-------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 2 converged, 1 successes so far. Misfit function evaluations this try => 297 Misfit this try = 0.174113 Best Misfit so far = 0.174113 obtained on Try 2 Prior probability, PP = 4.575279E-07 Bayes score, PP * exp(-Misfit) = 3.844157E-07 Best Bayes score so far = 3.844157E-07 obtained on Try 2 P_bar T_K C_O2 C_H2O Initial coordinates: 5474.26 810.966 0.292163 0.731351 Final coordinates: 7386.46 851.162 0.288252 0.533626 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.173100 Extraneous predicted phases: 1.013750E-3 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.980 0.024709 0.022130 0.000000 0.063463 0.002756 0.000000 0.004878 0.301141 0.580924 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 8.3E-03 0. 0. 6.9E-03 2.6E-02 0. 1.5E-02 1.4E-03 6.3E-04 Composition Misfit: 8.046235E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.921 0.000000 0.030357 0.000000 0.000000 0.287796 0.050244 0.065113 0.139266 0.427225 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -2. -1. 0.3 -0.3 Chi 0. 3.2E-03 0. 0. 4.0E-03 5.1E-03 1.6E-03 1.5E-04 1.5E-05 Composition Misfit: 1.410922E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.147 0.095121 0.058417 0.000000 0.000671 0.000000 0.000000 0.000000 0.154208 0.691583 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.3E-04 8.0E-04 0. 7.0E-04 0. 0. 0. 2.9E-04 1.2E-05 Composition Misfit: 1.929883E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.289 0.000000 0.000000 0.012177 0.074998 0.207628 0.000824 0.185678 0.124976 0.393719 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -2. 0.2 -1. 1. 1. Chi 0. 0. 6.9E-03 8.6E-04 2.6E-03 4.4E-04 1.4E-03 1.9E-03 1.3E-03 Composition Misfit: 1.536482E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.415 0.000000 0.000000 0.004639 0.000000 0.147141 0.002753 0.051328 0.430149 0.363990 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 0.9 1. Chi 0. 0. 1.6E-03 0. 1.8E-03 4.3E-04 1.6E-02 7.9E-04 1.4E-03 Composition Misfit: 2.162264E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.662 0.000000 0.000000 0.443556 0.000000 0.530864 0.011554 0.014026 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -5. 0. 5. -0.2 -0.6 0. 0. Chi 0. 0. 2.0E-02 0. 1.9E-02 2.1E-04 1.2E-03 0. 0. Composition Misfit: 3.961078E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.631 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.936 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 ru 0.021 0.000000 0.000000 1.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023279 0.014729 0.006969 0.016447 0.052849 0.000917 0.040256 0.030996 0.000952 0.108324 0.704282 Mica 0.020617 0.018465 0.000000 0.052953 0.002299 0.000000 0.004070 0.165605 0.000000 0.251270 0.484720 Gt 0.000000 0.030309 0.000000 0.000000 0.287344 0.050165 0.065010 0.000000 0.001569 0.139047 0.426554 Fsp 0.095121 0.058417 0.000000 0.000671 0.000000 0.000000 0.000000 0.000000 0.000000 0.154208 0.691583 Bio 0.000000 0.000000 0.010673 0.065732 0.181976 0.000722 0.162738 0.120792 0.002758 0.109535 0.345075 St 0.000000 0.000000 0.004221 0.000000 0.133906 0.002506 0.046711 0.088333 0.001614 0.391458 0.331250 Ilm 0.000000 0.000000 0.431382 0.000000 0.516293 0.011237 0.013641 0.000000 0.027447 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -764663. -748115. -923664. -839196. -306872. -457587. -632738. -287117. -416486. -1626591. -881096. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 7 converged, 2 successes so far. Misfit function evaluations this try => 239 Misfit this try = 1.95040 Best Misfit so far = 0.174113 obtained on Try 2 Prior probability, PP = 8.334271E-08 Bayes score, PP * exp(-Misfit) = 1.185282E-08 Best Bayes score so far = 3.844157E-07 obtained on Try 2 P_bar T_K C_O2 C_H2O Initial coordinates: 5596.30 815.315 0.587327 0.928157 Final coordinates: 6227.05 810.906 0.357882 0.955063 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.95031 Extraneous predicted phases: 8.222088E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 13.910 0.064450 0.043167 0.000000 0.013920 0.000152 0.000000 0.000309 0.320984 0.557017 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -9. 0. 0. 6. 2. 0. 2. -2. 6. Chi 4.5E-02 0. 