E-02 Parameter standard deviation: 603.099 25.7084 4.098008E-02 3.904563E-02 3.904563E-02 4.743662E-03 -------------------------------------------------------------------------------- After 39 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9592.88 1173.89 0.272813 0.407688 0.592312 2.016809E-02 Mean perturbed parameters: 10124.6 1191.02 0.275280 0.402039 0.597961 2.380937E-02 Parameter standard deviation: 595.319 25.3692 4.043766E-02 3.853270E-02 3.853270E-02 4.684389E-03 -------------------------------------------------------------------------------- After 40 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9135.18 1171.62 0.250402 0.530887 0.469113 2.028427E-02 Mean perturbed parameters: 10099.9 1190.53 0.274658 0.405260 0.594740 2.372124E-02 Parameter standard deviation: 594.315 25.0494 4.009285E-02 4.311027E-02 4.311027E-02 4.626767E-03 -------------------------------------------------------------------------------- After 41 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9984.66 1195.38 0.198330 0.358580 0.641420 2.139705E-02 Mean perturbed parameters: 10097.0 1190.65 0.272797 0.404121 0.595879 2.366456E-02 Parameter standard deviation: 588.686 24.9337 4.135248E-02 4.317369E-02 4.317369E-02 4.568596E-03 -------------------------------------------------------------------------------- After 42 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9535.19 1153.65 0.265156 0.405226 0.594774 2.283161E-02 Mean perturbed parameters: 10083.7 1189.77 0.272615 0.404148 0.595852 2.364472E-02 Parameter standard deviation: 581.965 24.8626 4.086791E-02 4.264426E-02 4.264426E-02 4.518925E-03 -------------------------------------------------------------------------------- After 43 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 11509.0 1230.57 0.376017 0.420437 0.579563 3.417480E-02 Mean perturbed parameters: 10116.8 1190.72 0.275019 0.404527 0.595473 2.388961E-02 Parameter standard deviation: 639.839 25.9940 4.334386E-02 4.220833E-02 4.220833E-02 4.887233E-03 -------------------------------------------------------------------------------- After 44 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9563.83 1161.66 0.269459 0.405449 0.594551 1.812604E-02 Mean perturbed parameters: 10104.2 1190.06 0.274893 0.404547 0.595453 2.375862E-02 Parameter standard deviation: 632.648 25.7762 4.284226E-02 4.171511E-02 4.171511E-02 4.854165E-03 -------------------------------------------------------------------------------- After 45 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9992.53 1226.45 0.277561 0.378154 0.621846 2.990173E-02 Mean perturbed parameters: 10101.8 1190.87 0.274952 0.403961 0.596039 2.389513E-02 Parameter standard deviation: 627.079 26.6149 4.235621E-02 4.142428E-02 4.142428E-02 4.971063E-03 -------------------------------------------------------------------------------- After 46 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9798.79 1175.46 0.273503 0.405011 0.594989 2.386924E-02 Mean perturbed parameters: 10095.2 1190.53 0.274921 0.403984 0.596016 2.389457E-02 Parameter standard deviation: 620.284 26.3175 4.188298E-02 4.096162E-02 4.096162E-02 4.930490E-03 -------------------------------------------------------------------------------- After 47 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10760.7 1200.12 0.354888 0.469220 0.530780 2.856812E-02 Mean perturbed parameters: 10109.3 1190.74 0.276622 0.405372 0.594628 2.399401E-02 Parameter standard deviation: 633.489 26.2821 4.311184E-02 4.163414E-02 4.163414E-02 4.993160E-03 -------------------------------------------------------------------------------- After 48 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10080.2 1215.27 0.243620 0.403376 0.596624 2.474584E-02 Mean perturbed parameters: 10108.7 1191.25 0.275935 0.405330 0.594670 2.400967E-02 Parameter standard deviation: 629.292 26.6409 4.287885E-02 4.118900E-02 4.118900E-02 4.965355E-03 -------------------------------------------------------------------------------- After 49 