-------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 1 converged, 1 successes so far. Misfit function evaluations this try => 252 Misfit this try = 0.137073 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 9.637766E-07 Bayes score, PP * exp(-Misfit) = 8.403233E-07 Best Bayes score so far = 8.403233E-07 obtained on Try 1 P_bar T_K C_O2 C_H2O Initial coordinates: 10000.0 900.000 0.500000 0.500000 Final coordinates: 8590.21 924.439 0.455831 5.180154E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.137073 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.564 0.0178 0.0020 0.0000 0.0637 0.0057 0.0000 0.0050 0.1650 0.0005 0.2387 0.5016 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0074 -0.0020 0.0000 0.0207 0.0055 0.0000 0.0085 -0.1650 -0.0005 0.0418 0.0984 Composition Misfit: 0.580436E-01 Gt predicted* 1.072 0.0000 0.0305 0.0000 0.0000 0.2959 0.0397 0.0695 0.0000 0.0026 0.1366 0.4252 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0100 0.0000 0.0000 0.0260 -0.0054 -0.0147 0.0000 -0.0026 0.0073 -0.0006 Composition Misfit: 0.977395E-02 Fsp predicted* 27.471 0.0944 0.0581 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1541 0.6919 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0028 -0.0066 0.0000 -0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0068 0.0026 Composition Misfit: 0.114505E-02 Bio predicted* 21.068 0.0000 0.0000 0.0221 0.0670 0.1734 0.0009 0.1599 0.1118 0.0040 0.1205 0.3404 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0007 -0.0000 0.0111 0.0005 0.0096 -0.1118 -0.0040 0.0198 0.0756 Composition Misfit: 0.216757E-01 St predicted* 2.914 0.0000 0.0000 0.0044 0.0000 0.1343 0.0025 0.0486 0.0881 0.0023 0.3891 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0029 0.0000 -0.0033 0.0013 -0.0257 -0.0881 -0.0023 0.0595 0.0558 Composition Misfit: 0.347527E-01 Ilm predicted* 0.356 0.0000 0.0000 0.2947 0.0000 0.6041 0.0087 0.0103 0.0000 0.0821 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0553 0.0000 0.0259 0.0013 -0.0003 0.0000 -0.0821 0.0000 0.0000 Composition Misfit: 0.116817E-01 ky predicted 5.137 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.416 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -775444. CaO 15.215 -754310. TiO2 7.199 -931353. K2O 16.990 -849651. FeO 54.593 -313899. MnO 0.947 -467789. MgO 41.584 -638303. H2O 31.081 -291305. O2 1.555 -410185. Al2O3 111.899 -0.163544E+07 SiO2 727.525 -886106. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 2 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 3 converged, 2 successes so far. Misfit function evaluations this try => 442 Misfit this try = 0.334028 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.117967E-06 Bayes score, PP * exp(-Misfit) = 8.005023E-07 Best Bayes score so far = 8.403233E-07 obtained on Try 1 P_bar T_K C_O2 C_H2O Initial coordinates: 14414.9 976.777 0.271333 0.923576 Final coordinates: 9276.35 920.995 0.998261 6.775139E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.334028 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 7.392 0.0215 0.0028 0.0000 0.0596 0.0053 0.0000 0.0056 0.1649 0.0005 0.2391 0.5007 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0111 -0.0028 0.0000 0.0249 0.0059 0.0000 0.0079 -0.1649 -0.0005 0.0414 0.0993 Composition Misfit: 0.637188E-01 Gt predicted* 1.003 0.0000 0.0409 0.0000 0.0000 0.2786 0.0366 0.0819 0.0000 0.0035 0.1343 0.4241 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0204 0.0000 0.0000 0.0433 -0.0024 -0.0271 0.0000 -0.0035 0.0095 0.0006 Composition Misfit: 0.266815E-01 Fsp predicted* 25.809 0.0937 0.0602 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1551 0.6898 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0020 -0.0086 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0058 0.0047 Composition Misfit: 0.154395E-02 Bio predicted* 15.757 0.0000 0.0000 0.0195 0.0664 0.1507 0.0008 0.1888 0.1133 0.0044 0.1141 0.3421 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0019 0.0005 0.0338 0.0007 -0.0193 -0.1133 -0.0044 0.0262 0.0739 Composition Misfit: 0.323058E-01 St predicted* 7.131 0.0000 0.0000 0.0038 0.0000 0.1230 0.0023 0.0614 0.0881 0.0026 0.3885 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0035 0.0000 0.0080 0.0016 -0.0385 -0.0881 -0.0026 0.0601 0.0560 Composition Misfit: 0.476697E-01 Ilm predicted* 1.051 0.0000 0.0000 0.1828 0.0000 0.6784 0.0055 0.0065 0.0000 0.1269 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1672 0.0000 -0.0484 0.0045 0.0035 0.0000 -0.1269 0.0000 0.0000 Composition Misfit: 0.162108 ky predicted 0.238 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.619 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -771810. CaO 15.215 -751241. TiO2 7.199 -930772. K2O 16.990 -847128. FeO 54.593 -313456. MnO 0.947 -467396. MgO 41.584 -636034. H2O 40.651 -289425. O2 3.406 -401893. Al2O3 111.899 -0.163340E+07 SiO2 727.525 -884162. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 4 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 5 converged, 3 successes so far. Misfit function evaluations this try => 312 Misfit this try = 0.193119 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 9.797764E-07 Bayes score, PP * exp(-Misfit) = 8.077123E-07 Best Bayes score so far = 8.403233E-07 obtained on Try 1 P_bar T_K C_O2 C_H2O Initial coordinates: 5786.75 982.261 0.769568 0.803342 Final coordinates: 8776.11 926.661 0.578833 5.135079E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.193087 Extraneous predicted phases: 3.107573E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 1.030 0.0182 0.0021 0.0000 0.0632 0.0058 0.0000 0.0052 0.1649 0.0005 0.2385 0.5015 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0078 -0.0021 0.0000 0.0212 0.0054 0.0000 0.0083 -0.1649 -0.0005 0.0420 0.0985 Composition Misfit: 0.575533E-01 Gt predicted* 1.239 0.0000 0.0318 0.0000 0.0000 0.2957 0.0367 0.0720 0.0000 0.0028 0.1360 0.4250 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0112 0.0000 0.0000 0.0262 -0.0024 -0.0172 0.0000 -0.0028 0.0078 -0.0003 Composition Misfit: 0.110209E-01 Fsp predicted* 27.359 0.0945 0.0580 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1540 0.6920 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0029 -0.0064 0.0000 -0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0069 0.0025 Composition Misfit: 0.112293E-02 Bio predicted* 20.703 0.0000 0.0000 0.0218 0.0669 0.1710 0.0008 0.1634 0.1120 0.0041 0.1195 0.3406 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0004 0.0001 0.0135 0.0006 0.0062 -0.1120 -0.0041 0.0208 0.0753 Composition Misfit: 0.220535E-01 St predicted* 2.106 0.0000 0.0000 0.0043 0.0000 0.1331 0.0023 0.0504 0.0881 0.0024 0.3889 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0030 0.0000 -0.0021 0.0015 -0.0274 -0.0881 -0.0024 0.0597 0.0558 Composition Misfit: 0.366355E-01 Ilm predicted* 0.496 0.0000 0.0000 0.2301 0.0000 0.6469 0.0071 0.0080 0.0000 0.1080 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1199 0.0000 -0.0169 0.0029 0.0020 0.0000 -0.1080 0.0000 0.0000 Composition Misfit: 0.647013E-01 ky predicted 5.748 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.301 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.017 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -775119. CaO 15.215 -754081. TiO2 7.199 -931538. K2O 16.990 -849467. FeO 54.593 -314023. MnO 0.947 -468539. MgO 41.584 -638108. H2O 30.810 -291164. O2 1.975 -408483. Al2O3 111.899 -0.163539E+07 SiO2 727.525 -885922. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 6 converged, 4 successes so far. Misfit function evaluations this try => 214 Misfit this try = 0.202380 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.045421E-06 Bayes score, PP * exp(-Misfit) = 8.538834E-07 Best Bayes score so far = 8.538834E-07 obtained on Try 6 P_bar T_K C_O2 C_H2O Initial coordinates: 7316.63 812.575 0.920498 8.210769E-02 Final coordinates: 8642.01 915.750 0.582199 4.663882E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.202380 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.001 0.0182 0.0020 0.0000 0.0633 0.0056 0.0000 0.0050 0.1650 0.0005 0.2388 0.5016 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0078 -0.0020 0.0000 0.0212 0.0055 0.0000 0.0085 -0.1650 -0.0005 0.0417 0.0984 Composition Misfit: 0.588955E-01 Gt predicted* 1.411 0.0000 0.0325 0.0000 0.0000 0.2991 0.0356 0.0689 0.0000 0.0028 0.1362 0.4250 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0120 0.0000 0.0000 0.0229 -0.0014 -0.0141 0.0000 -0.0028 0.0077 -0.0004 Composition Misfit: 0.951075E-02 Fsp predicted* 27.544 0.0948 0.0575 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1537 0.6925 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0032 -0.0059 0.0000 -0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0072 0.0020 Composition Misfit: 0.105124E-02 Bio predicted* 21.628 0.0000 0.0000 0.0215 0.0668 0.1736 0.0008 0.1613 0.1122 0.0041 0.1189 0.3408 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0001 0.0001 0.0109 0.0007 0.0082 -0.1122 -0.0041 0.0214 0.0751 Composition Misfit: 0.221023E-01 St predicted* 0.066 0.0000 0.0000 0.0042 0.0000 0.1354 0.0022 0.0482 0.0881 0.0024 0.3890 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0032 0.0000 -0.0044 0.0016 -0.0253 -0.0881 -0.0024 0.0595 0.0558 Composition Misfit: 0.355434E-01 Ilm predicted* 0.498 0.0000 0.0000 0.2234 0.0000 0.6521 0.0065 0.0073 0.0000 0.1106 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1266 0.0000 -0.0221 0.0035 0.0027 0.0000 -0.1106 0.0000 0.0000 Composition Misfit: 0.752773E-01 ky predicted 7.725 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.127 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -773090. CaO 15.215 -753002. TiO2 7.199 -930488. K2O 16.990 -847370. FeO 54.593 -312745. MnO 0.947 -467438. MgO 41.584 -637438. H2O 27.983 -290482. O2 1.986 -408638. Al2O3 111.899 -0.163394E+07 SiO2 727.525 -885046. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 7 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 8 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 9 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 10 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 11 converged, 5 successes so far. Misfit function evaluations this try => 202 Misfit this try = 0.197218 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 8.795135E-07 Bayes score, PP * exp(-Misfit) = 7.220912E-07 Best Bayes score so far = 8.538834E-07 obtained on Try 6 P_bar T_K C_O2 C_H2O Initial coordinates: 6554.92 944.454 0.558262 0.470131 Final coordinates: 8129.51 921.219 0.552121 5.147531E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.197218 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.016 0.0172 0.0019 0.0000 0.0644 0.0055 0.0000 0.0048 0.1650 0.0005 0.2392 0.5015 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0069 -0.0019 0.0000 0.0201 0.0056 0.0000 0.0088 -0.1650 -0.0005 0.0413 0.0985 Composition Misfit: 0.590075E-01 Gt predicted* 0.589 0.0000 0.0279 0.0000 0.0000 0.2855 0.0543 0.0678 0.0000 0.0025 0.1367 0.4253 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0074 0.0000 0.0000 0.0364 -0.0200 -0.0130 0.0000 -0.0025 0.0071 -0.0007 Composition Misfit: 0.168470E-01 Fsp predicted* 27.640 0.0941 0.0587 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1543 0.6913 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0025 -0.0071 0.0000 -0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0066 0.0032 Composition Misfit: 0.123158E-02 Bio predicted* 21.482 0.0000 0.0000 0.0220 0.0671 0.1736 0.0012 0.1587 0.1121 0.0041 0.1221 0.3391 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0006 -0.0001 0.0109 0.0002 0.0108 -0.1121 -0.0041 0.0182 0.0769 Composition Misfit: 0.216159E-01 St predicted* 3.017 0.0000 0.0000 0.0042 0.0000 0.1341 0.0036 0.0481 0.0881 0.0024 0.3891 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0032 0.0000 -0.0031 0.0003 -0.0252 -0.0881 -0.0024 0.0595 0.0558 Composition Misfit: 0.341903E-01 Ilm predicted* 0.423 0.0000 0.0000 0.2296 0.0000 0.6443 0.0105 0.0075 0.0000 0.1082 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1204 0.0000 -0.0143 -0.0005 0.0025 0.0000 -0.1082 0.0000 0.0000 Composition Misfit: 0.643252E-01 ky predicted 5.212 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.620 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -776726. CaO 15.215 -755309. TiO2 7.199 -932153. K2O 16.990 -850983. FeO 54.593 -314171. MnO 0.947 -465440. MgO 41.584 -638619. H2O 30.885 -291754. O2 1.884 -409121. Al2O3 111.899 -0.163592E+07 SiO2 727.525 -886813. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 12 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 13 converged, 6 successes so far. Misfit function evaluations this try => 285 Misfit this try = 1.80766 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.080354E-06 Bayes score, PP * exp(-Misfit) = 1.772194E-07 Best Bayes score so far = 8.538834E-07 obtained on Try 6 P_bar T_K C_O2 C_H2O Initial coordinates: 13323.5 883.595 0.778514 0.854104 Final coordinates: 9679.43 927.933 0.686395 5.529395E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.198342 Extraneous predicted phases: 1.60931 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 5.090 0.0218 0.0027 0.0000 0.0592 0.0055 0.0000 0.0056 0.1649 0.0005 0.2386 0.5010 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0115 -0.0027 0.0000 0.0252 0.0057 0.0000 0.0079 -0.1649 -0.0005 0.0418 0.0990 Composition Misfit: 0.634294E-01 Gt predicted* 2.783 0.0000 0.0392 0.0000 0.0000 0.2967 0.0202 0.0812 0.0000 0.0033 0.1350 0.4244 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0187 0.0000 0.0000 0.0252 0.0140 -0.0264 0.0000 -0.0033 0.0089 0.0003 Composition Misfit: 0.299969E-01 Fsp predicted* 26.078 0.0955 0.0564 0.0000 0.0013 0.0000 0.0000 0.0000 0.0000 0.0000 0.1532 0.6936 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0038 -0.0048 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0077 0.0009 Composition Misfit: 0.959360E-03 Bio predicted* 17.724 0.0000 0.0000 0.0211 0.0666 0.1580 0.0004 0.1800 0.1120 0.0040 0.1145 0.3434 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0002 0.0004 0.0265 0.0010 -0.0104 -0.1120 -0.0040 0.0258 0.0726 Composition Misfit: 0.284626E-01 St predicted* 1.701 0.0000 0.0000 0.0047 0.0000 0.1268 0.0012 0.0579 0.0881 0.0024 0.3886 0.3304 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0027 0.0000 0.0043 0.0026 -0.0349 -0.0881 -0.0024 0.0600 0.0559 Composition Misfit: 0.469579E-01 Ilm predicted* 0.000 0.0000 0.0000 0.2775 0.0000 0.6190 0.0039 0.0106 0.0000 0.0890 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0725 0.0000 0.0110 0.0061 -0.0006 0.0000 -0.0890 0.0000 0.0000 Composition Misfit: 0.285358E-01 ky predicted 5.066 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.824 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.732 0.0000 0.0000 0.2290 0.0000 0.6493 0.0039 0.0093 0.0000 0.1084 0.0000 0.0000 F 0.001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -771314. CaO 15.215 -751545. TiO2 7.199 -929529. K2O 16.990 -846562. FeO 54.593 -313422. MnO 0.947 -472445. MgO 41.584 -636462. H2O 33.176 -289568. O2 2.342 -405909. Al2O3 111.899 -0.163364E+07 SiO2 727.525 -883994. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 14 converged, 7 successes so far. Misfit function evaluations this try => 251 Misfit this try = 0.289043 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.161528E-06 Bayes score, PP * exp(-Misfit) = 8.699616E-07 Best Bayes score so far = 8.699616E-07 obtained on Try 14 P_bar T_K C_O2 C_H2O Initial coordinates: 9090.75 829.673 0.800061 0.729953 Final coordinates: 9265.32 915.596 0.874887 6.763697E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.289043 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 7.155 0.0219 0.0028 0.0000 0.0592 0.0051 0.0000 0.0054 0.1650 0.0005 0.2394 0.5007 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0115 -0.0028 0.0000 0.0252 0.0061 0.0000 0.0081 -0.1650 -0.0005 0.0411 0.0993 Composition Misfit: 0.657451E-01 Gt predicted* 1.152 0.0000 0.0417 0.0000 0.0000 0.2825 0.0341 0.0795 0.0000 0.0034 0.1346 0.4242 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0212 0.0000 0.0000 0.0394 0.0002 -0.0247 0.0000 -0.0034 0.0092 0.0004 Composition Misfit: 0.245469E-01 Fsp predicted* 25.798 0.0939 0.0599 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1550 0.6901 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0022 -0.0083 0.0000 0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0059 0.0044 Composition Misfit: 0.148906E-02 Bio predicted* 15.995 0.0000 0.0000 0.0200 0.0665 0.1530 0.0007 0.1861 0.1129 0.0043 0.1140 0.3427 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0014 0.0005 0.0315 0.0007 -0.0165 -0.1129 -0.0043 0.0264 0.0732 Composition Misfit: 0.305702E-01 St predicted* 7.249 0.0000 0.0000 0.0042 0.0000 0.1248 0.0021 0.0594 0.0881 0.0025 0.3886 0.3304 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0032 0.0000 0.0063 0.0018 -0.0365 -0.0881 -0.0025 0.0599 0.0560 Composition Misfit: 0.453601E-01 Ilm predicted* 0.923 0.0000 0.0000 0.1989 0.0000 0.6677 0.0056 0.0073 0.0000 0.1204 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1511 0.0000 -0.0377 0.0044 0.0027 0.0000 -0.1204 0.0000 0.0000 Composition Misfit: 0.121331 ky predicted 0.152 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.575 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -770556. CaO 15.215 -750537. TiO2 7.199 -929382. K2O 16.990 -845874. FeO 54.593 -312698. MnO 0.947 -467228. MgO 41.584 -635706. H2O 40.582 -288985. O2 2.985 -403409. Al2O3 111.899 -0.163256E+07 SiO2 727.525 -883603. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 15 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 16 converged, 8 successes so far. Misfit function evaluations this try => 226 Misfit this try = 0.194106 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 9.698343E-07 Bayes score, PP * exp(-Misfit) = 7.987272E-07 Best Bayes score so far = 8.699616E-07 obtained on Try 14 P_bar T_K C_O2 C_H2O Initial coordinates: 13196.2 914.828 0.694309 0.686985 Final coordinates: 8509.30 921.728 0.563557 4.904189E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.194106 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.072 0.0177 0.0020 0.0000 0.0638 0.0057 0.0000 0.0050 0.1650 0.0005 0.2388 0.5016 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0074 -0.0020 0.0000 0.0207 0.0055 0.0000 0.0085 -0.1650 -0.0005 0.0417 0.0984 Composition Misfit: 0.581005E-01 Gt predicted* 1.048 0.0000 0.0306 0.0000 0.0000 0.2944 0.0417 0.0692 0.0000 0.0027 0.1363 0.4251 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0100 0.0000 0.0000 0.0276 -0.0075 -0.0144 0.0000 -0.0027 0.0075 -0.0005 Composition Misfit: 0.106236E-01 Fsp predicted* 27.582 0.0945 0.0580 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1540 0.6920 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0028 -0.0065 0.0000 -0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0069 0.0025 Composition Misfit: 0.113009E-02 Bio predicted* 21.500 0.0000 0.0000 0.0218 0.0669 0.1735 0.0009 0.1602 0.1121 0.0041 0.1203 0.3401 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0004 0.0000 0.0109 0.0005 0.0093 -0.1121 -0.0041 0.0200 0.0759 Composition Misfit: 0.217608E-01 St predicted* 1.520 0.0000 0.0000 0.0042 0.0000 0.1346 0.0027 0.0485 0.0881 0.0024 0.3890 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0031 0.0000 -0.0035 0.0012 -0.0256 -0.0881 -0.0024 0.0596 0.0558 Composition Misfit: 0.350052E-01 Ilm predicted* 0.458 0.0000 0.0000 0.2277 0.0000 0.6479 0.0079 0.0075 0.0000 0.1089 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1223 0.0000 -0.0179 0.0021 0.0025 0.0000 -0.1089 0.0000 0.0000 Composition Misfit: 0.674855E-01 ky predicted 6.469 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.351 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -775130. CaO 15.215 -754226. TiO2 7.199 -931498. K2O 16.990 -849367. FeO 54.593 -313687. MnO 0.947 -467140. MgO 41.584 -638144. H2O 29.425 -291208. O2 1.923 -408889. Al2O3 111.899 -0.163518E+07 SiO2 727.525 -885997. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 17 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 18 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 19 converged, 9 successes so far. Misfit function evaluations this try => 201 Misfit this try = 0.190218 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 9.314393E-07 Bayes score, PP * exp(-Misfit) = 7.700941E-07 Best Bayes score so far = 8.699616E-07 obtained on Try 14 P_bar T_K C_O2 C_H2O Initial coordinates: 7471.36 915.856 0.742251 5.221785E-02 Final coordinates: 8488.11 925.468 0.552255 4.992124E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.190169 Extraneous predicted phases: 4.939072E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.019 0.0175 0.0020 0.0000 0.0640 0.0058 0.0000 0.0050 0.1650 0.0005 0.2387 0.5016 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0072 -0.0020 0.0000 0.0205 0.0054 0.0000 0.0085 -0.1650 -0.0005 0.0418 0.0984 Composition Misfit: 0.575944E-01 Gt predicted* 0.965 0.0000 0.0297 0.0000 0.0000 0.2932 0.0433 0.0696 0.0000 0.0027 0.1364 0.4251 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0092 0.0000 0.0000 0.0287 -0.0090 -0.0149 0.0000 -0.0027 0.0075 -0.0005 Composition Misfit: 0.111089E-01 Fsp predicted* 27.601 0.0944 0.0582 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1541 0.6918 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0027 -0.0066 0.0000 -0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0068 0.0027 Composition Misfit: 0.115081E-02 Bio predicted* 21.515 0.0000 0.0000 0.0220 0.0670 0.1737 0.0010 0.1596 0.1120 0.0041 0.1209 0.3398 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0006 -0.0000 0.0108 0.0005 0.0099 -0.1120 -0.0041 0.0194 0.0761 Composition Misfit: 0.216923E-01 St predicted* 1.864 0.0000 0.0000 0.0042 0.0000 0.1343 0.0028 0.0487 0.0881 0.0024 0.3890 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0031 0.0000 -0.0032 0.0010 -0.0258 -0.0881 -0.0024 0.0596 0.0558 Composition Misfit: 0.349622E-01 Ilm predicted* 0.437 0.0000 0.0000 0.2303 0.0000 0.6458 0.0083 0.0077 0.0000 0.1079 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1197 0.0000 -0.0158 0.0017 0.0023 0.0000 -0.1079 0.0000 0.0000 Composition Misfit: 0.636602E-01 ky predicted 6.173 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.403 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.022 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -776114. CaO 15.215 -754827. TiO2 7.199 -932022. K2O 16.990 -850326. FeO 54.593 -314181. MnO 0.947 -467370. MgO 41.584 -638510. H2O 29.953 -291574. O2 1.884 -409036. Al2O3 111.899 -0.163582E+07 SiO2 727.525 -886452. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 20 converged, 10 successes so far. Misfit function evaluations this try => 231 Misfit this try = 0.221552 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.057046E-06 Bayes score, PP * exp(-Misfit) = 8.469836E-07 Best Bayes score so far = 8.699616E-07 obtained on Try 14 P_bar T_K C_O2 C_H2O Initial coordinates: 6968.56 888.318 0.883366 0.164340 Final coordinates: 9390.92 927.965 0.633602 4.939130E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.221552 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 2.670 0.0201 0.0024 0.0000 0.0612 0.0057 0.0000 0.0055 0.1649 0.0005 0.2383 0.5014 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0097 -0.0024 0.0000 0.0233 0.0054 0.0000 0.0080 -0.1649 -0.0005 0.0422 0.0986 Composition Misfit: 0.595282E-01 Gt predicted* 2.506 0.0000 0.0360 0.0000 0.0000 0.3011 0.0226 0.0772 0.0000 0.0031 0.1354 0.4246 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0155 0.0000 0.0000 0.0208 0.0116 -0.0224 0.0000 -0.0031 0.0085 0.0000 Composition Misfit: 0.211084E-01 Fsp predicted* 26.794 0.0954 0.0564 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1532 0.6936 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0038 -0.0048 0.0000 -0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0077 0.0009 Composition Misfit: 0.945418E-03 Bio predicted* 19.536 0.0000 0.0000 0.0214 0.0667 0.1650 0.0005 0.1717 0.1120 0.0040 0.1163 0.3424 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0000 0.0003 0.0195 0.0009 -0.0022 -0.1120 -0.0040 0.0240 0.0736 Composition Misfit: 0.248449E-01 St predicted* 0.007 0.0000 0.0000 0.0045 0.0000 0.1305 0.0014 0.0540 0.0881 0.0024 0.3887 0.3304 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0028 0.0000 0.0005 0.0024 -0.0310 -0.0881 -0.0024 0.0599 0.0559 Composition Misfit: 0.425954E-01 Ilm predicted* 0.629 0.0000 0.0000 0.2287 0.0000 0.6498 0.0043 0.0087 0.0000 0.1085 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1213 0.0000 -0.0198 0.0057 0.0013 0.0000 -0.1085 0.0000 0.0000 Composition Misfit: 0.725300E-01 ky predicted 7.064 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.795 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -772581. CaO 15.215 -752509. TiO2 7.199 -930337. K2O 16.990 -847385. FeO 54.593 -313541. MnO 0.947 -471841. MgO 41.584 -637137. H2O 29.635 -290190. O2 2.162 -407227. Al2O3 111.899 -0.163427E+07 SiO2 727.525 -884657. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 21 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 22 converged, 11 successes so far. Misfit function evaluations this try => 284 Misfit this try = 0.334706 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.122124E-06 Bayes score, PP * exp(-Misfit) = 8.029341E-07 Best Bayes score so far = 8.699616E-07 obtained on Try 14 P_bar T_K C_O2 C_H2O Initial coordinates: 7671.19 982.612 0.771516 0.813997 Final coordinates: 9333.65 921.309 0.998668 6.841268E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.334706 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 7.671 0.0218 0.0029 0.0000 0.0593 0.0052 0.0000 0.0056 0.1649 0.0005 0.2391 0.5007 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0114 -0.0029 0.0000 0.0252 0.0059 0.0000 0.0079 -0.1649 -0.0005 0.0414 0.0993 Composition Misfit: 0.643618E-01 Gt predicted* 1.051 0.0000 0.0415 0.0000 0.0000 0.2787 0.0355 0.0825 0.0000 0.0035 0.1342 0.4240 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0209 0.0000 0.0000 0.0432 -0.0013 -0.0277 0.0000 -0.0035 0.0096 0.0006 Composition Misfit: 0.272933E-01 Fsp predicted* 25.711 0.0937 0.0603 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1551 0.6897 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0020 -0.0087 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0058 0.0048 Composition Misfit: 0.155185E-02 Bio predicted* 15.570 0.0000 0.0000 0.0195 0.0664 0.1499 0.0007 0.1896 0.1133 0.0044 0.1138 0.3422 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0018 0.0005 0.0345 0.0007 -0.0201 -0.1133 -0.0044 0.0265 0.0737 Composition Misfit: 0.329287E-01 St predicted* 7.297 0.0000 0.0000 0.0039 0.0000 0.1226 0.0022 0.0619 0.0881 0.0026 0.3885 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0034 0.0000 0.0085 0.0016 -0.0390 -0.0881 -0.0026 0.0601 0.0560 Composition Misfit: 0.481605E-01 Ilm predicted* 1.056 0.0000 0.0000 0.1835 0.0000 0.6780 0.0053 0.0065 0.0000 0.1266 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1665 0.0000 -0.0480 0.0047 0.0035 0.0000 -0.1266 0.0000 0.0000 Composition Misfit: 0.160410 ky predicted 0.026 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.619 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -771634. CaO 15.215 -751097. TiO2 7.199 -930630. K2O 16.990 -847009. FeO 54.593 -313454. MnO 0.947 -467575. MgO 41.584 -635954. H2O 41.048 -289340. O2 3.408 -401767. Al2O3 111.899 -0.163332E+07 SiO2 727.525 -884065. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 23 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 24 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 25 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 26 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 27 converged, 12 successes so far. Misfit function evaluations this try => 163 Misfit this try = 0.278883 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.101790E-06 Bayes score, PP * exp(-Misfit) = 8.336456E-07 Best Bayes score so far = 8.699616E-07 obtained on Try 14 P_bar T_K C_O2 C_H2O Initial coordinates: 6365.52 929.894 0.697280 0.466721 Final coordinates: 9302.33 922.988 0.849782 6.651031E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.278882 Extraneous predicted phases: 1.516886E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 6.703 0.0211 0.0027 0.0000 0.0600 0.0053 0.0000 0.0056 0.1649 0.0005 0.2389 0.5009 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0108 -0.0027 0.0000 0.0245 0.0058 0.0000 0.0080 -0.1649 -0.0005 0.0416 0.0991 Composition Misfit: 0.627465E-01 Gt predicted* 1.178 0.0000 0.0398 0.0000 0.0000 0.2838 0.0335 0.0805 0.0000 0.0034 0.1347 0.4243 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0193 0.0000 0.0000 0.0381 0.0007 -0.0257 0.0000 -0.0034 0.0091 0.0004 Composition Misfit: 0.232817E-01 Fsp predicted* 25.966 0.0939 0.0597 0.0000 0.0013 0.0000 0.0000 0.0000 0.0000 0.0000 0.1548 0.6903 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0023 -0.0081 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0061 0.0042 Composition Misfit: 0.141950E-02 Bio predicted* 16.263 0.0000 0.0000 0.0203 0.0665 0.1543 0.0007 0.1840 0.1127 0.0043 0.1148 0.3423 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0011 0.0004 0.0302 0.0007 -0.0145 -0.1127 -0.0043 0.0255 0.0737 Composition Misfit: 0.293086E-01 St predicted* 7.009 0.0000 0.0000 0.0042 0.0000 0.1249 0.0021 0.0593 0.0881 0.0025 0.3886 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0032 0.0000 0.0062 0.0018 -0.0364 -0.0881 -0.0025 0.0600 0.0560 Composition Misfit: 0.452396E-01 Ilm predicted* 0.885 0.0000 0.0000 0.2009 0.0000 0.6663 0.0056 0.0075 0.0000 0.1197 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1491 0.0000 -0.0363 0.0044 0.0025 0.0000 -0.1197 0.0000 0.0000 Composition Misfit: 0.116886 ky predicted 0.437 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.555 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.004 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -772113. CaO 15.215 -751534. TiO2 7.199 -930328. K2O 16.990 -847294. FeO 54.593 -313514. MnO 0.947 -468269. MgO 41.584 -636350. H2O 39.906 -289623. O2 2.900 -403740. Al2O3 111.899 -0.163366E+07 SiO2 727.525 -884319. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 28 converged, 13 successes so far. Misfit function evaluations this try => 212 Misfit this try = 0.335485 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.114577E-06 Bayes score, PP * exp(-Misfit) = 7.969127E-07 Best Bayes score so far = 8.699616E-07 obtained on Try 14 P_bar T_K C_O2 C_H2O Initial coordinates: 13145.1 944.820 0.945279 0.911781 Final coordinates: 9295.19 921.604 0.999701 6.791689E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.335454 Extraneous predicted phases: 3.123013E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 7.381 0.0215 0.0028 0.0000 0.0595 0.0053 0.0000 0.0056 0.1649 0.0005 0.2390 0.5007 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0112 -0.0028 0.0000 0.0249 0.0059 0.0000 0.0079 -0.1649 -0.0005 0.0414 0.0993 Composition Misfit: 0.636871E-01 Gt predicted* 1.028 0.0000 0.0409 0.0000 0.0000 0.2789 0.0362 0.0822 0.0000 0.0035 0.1343 0.4240 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0203 0.0000 0.0000 0.0430 -0.0019 -0.0274 0.0000 -0.0035 0.0095 0.0006 Composition Misfit: 0.266169E-01 Fsp predicted* 25.802 0.0937 0.0602 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1551 0.6898 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0020 -0.0086 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0058 0.0047 Composition Misfit: 0.153355E-02 Bio predicted* 15.766 0.0000 0.0000 0.0195 0.0664 0.1506 0.0008 0.1888 0.1133 0.0044 0.1141 0.3421 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0018 0.0005 0.0338 0.0007 -0.0193 -0.1133 -0.0044 0.0263 0.0739 Composition Misfit: 0.323339E-01 St predicted* 7.035 0.0000 0.0000 0.0038 0.0000 0.1230 0.0023 0.0615 0.0881 0.0026 0.3885 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0035 0.0000 0.0081 0.0016 -0.0385 -0.0881 -0.0026 0.0601 0.0560 Composition Misfit: 0.477696E-01 Ilm predicted* 1.053 0.0000 0.0000 0.1824 0.0000 0.6788 0.0053 0.0064 0.0000 0.1270 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1676 0.0000 -0.0488 0.0047 0.0036 0.0000 -0.1270 0.0000 0.0000 Composition Misfit: 0.163512 ky predicted 0.317 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.600 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.017 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -771863. CaO 15.215 -751281. TiO2 7.199 -930827. K2O 16.990 -847193. FeO 54.593 -313513. MnO 0.947 -467515. MgO 41.584 -636054. H2O 40.750 -289447. O2 3.411 -401837. Al2O3 111.899 -0.163345E+07 SiO2 727.525 -884185. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 29 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 30 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 31 converged, 14 successes so far. Misfit function evaluations this try => 236 Misfit this try = 0.191048 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 9.372342E-07 Bayes score, PP * exp(-Misfit) = 7.742427E-07 Best Bayes score so far = 8.699616E-07 obtained on Try 14 P_bar T_K C_O2 C_H2O Initial coordinates: 12423.2 914.329 0.188346 0.122713 Final coordinates: 8526.50 925.758 0.553520 5.131219E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.190014 Extraneous predicted phases: 1.033511E-03 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.056 0.0176 0.0020 0.0000 0.0639 0.0058 0.0000 0.0051 0.1649 0.0005 0.2386 0.5016 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0072 -0.0020 0.0000 0.0205 0.0054 0.0000 0.0085 -0.1649 -0.0005 0.0418 0.0984 Composition Misfit: 0.574699E-01 Gt predicted* 1.012 0.0000 0.0300 0.0000 0.0000 0.2939 0.0421 0.0699 0.0000 0.0027 0.1363 0.4251 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0094 0.0000 0.0000 0.0280 -0.0079 -0.0151 0.0000 -0.0027 0.0075 -0.0005 Composition Misfit: 0.107863E-01 Fsp predicted* 27.567 0.0944 0.0581 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1540 0.6919 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0028 -0.0065 0.0000 -0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0068 0.0026 Composition Misfit: 0.114183E-02 Bio predicted* 21.472 0.0000 0.0000 0.0219 0.0670 0.1735 0.0009 0.1598 0.1120 0.0041 0.1208 0.3399 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0006 -0.0000 0.0109 0.0005 0.0097 -0.1120 -0.0041 0.0196 0.0760 Composition Misfit: 0.217154E-01 St predicted* 1.756 0.0000 0.0000 0.0042 0.0000 0.1343 0.0027 0.0488 0.0881 0.0024 0.3890 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0031 0.0000 -0.0032 0.0011 -0.0259 -0.0881 -0.0024 0.0596 0.0558 Composition Misfit: 0.351043E-01 Ilm predicted* 0.441 0.0000 0.0000 0.2302 0.0000 0.6460 0.0081 0.0077 0.0000 0.1079 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1198 0.0000 -0.0160 0.0019 0.0023 0.0000 -0.1079 0.0000 0.0000 Composition Misfit: 0.637965E-01 ky predicted 6.248 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.347 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.101 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -776012. CaO 15.215 -754747. TiO2 7.199 -931982. K2O 16.990 -850225. FeO 54.593 -314166. MnO 0.947 -467572. MgO 41.584 -638479. H2O 30.787 -291537. O2 1.889 -409006. Al2O3 111.899 -0.163579E+07 SiO2 727.525 -886396. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 32 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 33 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 34 converged, 15 successes so far. Misfit function evaluations this try => 140 Misfit this try = 0.172893 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 4.569329E-07 Bayes score, PP * exp(-Misfit) = 3.843844E-07 Best Bayes score so far = 8.699616E-07 obtained on Try 14 P_bar T_K C_O2 C_H2O Initial coordinates: 6884.72 845.172 0.325950 0.111934 Final coordinates: 7150.65 856.683 0.441756 5.333461E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.172856 Extraneous predicted phases: 3.782070E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.133 0.0184 0.0014 0.0000 0.0636 0.0040 0.0000 0.0037 0.1654 0.0004 0.2418 0.5012 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0081 -0.0014 0.0000 0.0208 0.0072 0.0000 0.0098 -0.1654 -0.0004 0.0386 0.0988 Composition Misfit: 0.759074E-01 Gt predicted* 0.383 0.0000 0.0319 0.0000 0.0000 0.2791 0.0688 0.0543 0.0000 0.0020 0.1379 0.4260 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0114 0.0000 0.0000 0.0428 -0.0345 0.0005 0.0000 -0.0020 0.0059 -0.0013 Composition Misfit: 0.282161E-01 Fsp predicted* 27.553 0.0944 0.0591 0.0000 0.0011 0.0000 0.0000 0.0000 0.0000 0.0000 0.1545 0.6909 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0027 -0.0075 0.0000 0.0003 0.0000 0.0000 0.0000 0.0000 0.0000 0.0063 0.0036 Composition Misfit: 0.138075E-02 Bio predicted* 21.547 0.0000 0.0000 0.0207 0.0668 0.1761 0.0011 0.1587 0.1129 0.0039 0.1188 0.3410 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0007 0.0002 0.0084 0.0003 0.0108 -0.1129 -0.0039 0.0216 0.0749 Composition Misfit: 0.216061E-01 St predicted* 3.547 0.0000 0.0000 0.0039 0.0000 0.1399 0.0038 0.0410 0.0882 0.0021 0.3902 0.3308 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0034 0.0000 -0.0089 0.0000 -0.0181 -0.0882 -0.0021 0.0584 0.0555 Composition Misfit: 0.295121E-01 Ilm predicted* 0.372 0.0000 0.0000 0.3155 0.0000 0.5769 0.0233 0.0105 0.0000 0.0738 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0345 0.0000 0.0531 -0.0133 -0.0005 0.0000 -0.0738 0.0000 0.0000 Composition Misfit: 0.162332E-01 ky predicted 4.897 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.564 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.004 0.0000 0.0000 0.3810 0.0000 0.5714 0.0000 0.0000 0.0000 0.0476 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -765991. CaO 15.215 -749154. TiO2 7.199 -925235. K2O 16.990 -840502. FeO 54.593 -307520. MnO 0.947 -456595. MgO 41.584 -634462. H2O 32.001 -287806. O2 1.507 -410930. Al2O3 111.899 -0.162799E+07 SiO2 727.525 -882215. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 35 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 36 converged, 16 successes so far. Misfit function evaluations this try => 237 Misfit this try = 0.291414 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.190480E-06 Bayes score, PP * exp(-Misfit) = 8.895339E-07 Best Bayes score so far = 8.895339E-07 obtained on Try 36 P_bar T_K C_O2 C_H2O Initial coordinates: 6429.45 988.108 0.647897 0.805315 Final coordinates: 9143.03 906.502 0.877074 6.823151E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.291414 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 7.254 0.0225 0.0027 0.0000 0.0587 0.0048 0.0000 0.0052 0.1651 0.0005 0.2400 0.5006 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0121 -0.0027 0.0000 0.0257 0.0063 0.0000 0.0084 -0.1651 -0.0005 0.0405 0.0994 Composition Misfit: 0.690235E-01 Gt predicted* 1.069 0.0000 0.0432 0.0000 0.0000 0.2815 0.0357 0.0772 0.0000 0.0033 0.1347 0.4243 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0226 0.0000 0.0000 0.0404 -0.0015 -0.0224 0.0000 -0.0033 0.0091 0.0004 Composition Misfit: 0.248678E-01 Fsp predicted* 25.735 0.0938 0.0602 0.0000 0.0011 0.0000 0.0000 0.0000 0.0000 0.0000 0.1551 0.6898 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0021 -0.0086 0.0000 0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0058 0.0047 Composition Misfit: 0.157064E-02 Bio predicted* 15.986 0.0000 0.0000 0.0198 0.0664 0.1529 0.0007 0.1866 0.1130 0.0042 0.1133 0.3430 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0016 0.0005 0.0316 0.0007 -0.0171 -0.1130 -0.0042 0.0270 0.0729 Composition Misfit: 0.308948E-01 St predicted* 7.399 0.0000 0.0000 0.0041 0.0000 0.1255 0.0021 0.0585 0.0881 0.0025 0.3887 0.3304 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0032 0.0000 0.0055 0.0017 -0.0356 -0.0881 -0.0025 0.0598 0.0559 Composition Misfit: 0.443732E-01 Ilm predicted* 0.931 0.0000 0.0000 0.1990 0.0000 0.6676 0.0059 0.0072 0.0000 0.1204 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1510 0.0000 -0.0376 0.0041 0.0028 0.0000 -0.1204 0.0000 0.0000 Composition Misfit: 0.120684 ky predicted 0.025 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.601 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -768975. CaO 15.215 -749580. TiO2 7.199 -928327. K2O 16.990 -844379. FeO 54.593 -311739. MnO 0.947 -465786. MgO 41.584 -635085. H2O 40.939 -288361. O2 2.993 -403489. Al2O3 111.899 -0.163138E+07 SiO2 727.525 -882904. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 37 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 38 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 39 converged, 17 successes so far. Misfit function evaluations this try => 248 Misfit this try = 0.191792 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 9.186696E-07 Bayes score, PP * exp(-Misfit) = 7.583423E-07 Best Bayes score so far = 8.895339E-07 obtained on Try 36 P_bar T_K C_O2 C_H2O Initial coordinates: 6118.90 928.832 0.721554 0.323346 Final coordinates: 8382.41 924.193 0.553931 5.038595E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.191792 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.082 0.0174 0.0019 0.0000 0.0641 0.0057 0.0000 0.0050 0.1650 0.0005 0.2388 0.5015 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0071 -0.0019 0.0000 0.0204 0.0055 0.0000 0.0086 -0.1650 -0.0005 0.0416 0.0985 Composition Misfit: 0.579626E-01 Gt predicted* 0.830 0.0000 0.0293 0.0000 0.0000 0.2908 0.0466 0.0691 0.0000 0.0026 0.1365 0.4252 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0087 0.0000 0.0000 0.0312 -0.0124 -0.0143 0.0000 -0.0026 0.0074 -0.0005 Composition Misfit: 0.125673E-01 Fsp predicted* 27.607 0.0943 0.0584 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1542 0.6916 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0026 -0.0068 0.0000 -0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0067 0.0029 Composition Misfit: 0.118147E-02 Bio predicted* 21.452 0.0000 0.0000 0.0219 0.0670 0.1735 0.0010 0.1595 0.1121 0.0041 0.1212 0.3396 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0006 -0.0001 0.0110 0.0004 0.0100 -0.1121 -0.0041 0.0191 0.0764 Composition Misfit: 0.216483E-01 St predicted* 2.344 0.0000 0.0000 0.0042 0.0000 0.1342 0.0030 0.0486 0.0881 0.0024 0.3890 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0031 0.0000 -0.0031 0.0008 -0.0257 -0.0881 -0.0024 0.0595 0.0558 Composition Misfit: 0.347036E-01 Ilm predicted* 0.436 0.0000 0.0000 0.2301 0.0000 0.6453 0.0090 0.0076 0.0000 0.1080 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1199 0.0000 -0.0153 0.0010 0.0024 0.0000 -0.1080 0.0000 0.0000 Composition Misfit: 0.637284E-01 ky predicted 5.762 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.487 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -776297. CaO 15.215 -754953. TiO2 7.199 -932052. K2O 16.990 -850524. FeO 54.593 -314182. MnO 0.947 -466732. MgO 41.584 -638534. H2O 30.232 -291620. O2 1.890 -409036. Al2O3 111.899 -0.163585E+07 SiO2 727.525 -886556. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 40 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 41 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 42 converged, 18 successes so far. Misfit function evaluations this try => 231 Misfit this try = 0.145637 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.060562E-06 Bayes score, PP * exp(-Misfit) = 9.168258E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 5854.86 823.473 0.527823 0.148680 Final coordinates: 8489.30 899.031 0.494201 4.888900E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.145581 Extraneous predicted phases: 5.561713E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.466 0.0187 0.0019 0.0000 0.0629 0.0053 0.0000 0.0048 0.1651 0.0005 0.2394 0.5015 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0083 -0.0019 0.0000 0.0215 0.0059 0.0000 0.0088 -0.1651 -0.0005 0.0410 0.0985 Composition Misfit: 0.619363E-01 Gt predicted* 1.426 0.0000 0.0349 0.0000 0.0000 0.3003 0.0354 0.0654 0.0000 0.0027 0.1362 0.4250 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0143 0.0000 0.0000 0.0216 -0.0011 -0.0106 0.0000 -0.0027 0.0076 -0.0004 Composition Misfit: 0.963111E-02 Fsp predicted* 27.402 0.0950 0.0575 0.0000 0.0013 0.0000 0.0000 0.0000 0.0000 0.0000 0.1538 0.6925 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0033 -0.0059 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0071 0.0020 Composition Misfit: 0.106557E-02 Bio predicted* 21.288 0.0000 0.0000 0.0209 0.0667 0.1744 0.0007 0.1618 0.1125 0.0041 0.1175 0.3414 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0004 0.0002 0.0101 0.0007 0.0077 -0.1125 -0.0041 0.0228 0.0745 Composition Misfit: 0.224402E-01 St predicted* 0.928 0.0000 0.0000 0.0040 0.0000 0.1372 0.0021 0.0465 0.0881 0.0024 0.3892 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0033 0.0000 -0.0062 0.0018 -0.0235 -0.0881 -0.0024 0.0594 0.0558 Composition Misfit: 0.348590E-01 Ilm predicted* 0.434 0.0000 0.0000 0.2873 0.0000 0.6116 0.0070 0.0090 0.0000 0.0851 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0627 0.0000 0.0184 0.0030 0.0010 0.0000 -0.0851 0.0000 0.0000 Composition Misfit: 0.156492E-01 ky predicted 6.934 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.118 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.004 0.0000 0.0000 0.2157 0.0000 0.6580 0.0061 0.0065 0.0000 0.1137 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -769839. CaO 15.215 -751065. TiO2 7.199 -928676. K2O 16.990 -844150. FeO 54.593 -310859. MnO 0.947 -465461. MgO 41.584 -636212. H2O 29.333 -289284. O2 1.686 -408370. Al2O3 111.899 -0.163162E+07 SiO2 727.525 -883600. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 43 converged, 19 successes so far. Misfit function evaluations this try => 148 Misfit this try = 0.167261 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 3.558921E-07 Bayes score, PP * exp(-Misfit) = 3.010772E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 6984.84 814.045 5.325700E-02 0.862009 Final coordinates: 7510.99 837.587 0.357110 5.009528E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.167261 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.143 0.0198 0.0014 0.0000 0.0623 0.0037 0.0000 0.0037 0.1655 0.0003 0.2421 0.5013 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0094 -0.0014 0.0000 0.0222 0.0074 0.0000 0.0099 -0.1655 -0.0003 0.0384 0.0987 Composition Misfit: 0.803456E-01 Gt predicted* 1.097 0.0000 0.0395 0.0000 0.0000 0.2971 0.0459 0.0517 0.0000 0.0021 0.1378 0.4259 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0190 0.0000 0.0000 0.0248 -0.0116 0.0031 0.0000 -0.0021 0.0061 -0.0012 Composition Misfit: 0.145681E-01 Fsp predicted* 27.424 0.0951 0.0579 0.0000 0.0009 0.0000 0.0000 0.0000 0.0000 0.0000 0.1539 0.6921 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0035 -0.0063 0.0000 0.0004 0.0000 0.0000 0.0000 0.0000 0.0000 0.0070 0.0024 Composition Misfit: 0.134104E-02 Bio predicted* 21.688 0.0000 0.0000 0.0196 0.0665 0.1782 0.0007 0.1600 0.1134 0.0036 0.1142 0.3439 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0018 0.0005 0.0063 0.0008 0.0095 -0.1134 -0.0036 0.0262 0.0721 Composition Misfit: 0.228807E-01 St predicted* 1.356 0.0000 0.0000 0.0037 0.0000 0.1434 0.0023 0.0387 0.0883 0.0020 0.3908 0.3310 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0036 0.0000 -0.0123 0.0016 -0.0158 -0.0883 -0.0020 0.0578 0.0553 Composition Misfit: 0.298703E-01 Ilm predicted* 0.372 0.0000 0.0000 0.3934 0.0000 0.5476 0.0074 0.0090 0.0000 0.0426 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 -0.0434 0.0000 0.0824 0.0026 0.0010 0.0000 -0.0426 0.0000 0.0000 Composition Misfit: 0.182550E-01 ky predicted 6.844 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.077 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -759911. CaO 15.215 -745410. TiO2 7.199 -922545. K2O 16.990 -834287. FeO 54.593 -304574. MnO 0.947 -456731. MgO 41.584 -632450. H2O 30.057 -285764. O2 1.218 -412684. Al2O3 111.899 -0.162435E+07 SiO2 727.525 -879432. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 44 converged, 20 successes so far. Misfit function evaluations this try => 587 Misfit this try = 0.308496 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 4.630134E-07 Bayes score, PP * exp(-Misfit) = 3.401069E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 10617.9 986.757 0.788518 0.560386 Final coordinates: 7216.40 855.746 0.809068 6.674096E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.308496 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 4.990 0.0209 0.0017 0.0000 0.0610 0.0036 0.0000 0.0038 0.1655 0.0004 0.2425 0.5006 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0106 -0.0017 0.0000 0.0235 0.0076 0.0000 0.0098 -0.1655 -0.0004 0.0379 0.0994 Composition Misfit: 0.833272E-01 Gt predicted* 0.033 0.0000 0.0348 0.0000 0.0000 0.2571 0.0828 0.0601 0.0000 0.0023 0.1373 0.4256 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0143 0.0000 0.0000 0.0648 -0.0485 -0.0053 0.0000 -0.0023 0.0066 -0.0010 Composition Misfit: 0.514500E-01 Fsp predicted* 26.502 0.0934 0.0614 0.0000 0.0010 0.0000 0.0000 0.0000 0.0000 0.0000 0.1557 0.6886 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0017 -0.0098 0.0000 0.0004 0.0000 0.0000 0.0000 0.0000 0.0000 0.0052 0.0059 Composition Misfit: 0.198447E-02 Bio predicted* 17.604 0.0000 0.0000 0.0194 0.0665 0.1589 0.0013 0.1785 0.1137 0.0042 0.1161 0.3413 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0019 0.0004 0.0256 0.0001 -0.0090 -0.1137 -0.0042 0.0242 0.0747 Composition Misfit: 0.261804E-01 St predicted* 7.996 0.0000 0.0000 0.0038 0.0000 0.1318 0.0047 0.0489 0.0882 0.0023 0.3897 0.3307 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0035 0.0000 -0.0008 -0.0009 -0.0259 -0.0882 -0.0023 0.0588 0.0557 Composition Misfit: 0.354745E-01 Ilm predicted* 0.824 0.0000 0.0000 0.2039 0.0000 0.6585 0.0135 0.0057 0.0000 0.1184 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1461 0.0000 -0.0285 -0.0035 0.0043 0.0000 -0.1184 0.0000 0.0000 Composition Misfit: 0.110079 ky predicted 0.117 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.933 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -765678. CaO 15.215 -748484. TiO2 7.199 -925222. K2O 16.990 -841204. FeO 54.593 -307971. MnO 0.947 -455149. MgO 41.584 -633580. H2O 40.045 -287160. O2 2.761 -405811. Al2O3 111.899 -0.162771E+07 SiO2 727.525 -881967. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 45 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 46 converged, 21 successes so far. Misfit function evaluations this try => 5037 Misfit this try = 0.342758 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 5.949852E-07 Bayes score, PP * exp(-Misfit) = 4.223265E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 7984.00 831.714 0.921737 0.144487 Final coordinates: 7999.68 853.060 0.945236 6.609389E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.342758 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 6.199 0.0242 0.0022 0.0000 0.0575 0.0035 0.0000 0.0038 0.1655 0.0004 0.2428 0.5002 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0138 -0.0022 0.0000 0.0270 0.0077 0.0000 0.0097 -0.1655 -0.0004 0.0377 0.0998 Composition Misfit: 0.904415E-01 Gt predicted* 0.519 0.0000 0.0460 0.0000 0.0000 0.2711 0.0565 0.0627 0.0000 0.0029 0.1359 0.4249 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0255 0.0000 0.0000 0.0508 -0.0223 -0.0079 0.0000 -0.0029 0.0080 -0.0002 Composition Misfit: 0.338771E-01 Fsp predicted* 25.968 0.0935 0.0612 0.0000 0.0008 0.0000 0.0000 0.0000 0.0000 0.0000 0.1556 0.6888 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0019 -0.0096 0.0000 0.0005 0.0000 0.0000 0.0000 0.0000 0.0000 0.0053 0.0057 Composition Misfit: 0.209783E-02 Bio predicted* 17.001 0.0000 0.0000 0.0185 0.0662 0.1554 0.0009 0.1859 0.1140 0.0042 0.1114 0.3436 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0029 0.0007 0.0291 0.0006 -0.0164 -0.1140 -0.0042 0.0290 0.0723 Composition Misfit: 0.304645E-01 St predicted* 6.336 0.0000 0.0000 0.0037 0.0000 0.1316 0.0030 0.0511 0.0882 0.0023 0.3895 0.3306 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0036 0.0000 -0.0006 0.0008 -0.0282 -0.0882 -0.0023 0.0590 0.0557 Composition Misfit: 0.376665E-01 Ilm predicted* 1.014 0.0000 0.0000 0.1877 0.0000 0.6742 0.0080 0.0052 0.0000 0.1249 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1623 0.0000 -0.0442 0.0020 0.0048 0.0000 -0.1249 0.0000 0.0000 Composition Misfit: 0.148211 ky predicted 1.323 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.641 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -761619. CaO 15.215 -745517. TiO2 7.199 -923701. K2O 16.990 -837310. FeO 54.593 -306656. MnO 0.947 -456772. MgO 41.584 -632172. H2O 39.656 -285617. O2 3.225 -404111. Al2O3 111.899 -0.162561E+07 SiO2 727.525 -879899. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 47 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 48 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 49 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 50 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 51 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 52 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 53 converged, 22 successes so far. Misfit function evaluations this try => 247 Misfit this try = 0.205617 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.037896E-06 Bayes score, PP * exp(-Misfit) = 8.449971E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 12048.9 901.134 0.667233 0.588713 Final coordinates: 9191.44 927.574 0.623184 5.385878E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.205610 Extraneous predicted phases: 7.229210E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 2.861 0.0195 0.0023 0.0000 0.0618 0.0057 0.0000 0.0055 0.1649 0.0005 0.2384 0.5014 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0091 -0.0023 0.0000 0.0227 0.0054 0.0000 0.0081 -0.1649 -0.0005 0.0421 0.0986 Composition Misfit: 0.587801E-01 Gt predicted* 1.779 0.0000 0.0352 0.0000 0.0000 0.2974 0.0283 0.0759 0.0000 0.0030 0.1355 0.4247 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0147 0.0000 0.0000 0.0246 0.0060 -0.0211 0.0000 -0.0030 0.0083 -0.0000 Composition Misfit: 0.157905E-01 Fsp predicted* 26.862 0.0948 0.0576 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1538 0.6924 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0032 -0.0060 0.0000 -0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0071 0.0021 Composition Misfit: 0.106571E-02 Bio predicted* 19.282 0.0000 0.0000 0.0215 0.0667 0.1656 0.0006 0.1703 0.1120 0.0041 0.1173 0.3419 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0001 0.0002 0.0188 0.0008 -0.0008 -0.1120 -0.0041 0.0231 0.0741 Composition Misfit: 0.237834E-01 St predicted* 2.449 0.0000 0.0000 0.0045 0.0000 0.1307 0.0018 0.0534 0.0881 0.0024 0.3887 0.3304 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0029 0.0000 0.0004 0.0021 -0.0305 -0.0881 -0.0024 0.0598 0.0559 Composition Misfit: 0.403158E-01 Ilm predicted* 0.596 0.0000 0.0000 0.2309 0.0000 0.6474 0.0055 0.0086 0.0000 0.1076 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1191 0.0000 -0.0174 0.0045 0.0014 0.0000 -0.1076 0.0000 0.0000 Composition Misfit: 0.658748E-01 ky predicted 5.028 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.134 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.008 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -773482. CaO 15.215 -752903. TiO2 7.199 -930678. K2O 16.990 -848148. FeO 54.593 -313755. MnO 0.947 -470270. MgO 41.584 -637404. H2O 32.315 -290470. O2 2.126 -407445. Al2O3 111.899 -0.163464E+07 SiO2 727.525 -885071. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 54 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 55 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 56 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 57 converged, 23 successes so far. Misfit function evaluations this try => 421 Misfit this try = 1.45701 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 4.294700E-07 Bayes score, PP * exp(-Misfit) = 1.000369E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 8778.02 970.924 0.356277 0.566523 Final coordinates: 6320.96 904.440 0.968259 0.111703 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.470839 Extraneous predicted phases: 0.986174 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.001 0.0159 0.0014 0.0000 0.0661 0.0048 0.0000 0.0039 0.1653 0.0006 0.2410 0.5010 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0055 -0.0014 0.0000 0.0183 0.0063 0.0000 0.0096 -0.1653 -0.0006 0.0395 0.0990 Composition Misfit: 0.661857E-01 Gt predicted* 0.000 0.0000 0.0191 0.0000 0.0000 0.2439 0.1085 0.0631 0.0000 0.0023 0.1374 0.4257 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 0.0014 0.0000 0.0000 0.0780 -0.0743 -0.0083 0.0000 -0.0023 0.0064 -0.0010 Composition Misfit: 0.773279E-01 Fsp predicted* 26.813 0.0937 0.0593 0.0000 0.0016 0.0000 0.0000 0.0000 0.0000 0.0000 0.1546 0.6907 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0021 -0.0077 0.0000 -0.0003 0.0000 0.0000 0.0000 0.0000 0.0000 0.0062 0.0038 Composition Misfit: 0.136597E-02 Bio predicted* 20.728 0.0000 0.0000 0.0195 0.0671 0.1675 0.0024 0.1638 0.1147 0.0048 0.1262 0.3339 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0019 -0.0002 0.0169 -0.0009 0.0057 -0.1147 -0.0048 0.0141 0.0820 Composition Misfit: 0.241829E-01 St predicted* 1.832 0.0000 0.0000 0.0027 0.0000 0.1306 0.0077 0.0487 0.0881 0.0027 0.3892 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0046 0.0000 0.0004 -0.0039 -0.0257 -0.0881 -0.0027 0.0594 0.0560 Composition Misfit: 0.419023E-01 Ilm predicted* 0.831 0.0000 0.0000 0.1559 0.0000 0.6902 0.0128 0.0035 0.0000 0.1376 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1941 0.0000 -0.0602 -0.0028 0.0065 0.0000 -0.1376 0.0000 0.0000 Composition Misfit: 0.259874 ky predicted 5.947 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.620 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 3.228 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -780735. CaO 15.215 -758752. TiO2 7.199 -936314. K2O 16.990 -855510. FeO 54.593 -314887. MnO 0.947 -459871. MgO 41.584 -639142. H2O 67.022 -293131. O2 3.304 -404329. Al2O3 111.899 -0.163717E+07 SiO2 727.525 -889158. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 58 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 59 converged, 24 successes so far. Misfit function evaluations this try => 322 Misfit this try = 0.342397 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.105501E-06 Bayes score, PP * exp(-Misfit) = 7.849790E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 10529.9 886.354 0.141100 0.819862 Final coordinates: 9411.25 923.826 0.999173 6.280813E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.342366 Extraneous predicted phases: 3.042846E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 6.467 0.0214 0.0028 0.0000 0.0596 0.0054 0.0000 0.0057 0.1649 0.0006 0.2387 0.5008 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0111 -0.0028 0.0000 0.0248 0.0057 0.0000 0.0078 -0.1649 -0.0006 0.0418 0.0992 Composition Misfit: 0.626324E-01 Gt predicted* 1.458 0.0000 0.0406 0.0000 0.0000 0.2841 0.0310 0.0826 0.0000 0.0036 0.1342 0.4240 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0200 0.0000 0.0000 0.0378 0.0033 -0.0278 0.0000 -0.0036 0.0097 0.0007 Composition Misfit: 0.253525E-01 Fsp predicted* 25.967 0.0942 0.0591 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1545 0.6909 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0026 -0.0075 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0064 0.0036 Composition Misfit: 0.130900E-02 Bio predicted* 16.523 0.0000 0.0000 0.0195 0.0664 0.1523 0.0007 0.1873 0.1133 0.0044 0.1139 0.3421 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0019 0.0005 0.0321 0.0008 -0.0178 -0.1133 -0.0044 0.0264 0.0738 Composition Misfit: 0.316180E-01 St predicted* 4.691 0.0000 0.0000 0.0038 0.0000 0.1240 0.0019 0.0609 0.0881 0.0027 0.3884 0.3302 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0035 0.0000 0.0070 0.0019 -0.0379 -0.0881 -0.0027 0.0601 0.0561 Composition Misfit: 0.481064E-01 Ilm predicted* 1.053 0.0000 0.0000 0.1801 0.0000 0.6813 0.0045 0.0062 0.0000 0.1280 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1699 0.0000 -0.0513 0.0055 0.0038 0.0000 -0.1280 0.0000 0.0000 Composition Misfit: 0.173348 ky predicted 2.481 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.344 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.017 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -771781. CaO 15.215 -751383. TiO2 7.199 -931081. K2O 16.990 -847042. FeO 54.593 -313539. MnO 0.947 -468900. MgO 41.584 -636150. H2O 37.685 -289526. O2 3.409 -401988. Al2O3 111.899 -0.163356E+07 SiO2 727.525 -884161. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 60 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 61 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 62 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 63 converged, 25 successes so far. Misfit function evaluations this try => 335 Misfit this try = 0.487981 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 4.175454E-07 Bayes score, PP * exp(-Misfit) = 2.563163E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 9144.48 982.627 0.852612 0.930996 Final coordinates: 6271.82 903.858 0.998653 5.029471E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.487979 Extraneous predicted phases: 1.504039E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.020 0.0158 0.0014 0.0000 0.0661 0.0048 0.0000 0.0039 0.1653 0.0006 0.2411 0.5010 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0055 -0.0014 0.0000 0.0183 0.0064 0.0000 0.0096 -0.1653 -0.0006 0.0394 0.0990 Composition Misfit: 0.664177E-01 Gt predicted* 0.003 0.0000 0.0189 0.0000 0.0000 0.2426 0.1101 0.0631 0.0000 0.0022 0.1374 0.4257 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 0.0016 0.0000 0.0000 0.0793 -0.0758 -0.0083 0.0000 -0.0022 0.0064 -0.0010 Composition Misfit: 0.797305E-01 Fsp predicted* 27.705 0.0937 0.0593 0.0000 0.0016 0.0000 0.0000 0.0000 0.0000 0.0000 0.1547 0.6907 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0021 -0.0077 0.0000 -0.0003 0.0000 0.0000 0.0000 0.0000 0.0000 0.0062 0.0038 Composition Misfit: 0.136661E-02 Bio predicted* 21.403 0.0000 0.0000 0.0193 0.0671 0.1671 0.0024 0.1644 0.1149 0.0048 0.1262 0.3338 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0020 -0.0001 0.0174 -0.0010 0.0052 -0.1149 -0.0048 0.0141 0.0822 Composition Misfit: 0.243726E-01 St predicted* 1.689 0.0000 0.0000 0.0027 0.0000 0.1304 0.0079 0.0488 0.0881 0.0027 0.3892 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0047 0.0000 0.0007 -0.0040 -0.0259 -0.0881 -0.0027 0.0594 0.0560 Composition Misfit: 0.424574E-01 Ilm predicted* 0.892 0.0000 0.0000 0.1529 0.0000 0.6923 0.0127 0.0033 0.0000 0.1388 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1971 0.0000 -0.0623 -0.0027 0.0067 0.0000 -0.1388 0.0000 0.0000 Composition Misfit: 0.273635 ky predicted 6.317 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.967 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.004 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -780812. CaO 15.215 -758831. TiO2 7.199 -936489. K2O 16.990 -855615. FeO 54.593 -314901. MnO 0.947 -459744. MgO 41.584 -639129. H2O 30.177 -293155. O2 3.407 -404096. Al2O3 111.899 -0.163718E+07 SiO2 727.525 -889209. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 64 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 65 converged, 26 successes so far. Misfit function evaluations this try => 175 Misfit this try = 0.343068 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.054446E-06 Bayes score, PP * exp(-Misfit) = 7.482243E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 8697.66 920.532 0.907204 0.910744 Final coordinates: 8954.96 922.492 0.994982 6.057492E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.343068 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 5.011 0.0197 0.0024 0.0000 0.0615 0.0055 0.0000 0.0055 0.1649 0.0006 0.2386 0.5011 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0094 -0.0024 0.0000 0.0230 0.0056 0.0000 0.0080 -0.1649 -0.0006 0.0418 0.0989 Composition Misfit: 0.595716E-01 Gt predicted* 0.908 0.0000 0.0363 0.0000 0.0000 0.2811 0.0412 0.0791 0.0000 0.0033 0.1348 0.4243 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0158 0.0000 0.0000 0.0408 -0.0069 -0.0243 0.0000 -0.0033 0.0091 0.0004 Composition Misfit: 0.219975E-01 Fsp predicted* 26.508 0.0939 0.0596 0.0000 0.0013 0.0000 0.0000 0.0000 0.0000 0.0000 0.1548 0.6904 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0022 -0.0080 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0061 0.0041 Composition Misfit: 0.139116E-02 Bio predicted* 17.501 0.0000 0.0000 0.0195 0.0665 0.1566 0.0009 0.1818 0.1135 0.0045 0.1159 0.3408 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0019 0.0004 0.0279 0.0005 -0.0123 -0.1135 -0.0045 0.0244 0.0752 Composition Misfit: 0.280244E-01 St predicted* 4.687 0.0000 0.0000 0.0035 0.0000 0.1263 0.0026 0.0580 0.0881 0.0027 0.3886 0.3302 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0038 0.0000 0.0048 0.0012 -0.0351 -0.0881 -0.0027 0.0600 0.0561 Composition Misfit: 0.448038E-01 Ilm predicted* 1.012 0.0000 0.0000 0.1747 0.0000 0.6840 0.0056 0.0055 0.0000 0.1301 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1753 0.0000 -0.0540 0.0044 0.0045 0.0000 -0.1301 0.0000 0.0000 Composition Misfit: 0.187279 ky predicted 2.864 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.508 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -773505. CaO 15.215 -752623. TiO2 7.199 -932224. K2O 16.990 -848450. FeO 54.593 -313831. MnO 0.947 -466957. MgO 41.584 -636797. H2O 36.345 -290237. O2 3.395 -402590. Al2O3 111.899 -0.163434E+07 SiO2 727.525 -885059. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 66 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 67 converged, 27 successes so far. Misfit function evaluations this try => 209 Misfit this try = 0.316593 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.136054E-06 Bayes score, PP * exp(-Misfit) = 8.277605E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 9461.51 938.362 0.630594 0.703393 Final coordinates: 9850.93 923.688 0.898148 6.885203E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.316592 Extraneous predicted phases: 2.966808E-07 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 9.054 0.0245 0.0034 0.0000 0.0563 0.0050 0.0000 0.0055 0.1650 0.0005 0.2397 0.5001 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0141 -0.0034 0.0000 0.0281 0.0062 0.0000 0.0080 -0.1650 -0.0005 0.0408 0.0999 Composition Misfit: 0.716964E-01 Gt predicted* 2.130 0.0000 0.0456 0.0000 0.0000 0.2840 0.0232 0.0859 0.0000 0.0037 0.1339 0.4238 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0250 0.0000 0.0000 0.0379 0.0111 -0.0311 0.0000 -0.0037 0.0099 0.0008 Composition Misfit: 0.360639E-01 Fsp predicted* 24.910 0.0945 0.0587 0.0000 0.0011 0.0000 0.0000 0.0000 0.0000 0.0000 0.1544 0.6913 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0028 -0.0071 0.0000 0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0065 0.0032 Composition Misfit: 0.127768E-02 Bio predicted* 14.910 0.0000 0.0000 0.0200 0.0663 0.1470 0.0005 0.1933 0.1127 0.0042 0.1121 0.3440 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0014 0.0006 0.0375 0.0009 -0.0238 -0.1127 -0.0042 0.0283 0.0720 Composition Misfit: 0.366447E-01 St predicted* 6.286 0.0000 0.0000 0.0044 0.0000 0.1207 0.0014 0.0641 0.0881 0.0025 0.3884 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0029 0.0000 0.0103 0.0024 -0.0412 -0.0881 -0.0025 0.0602 0.0560 Composition Misfit: 0.522807E-01 Ilm predicted* 0.991 0.0000 0.0000 0.2025 0.0000 0.6661 0.0040 0.0084 0.0000 0.1190 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1475 0.0000 -0.0361 0.0060 0.0016 0.0000 -0.1190 0.0000 0.0000 Composition Misfit: 0.118629 ky predicted 0.391 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.327 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -769786. CaO 15.215 -749977. TiO2 7.199 -928986. K2O 16.990 -845556. FeO 54.593 -313156. MnO 0.947 -470686. MgO 41.584 -635390. H2O 41.311 -288656. O2 3.065 -402277. Al2O3 111.899 -0.163258E+07 SiO2 727.525 -883141. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 68 converged, 28 successes so far. Misfit function evaluations this try => 322 Misfit this try = 0.201498 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.000958E-06 Bayes score, PP * exp(-Misfit) = 8.182884E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 7891.16 916.888 0.832655 0.728486 Final coordinates: 8634.07 921.371 0.620718 5.863806E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.201498 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 2.802 0.0186 0.0022 0.0000 0.0629 0.0055 0.0000 0.0051 0.1650 0.0005 0.2389 0.5014 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0082 -0.0022 0.0000 0.0216 0.0057 0.0000 0.0084 -0.1650 -0.0005 0.0415 0.0986 Composition Misfit: 0.593892E-01 Gt predicted* 0.761 0.0000 0.0326 0.0000 0.0000 0.2871 0.0443 0.0722 0.0000 0.0028 0.1361 0.4250 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0120 0.0000 0.0000 0.0349 -0.0100 -0.0174 0.0000 -0.0028 0.0077 -0.0003 Composition Misfit: 0.155842E-01 Fsp predicted* 27.027 0.0940 0.0592 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1546 0.6908 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0024 -0.0076 0.0000 -0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0063 0.0037 Composition Misfit: 0.130823E-02 Bio predicted* 19.201 0.0000 0.0000 0.0216 0.0669 0.1667 0.0010 0.1679 0.1121 0.0041 0.1191 0.3407 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0002 0.0001 0.0178 0.0005 0.0016 -0.1121 -0.0041 0.0212 0.0753 Composition Misfit: 0.225360E-01 St predicted* 5.395 0.0000 0.0000 0.0043 0.0000 0.1311 0.0028 0.0519 0.0881 0.0024 0.3889 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0030 0.0000 -0.0000 0.0010 -0.0289 -0.0881 -0.0024 0.0596 0.0558 Composition Misfit: 0.371609E-01 Ilm predicted* 0.560 0.0000 0.0000 0.2286 0.0000 0.6462 0.0085 0.0081 0.0000 0.1085 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1214 0.0000 -0.0162 0.0015 0.0019 0.0000 -0.1085 0.0000 0.0000 Composition Misfit: 0.655195E-01 ky predicted 2.639 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.614 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -774607. CaO 15.215 -753582. TiO2 7.199 -930976. K2O 16.990 -849169. FeO 54.593 -313742. MnO 0.947 -466542. MgO 41.584 -637657. H2O 35.183 -290801. O2 2.118 -407748. Al2O3 111.899 -0.163485E+07 SiO2 727.525 -885673. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 69 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 70 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 71 converged, 29 successes so far. Misfit function evaluations this try => 369 Misfit this try = 0.161887 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.038366E-06 Bayes score, PP * exp(-Misfit) = 8.831697E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 8741.21 812.934 0.918267 0.234843 Final coordinates: 8929.67 923.692 0.550187 6.818441E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.159602 Extraneous predicted phases: 2.285022E-03 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 4.780 0.0193 0.0024 0.0000 0.0620 0.0055 0.0000 0.0053 0.1649 0.0005 0.2388 0.5013 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0089 -0.0024 0.0000 0.0225 0.0056 0.0000 0.0082 -0.1649 -0.0005 0.0417 0.0987 Composition Misfit: 0.597252E-01 Gt predicted* 0.895 0.0000 0.0352 0.0000 0.0000 0.2879 0.0384 0.0750 0.0000 0.0029 0.1357 0.4248 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0147 0.0000 0.0000 0.0340 -0.0041 -0.0202 0.0000 -0.0029 0.0081 -0.0001 Composition Misfit: 0.165114E-01 Fsp predicted* 26.503 0.0939 0.0595 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1548 0.6905 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0022 -0.0079 0.0000 -0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0061 0.0040 Composition Misfit: 0.137683E-02 Bio predicted* 17.574 0.0000 0.0000 0.0214 0.0668 0.1631 0.0008 0.1724 0.1121 0.0041 0.1178 0.3415 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0001 0.0002 0.0214 0.0006 -0.0029 -0.1121 -0.0041 0.0226 0.0745 Composition Misfit: 0.238383E-01 St predicted* 7.929 0.0000 0.0000 0.0044 0.0000 0.1292 0.0024 0.0541 0.0881 0.0024 0.3888 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0029 0.0000 0.0018 0.0014 -0.0312 -0.0881 -0.0024 0.0597 0.0559 Composition Misfit: 0.393098E-01 Ilm predicted* 0.528 0.0000 0.0000 0.2798 0.0000 0.6150 0.0075 0.0096 0.0000 0.0881 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0702 0.0000 0.0150 0.0025 0.0004 0.0000 -0.0881 0.0000 0.0000 Composition Misfit: 0.188400E-01 ky predicted 0.014 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.629 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.147 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -773897. CaO 15.215 -752890. TiO2 7.199 -930580. K2O 16.990 -848608. FeO 54.593 -313760. MnO 0.947 -467661. MgO 41.584 -637316. H2O 40.911 -290452. O2 1.877 -407055. Al2O3 111.899 -0.163458E+07 SiO2 727.525 -885248. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 72 converged, 30 successes so far. Misfit function evaluations this try => 243 Misfit this try = 0.329270 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.107953E-06 Bayes score, PP * exp(-Misfit) = 7.971149E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 5922.21 871.059 0.936424 0.365649 Final coordinates: 9263.50 921.869 0.983183 6.675993E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.329270 Extraneous predicted phases: 6.511105E-07 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 7.060 0.0213 0.0028 0.0000 0.0598 0.0053 0.0000 0.0056 0.1649 0.0005 0.2390 0.5008 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0109 -0.0028 0.0000 0.0246 0.0058 0.0000 0.0079 -0.1649 -0.0005 0.0415 0.0992 Composition Misfit: 0.630304E-01 Gt predicted* 1.033 0.0000 0.0403 0.0000 0.0000 0.2797 0.0363 0.0817 0.0000 0.0035 0.1344 0.4241 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0198 0.0000 0.0000 0.0422 -0.0021 -0.0269 0.0000 -0.0035 0.0095 0.0006 Composition Misfit: 0.256822E-01 Fsp predicted* 25.902 0.0937 0.0601 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1550 0.6899 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0021 -0.0085 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0059 0.0046 Composition Misfit: 0.150264E-02 Bio predicted* 15.996 0.0000 0.0000 0.0196 0.0664 0.1516 0.0008 0.1876 0.1133 0.0044 0.1143 0.3420 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0018 0.0005 0.0328 0.0007 -0.0181 -0.1133 -0.0044 0.0260 0.0740 Composition Misfit: 0.315013E-01 St predicted* 6.791 0.0000 0.0000 0.0039 0.0000 0.1235 0.0023 0.0609 0.0881 0.0026 0.3885 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0035 0.0000 0.0075 0.0016 -0.0379 -0.0881 -0.0026 0.0601 0.0560 Composition Misfit: 0.471343E-01 Ilm predicted* 1.031 0.0000 0.0000 0.1835 0.0000 0.6781 0.0054 0.0064 0.0000 0.1266 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1665 0.0000 -0.0481 0.0046 0.0036 0.0000 -0.1266 0.0000 0.0000 Composition Misfit: 0.160419 ky predicted 0.596 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.588 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -772054. CaO 15.215 -751441. TiO2 7.199 -930919. K2O 16.990 -847326. FeO 54.593 -313545. MnO 0.947 -467548. MgO 41.584 -636160. H2O 40.056 -289546. O2 3.355 -402105. Al2O3 111.899 -0.163357E+07 SiO2 727.525 -884286. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 73 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 74 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 75 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 76 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 77 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 78 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 79 converged, 31 successes so far. Misfit function evaluations this try => 520 Misfit this try = 0.378018 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 3.124322E-07 Bayes score, PP * exp(-Misfit) = 2.140842E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 5888.94 816.643 0.435238 0.730301 Final coordinates: 7597.08 831.334 0.993560 5.744786E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.378018 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 4.089 0.0239 0.0018 0.0000 0.0580 0.0032 0.0000 0.0034 0.1656 0.0003 0.2434 0.5004 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0135 -0.0018 0.0000 0.0264 0.0080 0.0000 0.0101 -0.1656 -0.0003 0.0371 0.0996 Composition Misfit: 0.965893E-01 Gt predicted* 0.697 0.0000 0.0464 0.0000 0.0000 0.2761 0.0573 0.0562 0.0000 0.0027 0.1363 0.4251 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0259 0.0000 0.0000 0.0459 -0.0231 -0.0014 0.0000 -0.0027 0.0076 -0.0004 Composition Misfit: 0.317728E-01 Fsp predicted* 26.496 0.0942 0.0600 0.0000 0.0008 0.0000 0.0000 0.0000 0.0000 0.0000 0.1550 0.6900 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0026 -0.0084 0.0000 0.0006 0.0000 0.0000 0.0000 0.0000 0.0000 0.0059 0.0045 Composition Misfit: 0.195157E-02 Bio predicted* 18.670 0.0000 0.0000 0.0178 0.0661 0.1613 0.0008 0.1809 0.1144 0.0043 0.1105 0.3439 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0035 0.0008 0.0231 0.0006 -0.0114 -0.1144 -0.0043 0.0299 0.0721 Composition Misfit: 0.284275E-01 St predicted* 2.617 0.0000 0.0000 0.0034 0.0000 0.1370 0.0028 0.0458 0.0882 0.0023 0.3899 0.3306 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0040 0.0000 -0.0059 0.0010 -0.0229 -0.0882 -0.0023 0.0586 0.0557 Composition Misfit: 0.349373E-01 Ilm predicted* 1.062 0.0000 0.0000 0.1766 0.0000 0.6829 0.0071 0.0040 0.0000 0.1293 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1734 0.0000 -0.0529 0.0029 0.0060 0.0000 -0.1293 0.0000 0.0000 Composition Misfit: 0.184340 ky predicted 5.064 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.306 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -758276. CaO 15.215 -743934. TiO2 7.199 -922128. K2O 16.990 -833775. FeO 54.593 -304350. MnO 0.947 -454385. MgO 41.584 -631121. H2O 34.469 -284649. O2 3.390 -404924. Al2O3 111.899 -0.162324E+07 SiO2 727.525 -878601. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 80 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 81 converged, 32 successes so far. Misfit function evaluations this try => 165 Misfit this try = 0.324532 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.120084E-06 Bayes score, PP * exp(-Misfit) = 8.096706E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 13531.5 836.829 0.914639 7.632803E-02 Final coordinates: 9118.30 918.162 0.973128 6.796970E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.324532 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 7.100 0.0212 0.0027 0.0000 0.0600 0.0052 0.0000 0.0055 0.1650 0.0005 0.2392 0.5008 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0108 -0.0027 0.0000 0.0245 0.0060 0.0000 0.0081 -0.1650 -0.0005 0.0413 0.0992 Composition Misfit: 0.636567E-01 Gt predicted* 0.827 0.0000 0.0399 0.0000 0.0000 0.2775 0.0401 0.0802 0.0000 0.0034 0.1346 0.4242 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0194 0.0000 0.0000 0.0444 -0.0058 -0.0255 0.0000 -0.0034 0.0093 0.0005 Composition Misfit: 0.260823E-01 Fsp predicted* 25.929 0.0935 0.0605 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1552 0.6895 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0019 -0.0089 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0057 0.0050 Composition Misfit: 0.159677E-02 Bio predicted* 15.939 0.0000 0.0000 0.0196 0.0665 0.1519 0.0008 0.1871 0.1133 0.0044 0.1145 0.3419 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0018 0.0005 0.0326 0.0006 -0.0176 -0.1133 -0.0044 0.0258 0.0741 Composition Misfit: 0.310724E-01 St predicted* 7.497 0.0000 0.0000 0.0039 0.0000 0.1239 0.0025 0.0602 0.0881 0.0026 0.3886 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0035 0.0000 0.0072 0.0013 -0.0373 -0.0881 -0.0026 0.0600 0.0560 Composition Misfit: 0.461641E-01 Ilm predicted* 1.016 0.0000 0.0000 0.1847 0.0000 0.6768 0.0060 0.0064 0.0000 0.1261 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1653 0.0000 -0.0468 0.0040 0.0036 0.0000 -0.1261 0.0000 0.0000 Composition Misfit: 0.155959 ky predicted 0.007 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.685 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -771854. CaO 15.215 -751315. TiO2 7.199 -930631. K2O 16.990 -847124. FeO 54.593 -313277. MnO 0.947 -466452. MgO 41.584 -636049. H2O 40.782 -289439. O2 3.320 -402302. Al2O3 111.899 -0.163329E+07 SiO2 727.525 -884217. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 82 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 83 converged, 33 successes so far. Misfit function evaluations this try => 266 Misfit this try = 0.191616 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 9.667800E-07 Bayes score, PP * exp(-Misfit) = 7.981963E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 14116.7 846.471 0.162712 6.069587E-02 Final coordinates: 8701.04 926.492 0.569720 5.035129E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.191615 Extraneous predicted phases: 1.228615E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.672 0.0180 0.0021 0.0000 0.0635 0.0058 0.0000 0.0052 0.1649 0.0005 0.2385 0.5016 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0076 -0.0021 0.0000 0.0210 0.0054 0.0000 0.0084 -0.1649 -0.0005 0.0420 0.0984 Composition Misfit: 0.574166E-01 Gt predicted* 1.177 0.0000 0.0312 0.0000 0.0000 0.2955 0.0381 0.0713 0.0000 0.0028 0.1361 0.4250 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0107 0.0000 0.0000 0.0264 -0.0039 -0.0165 0.0000 -0.0028 0.0077 -0.0004 Composition Misfit: 0.106631E-01 Fsp predicted* 27.447 0.0945 0.0580 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1540 0.6920 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0028 -0.0064 0.0000 -0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0069 0.0025 Composition Misfit: 0.112512E-02 Bio predicted* 20.996 0.0000 0.0000 0.0218 0.0669 0.1719 0.0009 0.1621 0.1120 0.0041 0.1199 0.3404 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0005 0.0000 0.0126 0.0006 0.0074 -0.1120 -0.0041 0.0204 0.0756 Composition Misfit: 0.219053E-01 St predicted* 1.913 0.0000 0.0000 0.0043 0.0000 0.1336 0.0024 0.0498 0.0881 0.0024 0.3889 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0030 0.0000 -0.0025 0.0014 -0.0269 -0.0881 -0.0024 0.0596 0.0558 Composition Misfit: 0.361113E-01 Ilm predicted* 0.477 0.0000 0.0000 0.2301 0.0000 0.6467 0.0073 0.0079 0.0000 0.1079 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1199 0.0000 -0.0167 0.0027 0.0021 0.0000 -0.1079 0.0000 0.0000 Composition Misfit: 0.643937E-01 ky predicted 5.990 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.324 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.003 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -775412. CaO 15.215 -754295. TiO2 7.199 -931691. K2O 16.990 -849705. FeO 54.593 -314071. MnO 0.947 -468282. MgO 41.584 -638237. H2O 30.211 -291290. O2 1.944 -408676. Al2O3 111.899 -0.163553E+07 SiO2 727.525 -886076. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 84 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 85 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 86 converged, 34 successes so far. Misfit function evaluations this try => 520 Misfit this try = 0.185507 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.296426E-07 Bayes score, PP * exp(-Misfit) = 1.076920E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 6091.29 811.511 0.269649 8.930930E-02 Final coordinates: 7309.98 807.652 0.381326 4.958254E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.185485 Extraneous predicted phases: 2.179780E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.574 0.0214 0.0012 0.0000 0.0608 0.0031 0.0000 0.0032 0.1656 0.0003 0.2433 0.5010 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0111 -0.0012 0.0000 0.0237 0.0080 0.0000 0.0103 -0.1656 -0.0003 0.0372 0.0990 Composition Misfit: 0.948105E-01 Gt predicted* 1.332 0.0000 0.0464 0.0000 0.0000 0.3003 0.0413 0.0465 0.0000 0.0022 0.1376 0.4258 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0259 0.0000 0.0000 0.0216 -0.0070 0.0083 0.0000 -0.0022 0.0063 -0.0011 Composition Misfit: 0.189602E-01 Fsp predicted* 27.229 0.0956 0.0573 0.0000 0.0007 0.0000 0.0000 0.0000 0.0000 0.0000 0.1537 0.6927 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0039 -0.0057 0.0000 0.0006 0.0000 0.0000 0.0000 0.0000 0.0000 0.0072 0.0018 Composition Misfit: 0.159327E-02 Bio predicted* 21.449 0.0000 0.0000 0.0183 0.0662 0.1787 0.0005 0.1627 0.1140 0.0037 0.1103 0.3455 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0030 0.0008 0.0058 0.0009 0.0068 -0.1140 -0.0037 0.0300 0.0705 Composition Misfit: 0.251551E-01 St predicted* 0.436 0.0000 0.0000 0.0034 0.0000 0.1467 0.0018 0.0358 0.0883 0.0020 0.3910 0.3310 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0039 0.0000 -0.0157 0.0020 -0.0129 -0.0883 -0.0020 0.0575 0.0553 Composition Misfit: 0.309243E-01 Ilm predicted* 0.447 0.0000 0.0000 0.3808 0.0000 0.5564 0.0069 0.0083 0.0000 0.0477 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 -0.0308 0.0000 0.0736 0.0031 0.0017 0.0000 -0.0477 0.0000 0.0000 Composition Misfit: 0.140417E-01 ky predicted 7.677 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.854 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.003 0.0000 0.0000 0.4107 0.0000 0.5365 0.0076 0.0094 0.0000 0.0357 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -753908. CaO 15.215 -741918. TiO2 7.199 -919500. K2O 16.990 -828421. FeO 54.593 -301287. MnO 0.947 -453949. MgO 41.584 -630257. H2O 29.750 -283713. O2 1.301 -411520. Al2O3 111.899 -0.162040E+07 SiO2 727.525 -876884. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 87 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 88 converged, 35 successes so far. Misfit function evaluations this try => 247 Misfit this try = 0.361609 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.336093E-07 Bayes score, PP * exp(-Misfit) = 9.306622E-08 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 6074.98 813.628 0.148409 0.899630 Final coordinates: 5936.33 831.687 0.792114 5.762535E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.361609 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 1.983 0.0189 0.0012 0.0000 0.0634 0.0032 0.0000 0.0031 0.1657 0.0003 0.2435 0.5008 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0085 -0.0012 0.0000 0.0211 0.0080 0.0000 0.0105 -0.1657 -0.0003 0.0369 0.0992 Composition Misfit: 0.929060E-01 Gt predicted* 0.001 0.0000 0.0268 0.0000 0.0000 0.2439 0.1115 0.0512 0.0000 0.0018 0.1385 0.4263 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0063 0.0000 0.0000 0.0780 -0.0773 0.0036 0.0000 -0.0018 0.0053 -0.0016 Composition Misfit: 0.804060E-01 Fsp predicted* 27.206 0.0939 0.0603 0.0000 0.0010 0.0000 0.0000 0.0000 0.0000 0.0000 0.1551 0.6897 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0023 -0.0087 0.0000 0.0004 0.0000 0.0000 0.0000 0.0000 0.0000 0.0058 0.0048 Composition Misfit: 0.171919E-02 Bio predicted* 19.996 0.0000 0.0000 0.0193 0.0667 0.1664 0.0017 0.1689 0.1142 0.0043 0.1197 0.3388 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0021 0.0002 0.0181 -0.0002 0.0006 -0.1142 -0.0043 0.0206 0.0771 Composition Misfit: 0.233493E-01 St predicted* 4.588 0.0000 0.0000 0.0034 0.0000 0.1365 0.0063 0.0424 0.0882 0.0022 0.3903 0.3308 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0040 0.0000 -0.0054 -0.0024 -0.0195 -0.0882 -0.0022 0.0583 0.0555 Composition Misfit: 0.328912E-01 Ilm predicted* 0.762 0.0000 0.0000 0.1969 0.0000 0.6606 0.0169 0.0044 0.0000 0.1212 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1531 0.0000 -0.0306 -0.0069 0.0056 0.0000 -0.1212 0.0000 0.0000 Composition Misfit: 0.130337 ky predicted 3.621 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.843 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -765651. CaO 15.215 -749478. TiO2 7.199 -924988. K2O 16.990 -841099. FeO 54.593 -306592. MnO 0.947 -451426. MgO 41.584 -633523. H2O 34.575 -287428. O2 2.703 -407289. Al2O3 111.899 -0.162689E+07 SiO2 727.525 -882438. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 89 converged, 36 successes so far. Misfit function evaluations this try => 285 Misfit this try = 0.330595 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.102701E-06 Bayes score, PP * exp(-Misfit) = 7.922869E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 5693.18 896.112 0.944492 0.356238 Final coordinates: 9144.39 920.644 0.992921 6.798953E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.330595 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 7.159 0.0210 0.0027 0.0000 0.0601 0.0053 0.0000 0.0056 0.1650 0.0005 0.2390 0.5008 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0107 -0.0027 0.0000 0.0244 0.0059 0.0000 0.0080 -0.1650 -0.0005 0.0414 0.0992 Composition Misfit: 0.628570E-01 Gt predicted* 0.820 0.0000 0.0396 0.0000 0.0000 0.2771 0.0401 0.0811 0.0000 0.0034 0.1345 0.4241 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0191 0.0000 0.0000 0.0448 -0.0058 -0.0263 0.0000 -0.0034 0.0093 0.0005 Composition Misfit: 0.264615E-01 Fsp predicted* 25.931 0.0935 0.0605 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1552 0.6895 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0019 -0.0089 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0057 0.0050 Composition Misfit: 0.159508E-02 Bio predicted* 15.874 0.0000 0.0000 0.0195 0.0665 0.1514 0.0008 0.1876 0.1134 0.0044 0.1146 0.3417 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0018 0.0005 0.0330 0.0006 -0.0181 -0.1134 -0.0044 0.0257 0.0743 Composition Misfit: 0.314084E-01 St predicted* 7.482 0.0000 0.0000 0.0038 0.0000 0.1235 0.0025 0.0607 0.0881 0.0026 0.3885 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0036 0.0000 0.0076 0.0013 -0.0378 -0.0881 -0.0026 0.0600 0.0560 Composition Misfit: 0.468344E-01 Ilm predicted* 1.037 0.0000 0.0000 0.1827 0.0000 0.6781 0.0060 0.0063 0.0000 0.1269 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1673 0.0000 -0.0481 0.0040 0.0037 0.0000 -0.1269 0.0000 0.0000 Composition Misfit: 0.161438 ky predicted 0.008 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.689 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -772327. CaO 15.215 -751589. TiO2 7.199 -931027. K2O 16.990 -847582. FeO 54.593 -313568. MnO 0.947 -466752. MgO 41.584 -636209. H2O 40.794 -289617. O2 3.388 -402066. Al2O3 111.899 -0.163363E+07 SiO2 727.525 -884426. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 90 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 91 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 92 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 93 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 94 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 95 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 96 converged, 37 successes so far. Misfit function evaluations this try => 309 Misfit this try = 0.191825 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 9.121354E-07 Bayes score, PP * exp(-Misfit) = 7.529234E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 11354.6 977.822 0.583399 0.763059 Final coordinates: 8358.15 924.277 0.551387 5.035798E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.191825 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.023 0.0174 0.0019 0.0000 0.0641 0.0057 0.0000 0.0049 0.1650 0.0005 0.2389 0.5015 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0070 -0.0019 0.0000 0.0203 0.0055 0.0000 0.0086 -0.1650 -0.0005 0.0416 0.0985 Composition Misfit: 0.579944E-01 Gt predicted* 0.805 0.0000 0.0290 0.0000 0.0000 0.2904 0.0473 0.0690 0.0000 0.0026 0.1365 0.4252 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0085 0.0000 0.0000 0.0316 -0.0131 -0.0142 0.0000 -0.0026 0.0074 -0.0005 Composition Misfit: 0.128399E-01 Fsp predicted* 27.622 0.0943 0.0584 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1542 0.6916 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0026 -0.0068 0.0000 -0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0067 0.0029 Composition Misfit: 0.118524E-02 Bio predicted* 21.499 0.0000 0.0000 0.0220 0.0670 0.1737 0.0011 0.1592 0.1121 0.0041 0.1214 0.3395 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0006 -0.0001 0.0108 0.0004 0.0103 -0.1121 -0.0041 0.0189 0.0764 Composition Misfit: 0.216357E-01 St predicted* 2.370 0.0000 0.0000 0.0042 0.0000 0.1342 0.0031 0.0485 0.0881 0.0024 0.3890 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0031 0.0000 -0.0031 0.0008 -0.0256 -0.0881 -0.0024 0.0595 0.0558 Composition Misfit: 0.346210E-01 Ilm predicted* 0.430 0.0000 0.0000 0.2302 0.0000 0.6451 0.0091 0.0076 0.0000 0.1079 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1198 0.0000 -0.0151 0.0009 0.0024 0.0000 -0.1079 0.0000 0.0000 Composition Misfit: 0.635487E-01 ky predicted 5.752 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.500 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -776423. CaO 15.215 -755044. TiO2 7.199 -932114. K2O 16.990 -850643. FeO 54.593 -314220. MnO 0.947 -466657. MgO 41.584 -638582. H2O 30.215 -291670. O2 1.881 -409081. Al2O3 111.899 -0.163592E+07 SiO2 727.525 -886621. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 97 converged, 38 successes so far. Misfit function evaluations this try => 305 Misfit this try = 0.331301 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 1.125603E-06 Bayes score, PP * exp(-Misfit) = 8.081712E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 6881.83 940.752 0.910279 0.930375 Final coordinates: 9148.25 918.056 0.990966 6.800878E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.331301 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 7.225 0.0213 0.0027 0.0000 0.0598 0.0052 0.0000 0.0055 0.1650 0.0005 0.2392 0.5007 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0110 -0.0027 0.0000 0.0247 0.0060 0.0000 0.0080 -0.1650 -0.0005 0.0413 0.0993 Composition Misfit: 0.639643E-01 Gt predicted* 0.855 0.0000 0.0404 0.0000 0.0000 0.2773 0.0396 0.0806 0.0000 0.0034 0.1345 0.4241 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0198 0.0000 0.0000 0.0446 -0.0053 -0.0258 0.0000 -0.0034 0.0093 0.0005 Composition Misfit: 0.265609E-01 Fsp predicted* 25.884 0.0936 0.0605 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1552 0.6895 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0019 -0.0089 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0057 0.0050 Composition Misfit: 0.159768E-02 Bio predicted* 15.861 0.0000 0.0000 0.0195 0.0664 0.1513 0.0008 0.1879 0.1134 0.0044 0.1143 0.3419 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0019 0.0005 0.0332 0.0006 -0.0184 -0.1134 -0.0044 0.0260 0.0740 Composition Misfit: 0.316356E-01 St predicted* 7.402 0.0000 0.0000 0.0038 0.0000 0.1236 0.0025 0.0606 0.0881 0.0026 0.3886 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0035 0.0000 0.0075 0.0014 -0.0377 -0.0881 -0.0026 0.0600 0.0560 Composition Misfit: 0.466567E-01 Ilm predicted* 1.039 0.0000 0.0000 0.1830 0.0000 0.6780 0.0058 0.0063 0.0000 0.1268 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1670 0.0000 -0.0480 0.0042 0.0037 0.0000 -0.1268 0.0000 0.0000 Composition Misfit: 0.160885 ky predicted 0.062 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.672 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -771698. CaO 15.215 -751201. TiO2 7.199 -930614. K2O 16.990 -847000. FeO 54.593 -313247. MnO 0.947 -466517. MgO 41.584 -635973. H2O 40.805 -289372. O2 3.381 -402075. Al2O3 111.899 -0.163321E+07 SiO2 727.525 -884137. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 98 converged, 39 successes so far. Misfit function evaluations this try => 687 Misfit this try = 0.198822 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 8.746035E-07 Bayes score, PP * exp(-Misfit) = 7.169088E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 5831.66 974.785 0.894253 0.491679 Final coordinates: 8114.16 921.335 0.560594 5.480718E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.198336 Extraneous predicted phases: 4.858894E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.521 0.0173 0.0019 0.0000 0.0643 0.0055 0.0000 0.0048 0.1650 0.0005 0.2392 0.5014 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0070 -0.0019 0.0000 0.0202 0.0057 0.0000 0.0087 -0.1650 -0.0005 0.0412 0.0986 Composition Misfit: 0.592353E-01 Gt predicted* 0.503 0.0000 0.0279 0.0000 0.0000 0.2833 0.0561 0.0682 0.0000 0.0025 0.1367 0.4253 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0074 0.0000 0.0000 0.0387 -0.0218 -0.0134 0.0000 -0.0025 0.0071 -0.0007 Composition Misfit: 0.187221E-01 Fsp predicted* 27.528 0.0940 0.0589 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1545 0.6911 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0024 -0.0073 0.0000 -0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0064 0.0034 Composition Misfit: 0.127100E-02 Bio predicted* 21.027 0.0000 0.0000 0.0220 0.0671 0.1723 0.0012 0.1600 0.1121 0.0041 0.1220 0.3391 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0006 -0.0001 0.0121 0.0002 0.0095 -0.1121 -0.0041 0.0183 0.0769 Composition Misfit: 0.216175E-01 St predicted* 3.872 0.0000 0.0000 0.0042 0.0000 0.1334 0.0037 0.0487 0.0881 0.0024 0.3891 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0031 0.0000 -0.0023 0.0001 -0.0257 -0.0881 -0.0024 0.0595 0.0558 Composition Misfit: 0.345445E-01 Ilm predicted* 0.438 0.0000 0.0000 0.2306 0.0000 0.6432 0.0109 0.0076 0.0000 0.1078 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1194 0.0000 -0.0132 -0.0009 0.0024 0.0000 -0.1078 0.0000 0.0000 Composition Misfit: 0.629458E-01 ky predicted 4.380 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.661 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.070 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -776843. CaO 15.215 -755338. TiO2 7.199 -932148. K2O 16.990 -851164. FeO 54.593 -314259. MnO 0.947 -465224. MgO 41.584 -638596. H2O 32.884 -291754. O2 1.913 -408952. Al2O3 111.899 -0.163597E+07 SiO2 727.525 -886861. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 99 converged, 40 successes so far. Misfit function evaluations this try => 367 Misfit this try = 0.232239 Best Misfit so far = 0.137073 obtained on Try 1 Prior probability, PP = 6.266292E-07 Bayes score, PP * exp(-Misfit) = 4.967643E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 12604.5 917.230 0.856858 0.737114 Final coordinates: 7083.15 911.900 0.470273 6.918149E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.185290 Extraneous predicted phases: 4.694916E-02 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.002 0.0165 0.0016 0.0000 0.0654 0.0049 0.0000 0.0042 0.1652 0.0005 0.2405 0.5012 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0061 -0.0016 0.0000 0.0191 0.0062 0.0000 0.0094 -0.1652 -0.0005 0.0399 0.0988 Composition Misfit: 0.645551E-01 Gt predicted* 0.001 0.0000 0.0223 0.0000 0.0000 0.2630 0.0862 0.0629 0.0000 0.0021 0.1377 0.4258 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0018 0.0000 0.0000 0.0590 -0.0519 -0.0081 0.0000 -0.0021 0.0062 -0.0012 Composition Misfit: 0.459887E-01 Fsp predicted* 27.469 0.0937 0.0593 0.0000 0.0016 0.0000 0.0000 0.0000 0.0000 0.0000 0.1547 0.6907 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0021 -0.0077 0.0000 -0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0062 0.0038 Composition Misfit: 0.135992E-02 Bio predicted* 21.244 0.0000 0.0000 0.0222 0.0673 0.1732 0.0019 0.1561 0.1124 0.0042 0.1259 0.3368 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0008 -0.0003 0.0112 -0.0005 0.0135 -0.1124 -0.0042 0.0144 0.0791 Composition Misfit: 0.222805E-01 St predicted* 5.608 0.0000 0.0000 0.0040 0.0000 0.1331 0.0059 0.0465 0.0882 0.0023 0.3894 0.3306 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0033 0.0000 -0.0021 -0.0021 -0.0236 -0.0882 -0.0023 0.0592 0.0557 Composition Misfit: 0.338604E-01 Ilm predicted* 0.311 0.0000 0.0000 0.2885 0.0000 0.6029 0.0161 0.0078 0.0000 0.0846 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0615 0.0000 0.0271 -0.0061 0.0022 0.0000 -0.0846 0.0000 0.0000 Composition Misfit: 0.172457E-01 ky predicted 2.880 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.787 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.699 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -779161. CaO 15.215 -757309. TiO2 7.199 -932878. K2O 16.990 -853678. FeO 54.593 -314536. MnO 0.947 -461773. MgO 41.584 -639203. H2O 41.509 -292561. O2 1.605 -409600. Al2O3 111.899 -0.163670E+07 SiO2 727.525 -888207. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 100 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 101 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 102 converged, 41 successes so far. Misfit function evaluations this try => 222 Misfit this try = 0.135226 Best Misfit so far = 0.135226 obtained on Try 102 Prior probability, PP = 1.002638E-06 Bayes score, PP * exp(-Misfit) = 8.758231E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 7951.25 830.562 0.191315 0.899730 Final coordinates: 8605.11 920.405 0.386497 5.038572E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.135226 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.020 0.0180 0.0020 0.0000 0.0635 0.0055 0.0000 0.0050 0.1650 0.0005 0.2390 0.5016 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0076 -0.0020 0.0000 0.0210 0.0057 0.0000 0.0086 -0.1650 -0.0005 0.0415 0.0984 Composition Misfit: 0.594207E-01 Gt predicted* 1.133 0.0000 0.0310 0.0000 0.0000 0.2983 0.0377 0.0681 0.0000 0.0024 0.1371 0.4255 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0104 0.0000 0.0000 0.0237 -0.0035 -0.0133 0.0000 -0.0024 0.0068 -0.0008 Composition Misfit: 0.863053E-02 Fsp predicted* 27.562 0.0946 0.0579 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1540 0.6921 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0029 -0.0063 0.0000 -0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0069 0.0024 Composition Misfit: 0.110942E-02 Bio predicted* 21.545 0.0000 0.0000 0.0227 0.0670 0.1749 0.0008 0.1576 0.1114 0.0037 0.1206 0.3414 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0013 -0.0001 0.0096 0.0006 0.0119 -0.1114 -0.0037 0.0197 0.0746 Composition Misfit: 0.214780E-01 St predicted* 2.533 0.0000 0.0000 0.0048 0.0000 0.1350 0.0024 0.0474 0.0882 0.0021 0.3894 0.3307 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0025 0.0000 -0.0039 0.0015 -0.0245 -0.0882 -0.0021 0.0591 0.0556 Composition Misfit: 0.333047E-01 Ilm predicted* 0.280 0.0000 0.0000 0.3238 0.0000 0.5749 0.0167 0.0141 0.0000 0.0705 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0262 0.0000 0.0551 -0.0067 -0.0041 0.0000 -0.0705 0.0000 0.0000 Composition Misfit: 0.112827E-01 ky predicted 5.566 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.360 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -774389. CaO 15.215 -753735. TiO2 7.199 -930151. K2O 16.990 -848621. FeO 54.593 -313307. MnO 0.947 -467650. MgO 41.584 -638025. H2O 30.231 -290930. O2 1.319 -413080. Al2O3 111.899 -0.163476E+07 SiO2 727.525 -885634. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 103 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 104 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 105 converged, 42 successes so far. Misfit function evaluations this try => 273 Misfit this try = 0.467972 Best Misfit so far = 0.135226 obtained on Try 102 Prior probability, PP = 4.416154E-07 Bayes score, PP * exp(-Misfit) = 2.765708E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 9124.09 856.125 0.877296 0.828328 Final coordinates: 6369.80 904.801 0.971532 5.121674E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.467928 Extraneous predicted phases: 4.451506E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.120 0.0159 0.0014 0.0000 0.0660 0.0048 0.0000 0.0040 0.1653 0.0006 0.2410 0.5010 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0056 -0.0014 0.0000 0.0184 0.0063 0.0000 0.0096 -0.1653 -0.0006 0.0395 0.0990 Composition Misfit: 0.659122E-01 Gt predicted* 0.001 0.0000 0.0193 0.0000 0.0000 0.2445 0.1074 0.0634 0.0000 0.0023 0.1374 0.4257 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 0.0012 0.0000 0.0000 0.0774 -0.0732 -0.0086 0.0000 -0.0023 0.0065 -0.0010 Composition Misfit: 0.759205E-01 Fsp predicted* 27.680 0.0937 0.0593 0.0000 0.0016 0.0000 0.0000 0.0000 0.0000 0.0000 0.1547 0.6907 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0021 -0.0077 0.0000 -0.0003 0.0000 0.0000 0.0000 0.0000 0.0000 0.0062 0.0038 Composition Misfit: 0.137065E-02 Bio predicted* 21.313 0.0000 0.0000 0.0195 0.0671 0.1673 0.0023 0.1642 0.1147 0.0048 0.1260 0.3341 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0019 -0.0001 0.0172 -0.0009 0.0053 -0.1147 -0.0048 0.0143 0.0819 Composition Misfit: 0.241773E-01 St predicted* 2.009 0.0000 0.0000 0.0027 0.0000 0.1305 0.0076 0.0489 0.0881 0.0027 0.3891 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0046 0.0000 0.0005 -0.0038 -0.0259 -0.0881 -0.0027 0.0594 0.0560 Composition Misfit: 0.419172E-01 Ilm predicted* 0.864 0.0000 0.0000 0.1562 0.0000 0.6901 0.0127 0.0035 0.0000 0.1375 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1938 0.0000 -0.0601 -0.0027 0.0065 0.0000 -0.1375 0.0000 0.0000 Composition Misfit: 0.258630 ky predicted 6.028 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.962 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.022 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -780610. CaO 15.215 -758637. TiO2 7.199 -936239. K2O 16.990 -855385. FeO 54.593 -314873. MnO 0.947 -459944. MgO 41.584 -639098. H2O 30.730 -293077. O2 3.315 -404289. Al2O3 111.899 -0.163712E+07 SiO2 727.525 -889085. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 106 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 107 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 108 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 109 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 110 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 111 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 112 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 113 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 114 converged, 43 successes so far. Misfit function evaluations this try => 314 Misfit this try = 0.334420 Best Misfit so far = 0.135226 obtained on Try 102 Prior probability, PP = 1.101076E-06 Bayes score, PP * exp(-Misfit) = 7.880984E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 10784.0 926.721 0.831098 0.890945 Final coordinates: 9116.47 920.350 0.999912 6.768999E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.334420 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 7.056 0.0210 0.0027 0.0000 0.0602 0.0053 0.0000 0.0055 0.1650 0.0005 0.2391 0.5008 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0106 -0.0027 0.0000 0.0243 0.0059 0.0000 0.0080 -0.1650 -0.0005 0.0414 0.0992 Composition Misfit: 0.627905E-01 Gt predicted* 0.796 0.0000 0.0394 0.0000 0.0000 0.2767 0.0408 0.0809 0.0000 0.0034 0.1345 0.4242 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0189 0.0000 0.0000 0.0452 -0.0066 -0.0261 0.0000 -0.0034 0.0093 0.0005 Composition Misfit: 0.265673E-01 Fsp predicted* 25.964 0.0935 0.0605 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1552 0.6895 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0019 -0.0089 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0057 0.0050 Composition Misfit: 0.159592E-02 Bio predicted* 15.949 0.0000 0.0000 0.0195 0.0665 0.1516 0.0009 0.1874 0.1134 0.0044 0.1147 0.3416 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0019 0.0005 0.0329 0.0006 -0.0179 -0.1134 -0.0044 0.0256 0.0743 Composition Misfit: 0.312700E-01 St predicted* 7.376 0.0000 0.0000 0.0038 0.0000 0.1235 0.0026 0.0606 0.0881 0.0026 0.3885 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0036 0.0000 0.0075 0.0013 -0.0377 -0.0881 -0.0026 0.0600 0.0560 Composition Misfit: 0.467112E-01 Ilm predicted* 1.043 0.0000 0.0000 0.1813 0.0000 0.6790 0.0060 0.0062 0.0000 0.1275 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1687 0.0000 -0.0490 0.0040 0.0038 0.0000 -0.1275 0.0000 0.0000 Composition Misfit: 0.165485 ky predicted 0.126 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.690 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -772379. CaO 15.215 -751638. TiO2 7.199 -931100. K2O 16.990 -847627. FeO 54.593 -313565. MnO 0.947 -466607. MgO 41.584 -636222. H2O 40.614 -289640. O2 3.412 -402022. Al2O3 111.899 -0.163364E+07 SiO2 727.525 -884458. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 115 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 116 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 117 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 118 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 119 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 120 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 121 converged, 44 successes so far. Misfit function evaluations this try => 238 Misfit this try = 0.145260 Best Misfit so far = 0.135226 obtained on Try 102 Prior probability, PP = 9.867723E-07 Bayes score, PP * exp(-Misfit) = 8.533578E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 14189.3 849.681 6.617669E-02 8.273436E-02 Final coordinates: 8380.71 884.982 0.393300 4.883561E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.145260 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.376 0.0191 0.0017 0.0000 0.0626 0.0050 0.0000 0.0046 0.1652 0.0004 0.2400 0.5015 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0087 -0.0017 0.0000 0.0218 0.0062 0.0000 0.0090 -0.1652 -0.0004 0.0405 0.0985 Composition Misfit: 0.650745E-01 Gt predicted* 1.576 0.0000 0.0368 0.0000 0.0000 0.3034 0.0334 0.0622 0.0000 0.0027 0.1364 0.4252 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0163 0.0000 0.0000 0.0185 0.0008 -0.0074 0.0000 -0.0027 0.0074 -0.0005 Composition Misfit: 0.961171E-02 Fsp predicted* 27.365 0.0952 0.0572 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1536 0.6928 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0036 -0.0056 0.0000 0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0073 0.0017 Composition Misfit: 0.105638E-02 Bio predicted* 21.415 0.0000 0.0000 0.0207 0.0667 0.1761 0.0006 0.1608 0.1126 0.0040 0.1164 0.3422 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0007 0.0003 0.0084 0.0008 0.0087 -0.1126 -0.0040 0.0239 0.0737 Composition Misfit: 0.227884E-01 St predicted* 0.854 0.0000 0.0000 0.0040 0.0000 0.1392 0.0019 0.0444 0.0882 0.0023 0.3895 0.3306 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0033 0.0000 -0.0082 0.0020 -0.0215 -0.0882 -0.0023 0.0591 0.0557 Composition Misfit: 0.340159E-01 Ilm predicted* 0.356 0.0000 0.0000 0.3749 0.0000 0.5556 0.0076 0.0119 0.0000 0.0500 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 -0.0249 0.0000 0.0744 0.0024 -0.0019 0.0000 -0.0500 0.0000 0.0000 Composition Misfit: 0.127134E-01 ky predicted 7.031 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.027 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -767004. CaO 15.215 -749436. TiO2 7.199 -926937. K2O 16.990 -841312. FeO 54.593 -309213. MnO 0.947 -464167. MgO 41.584 -635225. H2O 29.301 -288286. O2 1.342 -409158. Al2O3 111.899 -0.162967E+07 SiO2 727.525 -882357. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 122 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 123 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 124 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 125 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 126 converged, 45 successes so far. Misfit function evaluations this try => 202 Misfit this try = 0.326519 Best Misfit so far = 0.135226 obtained on Try 102 Prior probability, PP = 1.114848E-06 Bayes score, PP * exp(-Misfit) = 8.042852E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 8171.02 820.661 0.946827 0.525180 Final coordinates: 9151.58 919.399 0.979639 6.795044E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.326519 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 7.153 0.0212 0.0027 0.0000 0.0599 0.0052 0.0000 0.0055 0.1650 0.0005 0.2391 0.5008 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0108 -0.0027 0.0000 0.0245 0.0059 0.0000 0.0080 -0.1650 -0.0005 0.0414 0.0992 Composition Misfit: 0.634314E-01 Gt predicted* 0.852 0.0000 0.0399 0.0000 0.0000 0.2776 0.0395 0.0808 0.0000 0.0034 0.1345 0.4242 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0194 0.0000 0.0000 0.0443 -0.0053 -0.0260 0.0000 -0.0034 0.0093 0.0005 Composition Misfit: 0.262098E-01 Fsp predicted* 25.914 0.0936 0.0604 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1552 0.6896 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0019 -0.0088 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0057 0.0049 Composition Misfit: 0.158761E-02 Bio predicted* 15.898 0.0000 0.0000 0.0196 0.0665 0.1517 0.0008 0.1874 0.1133 0.0044 0.1145 0.3418 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0018 0.0005 0.0328 0.0006 -0.0179 -0.1133 -0.0044 0.0258 0.0741 Composition Misfit: 0.312949E-01 St predicted* 7.449 0.0000 0.0000 0.0038 0.0000 0.1237 0.0025 0.0605 0.0881 0.0026 0.3885 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0035 0.0000 0.0074 0.0014 -0.0376 -0.0881 -0.0026 0.0600 0.0560 Composition Misfit: 0.464837E-01 Ilm predicted* 1.024 0.0000 0.0000 0.1842 0.0000 0.6772 0.0059 0.0064 0.0000 0.1263 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1658 0.0000 -0.0472 0.0041 0.0036 0.0000 -0.1263 0.0000 0.0000 Composition Misfit: 0.157512 ky predicted 0.033 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.676 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -771998. CaO 15.215 -751390. TiO2 7.199 -930765. K2O 16.990 -847272. FeO 54.593 -313398. MnO 0.947 -466686. MgO 41.584 -636098. H2O 40.770 -289493. O2 3.343 -402179. Al2O3 111.899 -0.163341E+07 SiO2 727.525 -884274. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 127 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 128 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 129 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 130 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 131 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 132 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 133 converged, 46 successes so far. Misfit function evaluations this try => 311 Misfit this try = 0.149543 Best Misfit so far = 0.135226 obtained on Try 102 Prior probability, PP = 9.989449E-07 Bayes score, PP * exp(-Misfit) = 8.601931E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 11039.9 960.530 9.429390E-02 0.284882 Final coordinates: 8511.13 918.067 0.385127 6.321571E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.147206 Extraneous predicted phases: 2.337195E-03 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 2.941 0.0185 0.0021 0.0000 0.0630 0.0052 0.0000 0.0049 0.1651 0.0004 0.2394 0.5014 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0081 -0.0021 0.0000 0.0215 0.0060 0.0000 0.0086 -0.1651 -0.0004 0.0411 0.0986 Composition Misfit: 0.612874E-01 Gt predicted* 0.557 0.0000 0.0317 0.0000 0.0000 0.2876 0.0461 0.0695 0.0000 0.0023 0.1372 0.4256 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0112 0.0000 0.0000 0.0344 -0.0119 -0.0147 0.0000 -0.0023 0.0067 -0.0009 Composition Misfit: 0.145451E-01 Fsp predicted* 26.994 0.0938 0.0595 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1548 0.6905 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0022 -0.0079 0.0000 -0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0061 0.0040 Composition Misfit: 0.137508E-02 Bio predicted* 19.039 0.0000 0.0000 0.0226 0.0670 0.1689 0.0010 0.1636 0.1114 0.0036 0.1203 0.3416 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0013 -0.0001 0.0156 0.0004 0.0059 -0.1114 -0.0036 0.0200 0.0744 Composition Misfit: 0.214456E-01 St predicted* 8.162 0.0000 0.0000 0.0050 0.0000 0.1318 0.0029 0.0499 0.0882 0.0021 0.3895 0.3307 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0024 0.0000 -0.0007 0.0009 -0.0270 -0.0882 -0.0021 0.0591 0.0556 Composition Misfit: 0.342851E-01 Ilm predicted* 0.259 0.0000 0.0000 0.3267 0.0000 0.5698 0.0200 0.0141 0.0000 0.0693 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0233 0.0000 0.0602 -0.0100 -0.0041 0.0000 -0.0693 0.0000 0.0000 Composition Misfit: 0.142673E-01 ky predicted 0.198 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.820 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 ru 0.032 0.0000 0.0000 1.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -774394. CaO 15.215 -753461. TiO2 7.199 -929735. K2O 16.990 -848904. FeO 54.593 -313388. MnO 0.947 -465907. MgO 41.584 -637696. H2O 37.929 -290707. O2 1.314 -412607. Al2O3 111.899 -0.163459E+07 SiO2 727.525 -885596. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 134 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 135 converged, 47 successes so far. Misfit function evaluations this try => 244 Misfit this try = 0.230605 Best Misfit so far = 0.135226 obtained on Try 102 Prior probability, PP = 1.115016E-06 Bayes score, PP * exp(-Misfit) = 8.853823E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 13950.2 848.937 0.339176 0.349695 Final coordinates: 9931.31 925.721 0.616326 7.164869E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.226934 Extraneous predicted phases: 3.670983E-03 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 9.038 0.0243 0.0033 0.0000 0.0565 0.0050 0.0000 0.0055 0.1650 0.0005 0.2395 0.5003 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0140 -0.0033 0.0000 0.0279 0.0061 0.0000 0.0080 -0.1650 -0.0005 0.0410 0.0997 Composition Misfit: 0.709293E-01 Gt predicted* 2.814 0.0000 0.0441 0.0000 0.0000 0.2902 0.0189 0.0849 0.0000 0.0035 0.1344 0.4241 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0235 0.0000 0.0000 0.0318 0.0153 -0.0301 0.0000 -0.0035 0.0095 0.0006 Composition Misfit: 0.398520E-01 Fsp predicted* 24.772 0.0951 0.0574 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1537 0.6926 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0035 -0.0058 0.0000 0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0072 0.0019 Composition Misfit: 0.108605E-02 Bio predicted* 14.889 0.0000 0.0000 0.0208 0.0664 0.1502 0.0004 0.1891 0.1121 0.0040 0.1125 0.3444 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0006 0.0005 0.0342 0.0010 -0.0196 -0.1121 -0.0040 0.0278 0.0716 Composition Misfit: 0.342442E-01 St predicted* 6.528 0.0000 0.0000 0.0048 0.0000 0.1224 0.0011 0.0622 0.0881 0.0024 0.3885 0.3304 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0025 0.0000 0.0086 0.0027 -0.0393 -0.0881 -0.0024 0.0601 0.0559 Composition Misfit: 0.518630E-01 Ilm predicted* 0.694 0.0000 0.0000 0.2789 0.0000 0.6175 0.0038 0.0114 0.0000 0.0884 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0711 0.0000 0.0125 0.0062 -0.0014 0.0000 -0.0884 0.0000 0.0000 Composition Misfit: 0.289594E-01 ky predicted 0.002 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.106 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.024 0.0000 0.0000 0.2282 0.0000 0.6493 0.0037 0.0101 0.0000 0.1087 0.0000 0.0000 F 0.134 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -769788. CaO 15.215 -750221. TiO2 7.199 -928459. K2O 16.990 -845491. FeO 54.593 -313140. MnO 0.947 -472439. MgO 41.584 -635624. H2O 42.989 -288779. O2 2.103 -404319. Al2O3 111.899 -0.163273E+07 SiO2 727.525 -883179. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 136 converged, 48 successes so far. Misfit function evaluations this try => 204 Misfit this try = 0.401569 Best Misfit so far = 0.135226 obtained on Try 102 Prior probability, PP = 6.401573E-07 Bayes score, PP * exp(-Misfit) = 4.284376E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 8343.14 887.084 0.842205 0.820014 Final coordinates: 7109.99 909.857 0.956664 5.663973E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.401566 Extraneous predicted phases: 2.638478E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 1.977 0.0169 0.0016 0.0000 0.0649 0.0050 0.0000 0.0044 0.1652 0.0006 0.2403 0.5011 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0065 -0.0016 0.0000 0.0196 0.0061 0.0000 0.0091 -0.1652 -0.0006 0.0402 0.0989 Composition Misfit: 0.627523E-01 Gt predicted* 0.001 0.0000 0.0233 0.0000 0.0000 0.2536 0.0905 0.0679 0.0000 0.0025 0.1368 0.4254 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0028 0.0000 0.0000 0.0683 -0.0563 -0.0131 0.0000 -0.0025 0.0070 -0.0007 Composition Misfit: 0.565980E-01 Fsp predicted* 27.330 0.0935 0.0599 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1549 0.6901 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0019 -0.0083 0.0000 -0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0060 0.0044 Composition Misfit: 0.146147E-02 Bio predicted* 19.752 0.0000 0.0000 0.0197 0.0669 0.1636 0.0020 0.1697 0.1142 0.0047 0.1231 0.3361 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0017 0.0000 0.0208 -0.0005 -0.0001 -0.1142 -0.0047 0.0172 0.0798 Composition Misfit: 0.243139E-01 St predicted* 4.335 0.0000 0.0000 0.0030 0.0000 0.1290 0.0062 0.0516 0.0881 0.0027 0.3890 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0043 0.0000 0.0020 -0.0024 -0.0287 -0.0881 -0.0027 0.0595 0.0560 Composition Misfit: 0.415152E-01 Ilm predicted* 0.885 0.0000 0.0000 0.1664 0.0000 0.6842 0.0117 0.0042 0.0000 0.1334 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1836 0.0000 -0.0542 -0.0017 0.0058 0.0000 -0.1334 0.0000 0.0000 Composition Misfit: 0.214925 ky predicted 3.754 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.962 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.005 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -778614. CaO 15.215 -756837. TiO2 7.199 -934824. K2O 16.990 -853424. FeO 54.593 -314596. MnO 0.947 -461142. MgO 41.584 -638425. H2O 33.984 -292222. O2 3.264 -403983. Al2O3 111.899 -0.163632E+07 SiO2 727.525 -887925. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 137 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 138 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 139 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 140 converged, 49 successes so far. Misfit function evaluations this try => 507 Misfit this try = 0.488750 Best Misfit so far = 0.135226 obtained on Try 102 Prior probability, PP = 4.183981E-07 Bayes score, PP * exp(-Misfit) = 2.566423E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 11064.6 989.223 0.832309 0.891453 Final coordinates: 6275.33 903.894 0.999973 5.023092E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.488750 Extraneous predicted phases: 3.767712E-07 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.020 0.0158 0.0014 0.0000 0.0661 0.0048 0.0000 0.0039 0.1653 0.0006 0.2411 0.5010 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0055 -0.0014 0.0000 0.0183 0.0064 0.0000 0.0096 -0.1653 -0.0006 0.0394 0.0990 Composition Misfit: 0.663774E-01 Gt predicted* 0.004 0.0000 0.0189 0.0000 0.0000 0.2426 0.1100 0.0632 0.0000 0.0023 0.1374 0.4257 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 0.0016 0.0000 0.0000 0.0793 -0.0757 -0.0084 0.0000 -0.0023 0.0064 -0.0010 Composition Misfit: 0.796261E-01 Fsp predicted* 27.705 0.0937 0.0593 0.0000 0.0016 0.0000 0.0000 0.0000 0.0000 0.0000 0.1546 0.6907 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0021 -0.0077 0.0000 -0.0003 0.0000 0.0000 0.0000 0.0000 0.0000 0.0062 0.0038 Composition Misfit: 0.136634E-02 Bio predicted* 21.404 0.0000 0.0000 0.0193 0.0671 0.1671 0.0024 0.1644 0.1149 0.0048 0.1262 0.3338 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0020 -0.0001 0.0174 -0.0010 0.0051 -0.1149 -0.0048 0.0141 0.0822 Composition Misfit: 0.243724E-01 St predicted* 1.673 0.0000 0.0000 0.0027 0.0000 0.1304 0.0079 0.0488 0.0881 0.0027 0.3892 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0047 0.0000 0.0007 -0.0040 -0.0259 -0.0881 -0.0027 0.0594 0.0560 Composition Misfit: 0.424938E-01 Ilm predicted* 0.893 0.0000 0.0000 0.1527 0.0000 0.6924 0.0126 0.0033 0.0000 0.1389 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1973 0.0000 -0.0624 -0.0026 0.0067 0.0000 -0.1389 0.0000 0.0000 Composition Misfit: 0.274514 ky predicted 6.331 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.966 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -780806. CaO 15.215 -758825. TiO2 7.199 -936497. K2O 16.990 -855608. FeO 54.593 -314902. MnO 0.947 -459751. MgO 41.584 -639125. H2O 30.139 -293152. O2 3.412 -404080. Al2O3 111.899 -0.163718E+07 SiO2 727.525 -889205. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 141 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 142 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 143 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 144 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 145 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 146 converged, 50 successes so far. Misfit function evaluations this try => 270 Misfit this try = 0.333837 Best Misfit so far = 0.135226 obtained on Try 102 Prior probability, PP = 1.106647E-06 Bayes score, PP * exp(-Misfit) = 7.925483E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 11067.1 899.099 0.912811 0.844594 Final coordinates: 9185.90 920.882 0.998431 6.863856E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.333760 Extraneous predicted phases: 7.697458E-05 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 7.275 0.0212 0.0028 0.0000 0.0599 0.0053 0.0000 0.0056 0.1650 0.0005 0.2391 0.5007 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0108 -0.0028 0.0000 0.0246 0.0059 0.0000 0.0080 -0.1650 -0.0005 0.0414 0.0993 Composition Misfit: 0.632001E-01 Gt predicted* 0.860 0.0000 0.0400 0.0000 0.0000 0.2772 0.0393 0.0815 0.0000 0.0035 0.1344 0.4241 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0195 0.0000 0.0000 0.0447 -0.0050 -0.0267 0.0000 -0.0035 0.0094 0.0005 Composition Misfit: 0.267370E-01 Fsp predicted* 25.877 0.0935 0.0604 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1552 0.6896 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0019 -0.0089 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0057 0.0049 Composition Misfit: 0.159039E-02 Bio predicted* 15.798 0.0000 0.0000 0.0195 0.0664 0.1511 0.0008 0.1881 0.1134 0.0044 0.1145 0.3418 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0018 0.0005 0.0334 0.0006 -0.0186 -0.1134 -0.0044 0.0259 0.0741 Composition Misfit: 0.317616E-01 St predicted* 7.446 0.0000 0.0000 0.0038 0.0000 0.1232 0.0025 0.0611 0.0881 0.0026 0.3885 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0035 0.0000 0.0079 0.0014 -0.0381 -0.0881 -0.0026 0.0600 0.0560 Composition Misfit: 0.471379E-01 Ilm predicted* 1.045 0.0000 0.0000 0.1822 0.0000 0.6786 0.0058 0.0063 0.0000 0.1271 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1678 0.0000 -0.0486 0.0042 0.0037 0.0000 -0.1271 0.0000 0.0000 Composition Misfit: 0.163333 ky predicted 0.007 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.666 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.027 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -772198. CaO 15.215 -751492. TiO2 7.199 -930979. K2O 16.990 -847485. FeO 54.593 -313561. MnO 0.947 -466905. MgO 41.584 -636153. H2O 41.183 -289562. O2 3.407 -401926. Al2O3 111.899 -0.163358E+07 SiO2 727.525 -884356. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 147 converged, 51 successes so far. Misfit function evaluations this try => 343 Misfit this try = 1.03656 Best Misfit so far = 0.135226 obtained on Try 102 Prior probability, PP = 9.695116E-07 Bayes score, PP * exp(-Misfit) = 3.438589E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 5861.49 917.228 0.789398 8.410294E-02 Final coordinates: 8537.24 922.511 0.610707 5.968285E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.155068 Extraneous predicted phases: 0.881494 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 2.582 0.0183 0.0021 0.0000 0.0631 0.0055 0.0000 0.0051 0.1650 0.0005 0.2390 0.5014 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0079 -0.0021 0.0000 0.0213 0.0056 0.0000 0.0084 -0.1650 -0.0005 0.0415 0.0986 Composition Misfit: 0.591373E-01 Gt predicted* 0.648 0.0000 0.0315 0.0000 0.0000 0.2853 0.0473 0.0719 0.0000 0.0027 0.1362 0.4251 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0109 0.0000 0.0000 0.0366 -0.0130 -0.0171 0.0000 -0.0027 0.0076 -0.0004 Composition Misfit: 0.165792E-01 Fsp predicted* 27.081 0.0939 0.0593 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1546 0.6907 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0023 -0.0077 0.0000 -0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0063 0.0038 Composition Misfit: 0.132763E-02 Bio predicted* 19.344 0.0000 0.0000 0.0217 0.0669 0.1673 0.0010 0.1668 0.1121 0.0041 0.1198 0.3403 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0003 0.0000 0.0172 0.0004 0.0027 -0.1121 -0.0041 0.0205 0.0756 Composition Misfit: 0.222851E-01 St predicted* 5.580 0.0000 0.0000 0.0043 0.0000 0.1312 0.0030 0.0515 0.0881 0.0024 0.3889 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0030 0.0000 -0.0001 0.0008 -0.0286 -0.0881 -0.0024 0.0596 0.0558 Composition Misfit: 0.367671E-01 Ilm predicted* 0.001 0.0000 0.0000 0.2784 0.0000 0.6148 0.0091 0.0090 0.0000 0.0886 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0716 0.0000 0.0152 0.0009 0.0010 0.0000 -0.0886 0.0000 0.0000 Composition Misfit: 0.189712E-01 ky predicted 2.523 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.651 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.538 0.0000 0.0000 0.2297 0.0000 0.6449 0.0092 0.0081 0.0000 0.1081 0.0000 0.0000 F 0.052 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -775305. CaO 15.215 -754057. TiO2 7.199 -931325. K2O 16.990 -849834. FeO 54.593 -314001. MnO 0.947 -466283. MgO 41.584 -637914. H2O 35.810 -291067. O2 2.084 -407936. Al2O3 111.899 -0.163524E+07 SiO2 727.525 -886018. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 148 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 149 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 150 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 151 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 152 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 153 converged, 52 successes so far. Misfit function evaluations this try => 177 Misfit this try = 0.325096 Best Misfit so far = 0.135226 obtained on Try 102 Prior probability, PP = 1.112205E-06 Bayes score, PP * exp(-Misfit) = 8.035212E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 12046.2 878.760 0.941794 9.184474E-02 Final coordinates: 9258.50 921.358 0.975609 6.812938E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.325096 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 7.367 0.0214 0.0028 0.0000 0.0597 0.0053 0.0000 0.0056 0.1649 0.0005 0.2390 0.5007 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0110 -0.0028 0.0000 0.0248 0.0059 0.0000 0.0080 -0.1649 -0.0005 0.0414 0.0993 Composition Misfit: 0.635357E-01 Gt predicted* 0.967 0.0000 0.0406 0.0000 0.0000 0.2787 0.0371 0.0817 0.0000 0.0035 0.1344 0.4241 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0200 0.0000 0.0000 0.0433 -0.0028 -0.0269 0.0000 -0.0035 0.0094 0.0006 Composition Misfit: 0.263558E-01 Fsp predicted* 25.827 0.0936 0.0603 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1551 0.6897 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0020 -0.0087 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0058 0.0048 Composition Misfit: 0.155579E-02 Bio predicted* 15.759 0.0000 0.0000 0.0196 0.0664 0.1511 0.0008 0.1881 0.1133 0.0044 0.1143 0.3420 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0017 0.0005 0.0334 0.0006 -0.0186 -0.1133 -0.0044 0.0260 0.0739 Composition Misfit: 0.317985E-01 St predicted* 7.400 0.0000 0.0000 0.0039 0.0000 0.1232 0.0023 0.0611 0.0881 0.0026 0.3885 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0034 0.0000 0.0078 0.0015 -0.0382 -0.0881 -0.0026 0.0600 0.0560 Composition Misfit: 0.472136E-01 Ilm predicted* 1.025 0.0000 0.0000 0.1854 0.0000 0.6766 0.0056 0.0066 0.0000 0.1258 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1646 0.0000 -0.0466 0.0044 0.0034 0.0000 -0.1258 0.0000 0.0000 Composition Misfit: 0.154637 ky predicted 0.010 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.644 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -771979. CaO 15.215 -751345. TiO2 7.199 -930745. K2O 16.990 -847284. FeO 54.593 -313517. MnO 0.947 -467332. MgO 41.584 -636106. H2O 40.878 -289486. O2 3.329 -402120. Al2O3 111.899 -0.163350E+07 SiO2 727.525 -884242. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 154 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 155 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 156 converged, 53 successes so far. Misfit function evaluations this try => 186 Misfit this try = 0.144051 Best Misfit so far = 0.135226 obtained on Try 102 Prior probability, PP = 9.386334E-07 Bayes score, PP * exp(-Misfit) = 8.127099E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 8019.86 966.039 0.111824 0.495640 Final coordinates: 8052.62 902.748 0.424379 5.281036E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.144043 Extraneous predicted phases: 7.757447E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.191 0.0180 0.0018 0.0000 0.0637 0.0050 0.0000 0.0045 0.1652 0.0004 0.2400 0.5015 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0076 -0.0018 0.0000 0.0207 0.0062 0.0000 0.0090 -0.1652 -0.0004 0.0405 0.0985 Composition Misfit: 0.635468E-01 Gt predicted* 0.656 0.0000 0.0302 0.0000 0.0000 0.2884 0.0522 0.0638 0.0000 0.0022 0.1374 0.4257 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0096 0.0000 0.0000 0.0335 -0.0180 -0.0090 0.0000 -0.0022 0.0064 -0.0010 Composition Misfit: 0.147268E-01 Fsp predicted* 27.559 0.0943 0.0587 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1543 0.6913 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0027 -0.0071 0.0000 -0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0066 0.0032 Composition Misfit: 0.121826E-02 Bio predicted* 21.398 0.0000 0.0000 0.0222 0.0670 0.1744 0.0011 0.1580 0.1118 0.0037 0.1208 0.3409 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0009 -0.0001 0.0100 0.0004 0.0115 -0.1118 -0.0037 0.0195 0.0751 Composition Misfit: 0.212611E-01 St predicted* 3.686 0.0000 0.0000 0.0046 0.0000 0.1357 0.0032 0.0459 0.0882 0.0021 0.3897 0.3307 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0028 0.0000 -0.0046 0.0006 -0.0229 -0.0882 -0.0021 0.0589 0.0556 Composition Misfit: 0.316409E-01 Ilm predicted* 0.317 0.0000 0.0000 0.2967 0.0000 0.5993 0.0126 0.0101 0.0000 0.0813 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0533 0.0000 0.0307 -0.0026 -0.0001 0.0000 -0.0813 0.0000 0.0000 Composition Misfit: 0.116491E-01 ky predicted 4.626 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.564 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.002 0.0000 0.0000 0.3261 0.0000 0.5688 0.0220 0.0135 0.0000 0.0695 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -772722. CaO 15.215 -752875. TiO2 7.199 -928996. K2O 16.990 -847071. FeO 54.593 -311926. MnO 0.947 -463455. MgO 41.584 -637194. H2O 31.686 -290242. O2 1.448 -412404. Al2O3 111.899 -0.163315E+07 SiO2 727.525 -884997. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 157 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 158 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 159 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 160 converged, 54 successes so far. Misfit function evaluations this try => 256 Misfit this try = 0.215216 Best Misfit so far = 0.135226 obtained on Try 102 Prior probability, PP = 8.047974E-07 Bayes score, PP * exp(-Misfit) = 6.489620E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 7868.01 922.897 0.761137 0.656291 Final coordinates: 7692.19 912.777 0.568881 5.418563E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.215216 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.391 0.0171 0.0017 0.0000 0.0646 0.0052 0.0000 0.0045 0.1651 0.0005 0.2399 0.5013 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0068 -0.0017 0.0000 0.0199 0.0060 0.0000 0.0090 -0.1651 -0.0005 0.0406 0.0987 Composition Misfit: 0.618311E-01 Gt predicted* 0.276 0.0000 0.0263 0.0000 0.0000 0.2752 0.0679 0.0655 0.0000 0.0024 0.1371 0.4255 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0057 0.0000 0.0000 0.0467 -0.0337 -0.0107 0.0000 -0.0024 0.0067 -0.0009 Composition Misfit: 0.279663E-01 Fsp predicted* 27.583 0.0939 0.0592 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1546 0.6908 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0023 -0.0076 0.0000 -0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0063 0.0037 Composition Misfit: 0.131439E-02 Bio predicted* 21.138 0.0000 0.0000 0.0218 0.0671 0.1723 0.0015 0.1594 0.1123 0.0041 0.1230 0.3384 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0005 -0.0001 0.0122 -0.0001 0.0101 -0.1123 -0.0041 0.0174 0.0775 Composition Misfit: 0.217183E-01 St predicted* 4.324 0.0000 0.0000 0.0041 0.0000 0.1336 0.0045 0.0476 0.0881 0.0023 0.3892 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0033 0.0000 -0.0025 -0.0006 -0.0247 -0.0881 -0.0023 0.0593 0.0558 Composition Misfit: 0.340166E-01 Ilm predicted* 0.440 0.0000 0.0000 0.2273 0.0000 0.6434 0.0131 0.0072 0.0000 0.1091 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1227 0.0000 -0.0134 -0.0031 0.0028 0.0000 -0.1091 0.0000 0.0000 Composition Misfit: 0.683696E-01 ky predicted 4.033 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.815 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -776697. CaO 15.215 -755443. TiO2 7.199 -931856. K2O 16.990 -851118. FeO 54.593 -313800. MnO 0.947 -463091. MgO 41.584 -638409. H2O 32.511 -291662. O2 1.941 -408949. Al2O3 111.899 -0.163552E+07 SiO2 727.525 -886902. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 161 converged, 55 successes so far. Misfit function evaluations this try => 238 Misfit this try = 0.317921 Best Misfit so far = 0.135226 obtained on Try 102 Prior probability, PP = 1.048503E-06 Bayes score, PP * exp(-Misfit) = 7.629539E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 10428.6 944.887 0.527973 0.642789 Final coordinates: 8772.16 919.182 0.947914 6.699815E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.317921 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 6.150 0.0199 0.0025 0.0000 0.0614 0.0053 0.0000 0.0054 0.1650 0.0005 0.2391 0.5010 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0095 -0.0025 0.0000 0.0231 0.0059 0.0000 0.0082 -0.1650 -0.0005 0.0414 0.0990 Composition Misfit: 0.613163E-01 Gt predicted* 0.487 0.0000 0.0360 0.0000 0.0000 0.2739 0.0492 0.0781 0.0000 0.0032 0.1351 0.4245 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0154 0.0000 0.0000 0.0480 -0.0150 -0.0233 0.0000 -0.0032 0.0087 0.0002 Composition Misfit: 0.271098E-01 Fsp predicted* 26.290 0.0934 0.0607 0.0000 0.0013 0.0000 0.0000 0.0000 0.0000 0.0000 0.1553 0.6893 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0017 -0.0091 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0056 0.0052 Composition Misfit: 0.162793E-02 Bio predicted* 16.536 0.0000 0.0000 0.0198 0.0666 0.1547 0.0010 0.1830 0.1134 0.0044 0.1164 0.3407 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0016 0.0004 0.0298 0.0004 -0.0135 -0.1134 -0.0044 0.0239 0.0752 Composition Misfit: 0.285167E-01 St predicted* 7.722 0.0000 0.0000 0.0037 0.0000 0.1251 0.0031 0.0584 0.0881 0.0026 0.3886 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0036 0.0000 0.0060 0.0007 -0.0355 -0.0881 -0.0026 0.0599 0.0560 Composition Misfit: 0.441801E-01 Ilm predicted* 0.964 0.0000 0.0000 0.1844 0.0000 0.6758 0.0074 0.0061 0.0000 0.1262 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1656 0.0000 -0.0458 0.0026 0.0039 0.0000 -0.1262 0.0000 0.0000 Composition Misfit: 0.155170 ky predicted 0.045 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.807 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -773626. CaO 15.215 -752577. TiO2 7.199 -931611. K2O 16.990 -848701. FeO 54.593 -313776. MnO 0.947 -465355. MgO 41.584 -636706. H2O 40.199 -290146. O2 3.234 -402889. Al2O3 111.899 -0.163420E+07 SiO2 727.525 -885119. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 162 converged, 56 successes so far. Misfit function evaluations this try => 206 Misfit this try = 0.332786 Best Misfit so far = 0.135226 obtained on Try 102 Prior probability, PP = 1.106071E-06 Bayes score, PP * exp(-Misfit) = 7.929683E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 6758.56 918.872 0.948310 0.742854 Final coordinates: 9153.43 920.422 0.995257 6.753847E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.332786 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 7.080 0.0211 0.0027 0.0000 0.0600 0.0053 0.0000 0.0056 0.1650 0.0005 0.2390 0.5008 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0107 -0.0027 0.0000 0.0244 0.0059 0.0000 0.0080 -0.1650 -0.0005 0.0414 0.0992 Composition Misfit: 0.629651E-01 Gt predicted* 0.851 0.0000 0.0397 0.0000 0.0000 0.2775 0.0397 0.0811 0.0000 0.0034 0.1345 0.4241 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0192 0.0000 0.0000 0.0445 -0.0054 -0.0263 0.0000 -0.0034 0.0093 0.0005 Composition Misfit: 0.262893E-01 Fsp predicted* 25.942 0.0936 0.0604 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1552 0.6896 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0019 -0.0088 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0057 0.0049 Composition Misfit: 0.157719E-02 Bio predicted* 15.946 0.0000 0.0000 0.0195 0.0665 0.1516 0.0008 0.1875 0.1134 0.0044 0.1146 0.3417 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0018 0.0005 0.0329 0.0006 -0.0180 -0.1134 -0.0044 0.0257 0.0742 Composition Misfit: 0.313556E-01 St predicted* 7.265 0.0000 0.0000 0.0038 0.0000 0.1235 0.0025 0.0607 0.0881 0.0026 0.3885 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0035 0.0000 0.0075 0.0014 -0.0378 -0.0881 -0.0026 0.0600 0.0560 Composition Misfit: 0.467926E-01 Ilm predicted* 1.040 0.0000 0.0000 0.1820 0.0000 0.6787 0.0058 0.0063 0.0000 0.1272 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1680 0.0000 -0.0487 0.0042 0.0037 0.0000 -0.1272 0.0000 0.0000 Composition Misfit: 0.163806 ky predicted 0.210 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.667 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -772227. CaO 15.215 -751540. TiO2 7.199 -931011. K2O 16.990 -847488. FeO 54.593 -313526. MnO 0.947 -466792. MgO 41.584 -636176. H2O 40.523 -289586. O2 3.396 -402021. Al2O3 111.899 -0.163357E+07 SiO2 727.525 -884381. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 163 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 164 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 165 converged, 57 successes so far. Misfit function evaluations this try => 378 Misfit this try = 0.421179 Best Misfit so far = 0.135226 obtained on Try 102 Prior probability, PP = 1.109815E-06 Bayes score, PP * exp(-Misfit) = 7.283412E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 7451.47 976.394 0.342297 0.298761 Final coordinates: 10348.9 925.262 0.653213 9.242017E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.313534 Extraneous predicted phases: 0.107645 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 12.392 0.0319 0.0046 0.0000 0.0484 0.0040 0.0000 0.0045 0.1653 0.0004 0.2426 0.4982 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0216 -0.0046 0.0000 0.0360 0.0072 0.0000 0.0090 -0.1653 -0.0004 0.0379 0.1018 Composition Misfit: 0.103467 Gt predicted* 4.176 0.0000 0.0487 0.0000 0.0000 0.2858 0.0139 0.0905 0.0000 0.0038 0.1337 0.4237 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0281 0.0000 0.0000 0.0362 0.0203 -0.0357 0.0000 -0.0038 0.0101 0.0009 Composition Misfit: 0.654084E-01 Fsp predicted* 22.402 0.0958 0.0563 0.0000 0.0011 0.0000 0.0000 0.0000 0.0000 0.0000 0.1532 0.6937 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0041 -0.0047 0.0000 0.0003 0.0000 0.0000 0.0000 0.0000 0.0000 0.0077 0.0008 Composition Misfit: 0.103528E-02 Bio predicted* 13.607 0.0000 0.0000 0.0204 0.0663 0.1419 0.0003 0.1991 0.1121 0.0040 0.1101 0.3458 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0010 0.0007 0.0425 0.0011 -0.0296 -0.1121 -0.0040 0.0302 0.0702 Composition Misfit: 0.443574E-01 St predicted* 4.543 0.0000 0.0000 0.0051 0.0000 0.1174 0.0008 0.0676 0.0881 0.0024 0.3883 0.3304 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0023 0.0000 0.0137 0.0030 -0.0447 -0.0881 -0.0024 0.0603 0.0559 Composition Misfit: 0.620444E-01 Ilm predicted* 0.767 0.0000 0.0000 0.2793 0.0000 0.6170 0.0028 0.0125 0.0000 0.0883 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0707 0.0000 0.0130 0.0072 -0.0025 0.0000 -0.0883 0.0000 0.0000 Composition Misfit: 0.372215E-01 ky predicted 0.513 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.604 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.044 0.0000 0.0000 0.2279 0.0000 0.6494 0.0028 0.0110 0.0000 0.1088 0.0000 0.0000 F 0.952 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -767741. CaO 15.215 -748964. TiO2 7.199 -927273. K2O 16.990 -844172. FeO 54.593 -312876. MnO 0.947 -474335. MgO 41.584 -634689. H2O 55.452 -287917. O2 2.229 -402543. Al2O3 111.899 -0.163175E+07 SiO2 727.525 -882176. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 166 converged, 58 successes so far. Misfit function evaluations this try => 333 Misfit this try = 0.360138 Best Misfit so far = 0.135226 obtained on Try 102 Prior probability, PP = 9.250945E-07 Bayes score, PP * exp(-Misfit) = 6.453273E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 7734.53 953.529 0.880854 0.801708 Final coordinates: 8432.39 924.782 0.925432 5.084058E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.358097 Extraneous predicted phases: 2.041635E-03 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.879 0.0174 0.0020 0.0000 0.0641 0.0059 0.0000 0.0053 0.1649 0.0006 0.2384 0.5015 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0071 -0.0020 0.0000 0.0204 0.0052 0.0000 0.0083 -0.1649 -0.0006 0.0421 0.0985 Composition Misfit: 0.557834E-01 Gt predicted* 0.935 0.0000 0.0300 0.0000 0.0000 0.2869 0.0466 0.0734 0.0000 0.0031 0.1354 0.4246 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0095 0.0000 0.0000 0.0350 -0.0123 -0.0186 0.0000 -0.0031 0.0084 0.0000 Composition Misfit: 0.157484E-01 Fsp predicted* 27.439 0.0943 0.0584 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1542 0.6916 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0026 -0.0068 0.0000 -0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0067 0.0029 Composition Misfit: 0.118839E-02 Bio predicted* 20.791 0.0000 0.0000 0.0196 0.0667 0.1679 0.0010 0.1685 0.1138 0.0046 0.1192 0.3387 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0017 0.0002 0.0165 0.0004 0.0011 -0.1138 -0.0046 0.0212 0.0773 Composition Misfit: 0.233271E-01 St predicted* 0.030 0.0000 0.0000 0.0032 0.0000 0.1321 0.0030 0.0520 0.0881 0.0028 0.3887 0.3302 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0042 0.0000 -0.0010 0.0008 -0.0291 -0.0881 -0.0028 0.0599 0.0561 Composition Misfit: 0.407738E-01 Ilm predicted* 0.871 0.0000 0.0000 0.1654 0.0000 0.6905 0.0058 0.0044 0.0000 0.1338 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1846 0.0000 -0.0605 0.0042 0.0056 0.0000 -0.1338 0.0000 0.0000 Composition Misfit: 0.221275 ky predicted 7.660 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.252 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.142 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -776220. CaO 15.215 -754869. TiO2 7.199 -934462. K2O 16.990 -850499. FeO 54.593 -314366. MnO 0.947 -466783. MgO 41.584 -638125. H2O 30.504 -291590. O2 3.158 -404200. Al2O3 111.899 -0.163584E+07 SiO2 727.525 -886505. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 167 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 168 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 169 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 170 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 171 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 172 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 173 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 174 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 175 converged, 59 successes so far. Misfit function evaluations this try => 152 Misfit this try = 0.132299 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.007196E-06 Bayes score, PP * exp(-Misfit) = 8.823835E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 5726.88 885.711 0.519637 0.608903 Final coordinates: 8619.94 920.252 0.411394 4.935613E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.132299 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.009 0.0179 0.0020 0.0000 0.0636 0.0056 0.0000 0.0050 0.1650 0.0005 0.2388 0.5016 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0076 -0.0020 0.0000 0.0209 0.0056 0.0000 0.0086 -0.1650 -0.0005 0.0416 0.0984 Composition Misfit: 0.587659E-01 Gt predicted* 1.283 0.0000 0.0312 0.0000 0.0000 0.2994 0.0364 0.0684 0.0000 0.0025 0.1367 0.4253 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0107 0.0000 0.0000 0.0225 -0.0022 -0.0136 0.0000 -0.0025 0.0072 -0.0006 Composition Misfit: 0.856499E-02 Fsp predicted* 27.553 0.0947 0.0577 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1539 0.6923 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0030 -0.0061 0.0000 -0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0070 0.0022 Composition Misfit: 0.108118E-02 Bio predicted* 21.571 0.0000 0.0000 0.0222 0.0670 0.1750 0.0008 0.1583 0.1117 0.0038 0.1201 0.3410 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0009 -0.0000 0.0094 0.0006 0.0112 -0.1117 -0.0038 0.0202 0.0750 Composition Misfit: 0.217114E-01 St predicted* 1.835 0.0000 0.0000 0.0046 0.0000 0.1352 0.0023 0.0477 0.0882 0.0022 0.3893 0.3306 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0028 0.0000 -0.0041 0.0016 -0.0248 -0.0882 -0.0022 0.0592 0.0557 Composition Misfit: 0.341329E-01 Ilm predicted* 0.314 0.0000 0.0000 0.3196 0.0000 0.5841 0.0094 0.0147 0.0000 0.0722 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0304 0.0000 0.0459 0.0006 -0.0047 0.0000 -0.0722 0.0000 0.0000 Composition Misfit: 0.804264E-02 ky predicted 6.157 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.278 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -774268. CaO 15.215 -753699. TiO2 7.199 -930554. K2O 16.990 -848478. FeO 54.593 -313271. MnO 0.947 -467827. MgO 41.584 -637961. H2O 29.614 -290916. O2 1.404 -411421. Al2O3 111.899 -0.163470E+07 SiO2 727.525 -885584. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 176 converged, 60 successes so far. Misfit function evaluations this try => 250 Misfit this try = 0.140397 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.021176E-06 Bayes score, PP * exp(-Misfit) = 8.874148E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 5783.38 935.066 0.563608 0.810323 Final coordinates: 8340.99 901.453 0.444402 4.956878E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.140397 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.014 0.0184 0.0018 0.0000 0.0633 0.0051 0.0000 0.0047 0.1651 0.0004 0.2397 0.5015 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0080 -0.0018 0.0000 0.0212 0.0060 0.0000 0.0089 -0.1651 -0.0004 0.0408 0.0985 Composition Misfit: 0.625878E-01 Gt predicted* 1.113 0.0000 0.0328 0.0000 0.0000 0.2969 0.0410 0.0646 0.0000 0.0024 0.1369 0.4254 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0122 0.0000 0.0000 0.0251 -0.0068 -0.0098 0.0000 -0.0024 0.0069 -0.0008 Composition Misfit: 0.961948E-02 Fsp predicted* 27.542 0.0947 0.0579 0.0000 0.0013 0.0000 0.0000 0.0000 0.0000 0.0000 0.1540 0.6921 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0031 -0.0063 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0069 0.0024 Composition Misfit: 0.111181E-02 Bio predicted* 21.615 0.0000 0.0000 0.0218 0.0669 0.1752 0.0008 0.1590 0.1120 0.0038 0.1191 0.3415 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0004 0.0001 0.0093 0.0006 0.0105 -0.1120 -0.0038 0.0212 0.0745 Composition Misfit: 0.216721E-01 St predicted* 1.796 0.0000 0.0000 0.0044 0.0000 0.1368 0.0025 0.0458 0.0882 0.0022 0.3895 0.3307 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0029 0.0000 -0.0057 0.0014 -0.0229 -0.0882 -0.0022 0.0590 0.0556 Composition Misfit: 0.326803E-01 Ilm predicted* 0.360 0.0000 0.0000 0.2917 0.0000 0.6066 0.0089 0.0095 0.0000 0.0833 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0583 0.0000 0.0234 0.0011 0.0005 0.0000 -0.0833 0.0000 0.0000 Composition Misfit: 0.127259E-01 ky predicted 6.277 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.282 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -771094. CaO 15.215 -751841. TiO2 7.199 -928573. K2O 16.990 -845379. FeO 54.593 -311323. MnO 0.947 -464829. MgO 41.584 -636709. H2O 29.741 -289716. O2 1.516 -411271. Al2O3 111.899 -0.163233E+07 SiO2 727.525 -884198. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 177 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 178 converged, 61 successes so far. Misfit function evaluations this try => 232 Misfit this try = 0.202986 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.022889E-06 Bayes score, PP * exp(-Misfit) = 8.349738E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 8348.49 920.424 0.336575 0.799579 Final coordinates: 8851.26 923.808 0.636571 6.050640E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.202983 Extraneous predicted phases: 3.273121E-06 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 3.635 0.0190 0.0023 0.0000 0.0623 0.0055 0.0000 0.0053 0.1649 0.0005 0.2388 0.5013 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0087 -0.0023 0.0000 0.0222 0.0056 0.0000 0.0083 -0.1649 -0.0005 0.0417 0.0987 Composition Misfit: 0.594183E-01 Gt predicted* 0.909 0.0000 0.0341 0.0000 0.0000 0.2882 0.0398 0.0743 0.0000 0.0029 0.1359 0.4249 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0135 0.0000 0.0000 0.0337 -0.0056 -0.0195 0.0000 -0.0029 0.0080 -0.0002 Composition Misfit: 0.156833E-01 Fsp predicted* 26.813 0.0940 0.0592 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1546 0.6908 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0024 -0.0076 0.0000 -0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0063 0.0037 Composition Misfit: 0.130972E-02 Bio predicted* 18.545 0.0000 0.0000 0.0215 0.0668 0.1645 0.0009 0.1707 0.1121 0.0041 0.1182 0.3412 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0001 0.0001 0.0200 0.0006 -0.0012 -0.1121 -0.0041 0.0221 0.0748 Composition Misfit: 0.232903E-01 St predicted* 5.871 0.0000 0.0000 0.0044 0.0000 0.1299 0.0025 0.0534 0.0881 0.0024 0.3888 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0029 0.0000 0.0011 0.0013 -0.0304 -0.0881 -0.0024 0.0597 0.0559 Composition Misfit: 0.385779E-01 Ilm predicted* 0.595 0.0000 0.0000 0.2294 0.0000 0.6462 0.0077 0.0084 0.0000 0.1082 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1206 0.0000 -0.0162 0.0023 0.0016 0.0000 -0.1082 0.0000 0.0000 Composition Misfit: 0.647030E-01 ky predicted 2.047 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.580 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.006 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -774232. CaO 15.215 -753222. TiO2 7.199 -930797. K2O 16.990 -848895. FeO 54.593 -313827. MnO 0.947 -467468. MgO 41.584 -637487. H2O 36.304 -290622. O2 2.172 -407331. Al2O3 111.899 -0.163477E+07 SiO2 727.525 -885440. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 179 converged, 62 successes so far. Misfit function evaluations this try => 152 Misfit this try = 0.169292 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 4.579414E-07 Bayes score, PP * exp(-Misfit) = 3.866229E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 7172.84 810.340 0.774747 0.102868 Final coordinates: 7713.10 845.037 0.521729 4.866494E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.169292 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.310 0.0201 0.0015 0.0000 0.0619 0.0040 0.0000 0.0038 0.1654 0.0004 0.2418 0.5012 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0097 -0.0015 0.0000 0.0226 0.0072 0.0000 0.0097 -0.1654 -0.0004 0.0387 0.0988 Composition Misfit: 0.777886E-01 Gt predicted* 1.143 0.0000 0.0406 0.0000 0.0000 0.2967 0.0440 0.0539 0.0000 0.0024 0.1369 0.4254 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0200 0.0000 0.0000 0.0252 -0.0098 0.0009 0.0000 -0.0024 0.0069 -0.0008 Composition Misfit: 0.145427E-01 Fsp predicted* 27.391 0.0952 0.0578 0.0000 0.0009 0.0000 0.0000 0.0000 0.0000 0.0000 0.1539 0.6922 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0035 -0.0062 0.0000 0.0004 0.0000 0.0000 0.0000 0.0000 0.0000 0.0070 0.0023 Composition Misfit: 0.130331E-02 Bio predicted* 21.555 0.0000 0.0000 0.0196 0.0664 0.1766 0.0007 0.1623 0.1133 0.0040 0.1139 0.3432 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0018 0.0005 0.0079 0.0008 0.0072 -0.1133 -0.0040 0.0264 0.0727 Composition Misfit: 0.232188E-01 St predicted* 0.436 0.0000 0.0000 0.0037 0.0000 0.1425 0.0022 0.0404 0.0882 0.0022 0.3900 0.3307 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0036 0.0000 -0.0115 0.0016 -0.0175 -0.0882 -0.0022 0.0585 0.0556 Composition Misfit: 0.312906E-01 Ilm predicted* 0.512 0.0000 0.0000 0.2773 0.0000 0.6186 0.0082 0.0068 0.0000 0.0891 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0727 0.0000 0.0114 0.0018 0.0032 0.0000 -0.0891 0.0000 0.0000 Composition Misfit: 0.211475E-01 ky predicted 7.618 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.035 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -760729. CaO 15.215 -745814. TiO2 7.199 -923109. K2O 16.990 -835220. FeO 54.593 -305293. MnO 0.947 -457757. MgO 41.584 -632738. H2O 29.199 -285998. O2 1.780 -409151. Al2O3 111.899 -0.162502E+07 SiO2 727.525 -879730. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 180 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 181 converged, 63 successes so far. Misfit function evaluations this try => 334 Misfit this try = 0.270038 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.117667E-06 Bayes score, PP * exp(-Misfit) = 8.531718E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 13317.9 812.370 7.872042E-02 0.918742 Final coordinates: 9136.49 918.797 0.829563 6.716932E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.270038 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 6.529 0.0209 0.0026 0.0000 0.0603 0.0052 0.0000 0.0054 0.1650 0.0005 0.2391 0.5009 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0105 -0.0026 0.0000 0.0242 0.0059 0.0000 0.0081 -0.1650 -0.0005 0.0413 0.0991 Composition Misfit: 0.631693E-01 Gt predicted* 0.959 0.0000 0.0393 0.0000 0.0000 0.2824 0.0371 0.0786 0.0000 0.0033 0.1350 0.4244 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0188 0.0000 0.0000 0.0396 -0.0029 -0.0238 0.0000 -0.0033 0.0089 0.0003 Composition Misfit: 0.225373E-01 Fsp predicted* 26.053 0.0937 0.0600 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1550 0.6900 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0021 -0.0084 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0059 0.0045 Composition Misfit: 0.149406E-02 Bio predicted* 16.366 0.0000 0.0000 0.0203 0.0665 0.1552 0.0008 0.1828 0.1127 0.0042 0.1152 0.3422 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0010 0.0004 0.0293 0.0006 -0.0133 -0.1127 -0.0042 0.0251 0.0738 Composition Misfit: 0.284669E-01 St predicted* 7.569 0.0000 0.0000 0.0042 0.0000 0.1257 0.0023 0.0582 0.0881 0.0025 0.3887 0.3304 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0032 0.0000 0.0054 0.0015 -0.0353 -0.0881 -0.0025 0.0599 0.0559 Composition Misfit: 0.437501E-01 Ilm predicted* 0.857 0.0000 0.0000 0.2033 0.0000 0.6642 0.0064 0.0075 0.0000 0.1187 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1467 0.0000 -0.0342 0.0036 0.0025 0.0000 -0.1187 0.0000 0.0000 Composition Misfit: 0.110621 ky predicted 0.024 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.645 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -771884. CaO 15.215 -751414. TiO2 7.199 -930005. K2O 16.990 -847025. FeO 54.593 -313183. MnO 0.947 -467098. MgO 41.584 -636254. H2O 40.302 -289524. O2 2.831 -404145. Al2O3 111.899 -0.163335E+07 SiO2 727.525 -884244. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 182 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 183 converged, 64 successes so far. Misfit function evaluations this try => 310 Misfit this try = 0.383095 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.767328E-07 Bayes score, PP * exp(-Misfit) = 1.204872E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 13823.5 815.435 0.363128 0.689714 Final coordinates: 7366.78 815.739 0.970724 5.197917E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.383095 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 2.652 0.0236 0.0015 0.0000 0.0585 0.0030 0.0000 0.0032 0.1657 0.0003 0.2437 0.5005 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0132 -0.0015 0.0000 0.0260 0.0081 0.0000 0.0104 -0.1657 -0.0003 0.0368 0.0995 Composition Misfit: 0.101404 Gt predicted* 0.863 0.0000 0.0475 0.0000 0.0000 0.2819 0.0549 0.0514 0.0000 0.0026 0.1365 0.4252 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0270 0.0000 0.0000 0.0400 -0.0206 0.0034 0.0000 -0.0026 0.0073 -0.0006 Composition Misfit: 0.293544E-01 Fsp predicted* 26.829 0.0947 0.0591 0.0000 0.0007 0.0000 0.0000 0.0000 0.0000 0.0000 0.1545 0.6909 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0031 -0.0075 0.0000 0.0006 0.0000 0.0000 0.0000 0.0000 0.0000 0.0064 0.0036 Composition Misfit: 0.188879E-02 Bio predicted* 19.824 0.0000 0.0000 0.0177 0.0661 0.1667 0.0007 0.1761 0.1145 0.0042 0.1097 0.3444 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0037 0.0009 0.0178 0.0007 -0.0066 -0.1145 -0.0042 0.0306 0.0716 Composition Misfit: 0.270887E-01 St predicted* 0.329 0.0000 0.0000 0.0033 0.0000 0.1411 0.0025 0.0417 0.0882 0.0023 0.3902 0.3307 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0041 0.0000 -0.0101 0.0013 -0.0188 -0.0882 -0.0023 0.0584 0.0556 Composition Misfit: 0.330089E-01 Ilm predicted* 1.035 0.0000 0.0000 0.1758 0.0000 0.6844 0.0065 0.0036 0.0000 0.1297 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1742 0.0000 -0.0544 0.0035 0.0064 0.0000 -0.1297 0.0000 0.0000 Composition Misfit: 0.190351 ky predicted 7.401 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.067 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -755641. CaO 15.215 -742626. TiO2 7.199 -920631. K2O 16.990 -830927. FeO 54.593 -302614. MnO 0.947 -452990. MgO 41.584 -630355. H2O 31.188 -283911. O2 3.312 -405977. Al2O3 111.899 -0.162145E+07 SiO2 727.525 -877559. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 184 converged, 65 successes so far. Misfit function evaluations this try => 183 Misfit this try = 0.137228 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 9.163447E-07 Bayes score, PP * exp(-Misfit) = 7.988431E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 8024.82 925.548 0.247375 0.693790 Final coordinates: 8350.03 923.573 0.402803 5.228003E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.137057 Extraneous predicted phases: 1.707754E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.012 0.0176 0.0019 0.0000 0.0640 0.0054 0.0000 0.0048 0.1650 0.0005 0.2392 0.5016 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0072 -0.0019 0.0000 0.0205 0.0057 0.0000 0.0087 -0.1650 -0.0005 0.0413 0.0984 Composition Misfit: 0.595707E-01 Gt predicted* 0.749 0.0000 0.0286 0.0000 0.0000 0.2907 0.0477 0.0678 0.0000 0.0023 0.1373 0.4256 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0081 0.0000 0.0000 0.0312 -0.0135 -0.0130 0.0000 -0.0023 0.0065 -0.0010 Composition Misfit: 0.122280E-01 Fsp predicted* 27.613 0.0942 0.0585 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1542 0.6915 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0026 -0.0069 0.0000 -0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0067 0.0030 Composition Misfit: 0.119646E-02 Bio predicted* 21.488 0.0000 0.0000 0.0230 0.0671 0.1743 0.0011 0.1568 0.1113 0.0037 0.1222 0.3405 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0016 -0.0002 0.0101 0.0004 0.0127 -0.1113 -0.0037 0.0181 0.0755 Composition Misfit: 0.212715E-01 St predicted* 3.713 0.0000 0.0000 0.0048 0.0000 0.1340 0.0031 0.0476 0.0882 0.0021 0.3895 0.3307 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0025 0.0000 -0.0030 0.0007 -0.0247 -0.0882 -0.0021 0.0591 0.0556 Composition Misfit: 0.326575E-01 Ilm predicted* 0.266 0.0000 0.0000 0.2994 0.0000 0.5996 0.0103 0.0105 0.0000 0.0802 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0506 0.0000 0.0304 -0.0003 -0.0005 0.0000 -0.0802 0.0000 0.0000 Composition Misfit: 0.101331E-01 ky predicted 4.564 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.587 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.008 0.0000 0.0000 0.3322 0.0000 0.5638 0.0215 0.0153 0.0000 0.0671 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -776300. CaO 15.215 -754954. TiO2 7.199 -931012. K2O 16.990 -850559. FeO 54.593 -314094. MnO 0.947 -466509. MgO 41.584 -638633. H2O 31.368 -291589. O2 1.374 -413218. Al2O3 111.899 -0.163582E+07 SiO2 727.525 -886563. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 185 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 186 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 187 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 188 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 189 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 190 converged, 66 successes so far. Misfit function evaluations this try => 231 Misfit this try = 0.137683 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 9.782573E-07 Bayes score, PP * exp(-Misfit) = 8.524285E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 9112.55 975.685 0.476375 0.922542 Final coordinates: 8542.73 921.640 0.458751 5.179237E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.137683 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.532 0.0178 0.0020 0.0000 0.0637 0.0057 0.0000 0.0050 0.1650 0.0005 0.2388 0.5016 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0074 -0.0020 0.0000 0.0208 0.0055 0.0000 0.0085 -0.1650 -0.0005 0.0417 0.0984 Composition Misfit: 0.583479E-01 Gt predicted* 1.040 0.0000 0.0308 0.0000 0.0000 0.2953 0.0405 0.0691 0.0000 0.0026 0.1365 0.4252 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0103 0.0000 0.0000 0.0266 -0.0063 -0.0143 0.0000 -0.0026 0.0074 -0.0005 Composition Misfit: 0.101491E-01 Fsp predicted* 27.478 0.0944 0.0582 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1541 0.6918 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0028 -0.0066 0.0000 -0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0068 0.0027 Composition Misfit: 0.114759E-02 Bio predicted* 21.101 0.0000 0.0000 0.0220 0.0670 0.1736 0.0009 0.1599 0.1119 0.0040 0.1203 0.3404 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0006 -0.0000 0.0109 0.0005 0.0097 -0.1119 -0.0040 0.0200 0.0755 Composition Misfit: 0.216752E-01 St predicted* 2.899 0.0000 0.0000 0.0043 0.0000 0.1346 0.0026 0.0484 0.0881 0.0023 0.3891 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0030 0.0000 -0.0035 0.0013 -0.0255 -0.0881 -0.0023 0.0594 0.0558 Composition Misfit: 0.346513E-01 Ilm predicted* 0.361 0.0000 0.0000 0.2945 0.0000 0.6042 0.0089 0.0102 0.0000 0.0822 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0555 0.0000 0.0258 0.0011 -0.0002 0.0000 -0.0822 0.0000 0.0000 Composition Misfit: 0.117123E-01 ky predicted 5.172 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.419 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -774977. CaO 15.215 -754080. TiO2 7.199 -931183. K2O 16.990 -849206. FeO 54.593 -313617. MnO 0.947 -467312. MgO 41.584 -638114. H2O 31.075 -291139. O2 1.565 -409775. Al2O3 111.899 -0.163509E+07 SiO2 727.525 -885911. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 191 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 192 converged, 67 successes so far. Misfit function evaluations this try => 205 Misfit this try = 0.229102 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.113278E-06 Bayes score, PP * exp(-Misfit) = 8.853315E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 7363.05 932.695 0.338340 0.830729 Final coordinates: 9991.99 925.908 0.567081 6.923547E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.228882 Extraneous predicted phases: 2.203309E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 9.110 0.0249 0.0033 0.0000 0.0560 0.0049 0.0000 0.0055 0.1650 0.0005 0.2398 0.5002 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0145 -0.0033 0.0000 0.0285 0.0063 0.0000 0.0081 -0.1650 -0.0005 0.0407 0.0998 Composition Misfit: 0.731894E-01 Gt predicted* 3.098 0.0000 0.0438 0.0000 0.0000 0.2910 0.0177 0.0850 0.0000 0.0033 0.1348 0.4243 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0233 0.0000 0.0000 0.0309 0.0166 -0.0302 0.0000 -0.0033 0.0090 0.0003 Composition Misfit: 0.425228E-01 Fsp predicted* 24.680 0.0953 0.0570 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1535 0.6930 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0037 -0.0054 0.0000 0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0074 0.0015 Composition Misfit: 0.104278E-02 Bio predicted* 14.944 0.0000 0.0000 0.0212 0.0665 0.1501 0.0004 0.1887 0.1117 0.0038 0.1125 0.3450 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0002 0.0005 0.0343 0.0011 -0.0192 -0.1117 -0.0038 0.0278 0.0709 Composition Misfit: 0.342568E-01 St predicted* 6.119 0.0000 0.0000 0.0052 0.0000 0.1222 0.0011 0.0621 0.0881 0.0023 0.3886 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0022 0.0000 0.0089 0.0028 -0.0392 -0.0881 -0.0023 0.0599 0.0558 Composition Misfit: 0.522045E-01 Ilm predicted* 0.676 0.0000 0.0000 0.2889 0.0000 0.6104 0.0036 0.0127 0.0000 0.0844 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0611 0.0000 0.0196 0.0064 -0.0027 0.0000 -0.0844 0.0000 0.0000 Composition Misfit: 0.256657E-01 ky predicted 0.271 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.058 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.045 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 ru 0.000 0.0000 0.0000 1.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -769524. CaO 15.215 -750119. TiO2 7.199 -927877. K2O 16.990 -845306. FeO 54.593 -313066. MnO 0.947 -472931. MgO 41.584 -635580. H2O 41.541 -288688. O2 1.935 -406046. Al2O3 111.899 -0.163263E+07 SiO2 727.525 -883061. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 193 converged, 68 successes so far. Misfit function evaluations this try => 328 Misfit this try = 0.374766 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 3.229089E-07 Bayes score, PP * exp(-Misfit) = 2.219838E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 5848.42 810.114 0.949155 0.749164 Final coordinates: 7661.87 831.641 0.985715 5.593822E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.374766 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 3.765 0.0238 0.0018 0.0000 0.0581 0.0032 0.0000 0.0035 0.1656 0.0003 0.2433 0.5004 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0134 -0.0018 0.0000 0.0264 0.0079 0.0000 0.0101 -0.1656 -0.0003 0.0372 0.0996 Composition Misfit: 0.955305E-01 Gt predicted* 0.802 0.0000 0.0469 0.0000 0.0000 0.2794 0.0538 0.0560 0.0000 0.0027 0.1362 0.4250 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0264 0.0000 0.0000 0.0426 -0.0195 -0.0012 0.0000 -0.0027 0.0077 -0.0004 Composition Misfit: 0.288626E-01 Fsp predicted* 26.560 0.0944 0.0596 0.0000 0.0008 0.0000 0.0000 0.0000 0.0000 0.0000 0.1548 0.6904 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0028 -0.0080 0.0000 0.0006 0.0000 0.0000 0.0000 0.0000 0.0000 0.0061 0.0041 Composition Misfit: 0.186906E-02 Bio predicted* 18.930 0.0000 0.0000 0.0179 0.0661 0.1625 0.0007 0.1799 0.1144 0.0042 0.1103 0.3440 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0035 0.0008 0.0220 0.0007 -0.0104 -0.1144 -0.0042 0.0300 0.0719 Composition Misfit: 0.281076E-01 St predicted* 1.964 0.0000 0.0000 0.0034 0.0000 0.1377 0.0026 0.0453 0.0882 0.0023 0.3899 0.3306 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0040 0.0000 -0.0066 0.0012 -0.0224 -0.0882 -0.0023 0.0587 0.0557 Composition Misfit: 0.348052E-01 Ilm predicted* 1.052 0.0000 0.0000 0.1765 0.0000 0.6835 0.0066 0.0040 0.0000 0.1294 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1735 0.0000 -0.0535 0.0034 0.0060 0.0000 -0.1294 0.0000 0.0000 Composition Misfit: 0.185591 ky predicted 5.699 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.228 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -758032. CaO 15.215 -743813. TiO2 7.199 -922079. K2O 16.990 -833462. FeO 54.593 -304252. MnO 0.947 -454785. MgO 41.584 -631102. H2O 33.563 -284607. O2 3.363 -405054. Al2O3 111.899 -0.162314E+07 SiO2 727.525 -878484. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 194 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 195 converged, 69 successes so far. Misfit function evaluations this try => 225 Misfit this try = 0.317497 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 9.633778E-07 Bayes score, PP * exp(-Misfit) = 7.013093E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 9874.08 825.926 0.942664 0.124196 Final coordinates: 8291.67 884.933 0.921525 6.786498E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.317497 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 6.275 0.0216 0.0023 0.0000 0.0599 0.0043 0.0000 0.0046 0.1653 0.0004 0.2410 0.5006 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0112 -0.0023 0.0000 0.0246 0.0068 0.0000 0.0090 -0.1653 -0.0004 0.0395 0.0994 Composition Misfit: 0.727505E-01 Gt predicted* 0.376 0.0000 0.0398 0.0000 0.0000 0.2701 0.0568 0.0698 0.0000 0.0029 0.1357 0.4248 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0193 0.0000 0.0000 0.0518 -0.0226 -0.0150 0.0000 -0.0029 0.0081 -0.0001 Composition Misfit: 0.319401E-01 Fsp predicted* 26.145 0.0934 0.0612 0.0000 0.0010 0.0000 0.0000 0.0000 0.0000 0.0000 0.1556 0.6888 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0017 -0.0096 0.0000 0.0003 0.0000 0.0000 0.0000 0.0000 0.0000 0.0053 0.0057 Composition Misfit: 0.185536E-02 Bio predicted* 16.640 0.0000 0.0000 0.0193 0.0664 0.1549 0.0010 0.1841 0.1136 0.0043 0.1143 0.3420 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0021 0.0005 0.0296 0.0004 -0.0146 -0.1136 -0.0043 0.0260 0.0740 Composition Misfit: 0.290830E-01 St predicted* 7.790 0.0000 0.0000 0.0038 0.0000 0.1280 0.0033 0.0547 0.0881 0.0025 0.3891 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0036 0.0000 0.0030 0.0005 -0.0318 -0.0881 -0.0025 0.0594 0.0558 Composition Misfit: 0.404572E-01 Ilm predicted* 0.959 0.0000 0.0000 0.1897 0.0000 0.6719 0.0085 0.0058 0.0000 0.1241 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1603 0.0000 -0.0419 0.0015 0.0042 0.0000 -0.1241 0.0000 0.0000 Composition Misfit: 0.141410 ky predicted 0.009 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.806 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -767740. CaO 15.215 -749125. TiO2 7.199 -927475. K2O 16.990 -843147. FeO 54.593 -310183. MnO 0.947 -460405. MgO 41.584 -634438. H2O 40.719 -287865. O2 3.144 -403693. Al2O3 111.899 -0.162985E+07 SiO2 727.525 -882556. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 196 converged, 70 successes so far. Misfit function evaluations this try => 166 Misfit this try = 0.137161 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 9.490085E-07 Bayes score, PP * exp(-Misfit) = 8.273736E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 6559.10 912.624 0.533315 0.561315 Final coordinates: 8541.51 924.872 0.445454 5.180863E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.137161 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.391 0.0177 0.0020 0.0000 0.0638 0.0057 0.0000 0.0050 0.1650 0.0005 0.2388 0.5016 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0073 -0.0020 0.0000 0.0207 0.0055 0.0000 0.0085 -0.1650 -0.0005 0.0417 0.0984 Composition Misfit: 0.581422E-01 Gt predicted* 0.985 0.0000 0.0301 0.0000 0.0000 0.2945 0.0416 0.0694 0.0000 0.0026 0.1366 0.4253 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0096 0.0000 0.0000 0.0274 -0.0073 -0.0146 0.0000 -0.0026 0.0072 -0.0006 Composition Misfit: 0.103257E-01 Fsp predicted* 27.517 0.0944 0.0582 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1541 0.6918 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0027 -0.0066 0.0000 -0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0068 0.0027 Composition Misfit: 0.115823E-02 Bio predicted* 21.200 0.0000 0.0000 0.0223 0.0670 0.1738 0.0009 0.1590 0.1117 0.0039 0.1209 0.3404 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0009 -0.0001 0.0107 0.0005 0.0105 -0.1117 -0.0039 0.0194 0.0756 Composition Misfit: 0.215481E-01 St predicted* 3.071 0.0000 0.0000 0.0045 0.0000 0.1342 0.0027 0.0484 0.0882 0.0023 0.3892 0.3306 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0028 0.0000 -0.0032 0.0012 -0.0255 -0.0882 -0.0023 0.0594 0.0557 Composition Misfit: 0.342998E-01 Ilm predicted* 0.337 0.0000 0.0000 0.2944 0.0000 0.6038 0.0093 0.0103 0.0000 0.0822 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0556 0.0000 0.0262 0.0007 -0.0003 0.0000 -0.0822 0.0000 0.0000 Composition Misfit: 0.116873E-01 ky predicted 5.041 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.458 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -775748. CaO 15.215 -754551. TiO2 7.199 -931406. K2O 16.990 -849973. FeO 54.593 -314015. MnO 0.947 -467552. MgO 41.584 -638420. H2O 31.085 -291420. O2 1.520 -410625. Al2O3 111.899 -0.163561E+07 SiO2 727.525 -886265. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 197 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 198 converged, 71 successes so far. Misfit function evaluations this try => 245 Misfit this try = 0.153585 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.050348E-06 Bayes score, PP * exp(-Misfit) = 9.008081E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 7197.59 815.529 0.169026 0.766387 Final coordinates: 8543.43 910.657 0.343102 4.955303E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.153585 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.007 0.0184 0.0019 0.0000 0.0632 0.0052 0.0000 0.0048 0.1651 0.0004 0.2394 0.5016 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0080 -0.0019 0.0000 0.0213 0.0059 0.0000 0.0087 -0.1651 -0.0004 0.0411 0.0984 Composition Misfit: 0.613974E-01 Gt predicted* 1.365 0.0000 0.0320 0.0000 0.0000 0.2996 0.0369 0.0663 0.0000 0.0023 0.1373 0.4256 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0115 0.0000 0.0000 0.0223 -0.0026 -0.0115 0.0000 -0.0023 0.0066 -0.0010 Composition Misfit: 0.828648E-02 Fsp predicted* 27.522 0.0948 0.0576 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1538 0.6924 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0032 -0.0060 0.0000 -0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0071 0.0021 Composition Misfit: 0.106453E-02 Bio predicted* 21.607 0.0000 0.0000 0.0225 0.0670 0.1751 0.0008 0.1580 0.1115 0.0036 0.1197 0.3420 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0011 -0.0000 0.0094 0.0007 0.0115 -0.1115 -0.0036 0.0206 0.0740 Composition Misfit: 0.215153E-01 St predicted* 1.967 0.0000 0.0000 0.0048 0.0000 0.1358 0.0023 0.0465 0.0882 0.0020 0.3897 0.3308 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0025 0.0000 -0.0048 0.0016 -0.0236 -0.0882 -0.0020 0.0589 0.0555 Composition Misfit: 0.328024E-01 Ilm predicted* 0.259 0.0000 0.0000 0.3810 0.0000 0.5714 0.0000 0.0000 0.0000 0.0476 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 -0.0310 0.0000 0.0586 0.0100 0.0100 0.0000 -0.0476 0.0000 0.0000 Composition Misfit: 0.285185E-01 ky predicted 6.041 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.232 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -772334. CaO 15.215 -752568. TiO2 7.199 -928955. K2O 16.990 -846621. FeO 54.593 -312159. MnO 0.947 -466606. MgO 41.584 -637262. H2O 29.732 -290181. O2 1.171 -413698. Al2O3 111.899 -0.163334E+07 SiO2 727.525 -884722. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 199 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 200 converged, 72 successes so far. Misfit function evaluations this try => 209 Misfit this try = 0.169446 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.048831E-06 Bayes score, PP * exp(-Misfit) = 8.853520E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 12232.3 899.675 0.518970 0.756877 Final coordinates: 9459.28 929.197 0.505493 5.323853E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.169446 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 3.570 0.0202 0.0024 0.0000 0.0610 0.0057 0.0000 0.0056 0.1649 0.0005 0.2382 0.5014 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0099 -0.0024 0.0000 0.0235 0.0054 0.0000 0.0080 -0.1649 -0.0005 0.0422 0.0986 Composition Misfit: 0.596681E-01 Gt predicted* 2.638 0.0000 0.0364 0.0000 0.0000 0.3016 0.0211 0.0777 0.0000 0.0031 0.1354 0.4246 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0159 0.0000 0.0000 0.0203 0.0131 -0.0229 0.0000 -0.0031 0.0084 0.0000 Composition Misfit: 0.237145E-01 Fsp predicted* 26.553 0.0954 0.0564 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1532 0.6936 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0038 -0.0048 0.0000 -0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0077 0.0009 Composition Misfit: 0.946985E-03 Bio predicted* 18.802 0.0000 0.0000 0.0215 0.0667 0.1645 0.0005 0.1722 0.1119 0.0040 0.1162 0.3426 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0001 0.0003 0.0200 0.0010 -0.0027 -0.1119 -0.0040 0.0241 0.0733 Composition Misfit: 0.251745E-01 St predicted* 1.706 0.0000 0.0000 0.0046 0.0000 0.1301 0.0013 0.0543 0.0881 0.0024 0.3887 0.3304 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0027 0.0000 0.0009 0.0025 -0.0314 -0.0881 -0.0024 0.0598 0.0559 Composition Misfit: 0.433577E-01 Ilm predicted* 0.518 0.0000 0.0000 0.2953 0.0000 0.6057 0.0050 0.0121 0.0000 0.0819 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0547 0.0000 0.0243 0.0050 -0.0021 0.0000 -0.0819 0.0000 0.0000 Composition Misfit: 0.165847E-01 ky predicted 5.358 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.855 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -772576. CaO 15.215 -752459. TiO2 7.199 -930237. K2O 16.990 -847403. FeO 54.593 -313615. MnO 0.947 -472463. MgO 41.584 -637141. H2O 31.943 -290177. O2 1.725 -407527. Al2O3 111.899 -0.163432E+07 SiO2 727.525 -884635. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 201 converged, 73 successes so far. Misfit function evaluations this try => 289 Misfit this try = 0.286157 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 4.198739E-07 Bayes score, PP * exp(-Misfit) = 3.153860E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 11508.2 814.127 0.361648 5.771764E-02 Final coordinates: 7308.98 848.520 0.733828 4.767000E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.286157 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.004 0.0192 0.0014 0.0000 0.0628 0.0040 0.0000 0.0038 0.1654 0.0004 0.2419 0.5011 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0088 -0.0014 0.0000 0.0216 0.0072 0.0000 0.0098 -0.1654 -0.0004 0.0386 0.0989 Composition Misfit: 0.769241E-01 Gt predicted* 0.698 0.0000 0.0356 0.0000 0.0000 0.2834 0.0616 0.0543 0.0000 0.0023 0.1372 0.4256 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0150 0.0000 0.0000 0.0385 -0.0273 0.0004 0.0000 -0.0023 0.0066 -0.0009 Composition Misfit: 0.240105E-01 Fsp predicted* 27.561 0.0947 0.0586 0.0000 0.0010 0.0000 0.0000 0.0000 0.0000 0.0000 0.1543 0.6914 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0031 -0.0070 0.0000 0.0004 0.0000 0.0000 0.0000 0.0000 0.0000 0.0066 0.0031 Composition Misfit: 0.135522E-02 Bio predicted* 21.754 0.0000 0.0000 0.0195 0.0665 0.1747 0.0010 0.1630 0.1136 0.0042 0.1160 0.3414 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0019 0.0004 0.0097 0.0005 0.0065 -0.1136 -0.0042 0.0243 0.0745 Composition Misfit: 0.225562E-01 St predicted* 0.022 0.0000 0.0000 0.0035 0.0000 0.1409 0.0033 0.0413 0.0882 0.0023 0.3899 0.3307 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0038 0.0000 -0.0099 0.0006 -0.0184 -0.0882 -0.0023 0.0587 0.0556 Composition Misfit: 0.313515E-01 Ilm predicted* 0.695 0.0000 0.0000 0.1960 0.0000 0.6690 0.0089 0.0045 0.0000 0.1216 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1540 0.0000 -0.0390 0.0011 0.0055 0.0000 -0.1216 0.0000 0.0000 Composition Misfit: 0.129960 ky predicted 8.048 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.218 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -763367. CaO 15.215 -747541. TiO2 7.199 -924702. K2O 16.990 -837956. FeO 54.593 -306362. MnO 0.947 -456225. MgO 41.584 -633461. H2O 28.602 -286880. O2 2.504 -407870. Al2O3 111.899 -0.162642E+07 SiO2 727.525 -881011. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 202 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 203 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 204 converged, 74 successes so far. Misfit function evaluations this try => 180 Misfit this try = 0.161387 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 6.968370E-07 Bayes score, PP * exp(-Misfit) = 5.929820E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 5533.79 856.459 0.278277 0.864144 Final coordinates: 7962.98 863.203 0.534816 5.112535E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.161270 Extraneous predicted phases: 1.177670E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.960 0.0196 0.0016 0.0000 0.0622 0.0044 0.0000 0.0042 0.1653 0.0004 0.2410 0.5012 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0093 -0.0016 0.0000 0.0223 0.0068 0.0000 0.0094 -0.1653 -0.0004 0.0395 0.0988 Composition Misfit: 0.714058E-01 Gt predicted* 1.104 0.0000 0.0388 0.0000 0.0000 0.2955 0.0431 0.0583 0.0000 0.0026 0.1365 0.4252 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0182 0.0000 0.0000 0.0264 -0.0088 -0.0035 0.0000 -0.0026 0.0073 -0.0006 Composition Misfit: 0.133429E-01 Fsp predicted* 27.280 0.0949 0.0581 0.0000 0.0010 0.0000 0.0000 0.0000 0.0000 0.0000 0.1540 0.6919 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0033 -0.0065 0.0000 0.0003 0.0000 0.0000 0.0000 0.0000 0.0000 0.0069 0.0026 Composition Misfit: 0.124834E-02 Bio predicted* 20.960 0.0000 0.0000 0.0198 0.0665 0.1742 0.0007 0.1641 0.1132 0.0041 0.1150 0.3424 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0016 0.0004 0.0102 0.0007 0.0054 -0.1132 -0.0041 0.0254 0.0736 Composition Misfit: 0.230214E-01 St predicted* 1.574 0.0000 0.0000 0.0037 0.0000 0.1401 0.0023 0.0432 0.0882 0.0023 0.3896 0.3306 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0036 0.0000 -0.0091 0.0015 -0.0203 -0.0882 -0.0023 0.0589 0.0557 Composition Misfit: 0.329515E-01 Ilm predicted* 0.512 0.0000 0.0000 0.2797 0.0000 0.6167 0.0081 0.0074 0.0000 0.0881 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0703 0.0000 0.0133 0.0019 0.0026 0.0000 -0.0881 0.0000 0.0000 Composition Misfit: 0.192997E-01 ky predicted 6.443 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.160 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.006 0.0000 0.0000 0.2019 0.0000 0.6672 0.0065 0.0052 0.0000 0.1193 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -763848. CaO 15.215 -747550. TiO2 7.199 -925185. K2O 16.990 -838338. FeO 54.593 -307218. MnO 0.947 -459979. MgO 41.584 -633834. H2O 30.675 -287060. O2 1.825 -407845. Al2O3 111.899 -0.162722E+07 SiO2 727.525 -881032. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 205 converged, 75 successes so far. Misfit function evaluations this try => 230 Misfit this try = 0.335927 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.180917E-06 Bayes score, PP * exp(-Misfit) = 8.439719E-07 Best Bayes score so far = 9.168258E-07 obtained on Try 42 P_bar T_K C_O2 C_H2O Initial coordinates: 6985.09 949.346 0.931726 0.935506 Final coordinates: 9172.07 910.108 0.996229 6.798744E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.335927 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 7.492 0.0223 0.0028 0.0000 0.0588 0.0049 0.0000 0.0053 0.1650 0.0005 0.2398 0.5005 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0120 -0.0028 0.0000 0.0257 0.0062 0.0000 0.0082 -0.1650 -0.0005 0.0407 0.0995 Composition Misfit: 0.678162E-01 Gt predicted* 0.996 0.0000 0.0429 0.0000 0.0000 0.2784 0.0374 0.0794 0.0000 0.0035 0.1344 0.4241 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0223 0.0000 0.0000 0.0435 -0.0031 -0.0246 0.0000 -0.0035 0.0094 0.0006 Composition Misfit: 0.269838E-01 Fsp predicted* 25.709 0.0937 0.0604 0.0000 0.0011 0.0000 0.0000 0.0000 0.0000 0.0000 0.1552 0.6896 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0020 -0.0088 0.0000 0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0057 0.0049 Composition Misfit: 0.160857E-02 Bio predicted* 15.789 0.0000 0.0000 0.0193 0.0664 0.1506 0.0007 0.1895 0.1134 0.0044 0.1132 0.3426 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0021 0.0006 0.0339 0.0007 -0.0200 -0.1134 -0.0044 0.0271 0.0734 Composition Misfit: 0.328058E-01 St predicted* 7.028 0.0000 0.0000 0.0038 0.0000 0.1240 0.0023 0.0603 0.0881 0.0026 0.3886 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0035 0.0000 0.0071 0.0016 -0.0374 -0.0881 -0.0026 0.0599 0.0560 Composition Misfit: 0.465801E-01 Ilm predicted* 1.058 0.0000 0.0000 0.1836 0.0000 0.6781 0.0055 0.0063 0.0000 0.1266 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1664 0.0000 -0.0481 0.0045 0.0037 0.0000 -0.1266 0.0000 0.0000 Composition Misfit: 0.160132 ky predicted 0.319 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.609 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -769714. CaO 15.215 -749977. TiO2 7.199 -929375. K2O 16.990 -845159. FeO 54.593 -312244. MnO 0.947 -465917. MgO 41.584 -635234. H2O 40.792 -288605. O2 3.399 -402037. Al2O3 111.899 -0.163189E+07 SiO2 727.525 -883225. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 206 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 207 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 208 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 209 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 210 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 211 converged, 76 successes so far. Misfit function evaluations this try => 236 Misfit this try = 0.149652 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.126168E-06 Bayes score, PP * exp(-Misfit) = 9.696393E-07 Best Bayes score so far = 9.696393E-07 obtained on Try 211 P_bar T_K C_O2 C_H2O Initial coordinates: 7724.60 835.929 0.821883 0.210212 Final coordinates: 8789.22 905.227 0.481782 5.638851E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.149652 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 2.678 0.0197 0.0021 0.0000 0.0617 0.0051 0.0000 0.0050 0.1651 0.0004 0.2395 0.5013 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0094 -0.0021 0.0000 0.0227 0.0061 0.0000 0.0086 -0.1651 -0.0004 0.0410 0.0987 Composition Misfit: 0.634251E-01 Gt predicted* 1.390 0.0000 0.0366 0.0000 0.0000 0.2967 0.0333 0.0692 0.0000 0.0027 0.1364 0.4251 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0161 0.0000 0.0000 0.0252 0.0009 -0.0144 0.0000 -0.0027 0.0075 -0.0005 Composition Misfit: 0.126079E-01 Fsp predicted* 26.902 0.0947 0.0582 0.0000 0.0013 0.0000 0.0000 0.0000 0.0000 0.0000 0.1541 0.6918 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0030 -0.0066 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0068 0.0027 Composition Misfit: 0.115700E-02 Bio predicted* 19.456 0.0000 0.0000 0.0215 0.0667 0.1684 0.0007 0.1675 0.1120 0.0038 0.1168 0.3427 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0001 0.0002 0.0161 0.0008 0.0020 -0.1120 -0.0038 0.0235 0.0733 Composition Misfit: 0.228350E-01 St predicted* 4.052 0.0000 0.0000 0.0046 0.0000 0.1335 0.0020 0.0496 0.0882 0.0022 0.3893 0.3306 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0028 0.0000 -0.0025 0.0019 -0.0267 -0.0882 -0.0022 0.0592 0.0557 Composition Misfit: 0.362112E-01 Ilm predicted* 0.458 0.0000 0.0000 0.2918 0.0000 0.6071 0.0074 0.0105 0.0000 0.0833 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0582 0.0000 0.0229 0.0026 -0.0005 0.0000 -0.0833 0.0000 0.0000 Composition Misfit: 0.134155E-01 ky predicted 3.772 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.292 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -770037. CaO 15.215 -750873. TiO2 7.199 -928059. K2O 16.990 -844675. FeO 54.593 -311414. MnO 0.947 -466465. MgO 41.584 -636141. H2O 33.833 -289169. O2 1.644 -409770. Al2O3 111.899 -0.163195E+07 SiO2 727.525 -883576. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 212 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 213 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 214 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 215 converged, 77 successes so far. Misfit function evaluations this try => 361 Misfit this try = 0.210677 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.075566E-06 Bayes score, PP * exp(-Misfit) = 8.712472E-07 Best Bayes score so far = 9.696393E-07 obtained on Try 211 P_bar T_K C_O2 C_H2O Initial coordinates: 9636.89 868.163 0.948241 0.873460 Final coordinates: 8612.25 908.558 0.608670 4.753063E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.210677 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.409 0.0186 0.0019 0.0000 0.0629 0.0054 0.0000 0.0049 0.1650 0.0005 0.2391 0.5015 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0083 -0.0019 0.0000 0.0215 0.0057 0.0000 0.0086 -0.1650 -0.0005 0.0414 0.0985 Composition Misfit: 0.604676E-01 Gt predicted* 1.411 0.0000 0.0339 0.0000 0.0000 0.2985 0.0357 0.0680 0.0000 0.0028 0.1361 0.4250 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0133 0.0000 0.0000 0.0234 -0.0014 -0.0132 0.0000 -0.0028 0.0077 -0.0003 Composition Misfit: 0.101548E-01 Fsp predicted* 27.442 0.0949 0.0575 0.0000 0.0013 0.0000 0.0000 0.0000 0.0000 0.0000 0.1538 0.6925 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0032 -0.0060 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0071 0.0020 Composition Misfit: 0.106177E-02 Bio predicted* 21.316 0.0000 0.0000 0.0212 0.0668 0.1726 0.0007 0.1630 0.1123 0.0041 0.1180 0.3412 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0002 0.0002 0.0118 0.0007 0.0065 -0.1123 -0.0041 0.0223 0.0747 Composition Misfit: 0.223146E-01 St predicted* 0.252 0.0000 0.0000 0.0041 0.0000 0.1356 0.0022 0.0480 0.0881 0.0024 0.3891 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0032 0.0000 -0.0045 0.0017 -0.0251 -0.0881 -0.0024 0.0595 0.0558 Composition Misfit: 0.355968E-01 Ilm predicted* 0.542 0.0000 0.0000 0.2200 0.0000 0.6546 0.0064 0.0070 0.0000 0.1120 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1300 0.0000 -0.0246 0.0036 0.0030 0.0000 -0.1120 0.0000 0.0000 Composition Misfit: 0.810811E-01 ky predicted 7.518 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.110 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -771535. CaO 15.215 -752042. TiO2 7.199 -929608. K2O 16.990 -845905. FeO 54.593 -311929. MnO 0.947 -466528. MgO 41.584 -636805. H2O 28.518 -289875. O2 2.077 -408284. Al2O3 111.899 -0.163286E+07 SiO2 727.525 -884339. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 216 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 217 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 218 converged, 78 successes so far. Misfit function evaluations this try => 156 Misfit this try = 0.257621 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.106267E-06 Bayes score, PP * exp(-Misfit) = 8.550200E-07 Best Bayes score so far = 9.696393E-07 obtained on Try 211 P_bar T_K C_O2 C_H2O Initial coordinates: 8174.74 860.226 0.936571 8.880096E-02 Final coordinates: 9367.36 923.297 0.789376 6.832661E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.257349 Extraneous predicted phases: 2.722347E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 6.896 0.0213 0.0028 0.0000 0.0597 0.0053 0.0000 0.0056 0.1649 0.0005 0.2390 0.5008 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0110 -0.0028 0.0000 0.0247 0.0059 0.0000 0.0080 -0.1649 -0.0005 0.0415 0.0992 Composition Misfit: 0.634326E-01 Gt predicted* 1.274 0.0000 0.0403 0.0000 0.0000 0.2852 0.0317 0.0804 0.0000 0.0033 0.1348 0.4243 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0197 0.0000 0.0000 0.0367 0.0025 -0.0256 0.0000 -0.0033 0.0090 0.0003 Composition Misfit: 0.233311E-01 Fsp predicted* 25.869 0.0940 0.0596 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1548 0.6904 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0023 -0.0080 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0061 0.0041 Composition Misfit: 0.140075E-02 Bio predicted* 16.124 0.0000 0.0000 0.0206 0.0665 0.1546 0.0007 0.1834 0.1124 0.0042 0.1148 0.3427 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0007 0.0004 0.0299 0.0008 -0.0139 -0.1124 -0.0042 0.0255 0.0733 Composition Misfit: 0.290322E-01 St predicted* 7.422 0.0000 0.0000 0.0044 0.0000 0.1249 0.0020 0.0592 0.0881 0.0025 0.3886 0.3304 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0029 0.0000 0.0061 0.0019 -0.0362 -0.0881 -0.0025 0.0600 0.0559 Composition Misfit: 0.449242E-01 Ilm predicted* 0.823 0.0000 0.0000 0.2116 0.0000 0.6589 0.0058 0.0083 0.0000 0.1154 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1384 0.0000 -0.0289 0.0042 0.0017 0.0000 -0.1154 0.0000 0.0000 Composition Misfit: 0.952282E-01 ky predicted 0.008 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.533 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.050 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -771893. CaO 15.215 -751380. TiO2 7.199 -929824. K2O 16.990 -847097. FeO 54.593 -313451. MnO 0.947 -468677. MgO 41.584 -636324. H2O 40.996 -289539. O2 2.693 -404494. Al2O3 111.899 -0.163357E+07 SiO2 727.525 -884204. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 219 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 220 converged, 79 successes so far. Misfit function evaluations this try => 344 Misfit this try = 0.665674 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.029183E-06 Bayes score, PP * exp(-Misfit) = 5.289251E-07 Best Bayes score so far = 9.696393E-07 obtained on Try 211 P_bar T_K C_O2 C_H2O Initial coordinates: 6979.86 986.425 0.576484 0.356501 Final coordinates: 9573.74 931.485 0.273562 8.833317E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.193230 Extraneous predicted phases: 0.472443 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 2.845 0.0205 0.0024 0.0000 0.0608 0.0056 0.0000 0.0055 0.1649 0.0004 0.2383 0.5016 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0101 -0.0024 0.0000 0.0237 0.0056 0.0000 0.0081 -0.1649 -0.0004 0.0421 0.0984 Composition Misfit: 0.606624E-01 Gt predicted* 3.870 0.0000 0.0343 0.0000 0.0000 0.3089 0.0158 0.0766 0.0000 0.0026 0.1366 0.4253 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0137 0.0000 0.0000 0.0131 0.0184 -0.0218 0.0000 -0.0026 0.0072 -0.0006 Composition Misfit: 0.341816E-01 Fsp predicted* 26.034 0.0963 0.0545 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1522 0.6955 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0047 -0.0029 0.0000 -0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0087 -0.0010 Composition Misfit: 0.877566E-03 Bio predicted* 19.036 0.0000 0.0000 0.0226 0.0668 0.1678 0.0004 0.1670 0.1110 0.0035 0.1170 0.3439 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0013 0.0001 0.0166 0.0011 0.0025 -0.1110 -0.0035 0.0233 0.0721 Composition Misfit: 0.248284E-01 St predicted* 0.061 0.0000 0.0000 0.0053 0.0000 0.1312 0.0010 0.0523 0.0882 0.0020 0.3893 0.3307 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0021 0.0000 -0.0002 0.0029 -0.0294 -0.0882 -0.0020 0.0593 0.0556 Composition Misfit: 0.441619E-01 Ilm predicted* 0.000 0.0000 0.0000 0.3810 0.0000 0.5714 0.0000 0.0000 0.0000 0.0476 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 -0.0310 0.0000 0.0586 0.0100 0.0100 0.0000 -0.0476 0.0000 0.0000 Composition Misfit: 0.285185E-01 ky predicted 6.430 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 39.620 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 1.930 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 ru 0.174 0.0000 0.0000 1.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -772425. CaO 15.215 -752755. TiO2 7.199 -929361. K2O 16.990 -847265. FeO 54.593 -313549. MnO 0.947 -474907. MgO 41.584 -637392. H2O 53.000 -290261. O2 0.933 -413205. Al2O3 111.899 -0.163444E+07 SiO2 727.525 -884623. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 221 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 222 converged, 80 successes so far. Misfit function evaluations this try => 245 Misfit this try = 0.215491 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.040961E-06 Bayes score, PP * exp(-Misfit) = 8.391655E-07 Best Bayes score so far = 9.696393E-07 obtained on Try 211 P_bar T_K C_O2 C_H2O Initial coordinates: 7559.24 901.734 0.713273 0.432223 Final coordinates: 8436.35 905.394 0.645188 5.580405E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.215491 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 2.193 0.0189 0.0020 0.0000 0.0627 0.0052 0.0000 0.0049 0.1651 0.0005 0.2396 0.5013 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0085 -0.0020 0.0000 0.0218 0.0060 0.0000 0.0087 -0.1651 -0.0005 0.0409 0.0987 Composition Misfit: 0.622853E-01 Gt predicted* 0.828 0.0000 0.0339 0.0000 0.0000 0.2882 0.0453 0.0685 0.0000 0.0027 0.1362 0.4251 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0134 0.0000 0.0000 0.0337 -0.0111 -0.0137 0.0000 -0.0027 0.0076 -0.0004 Composition Misfit: 0.151178E-01 Fsp predicted* 27.124 0.0942 0.0589 0.0000 0.0013 0.0000 0.0000 0.0000 0.0000 0.0000 0.1545 0.6911 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0026 -0.0073 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0064 0.0034 Composition Misfit: 0.127178E-02 Bio predicted* 19.779 0.0000 0.0000 0.0211 0.0668 0.1682 0.0009 0.1674 0.1125 0.0041 0.1180 0.3411 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0003 0.0002 0.0163 0.0005 0.0021 -0.1125 -0.0041 0.0223 0.0749 Composition Misfit: 0.225234E-01 St predicted* 3.958 0.0000 0.0000 0.0042 0.0000 0.1332 0.0028 0.0497 0.0881 0.0024 0.3891 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0032 0.0000 -0.0022 0.0011 -0.0268 -0.0881 -0.0024 0.0594 0.0558 Composition Misfit: 0.358070E-01 Ilm predicted* 0.593 0.0000 0.0000 0.2204 0.0000 0.6523 0.0082 0.0072 0.0000 0.1119 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1296 0.0000 -0.0223 0.0018 0.0028 0.0000 -0.1119 0.0000 0.0000 Composition Misfit: 0.784861E-01 ky predicted 4.042 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.483 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -771691. CaO 15.215 -751944. TiO2 7.199 -929375. K2O 16.990 -846277. FeO 54.593 -311967. MnO 0.947 -464520. MgO 41.584 -636585. H2O 33.482 -289749. O2 2.201 -407656. Al2O3 111.899 -0.163274E+07 SiO2 727.525 -884402. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 223 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 224 converged, 81 successes so far. Misfit function evaluations this try => 190 Misfit this try = 0.416150 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.436710E-07 Bayes score, PP * exp(-Misfit) = 9.476266E-08 Best Bayes score so far = 9.696393E-07 obtained on Try 211 P_bar T_K C_O2 C_H2O Initial coordinates: 5980.89 841.358 0.114479 0.892437 Final coordinates: 5735.82 839.703 0.880368 5.484110E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.416150 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 1.335 0.0180 0.0011 0.0000 0.0643 0.0033 0.0000 0.0031 0.1657 0.0004 0.2433 0.5008 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0076 -0.0011 0.0000 0.0202 0.0078 0.0000 0.0104 -0.1657 -0.0004 0.0372 0.0992 Composition Misfit: 0.890426E-01 Gt predicted* 0.002 0.0000 0.0238 0.0000 0.0000 0.2393 0.1182 0.0520 0.0000 0.0018 0.1385 0.4263 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0033 0.0000 0.0000 0.0826 -0.0840 0.0028 0.0000 -0.0018 0.0053 -0.0016 Composition Misfit: 0.889468E-01 Fsp predicted* 27.363 0.0940 0.0600 0.0000 0.0011 0.0000 0.0000 0.0000 0.0000 0.0000 0.1550 0.6900 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0023 -0.0084 0.0000 0.0003 0.0000 0.0000 0.0000 0.0000 0.0000 0.0059 0.0045 Composition Misfit: 0.157425E-02 Bio predicted* 20.496 0.0000 0.0000 0.0190 0.0668 0.1667 0.0019 0.1677 0.1147 0.0045 0.1215 0.3372 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0024 0.0001 0.0178 -0.0004 0.0018 -0.1147 -0.0045 0.0188 0.0787 Composition Misfit: 0.235941E-01 St predicted* 3.340 0.0000 0.0000 0.0031 0.0000 0.1356 0.0070 0.0430 0.0882 0.0023 0.3902 0.3307 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0043 0.0000 -0.0046 -0.0031 -0.0201 -0.0882 -0.0023 0.0584 0.0556 Composition Misfit: 0.350452E-01 Ilm predicted* 0.835 0.0000 0.0000 0.1794 0.0000 0.6728 0.0158 0.0037 0.0000 0.1283 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1706 0.0000 -0.0428 -0.0058 0.0063 0.0000 -0.1283 0.0000 0.0000 Composition Misfit: 0.177948 ky predicted 4.779 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.851 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -768343. CaO 15.215 -751319. TiO2 7.199 -927165. K2O 16.990 -843741. FeO 54.593 -307826. MnO 0.947 -452145. MgO 41.584 -634427. H2O 32.905 -288445. O2 3.004 -406374. Al2O3 111.899 -0.162851E+07 SiO2 727.525 -883715. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 225 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 226 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 227 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 228 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 229 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 230 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 231 converged, 82 successes so far. Misfit function evaluations this try => 245 Misfit this try = 0.161487 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.003290E-06 Bayes score, PP * exp(-Misfit) = 8.536775E-07 Best Bayes score so far = 9.696393E-07 obtained on Try 211 P_bar T_K C_O2 C_H2O Initial coordinates: 6901.81 976.148 5.003113E-02 0.857277 Final coordinates: 9026.53 928.501 0.270704 4.715194E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.139052 Extraneous predicted phases: 2.243436E-02 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 0.005 0.0185 0.0021 0.0000 0.0629 0.0056 0.0000 0.0052 0.1649 0.0004 0.2385 0.5018 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0081 -0.0021 0.0000 0.0215 0.0056 0.0000 0.0084 -0.1649 -0.0004 0.0419 0.0982 Composition Misfit: 0.586832E-01 Gt predicted* 2.264 0.0000 0.0312 0.0000 0.0000 0.3078 0.0250 0.0705 0.0000 0.0022 0.1375 0.4257 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0107 0.0000 0.0000 0.0141 0.0092 -0.0157 0.0000 -0.0022 0.0063 -0.0011 Composition Misfit: 0.114881E-01 Fsp predicted* 27.445 0.0953 0.0564 0.0000 0.0015 0.0000 0.0000 0.0000 0.0000 0.0000 0.1532 0.6936 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0037 -0.0048 0.0000 -0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0077 0.0009 Composition Misfit: 0.949745E-03 Bio predicted* 21.620 0.0000 0.0000 0.0232 0.0671 0.1750 0.0006 0.1571 0.1109 0.0033 0.1200 0.3428 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0018 -0.0001 0.0094 0.0009 0.0124 -0.1109 -0.0033 0.0203 0.0731 Composition Misfit: 0.219874E-01 St predicted* 0.792 0.0000 0.0000 0.0052 0.0000 0.1345 0.0016 0.0479 0.0882 0.0019 0.3898 0.3309 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0021 0.0000 -0.0034 0.0023 -0.0250 -0.0882 -0.0019 0.0587 0.0554 Composition Misfit: 0.353813E-01 Ilm predicted* 0.030 0.0000 0.0000 0.3520 0.0000 0.5670 0.0066 0.0152 0.0000 0.0592 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 -0.0020 0.0000 0.0630 0.0034 -0.0052 0.0000 -0.0592 0.0000 0.0000 Composition Misfit: 0.105627E-01 ky predicted 6.820 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.922 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 ru 0.101 0.0000 0.0000 1.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -774308. CaO 15.215 -753783. TiO2 7.199 -930035. K2O 16.990 -848575. FeO 54.593 -313647. MnO 0.947 -471458. MgO 41.584 -638203. H2O 28.291 -290994. O2 0.924 -417324. Al2O3 111.899 -0.163515E+07 SiO2 727.525 -885549. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 232 converged, 83 successes so far. Misfit function evaluations this try => 177 Misfit this try = 0.333033 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.107470E-06 Bayes score, PP * exp(-Misfit) = 7.937753E-07 Best Bayes score so far = 9.696393E-07 obtained on Try 211 P_bar T_K C_O2 C_H2O Initial coordinates: 13858.9 902.833 0.903380 0.855541 Final coordinates: 9147.64 920.170 0.996328 6.789401E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.333033 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 7.159 0.0211 0.0027 0.0000 0.0600 0.0053 0.0000 0.0055 0.1650 0.0005 0.2391 0.5008 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0107 -0.0027 0.0000 0.0245 0.0059 0.0000 0.0080 -0.1650 -0.0005 0.0414 0.0992 Composition Misfit: 0.631353E-01 Gt predicted* 0.829 0.0000 0.0398 0.0000 0.0000 0.2771 0.0400 0.0811 0.0000 0.0034 0.1345 0.4241 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0192 0.0000 0.0000 0.0449 -0.0058 -0.0263 0.0000 -0.0034 0.0093 0.0005 Composition Misfit: 0.265546E-01 Fsp predicted* 25.923 0.0935 0.0605 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1552 0.6895 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0019 -0.0089 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0057 0.0050 Composition Misfit: 0.159467E-02 Bio predicted* 15.885 0.0000 0.0000 0.0195 0.0665 0.1514 0.0008 0.1877 0.1134 0.0044 0.1146 0.3417 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0018 0.0005 0.0331 0.0006 -0.0182 -0.1134 -0.0044 0.0258 0.0742 Composition Misfit: 0.314708E-01 St predicted* 7.412 0.0000 0.0000 0.0038 0.0000 0.1234 0.0025 0.0608 0.0881 0.0026 0.3885 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0035 0.0000 0.0076 0.0013 -0.0378 -0.0881 -0.0026 0.0600 0.0560 Composition Misfit: 0.468188E-01 Ilm predicted* 1.041 0.0000 0.0000 0.1820 0.0000 0.6786 0.0059 0.0063 0.0000 0.1272 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1680 0.0000 -0.0486 0.0041 0.0037 0.0000 -0.1272 0.0000 0.0000 Composition Misfit: 0.163459 ky predicted 0.068 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.682 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -772199. CaO 15.215 -751512. TiO2 7.199 -930963. K2O 16.990 -847480. FeO 54.593 -313517. MnO 0.947 -466670. MgO 41.584 -636150. H2O 40.736 -289563. O2 3.400 -401980. Al2O3 111.899 -0.163355E+07 SiO2 727.525 -884367. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 233 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 234 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 235 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 236 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 237 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 238 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 239 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 240 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 241 converged, 84 successes so far. Misfit function evaluations this try => 320 Misfit this try = 0.330841 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.106269E-06 Bayes score, PP * exp(-Misfit) = 7.946549E-07 Best Bayes score so far = 9.696393E-07 obtained on Try 211 P_bar T_K C_O2 C_H2O Initial coordinates: 8501.44 966.571 0.913918 0.727198 Final coordinates: 9191.33 921.006 0.990540 6.861879E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.330739 Extraneous predicted phases: 1.019489E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 7.238 0.0212 0.0028 0.0000 0.0599 0.0053 0.0000 0.0056 0.1649 0.0005 0.2390 0.5008 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0108 -0.0028 0.0000 0.0246 0.0059 0.0000 0.0080 -0.1649 -0.0005 0.0414 0.0992 Composition Misfit: 0.631530E-01 Gt predicted* 0.875 0.0000 0.0400 0.0000 0.0000 0.2776 0.0390 0.0814 0.0000 0.0035 0.1345 0.4241 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0195 0.0000 0.0000 0.0443 -0.0047 -0.0266 0.0000 -0.0035 0.0094 0.0005 Composition Misfit: 0.264630E-01 Fsp predicted* 25.882 0.0936 0.0604 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1552 0.6896 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0019 -0.0088 0.0000 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0057 0.0049 Composition Misfit: 0.158071E-02 Bio predicted* 15.826 0.0000 0.0000 0.0196 0.0664 0.1513 0.0008 0.1878 0.1133 0.0044 0.1145 0.3418 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0018 0.0005 0.0332 0.0006 -0.0183 -0.1133 -0.0044 0.0258 0.0741 Composition Misfit: 0.316030E-01 St predicted* 7.420 0.0000 0.0000 0.0038 0.0000 0.1233 0.0024 0.0610 0.0881 0.0026 0.3885 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0035 0.0000 0.0078 0.0014 -0.0380 -0.0881 -0.0026 0.0600 0.0560 Composition Misfit: 0.470169E-01 Ilm predicted* 1.036 0.0000 0.0000 0.1830 0.0000 0.6780 0.0058 0.0064 0.0000 0.1268 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1670 0.0000 -0.0480 0.0042 0.0036 0.0000 -0.1268 0.0000 0.0000 Composition Misfit: 0.160922 ky predicted 0.034 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.658 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.031 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -772200. CaO 15.215 -751498. TiO2 7.199 -930952. K2O 16.990 -847478. FeO 54.593 -313560. MnO 0.947 -466977. MgO 41.584 -636166. H2O 41.171 -289568. O2 3.380 -402018. Al2O3 111.899 -0.163358E+07 SiO2 727.525 -884358. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 242 converged, 85 successes so far. Misfit function evaluations this try => 229 Misfit this try = 0.362972 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 5.604189E-07 Bayes score, PP * exp(-Misfit) = 3.898309E-07 Best Bayes score so far = 9.696393E-07 obtained on Try 211 P_bar T_K C_O2 C_H2O Initial coordinates: 8979.97 813.347 0.695432 0.680436 Final coordinates: 8014.86 849.732 0.991556 5.980258E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.362972 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 4.863 0.0238 0.0020 0.0000 0.0579 0.0036 0.0000 0.0038 0.1655 0.0004 0.2426 0.5004 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0134 -0.0020 0.0000 0.0265 0.0076 0.0000 0.0097 -0.1655 -0.0004 0.0378 0.0996 Composition Misfit: 0.885823E-01 Gt predicted* 0.777 0.0000 0.0464 0.0000 0.0000 0.2779 0.0510 0.0613 0.0000 0.0029 0.1357 0.4248 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0258 0.0000 0.0000 0.0440 -0.0167 -0.0065 0.0000 -0.0029 0.0081 -0.0001 Composition Misfit: 0.280222E-01 Fsp predicted* 26.291 0.0941 0.0601 0.0000 0.0008 0.0000 0.0000 0.0000 0.0000 0.0000 0.1551 0.6899 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0025 -0.0085 0.0000 0.0005 0.0000 0.0000 0.0000 0.0000 0.0000 0.0058 0.0046 Composition Misfit: 0.183518E-02 Bio predicted* 18.043 0.0000 0.0000 0.0181 0.0662 0.1587 0.0008 0.1832 0.1142 0.0043 0.1109 0.3437 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0032 0.0008 0.0258 0.0007 -0.0137 -0.1142 -0.0043 0.0294 0.0723 Composition Misfit: 0.293394E-01 St predicted* 3.568 0.0000 0.0000 0.0035 0.0000 0.1340 0.0026 0.0492 0.0881 0.0024 0.3896 0.3306 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0038 0.0000 -0.0030 0.0012 -0.0263 -0.0881 -0.0024 0.0590 0.0557 Composition Misfit: 0.372010E-01 Ilm predicted* 1.059 0.0000 0.0000 0.1783 0.0000 0.6820 0.0065 0.0045 0.0000 0.1287 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1717 0.0000 -0.0520 0.0035 0.0055 0.0000 -0.1287 0.0000 0.0000 Composition Misfit: 0.177991 ky predicted 4.025 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.373 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -760686. CaO 15.215 -745149. TiO2 7.199 -923686. K2O 16.990 -836203. FeO 54.593 -306087. MnO 0.947 -457054. MgO 41.584 -631984. H2O 35.882 -285432. O2 3.383 -404183. Al2O3 111.899 -0.162507E+07 SiO2 727.525 -879522. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 243 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 244 converged, 86 successes so far. Misfit function evaluations this try => 203 Misfit this try = 0.151246 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 9.206691E-07 Bayes score, PP * exp(-Misfit) = 7.914405E-07 Best Bayes score so far = 9.696393E-07 obtained on Try 211 P_bar T_K C_O2 C_H2O Initial coordinates: 8426.55 951.260 0.541700 0.748335 Final coordinates: 7990.69 897.520 0.499500 5.557636E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.151246 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 1.215 0.0181 0.0018 0.0000 0.0636 0.0050 0.0000 0.0046 0.1651 0.0005 0.2400 0.5014 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0077 -0.0018 0.0000 0.0208 0.0061 0.0000 0.0090 -0.1651 -0.0005 0.0405 0.0986 Composition Misfit: 0.633687E-01 Gt predicted* 0.595 0.0000 0.0315 0.0000 0.0000 0.2855 0.0541 0.0643 0.0000 0.0025 0.1367 0.4253 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0110 0.0000 0.0000 0.0364 -0.0199 -0.0095 0.0000 -0.0025 0.0071 -0.0007 Composition Misfit: 0.174977E-01 Fsp predicted* 27.355 0.0942 0.0590 0.0000 0.0013 0.0000 0.0000 0.0000 0.0000 0.0000 0.1545 0.6910 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0025 -0.0074 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0064 0.0035 Composition Misfit: 0.128462E-02 Bio predicted* 20.551 0.0000 0.0000 0.0211 0.0669 0.1724 0.0011 0.1621 0.1126 0.0041 0.1195 0.3402 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0003 0.0001 0.0121 0.0003 0.0074 -0.1126 -0.0041 0.0208 0.0757 Composition Misfit: 0.217861E-01 St predicted* 4.422 0.0000 0.0000 0.0040 0.0000 0.1356 0.0033 0.0468 0.0881 0.0023 0.3893 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0033 0.0000 -0.0045 0.0005 -0.0239 -0.0881 -0.0023 0.0592 0.0558 Composition Misfit: 0.336046E-01 Ilm predicted* 0.424 0.0000 0.0000 0.2895 0.0000 0.6078 0.0100 0.0086 0.0000 0.0842 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.0605 0.0000 0.0222 0.0000 0.0014 0.0000 -0.0842 0.0000 0.0000 Composition Misfit: 0.137042E-01 ky predicted 3.835 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.603 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -771805. CaO 15.215 -752260. TiO2 7.199 -929345. K2O 16.990 -846212. FeO 54.593 -311468. MnO 0.947 -462595. MgO 41.584 -636670. H2O 33.346 -289871. O2 1.704 -408405. Al2O3 111.899 -0.163247E+07 SiO2 727.525 -884580. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 245 converged, 87 successes so far. Misfit function evaluations this try => 197 Misfit this try = 0.205425 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.036550E-06 Bayes score, PP * exp(-Misfit) = 8.440636E-07 Best Bayes score so far = 9.696393E-07 obtained on Try 211 P_bar T_K C_O2 C_H2O Initial coordinates: 7862.02 906.762 0.869382 5.653848E-02 Final coordinates: 8955.80 924.335 0.643428 6.207347E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.204773 Extraneous predicted phases: 6.523740E-04 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 3.893 0.0193 0.0023 0.0000 0.0620 0.0055 0.0000 0.0054 0.1649 0.0005 0.2387 0.5013 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0089 -0.0023 0.0000 0.0225 0.0056 0.0000 0.0082 -0.1649 -0.0005 0.0418 0.0987 Composition Misfit: 0.595675E-01 Gt predicted* 1.034 0.0000 0.0349 0.0000 0.0000 0.2894 0.0372 0.0751 0.0000 0.0029 0.1357 0.4248 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0143 0.0000 0.0000 0.0325 -0.0030 -0.0203 0.0000 -0.0029 0.0081 -0.0001 Composition Misfit: 0.157377E-01 Fsp predicted* 26.710 0.0941 0.0591 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1545 0.6909 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0024 -0.0075 0.0000 -0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0064 0.0036 Composition Misfit: 0.128785E-02 Bio predicted* 18.344 0.0000 0.0000 0.0215 0.0668 0.1637 0.0008 0.1718 0.1121 0.0041 0.1178 0.3415 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 -0.0001 0.0002 0.0208 0.0006 -0.0023 -0.1121 -0.0041 0.0225 0.0745 Composition Misfit: 0.236884E-01 St predicted* 5.749 0.0000 0.0000 0.0044 0.0000 0.1296 0.0024 0.0539 0.0881 0.0024 0.3888 0.3305 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0029 0.0000 0.0015 0.0015 -0.0310 -0.0881 -0.0024 0.0597 0.0559 Composition Misfit: 0.392397E-01 Ilm predicted* 0.611 0.0000 0.0000 0.2293 0.0000 0.6466 0.0072 0.0085 0.0000 0.1083 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1207 0.0000 -0.0166 0.0028 0.0015 0.0000 -0.1083 0.0000 0.0000 Composition Misfit: 0.652514E-01 ky predicted 2.080 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.500 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 The following predicted phases are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.079 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 -0.0000 0.0000 0.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -773886. CaO 15.215 -752975. TiO2 7.199 -930644. K2O 16.990 -848595. FeO 54.593 -313774. MnO 0.947 -467962. MgO 41.584 -637361. H2O 37.244 -290488. O2 2.195 -407150. Al2O3 111.899 -0.163463E+07 SiO2 727.525 -885258. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 246 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 247 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 248 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 249 converged, 88 successes so far. Misfit function evaluations this try => 184 Misfit this try = 0.307320 Best Misfit so far = 0.132299 obtained on Try 175 Prior probability, PP = 1.166541E-06 Bayes score, PP * exp(-Misfit) = 8.578921E-07 Best Bayes score so far = 9.696393E-07 obtained on Try 211 P_bar T_K C_O2 C_H2O Initial coordinates: 6865.94 922.815 0.944981 0.230559 Final coordinates: 9238.23 914.335 0.924285 6.825352E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions: 0.307320 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Mica predicted* 7.398 0.0220 0.0028 0.0000 0.0591 0.0050 0.0000 0.0054 0.1650 0.0005 0.2395 0.5006 observed* 0.0104 0.0000 0.0000 0.0845 0.0112 0.0000 0.0135 0.0000 0.0000 0.2805 0.6000 residual -0.0117 -0.0028 0.0000 0.0254 0.0061 0.0000 0.0081 -0.1650 -0.0005 0.0410 0.0994 Composition Misfit: 0.663044E-01 Gt predicted* 1.066 0.0000 0.0422 0.0000 0.0000 0.2805 0.0355 0.0797 0.0000 0.0034 0.1345 0.4242 observed* 0.0000 0.0205 0.0000 0.0000 0.3219 0.0342 0.0548 0.0000 0.0000 0.1438 0.4247 residual 0.0000 -0.0216 0.0000 0.0000 0.0414 -0.0013 -0.0249 0.0000 -0.0034 0.0093 0.0005 Composition Misfit: 0.256936E-01 Fsp predicted* 25.743 0.0937 0.0602 0.0000 0.0012 0.0000 0.0000 0.0000 0.0000 0.0000 0.1551 0.6898 observed* 0.0916 0.0516 0.0000 0.0014 0.0000 0.0000 0.0000 0.0000 0.0000 0.1609 0.6945 residual -0.0021 -0.0086 0.0000 0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 0.0058 0.0047 Composition Misfit: 0.154884E-02 Bio predicted* 15.819 0.0000 0.0000 0.0197 0.0664 0.1518 0.0007 0.1876 0.1131 0.0043 0.1137 0.3426 observed* 0.0000 0.0000 0.0214 0.0670 0.1845 0.0014 0.1695 0.0000 0.0000 0.1403 0.4160 residual 0.0000 0.0000 0.0016 0.0005 0.0327 0.0007 -0.0181 -0.1131 -0.0043 0.0266 0.0733 Composition Misfit: 0.315501E-01 St predicted* 7.374 0.0000 0.0000 0.0040 0.0000 0.1242 0.0022 0.0600 0.0881 0.0026 0.3886 0.3303 observed* 0.0000 0.0000 0.0073 0.0000 0.1310 0.0038 0.0229 0.0000 0.0000 0.4485 0.3863 residual 0.0000 0.0000 0.0033 0.0000 0.0068 0.0017 -0.0371 -0.0881 -0.0026 0.0599 0.0560 Composition Misfit: 0.460106E-01 Ilm predicted* 0.978 0.0000 0.0000 0.1926 0.0000 0.6720 0.0056 0.0069 0.0000 0.1230 0.0000 0.0000 observed* 0.0000 0.0000 0.3500 0.0000 0.6300 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 residual 0.0000 0.0000 0.1574 0.0000 -0.0420 0.0044 0.0031 0.0000 -0.1230 0.0000 0.0000 Composition Misfit: 0.136213 ky predicted 0.013 Composition Misfit zero by definition. The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.609 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.0000 Effective Bulk* Chemical Potentials (J/mol) Na2O 24.047 -770402. CaO 15.215 -750403. TiO2 7.199 -929471. K2O 16.990 -845770. FeO 54.593 -312630. MnO 0.947 -466773. MgO 41.584 -635575. H2O 40.952 -288893. O2 3.154 -402808. Al2O3 111.899 -0.163242E+07 SiO2 727.525 -883529. *normalized molar units -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model Try 250 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model perturbation 1 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model perturbation 2 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 2 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 9212.71 912.858 0.347243 6.148712E-02 0.277511 Mean perturbed parameters: 8916.32 916.555 0.379319 5.542162E-02 0.204905 Parameter standard deviation: 592.767 7.39400 6.415068E-02 1.213099E-02 0.145212 -------------------------------------------------------------------------------- After 3 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 9227.07 916.509 0.373387 5.328184E-02 1.71799 Mean perturbed parameters: 9019.91 916.539 0.377342 5.470836E-02 0.709268 Parameter standard deviation: 599.992 5.86018 5.272499E-02 9.015879E-03 1.12595 -------------------------------------------------------------------------------- Although Central model perturbation 5 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 4 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 10036.8 933.444 0.302972 5.388909E-02 1.67341 Mean perturbed parameters: 9274.12 920.765 0.358749 5.450354E-02 0.950304 Parameter standard deviation: 953.481 8.99463 7.597191E-02 7.812809E-03 1.27939 -------------------------------------------------------------------------------- After 5 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 9479.55 904.572 0.428720 6.094115E-02 0.624538 Mean perturbed parameters: 9315.21 917.527 0.372743 5.579107E-02 0.885151 Parameter standard deviation: 930.902 11.0517 6.636148E-02 8.906918E-03 1.13499 -------------------------------------------------------------------------------- Although Central model perturbation 8 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model perturbation 9 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model perturbation 10 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 6 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8363.15 918.361 0.578820 4.035785E-02 0.159407 Mean perturbed parameters: 9156.53 917.666 0.407089 5.321886E-02 0.764193 Parameter standard deviation: 840.506 9.92102 9.554759E-02 8.925265E-03 1.01524 -------------------------------------------------------------------------------- Although Central model perturbation 12 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 7 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8850.32 915.920 0.540070 6.639119E-02 0.318997 Mean perturbed parameters: 9112.79 917.417 0.426087 5.510062E-02 0.700594 Parameter standard deviation: 773.017 9.22762 0.101820 1.071211E-02 0.929913 -------------------------------------------------------------------------------- Although Central model perturbation 14 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model perturbation 15 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 8 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8804.24 919.039 0.558395 6.099241E-02 0.184309 Mean perturbed parameters: 9074.22 917.619 0.442625 5.583710E-02 0.636058 Parameter standard deviation: 719.057 8.55541 0.109423 1.084895E-02 0.861157 -------------------------------------------------------------------------------- Although Central model perturbation 17 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 9 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 9454.23 923.044 0.346586 4.184162E-02 2.25085 Mean perturbed parameters: 9116.44 918.222 0.431954 5.428204E-02 0.815480 Parameter standard deviation: 734.451 8.06351 0.104889 1.049027E-02 1.09997 -------------------------------------------------------------------------------- After 10 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8240.25 918.237 0.531284 4.732086E-02 0.228684 Mean perturbed parameters: 9028.82 918.224 0.441887 5.358593E-02 0.756800 Parameter standard deviation: 703.918 7.63196 0.106660 9.913562E-03 1.03756 -------------------------------------------------------------------------------- After 11 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 9963.64 927.620 0.415952 5.000265E-02 0.275703 Mean perturbed parameters: 9113.81 919.078 0.439529 5.326017E-02 0.713064 Parameter standard deviation: 791.520 7.60599 0.101197 9.407052E-03 0.985356 -------------------------------------------------------------------------------- After 12 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 10170.2 906.458 0.316850 5.352203E-02 3.97396 Mean perturbed parameters: 9201.84 918.026 0.429306 5.328199E-02 0.984805 Parameter standard deviation: 887.705 8.35993 0.100610 9.056796E-03 1.49142 -------------------------------------------------------------------------------- Although Central model perturbation 22 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 13 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8493.56 921.664 0.483760 5.000652E-02 0.171775 Mean perturbed parameters: 9147.35 918.306 0.433495 5.303004E-02 0.922264 Parameter standard deviation: 850.695 8.01440 9.856610E-02 8.673254E-03 1.42797 -------------------------------------------------------------------------------- After 14 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8521.23 855.035 0.367100 6.137389E-02 0.277957 Mean perturbed parameters: 9102.63 913.787 0.428752 5.362602E-02 0.876242 Parameter standard deviation: 817.780 19.6586 9.549278E-02 8.974882E-03 1.37254 -------------------------------------------------------------------------------- Although Central model perturbation 25 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 15 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8622.92 904.877 0.547794 3.674479E-02 0.210133 Mean perturbed parameters: 9070.65 913.193 0.436688 5.250061E-02 0.831835 Parameter standard deviation: 788.033 19.3840 9.897704E-02 9.281997E-03 1.32278 -------------------------------------------------------------------------------- After 16 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 9955.47 917.552 0.335669 6.190997E-02 0.268864 Mean perturbed parameters: 9125.95 913.465 0.430375 5.308869E-02 0.796649 Parameter standard deviation: 835.766 18.7397 9.759941E-02 9.535112E-03 1.27841 -------------------------------------------------------------------------------- After 17 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 9129.00 907.479 0.366719 8.864016E-02 0.246299 Mean perturbed parameters: 9126.13 913.113 0.426630 5.517996E-02 0.764276 Parameter standard deviation: 819.174 18.4235 9.515794E-02 1.347917E-02 1.23815 -------------------------------------------------------------------------------- After 18 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 9531.39 929.938 0.508185 5.977105E-02 2.18517 Mean perturbed parameters: 9148.64 914.048 0.431161 5.543502E-02 0.843215 Parameter standard deviation: 824.887 18.0271 9.525474E-02 1.331845E-02 1.30028 -------------------------------------------------------------------------------- After 19 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 10005.1 919.367 0.413085 4.938454E-02 2.05579 Mean perturbed parameters: 9193.72 914.328 0.430210 5.511657E-02 0.907034 Parameter standard deviation: 865.576 17.5205 9.257183E-02 1.294321E-02 1.34251 -------------------------------------------------------------------------------- Although Central model perturbation 31 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model perturbation 32 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 20 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 7608.97 905.456 0.728966 6.103279E-02 0.201076 Mean perturbed parameters: 9114.48 913.884 0.445147 5.541238E-02 0.871736 Parameter standard deviation: 873.832 17.3877 0.115873 1.287966E-02 1.30680 -------------------------------------------------------------------------------- Although Central model perturbation 34 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 21 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8416.35 926.999 0.405340 6.369925E-02 0.162059 Mean perturbed parameters: 9081.24 914.509 0.443252 5.580699E-02 0.837942 Parameter standard deviation: 852.922 17.0145 0.112947 1.295676E-02 1.27373 -------------------------------------------------------------------------------- Although Central model perturbation 36 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model perturbation 37 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 22 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 9848.08 918.140 0.343661 4.378535E-02 0.463592 Mean perturbed parameters: 9116.09 914.674 0.438725 5.526056E-02 0.820926 Parameter standard deviation: 874.448 16.6108 0.111211 1.270280E-02 1.24513 -------------------------------------------------------------------------------- After 23 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 9921.33 917.620 0.396042 4.993635E-02 0.460305 Mean perturbed parameters: 9151.10 914.802 0.436869 5.502907E-02 0.805247 Parameter standard deviation: 898.267 16.2386 0.108704 1.241136E-02 1.21851 -------------------------------------------------------------------------------- After 24 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8541.71 924.548 0.470648 4.647624E-02 0.237485 Mean perturbed parameters: 9125.71 915.208 0.438277 5.467270E-02 0.781590 Parameter standard deviation: 878.674 15.9069 0.107030 1.215340E-02 1.19193 -------------------------------------------------------------------------------- After 25 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8480.45 911.496 0.627195 5.515824E-02 0.422984 Mean perturbed parameters: 9099.90 915.059 0.445833 5.469212E-02 0.767246 Parameter standard deviation: 860.645 15.6742 0.113660 1.195631E-02 1.16834 -------------------------------------------------------------------------------- After 26 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 9135.06 893.089 0.421767 6.464895E-02 0.680101 Mean perturbed parameters: 9101.25 914.214 0.444908 5.507508E-02 0.763894 Parameter standard deviation: 849.526 16.2901 0.111383 1.210744E-02 1.14997 -------------------------------------------------------------------------------- After 27 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8554.91 910.812 0.374764 6.731839E-02 0.227432 Mean perturbed parameters: 9081.02 914.088 0.442310 5.552853E-02 0.744025 Parameter standard deviation: 833.127 16.0807 0.109456 1.238391E-02 1.12779 -------------------------------------------------------------------------------- Although Central model perturbation 44 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model perturbation 45 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 28 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8642.42 922.820 0.430689 7.312952E-02 0.175505 Mean perturbed parameters: 9065.35 914.400 0.441895 5.615714E-02 0.723721 Parameter standard deviation: 817.564 15.7878 0.107474 1.298513E-02 1.10674 -------------------------------------------------------------------------------- Although Central model perturbation 47 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model perturbation 48 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 29 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8338.60 920.053 0.490928 5.895529E-02 0.166896 Mean perturbed parameters: 9040.29 914.595 0.443586 5.625363E-02 0.704520 Parameter standard deviation: 804.591 15.5034 0.106602 1.287954E-02 1.08682 -------------------------------------------------------------------------------- After 30 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8964.97 915.852 0.380473 5.319100E-02 0.185452 Mean perturbed parameters: 9037.78 914.637 0.441482 5.615154E-02 0.687218 Parameter standard deviation: 793.189 15.2556 0.104905 1.267555E-02 1.06796 -------------------------------------------------------------------------------- After 31 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 9171.59 916.446 0.357605 8.044489E-02 0.287305 Mean perturbed parameters: 9042.10 914.695 0.438776 5.693520E-02 0.674318 Parameter standard deviation: 786.334 15.0153 0.103608 1.369419E-02 1.05039 -------------------------------------------------------------------------------- After 32 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8878.00 923.091 0.519775 4.851786E-02 0.400403 Mean perturbed parameters: 9036.97 914.958 0.441307 5.667216E-02 0.665758 Parameter standard deviation: 774.934 14.7799 0.103766 1.347235E-02 1.03443 -------------------------------------------------------------------------------- After 33 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8755.08 918.266 0.520952 4.735890E-02 0.223991 Mean perturbed parameters: 9028.43 915.058 0.443721 5.638994E-02 0.652371 Parameter standard deviation: 763.104 14.5514 0.103952 1.326487E-02 1.01827 -------------------------------------------------------------------------------- Although Central model perturbation 54 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 34 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8659.97 916.037 0.396252 7.413595E-02 0.212205 Mean perturbed parameters: 9017.59 915.087 0.442325 5.691188E-02 0.639425 Parameter standard deviation: 751.485 14.3480 0.102398 1.375617E-02 1.00282 -------------------------------------------------------------------------------- Although Central model perturbation 56 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 35 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8263.68 893.074 0.553429 7.923402E-02 0.208098 Mean perturbed parameters: 8996.05 914.458 0.445499 5.754965E-02 0.627101 Parameter standard deviation: 742.868 14.8840 0.103781 1.448869E-02 0.988049 -------------------------------------------------------------------------------- After 36 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8444.72 907.087 0.528326 6.343720E-02 0.269208 Mean perturbed parameters: 8980.74 914.253 0.447800 5.771320E-02 0.617160 Parameter standard deviation: 732.778 14.8377 0.104179 1.447720E-02 0.974106 -------------------------------------------------------------------------------- Although Central model perturbation 59 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model perturbation 60 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 37 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 10332.5 925.117 0.729390 5.438745E-02 2.27069 Mean perturbed parameters: 9017.27 914.547 0.455410 5.762331E-02 0.661850 Parameter standard deviation: 776.863 14.6526 0.115589 1.429932E-02 1.02447 -------------------------------------------------------------------------------- After 38 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8423.28 921.307 0.432918 5.956600E-02 0.146481 Mean perturbed parameters: 9001.64 914.725 0.454819 5.767443E-02 0.648287 Parameter standard deviation: 766.974 14.4543 0.114071 1.420428E-02 1.01054 -------------------------------------------------------------------------------- After 39 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8537.03 905.525 0.590193 5.095017E-02 0.222726 Mean perturbed parameters: 8989.73 914.489 0.458290 5.750202E-02 0.637376 Parameter standard deviation: 756.935 14.4615 0.116237 1.401852E-02 0.997259 -------------------------------------------------------------------------------- After 40 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 7909.57 920.803 0.464878 9.357097E-02 0.326152 Mean perturbed parameters: 8962.72 914.647 0.458454 5.840374E-02 0.629595 Parameter standard deviation: 755.777 14.2752 0.115056 1.554371E-02 0.984880 -------------------------------------------------------------------------------- After 41 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 7703.01 914.276 0.467463 7.780598E-02 0.338640 Mean perturbed parameters: 8932.00 914.638 0.458674 5.887697E-02 0.622498 Parameter standard deviation: 760.222 14.1273 0.113954 1.599380E-02 0.973038 -------------------------------------------------------------------------------- After 42 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8359.51 922.960 0.444330 6.776471E-02 0.158019 Mean perturbed parameters: 8918.37 914.836 0.458333 5.908858E-02 0.611439 Parameter standard deviation: 751.994 13.9603 0.112674 1.605702E-02 0.961107 -------------------------------------------------------------------------------- After 43 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 9866.70 922.980 0.447148 4.447908E-02 0.249494 Mean perturbed parameters: 8940.42 915.025 0.458072 5.874882E-02 0.603022 Parameter standard deviation: 767.490 13.7995 0.111461 1.588255E-02 0.949769 -------------------------------------------------------------------------------- After 44 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 10140.3 925.196 0.625294 5.154227E-02 1.86839 Mean perturbed parameters: 8967.69 915.256 0.461873 5.858504E-02 0.631780 Parameter standard deviation: 793.159 13.6590 0.114885 1.570032E-02 0.975282 -------------------------------------------------------------------------------- Although Central model perturbation 69 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model perturbation 70 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 45 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 9095.02 896.792 0.375599 6.705680E-02 0.663374 Mean perturbed parameters: 8970.52 914.846 0.459956 5.877330E-02 0.632483 Parameter standard deviation: 787.358 13.9584 0.113700 1.574861E-02 0.967455 -------------------------------------------------------------------------------- Although Central model perturbation 72 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 46 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8609.40 917.104 0.347678 5.401497E-02 0.266634 Mean perturbed parameters: 8962.67 914.895 0.457515 5.866986E-02 0.624529 Parameter standard deviation: 778.562 13.8104 0.112830 1.558812E-02 0.956854 -------------------------------------------------------------------------------- After 47 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 10058.9 934.496 0.370783 4.895331E-02 2.44706 Mean perturbed parameters: 8986.00 915.312 0.455670 5.846312E-02 0.663307 Parameter standard deviation: 798.746 13.8200 0.111758 1.541787E-02 1.00606 -------------------------------------------------------------------------------- After 48 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8076.04 928.708 0.302276 6.946184E-02 0.127271 Mean perturbed parameters: 8967.04 915.591 0.452474 5.869226E-02 0.652139 Parameter standard deviation: 794.175 13.7277 0.111702 1.553235E-02 0.995295 -------------------------------------------------------------------------------- After 49 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8533.19 922.907 0.290698 3.814282E-02 0.163131 Mean perturbed parameters: 8958.18 915.740 0.449172 5.827289E-02 0.642159 Parameter standard deviation: 785.959 13.5893 0.111897 1.545468E-02 0.984883 -------------------------------------------------------------------------------- After 50 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 10847.6 942.430 0.463507 3.267931E-02 3.64894 Mean perturbed parameters: 8995.97 916.274 0.449459 5.776101E-02 0.702295 Parameter standard deviation: 840.477 13.8181 0.110999 1.548059E-02 1.09662 -------------------------------------------------------------------------------- After 51 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8654.76 911.925 0.425594 5.333105E-02 0.169517 Mean perturbed parameters: 8989.28 916.189 0.448991 5.767415E-02 0.691848 Parameter standard deviation: 832.044 13.7298 0.109902 1.533531E-02 1.08561 -------------------------------------------------------------------------------- Although Central model perturbation 79 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 52 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8623.99 921.955 0.441905 6.181571E-02 0.171921 Mean perturbed parameters: 8982.26 916.300 0.448855 5.775380E-02 0.681850 Parameter standard deviation: 823.847 13.5966 0.108903 1.528412E-02 1.07493 -------------------------------------------------------------------------------- Although Central model perturbation 81 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 53 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 9077.20 914.142 0.314508 5.458131E-02 0.320148 Mean perturbed parameters: 8984.05 916.259 0.446320 5.769394E-02 0.675025 Parameter standard deviation: 818.347 13.4919 0.108684 1.515378E-02 1.06486 -------------------------------------------------------------------------------- Although Central model perturbation 83 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model perturbation 84 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 54 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 9227.25 916.190 0.651937 5.201742E-02 0.223078 Mean perturbed parameters: 8988.55 916.258 0.450128 5.758882E-02 0.666656 Parameter standard deviation: 814.871 13.3756 0.112611 1.501459E-02 1.05484 -------------------------------------------------------------------------------- After 55 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8022.46 877.325 0.329112 8.566597E-02 0.189456 Mean perturbed parameters: 8970.99 915.550 0.447927 5.809931E-02 0.657979 Parameter standard deviation: 811.375 14.4817 0.112124 1.567412E-02 1.04506 -------------------------------------------------------------------------------- After 56 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8627.39 924.404 0.356893 7.205440E-02 0.202028 Mean perturbed parameters: 8964.85 915.708 0.446302 5.834851E-02 0.649837 Parameter standard deviation: 803.965 14.3603 0.111342 1.582968E-02 1.03556 -------------------------------------------------------------------------------- Although Central model perturbation 88 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model perturbation 89 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 57 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 10131.6 941.724 0.388701 4.997113E-02 1.66192 Mean perturbed parameters: 8985.32 916.164 0.445291 5.820154E-02 0.667593 Parameter standard deviation: 821.962 14.5179 0.110385 1.568792E-02 1.04643 -------------------------------------------------------------------------------- Although Central model perturbation 91 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 58 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8557.64 924.691 0.389535 6.372428E-02 0.150991 Mean perturbed parameters: 8977.95 916.311 0.444330 5.829676E-02 0.658686 Parameter standard deviation: 814.762 14.4020 0.109451 1.566572E-02 1.03721 -------------------------------------------------------------------------------- After 59 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8512.68 924.565 0.427223 4.747816E-02 0.190357 Mean perturbed parameters: 8970.06 916.451 0.444040 5.811339E-02 0.650749 Parameter standard deviation: 807.830 14.2885 0.108523 1.553204E-02 1.02826 -------------------------------------------------------------------------------- After 60 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8352.05 929.348 0.374235 6.721440E-02 0.226299 Mean perturbed parameters: 8959.76 916.666 0.442877 5.826508E-02 0.643674 Parameter standard deviation: 801.714 14.2163 0.107709 1.557437E-02 1.01958 -------------------------------------------------------------------------------- After 61 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 8624.54 913.202 0.652310 7.212989E-02 0.207146 Mean perturbed parameters: 8954.26 916.610 0.446310 5.849237E-02 0.636518 Parameter standard deviation: 795.005 14.1267 0.111244 1.572140E-02 1.01110 -------------------------------------------------------------------------------- Although Central model perturbation 96 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Central model perturbation 97 Try 1 converged the result will be rejected because one or more observed phases are not predicted. To use such results set the MC_fit no_missing phases optiion to F. -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 62 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 9037.97 920.018 0.379266 6.854738E-02 0.188587 Mean perturbed parameters: 8955.61 916.665 0.445229 5.865455E-02 0.629294 Parameter standard deviation: 790.276 14.0105 0.110405 1.578443E-02 1.00280 -------------------------------------------------------------------------------- After 63 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 9413.88 923.452 0.350342 4.784061E-02 0.185934 Mean perturbed parameters: 8962.89 916.772 0.443722 5.848290E-02 0.622256 Parameter standard deviation: 790.336 13.9030 0.109785 1.565780E-02 0.994704 -------------------------------------------------------------------------------- After 64 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8619.94 920.252 0.411394 4.935613E-02 0.132299 Perturbed central model parameter: 7930.06 907.715 0.542265 5.848336E-02 0.262995 Mean perturbed parameters: 8946.75 916.631 0.445262 5.848290E-02 0.616643 Parameter standard deviation: 788.841 13.8823 0.110151 1.557554E-02 0.986916