0. 0.4 0.8 0. 0.6 5.1E-03 3.3E-03 Composition Misfit: 1.81575 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.188 0.000000 0.028345 0.000000 0.000000 0.257490 0.091131 0.056115 0.139577 0.427341 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 4. -6. -0.1 0.3 -0.3 Chi 0. 2.1E-03 0. 0. 1.6E-02 3.6E-02 3.1E-05 1.3E-04 1.7E-05 Composition Misfit: 5.395082E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.105 0.095357 0.058169 0.000000 0.000559 0.000000 0.000000 0.000000 0.154084 0.691831 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.4E-04 7.4E-04 0. 1.1E-03 0. 0. 0. 3.0E-04 1.0E-05 Composition Misfit: 2.341747E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.571 0.000000 0.000000 0.010739 0.075092 0.202383 0.001253 0.192365 0.126385 0.391782 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 4.9E-02 -2. 1. 1. Chi 0. 0. 1.1E-02 8.8E-04 1.6E-03 2.3E-05 2.7E-03 1.5E-03 1.5E-03 Composition Misfit: 1.874940E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.429 0.000000 0.000000 0.003929 0.000000 0.147871 0.004805 0.049164 0.430270 0.363961 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -1. -0.2 -3. 0.9 1. Chi 0. 0. 2.9E-03 0. 1.9E-03 1.9E-04 1.4E-02 7.8E-04 1.4E-03 Composition Misfit: 2.120639E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.745 0.000000 0.000000 0.433016 0.000000 0.534872 0.020250 0.011862 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -5. 0. 4. -2. -0.3 0. 0. Chi 0. 0. 1.6E-02 0. 1.7E-02 5.2E-03 2.9E-04 0. 0. Composition Misfit: 3.831502E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.004 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 43.041 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 ru 0.006 0.000000 0.000000 1.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022718 0.014374 0.006801 0.016051 0.051575 0.000895 0.039285 0.054137 0.001154 0.105712 0.687300 Mica 0.053713 0.035976 0.000000 0.011601 0.000127 0.000000 0.000258 0.166603 0.000000 0.267507 0.464217 Gt 0.000000 0.028305 0.000000 0.000000 0.257121 0.091000 0.056035 0.000000 0.001433 0.139377 0.426729 Fsp 0.095357 0.058169 0.000000 0.000559 0.000000 0.000000 0.000000 0.000000 0.000000 0.154084 0.691831 Bio 0.000000 0.000000 0.009394 0.065687 0.177034 0.001096 0.168271 0.121980 0.003271 0.110555 0.342711 St 0.000000 0.000000 0.003575 0.000000 0.134552 0.004372 0.044736 0.088314 0.001758 0.391514 0.331178 Ilm 0.000000 0.000000 0.418984 0.000000 0.517538 0.019594 0.011477 0.000000 0.032406 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -761230. -746347. -921225. -835726. -304100. -449774. -630890. -285189. -410771. -1623159. -879673. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio F sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio F sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 10 converged, 3 successes so far. Misfit function evaluations this try => 318 Misfit this try = 0.189658 Best Misfit so far = 0.174113 obtained on Try 2 Prior probability, PP = 8.090370E-08 Bayes score, PP * exp(-Misfit) = 6.692696E-08 Best Bayes score so far = 3.844157E-07 obtained on Try 2 P_bar T_K C_O2 C_H2O Initial coordinates: 5530.50 824.246 0.951129 0.820856 Final coordinates: 6621.13 804.013 0.527806 0.542902 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.188707 Extraneous predicted phases: 9.508187E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.620 0.025123 0.020007 0.000000 0.064289 0.001945 0.000000 0.003901 0.302403 0.582332 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 8.7E-03 0. 0. 6.3E-03 4.4E-02 0. 2.4E-02 1.6E-03 5.4E-04 Composition Misfit: 0.104593 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.593 0.000000 0.035249 0.000000 0.000000 0.275069 0.069269 0.055386 0.138201 0.426826 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 3. -4. -0.1 0.4 -0.3 Chi 0. 6.1E-03 0. 0. 8.0E-03 1.8E-02 6.3E-06 2.3E-04 1.1E-05 Composition Misfit: 3.206421E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.971 0.095115 0.058789 0.000000 0.000491 0.000000 0.000000 0.000000 0.154394 0.691211 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.3 0. 0. 0. 0.4 0.1 Chi 1.3E-04 8.8E-04 0. 1.5E-03 0. 0. 0. 