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10248.0 1209.18 0.256980 0.411384 0.588616 2.321879E-02 Mean perturbed parameters: 10111.6 1191.61 0.275548 0.405454 0.594546 2.399353E-02 Parameter standard deviation: 627.889 26.8068 4.250009E-02 4.077103E-02 4.077103E-02 4.921211E-03 -------------------------------------------------------------------------------- After 50 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9907.49 1175.54 0.278879 0.380988 0.619012 2.463938E-02 Mean perturbed parameters: 10107.5 1191.29 0.275615 0.404964 0.595036 2.400645E-02 Parameter standard deviation: 622.225 26.5318 4.207019E-02 4.048839E-02 4.048839E-02 4.894131E-03 -------------------------------------------------------------------------------- After 51 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9572.88 1195.42 0.264245 0.402313 0.597687 2.518323E-02 Mean perturbed parameters: 10097.0 1191.37 0.275392 0.404912 0.595088 2.402952E-02 Parameter standard deviation: 616.194 26.4161 4.166975E-02 4.008231E-02 4.008231E-02 4.876068E-03 -------------------------------------------------------------------------------- After 52 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10027.9 1181.51 0.267718 0.409079 0.590921 2.086364E-02 Mean perturbed parameters: 10095.7 1191.18 0.275244 0.404993 0.595007 2.396864E-02 Parameter standard deviation: 611.954 26.1694 4.126829E-02 3.969338E-02 3.969338E-02 4.828402E-03 -------------------------------------------------------------------------------- After 53 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9721.26 1187.34 0.237426 0.390891 0.609109 2.032366E-02 Mean perturbed parameters: 10088.6 1191.11 0.274530 0.404727 0.595273 2.389987E-02 Parameter standard deviation: 606.057 25.9687 4.118139E-02 3.935290E-02 3.935290E-02 4.783641E-03 -------------------------------------------------------------------------------- After 54 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10196.9 1210.73 0.249693 0.405101 0.594899 2.336944E-02 Mean perturbed parameters: 10090.6 1191.47 0.274071 0.404733 0.595267 2.389004E-02 Parameter standard deviation: 604.336 26.1741 4.092636E-02 3.898009E-02 3.898009E-02 4.746869E-03 -------------------------------------------------------------------------------- After 55 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10878.5 1235.36 0.372934 0.470976 0.529024 2.688091E-02 Mean perturbed parameters: 10104.9 1192.27 0.275868 0.405938 0.594062 2.394442E-02 Parameter standard deviation: 620.175 27.1806 4.272663E-02 3.967349E-02 3.967349E-02 4.763779E-03 -------------------------------------------------------------------------------- After 56 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10206.9 1185.63 0.264791 0.405832 0.594168 2.380263E-02 Mean perturbed parameters: 10106.8 1192.15 0.275670 0.405936 0.594064 2.394189E-02 Parameter standard deviation: 618.450 26.9672 4.235425E-02 3.931182E-02 3.931182E-02 4.732381E-03 -------------------------------------------------------------------------------- After 57 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9817.75 1173.96 0.251483 0.435964 0.564036 2.337396E-02 Mean perturbed parameters: 10101.7 1191.83 0.275246 0.406463 0.593537 2.393193E-02 Parameter standard deviation: 613.141 26.7261 4.208116E-02 3.919039E-02 3.919039E-02 4.698169E-03 -------------------------------------------------------------------------------- After 58 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10230.7 1179.65 0.303423 0.422145 0.577855 2.858511E-02 Mean perturbed parameters: 10103.9 1191.62 0.275732 0.406733 0.593267 2.401215E-02 Parameter standard deviation: 611.944 26.4963 4.189326E-02 3.891807E-02 3.891807E-02 4.755868E-03 -------------------------------------------------------------------------------- After 59 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10375.9 1206.17 0.330871 0.456903 0.543097 2.631237E-02 Mean perturbed parameters: 10108.5 1191.87 0.276666 0.407583 0.592417 2.405114E-02 Parameter standard deviation: 613.294 26.5743 4.219884E-02 3.919779E-02 3.919779E-02 4.760522E-03 -------------------------------------------------------------------------------- After 60 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10537.9 1193.80 0.331600 0.424893 0.575107 2.777059E-02 Mean perturbed parameters: 10115.7 1191.90 0.277582 0.407872 0.592128 2.411313E-02 Parameter standard deviation: 618.012 26.4557 4.250864E-02 3.895782E-02 3.895782E-02 4.794736E-03 -------------------------------------------------------------------------------- After 61 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10577.2 1222.16 0.191240 0.421708 0.578292 2.413935E-02 Mean perturbed parameters: 10123.2 1192.40 0.276166 0.408099 0.591901 2.411356E-02 Parameter standard deviation: 623.451 26.9174 4.348279E-02 3.869818E-02 3.869818E-02 4.768784E-03 -------------------------------------------------------------------------------- After 62 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9780.14 1188.96 0.256044 0.396520 0.603480 2.043730E-02 Mean perturbed parameters: 10117.7 1192.34 0.275842 0.407912 0.592088 2.405427E-02 Parameter standard deviation: 618.427 26.7516 4.318547E-02 3.839213E-02 3.839213E-02 4.730805E-03 -------------------------------------------------------------------------------- After 63 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9394.55 1171.24 0.263520 0.419685 0.580315 1.955768E-02 Mean perturbed parameters: 10106.2 1192.01 0.275646 0.408099 0.591901 2.398289E-02 Parameter standard deviation: 614.566 26.5405 4.285607E-02 3.813228E-02 3.813228E-02 4.697674E-03 -------------------------------------------------------------------------------- After 64 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9877.81 1183.03 0.289634 0.414180 0.585820 2.215002E-02 Mean perturbed parameters: 10102.7 1191.87 0.275865 0.408194 0.591806 2.395425E-02 Parameter standard deviation: 610.128 26.3462 4.256076E-02 3.784950E-02 3.784950E-02 4.661491E-03 -------------------------------------------------------------------------------- After 65 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10616.1 1184.66 0.251229 0.415818 0.584182 2.284134E-02 Mean perturbed parameters: 10110.6 1191.76 0.275486 0.408311 0.591689 2.393713E-02 Parameter standard deviation: 616.311 26.1647 4.232195E-02 3.758091E-02 3.758091E-02 4.628974E-03 -------------------------------------------------------------------------------- After 66 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9467.51 1193.45 0.265752 0.431516 0.568484 2.591804E-02 Mean perturbed parameters: 10100.8 1191.78 0.275338 0.408663 0.591337 2.396715E-02 Parameter standard deviation: 612.174 26.0582 4.200730E-02 3.744477E-02 3.744477E-02 4.628903E-03 -------------------------------------------------------------------------------- After 67 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10083.1 1209.76 0.242386 0.404612 0.595388 2.514229E-02 Mean perturbed parameters: 10100.6 1192.05 0.274846 0.408602 0.591398 2.398469E-02 Parameter standard deviation: 609.443 26.2020 4.186796E-02 3.716006E-02 3.716006E-02 4.618065E-03 -------------------------------------------------------------------------------- After 68 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10051.9 1189.55 0.195536 0.373553 0.626447 1.989181E-02 Mean perturbed parameters: 10099.8 1192.01 0.273680 0.408087 0.591913 2.392450E-02 Parameter standard deviation: 606.491 26.0625 4.264299E-02 3.707075E-02 3.707075E-02 4.586670E-03 -------------------------------------------------------------------------------- After 69 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9564.43 1157.97 0.269240 0.404802 0.595198 1.950420E-02 Mean perturbed parameters: 10092.1 1191.52 0.273616 0.408039 0.591961 2.386043E-02 Parameter standard deviation: 602.208 25.9572 4.233206E-02 3.679724E-02 3.679724E-02 4.557989E-03 -------------------------------------------------------------------------------- After 70 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 11844.4 1257.93 0.370368 0.416172 0.583828 3.327817E-02 Mean perturbed parameters: 10117.1 1192.47 0.274998 0.408156 0.591844 2.399497E-02 Parameter standard deviation: 651.664 27.6139 4.359927E-02 3.655824E-02 3.655824E-02 4.749289E-03 -------------------------------------------------------------------------------- After 71 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10382.0 1229.02 0.348622 0.493349 0.506651 2.540483E-02 Mean perturbed parameters: 10120.8 1192.98 0.276035 0.409355 0.590645 2.401483E-02 Parameter standard deviation: 652.258 28.1527 4.419841E-02 3.782929E-02 3.782929E-02 4.740777E-03 -------------------------------------------------------------------------------- After 72 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10037.7 1171.77 0.272451 0.349956 0.650044 2.754890E-02 Mean perturbed parameters: 10119.7 1192.69 0.275985 0.408530 0.591470 2.406391E-02 Parameter standard deviation: 648.961 27.9573 4.388639E-02 3.810876E-02 3.810876E-02 4.765451E-03 -------------------------------------------------------------------------------- After 73 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9878.01 1194.78 0.264410 0.403580 0.596420 2.081822E-02 Mean perturbed parameters: 10116.4 1192.72 0.275827 0.408463 0.591537 2.401945E-02 Parameter standard deviation: 644.820 27.8554 4.359491E-02 3.784326E-02 3.784326E-02 4.732573E-03 -------------------------------------------------------------------------------- After 74 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10043.1 1173.22 0.255765 0.410553 0.589447 2.494637E-02 Mean perturbed parameters: 10115.4 1192.45 0.275555 0.408491 0.591509 2.403198E-02 Parameter standard deviation: 641.720 27.6653 4.334729E-02 3.759061E-02 3.759061E-02 4.719450E-03 -------------------------------------------------------------------------------- After 75 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10378.4 1209.54 0.240514 0.426192 0.573808 2.472505E-02 Mean perturbed parameters: 10118.9 1192.68 0.275088 0.408727 0.591273 2.404122E-02 Parameter standard deviation: 642.373 27.7614 4.322800E-02 3.742351E-02 3.742351E-02 4.704395E-03 -------------------------------------------------------------------------------- After 76 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9755.82 1176.84 0.274740 0.404277 0.595723 2.079205E-02 Mean perturbed parameters: 10114.1 1192.47 0.275084 0.408668 0.591332 2.399847E-02 Parameter standard deviation: 638.121 27.5762 4.293896E-02 3.717318E-02 3.717318E-02 4.673286E-03 -------------------------------------------------------------------------------- After 77 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10336.7 1145.78 0.268114 0.400920 0.599080 2.740818E-02 Mean perturbed parameters: 10117.0 1191.87 0.274993 0.408568 0.591432 2.404275E-02 Parameter standard deviation: 638.235 27.6052 4.266070E-02 3.692968E-02 3.692968E-02 4.695123E-03 -------------------------------------------------------------------------------- After 78 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10643.6 1222.82 0.196877 0.431979 0.568021 2.306470E-02 Mean perturbed parameters: 10123.8 1192.26 0.273992 0.408868 0.591132 2.403021E-02 Parameter standard deviation: 643.321 27.9509 4.328221E-02 3.682582E-02 3.682582E-02 4.668900E-03 -------------------------------------------------------------------------------- After 79 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10275.4 1208.68 0.228425 0.418684 0.581316 2.138771E-02 Mean perturbed parameters: 10125.7 1192.47 0.273415 0.408992 0.591008 2.399676E-02 Parameter standard deviation: 642.612 28.0245 4.331106E-02 3.662594E-02 3.662594E-02 4.638887E-03 -------------------------------------------------------------------------------- After 80 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10273.6 1188.36 0.331822 0.460585 0.539415 2.749291E-02 Mean perturbed parameters: 10127.5 1192.42 0.274145 0.409637 0.590363 2.404046E-02 Parameter standard deviation: 641.899 27.8842 4.352663E-02 3.694296E-02 3.694296E-02 4.661903E-03 -------------------------------------------------------------------------------- After 81 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9647.32 1155.29 0.271623 0.405719 0.594281 1.967709E-02 Mean perturbed parameters: 10121.6 1191.96 0.274114 0.409589 0.590411 2.398659E-02 Parameter standard deviation: 637.892 27.8012 4.325448E-02 3.671176E-02 3.671176E-02 4.636198E-03 -------------------------------------------------------------------------------- After 82 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10184.4 1196.67 0.235102 0.411148 0.588852 2.540270E-02 Mean perturbed parameters: 10122.4 1192.02 0.273638 0.409608 0.590392 2.400386E-02 Parameter standard deviation: 636.318 27.7292 4.320229E-02 3.649270E-02 3.649270E-02 4.630056E-03 -------------------------------------------------------------------------------- After 83 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10255.1 1208.76 0.224560 0.415536 0.584464 2.049172E-02 Mean perturbed parameters: 10124.0 1192.22 0.273047 0.409679 0.590321 2.396155E-02 Parameter standard deviation: 635.497 27.8035 4.328242E-02 3.629126E-02 3.629126E-02 4.602590E-03 -------------------------------------------------------------------------------- After 84 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 11041.8 1237.52 0.342977 0.378126 0.621874 3.090933E-02 Mean perturbed parameters: 10134.9 1192.76 0.273879 0.409303 0.590697 2.404426E-02 Parameter standard deviation: 648.851 28.4622 4.368390E-02 3.618498E-02 3.618498E-02 4.694954E-03 -------------------------------------------------------------------------------- After 85 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10116.1 1207.76 0.251074 0.415754 0.584246 2.547253E-02 Mean perturbed parameters: 10134.7 1192.94 0.273611 0.409379 0.590621 2.406106E-02 Parameter standard deviation: 646.651 28.5107 4.349448E-02 3.599119E-02 3.599119E-02 4.689144E-03 -------------------------------------------------------------------------------- After 86 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10344.4 1204.19 0.316929 0.423333 0.576667 2.407325E-02 Mean perturbed parameters: 10137.1 1193.07 0.274115 0.409542 0.590458 2.406121E-02 Parameter standard deviation: 646.742 28.5130 4.348901E-02 3.583925E-02 3.583925E-02 4.671219E-03 -------------------------------------------------------------------------------- After 87 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9925.20 1186.63 0.295791 0.430915 0.569085 1.999470E-02 Mean perturbed parameters: 10134.7 1192.99 0.274364 0.409787 0.590213 2.401446E-02 Parameter standard deviation: 643.471 28.3722 4.329980E-02 3.574690E-02 3.574690E-02 4.646093E-03 -------------------------------------------------------------------------------- After 88 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10455.4 1207.77 0.303431 0.382141 0.617859 2.808994E-02 Mean perturbed parameters: 10138.3 1193.16 0.274694 0.409473 0.590527 2.406078E-02 Parameter standard deviation: 645.003 28.4202 4.316648E-02 3.561917E-02 3.561917E-02 4.676428E-03 -------------------------------------------------------------------------------- After 89 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 8974.77 1197.94 0.194498 0.316962 0.683038 2.070351E-02 Mean perturbed parameters: 10125.2 1193.22 0.273793 0.408434 0.591566 2.402305E-02 Parameter standard deviation: 645.844 28.3595 4.374721E-02 3.661569E-02 3.661569E-02 4.650207E-03 -------------------------------------------------------------------------------- After 90 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10404.4 1183.29 0.306768 0.377759 0.622241 2.288328E-02 Mean perturbed parameters: 10128.3 1193.11 0.274159 0.408093 0.591907 2.401039E-02 Parameter standard deviation: 646.655 28.2119 4.364002E-02 3.651679E-02 3.651679E-02 4.627077E-03 -------------------------------------------------------------------------------- After 91 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9846.41 1177.12 0.278018 0.404322 0.595678 2.114974E-02 Mean perturbed parameters: 10125.2 1192.93 0.274202 0.408051 0.591949 2.397895E-02 Parameter standard deviation: 643.263 28.0552 4.339907E-02 3.631336E-02 3.631336E-02 4.601325E-03 -------------------------------------------------------------------------------- After 92 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9697.96 1158.87 0.274361 0.405081 0.594919 2.264723E-02 Mean perturbed parameters: 10120.6 1192.56 0.274204 0.408019 0.591981 2.396448E-02 Parameter standard deviation: 639.720 27.9550 4.315998E-02 3.611341E-02 3.611341E-02 4.578172E-03 -------------------------------------------------------------------------------- After 93 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 11217.8 1232.11 0.315838 0.372692 0.627308 3.916697E-02 Mean perturbed parameters: 10132.4 1192.98 0.274651 0.407639 0.592361 2.412795E-02 Parameter standard deviation: 655.870 28.4225 4.314686E-02 3.606612E-02 3.606612E-02 4.919774E-03 -------------------------------------------------------------------------------- After 94 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10338.1 1211.28 0.230781 0.423927 0.576073 2.640964E-02 Mean perturbed parameters: 10134.6 1193.18 0.274185 0.407813 0.592187 2.415222E-02 Parameter standard deviation: 655.787 28.5120 4.314658E-02 3.593021E-02 3.593021E-02 4.921925E-03 -------------------------------------------------------------------------------- After 95 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9878.56 1181.33 0.294220 0.415826 0.584174 2.054832E-02 Mean perturbed parameters: 10131.9 1193.05 0.274395 0.407897 0.592103 2.411428E-02 Parameter standard deviation: 652.579 28.3663 4.296760E-02 3.575884E-02 3.575884E-02 4.896278E-03 -------------------------------------------------------------------------------- After 96 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9613.83 1174.98 0.266506 0.403978 0.596022 2.581160E-02 Mean perturbed parameters: 10126.5 1192.87 0.274313 0.407856 0.592144 2.413196E-02 Parameter standard deviation: 649.183 28.2167 4.274759E-02 3.557014E-02 3.557014E-02 4.892448E-03 -------------------------------------------------------------------------------- After 97 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 11031.1 1242.87 0.312018 0.330972 0.669028 3.475700E-02 Mean perturbed parameters: 10135.8 1193.38 0.274702 0.407063 0.592937 2.424150E-02 Parameter standard deviation: 660.138 28.8996 4.270193E-02 3.616420E-02 3.616420E-02 5.057159E-03 -------------------------------------------------------------------------------- After 98 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 9990.78 1184.36 0.269960 0.339348 0.660652 2.192131E-02 Mean perturbed parameters: 10134.3 1193.29 0.274654 0.406372 0.593628 2.421783E-02 Parameter standard deviation: 657.436 28.7643 4.248313E-02 3.657417E-02 3.657417E-02 5.031427E-03 -------------------------------------------------------------------------------- After 99 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10395.8 1186.82 0.340873 0.476025 0.523975 2.627117E-02 Mean perturbed parameters: 10137.0 1193.22 0.275322 0.407076 0.592924 2.423857E-02 Parameter standard deviation: 657.948 28.6401 4.280382E-02 3.710420E-02 3.710420E-02 5.030880E-03 -------------------------------------------------------------------------------- After 100 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10535.1 1208.53 0.338881 0.438615 0.561385 2.835320E-02 Mean perturbed parameters: 10141.0 1193.38 0.275958 0.407391 0.592609 2.427971E-02 Parameter standard deviation: 660.103 28.6880 4.308490E-02 3.707840E-02 3.707840E-02 5.055443E-03 -------------------------------------------------------------------------------- After 101 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 9690.01 1175.48 0.273902 0.404159 0.595841 2.129366E-02 Perturbed central model parameter: 10102.3 1170.45 0.275079 0.355900 0.644100 2.718116E-02 Mean perturbed parameters: 10140.6 1193.15 0.275949 0.406882 0.593118 2.430844E-02 Parameter standard deviation: 658.087 28.5486 4.286909E-02 3.720684E-02 3.720684E-02 5.064440E-03