2.7E-04 1.6E-05 Composition Misfit: 2.829265E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.880 0.000000 0.000000 0.010179 0.074914 0.206607 0.000893 0.191752 0.123711 0.391944 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.2 -2. 1. 1. Chi 0. 0. 1.2E-02 8.5E-04 2.4E-03 3.2E-04 2.6E-03 2.2E-03 1.5E-03 Composition Misfit: 2.210993E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.049 0.000000 0.000000 0.003432 0.000000 0.152571 0.003395 0.047644 0.429289 0.363669 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. 0.1 -3. 1. 1. Chi 0. 0. 4.4E-03 0. 3.0E-03 5.8E-05 1.3E-02 8.6E-04 1.4E-03 Composition Misfit: 2.262415E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.900 0.000000 0.000000 0.377021 0.000000 0.600075 0.013684 0.009220 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 1. -0.6 0.1 0. 0. Chi 0. 0. 1.9E-03 0. 1.5E-03 9.9E-04 6.6E-05 0. 0. Composition Misfit: 4.486426E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.928 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.041 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.017 0.000000 0.000000 0.175867 0.000000 0.682754 0.008271 0.003455 0.000000 0.129653 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023248 0.014710 0.006960 0.016426 0.052779 0.000916 0.040202 0.031492 0.001741 0.108180 0.703347 Mica 0.020956 0.016689 0.000000 0.053626 0.001623 0.000000 0.003254 0.165854 0.000000 0.252248 0.485750 Gt 0.000000 0.035177 0.000000 0.000000 0.274510 0.069128 0.055274 0.000000 0.002033 0.137921 0.425958 Fsp 0.095115 0.058789 0.000000 0.000491 0.000000 0.000000 0.000000 0.000000 0.000000 0.154394 0.691211 Bio 0.000000 0.000000 0.008898 0.065483 0.180597 0.000780 0.167613 0.122069 0.003821 0.108137 0.342602 St 0.000000 0.000000 0.003122 0.000000 0.138778 0.003088 0.043337 0.088211 0.002195 0.390478 0.330791 Ilm 0.000000 0.000000 0.355181 0.000000 0.565314 0.012891 0.008686 0.000000 0.057928 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -758136. -744036. -920414. -832401. -302623. -450416. -629885. -284222. -404697. -1621313. -878087. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 20 converged, 4 successes so far. Misfit function evaluations this try => 270 Misfit this try = 0.121623 Best Misfit so far = 0.121623 obtained on Try 20 Prior probability, PP = 8.396817E-07 Bayes score, PP * exp(-Misfit) = 7.435228E-07 Best Bayes score so far = 7.435228E-07 obtained on Try 20 P_bar T_K C_O2 C_H2O Initial coordinates: 6968.56 888.318 0.883366 0.164340 Final coordinates: 8194.23 927.877 0.529184 0.521320 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121623 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.162 0.022868 0.024167 0.000000 0.063989 0.004032 0.000000 0.006565 0.298307 0.580072 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.8E-03 0. 0. 6.6E-03 1.3E-02 0. 7.4E-03 1.1E-03 6.8E-04 Composition Misfit: 5.931802E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.933 0.000000 0.024704 0.000000 0.000000 0.284494 0.044487 0.082642 0.137216 0.426456 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 7.0E-04 0. 0. 4.9E-03 2.4E-03 9.4E-03 3.2E-04 7.6E-06 Composition Misfit: 1.769034E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.188 0.094770 0.058300 0.000000 0.001080 0.000000 0.000000 0.000000 0.154150 0.691700 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.7E-04 0. 7.1E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.251624E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.986 0.000000 0.000000 0.013412 0.075309 0.203461 0.001042 0.188404 0.129630 0.388743 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.7E-03 9.3E-04 1.8E-03 1.4E-04 1.9E-03 8.8E-04 1.9E-03 Composition Misfit: 1.223811E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.018 0.000000 0.000000 0.004841 0.000000 0.139924 0.003035 0.060970 0.427816 0.363414 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.7 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.6E-04 2.1E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.824199E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.818 0.000000 0.000000 0.360994 0.000000 0.612006 0.011923 0.015077 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.6 0. 0.8 -0.3 -0.8 0. 0. Chi 0. 0. 3.3E-04 0. 5.3E-04 3.1E-04 1.7E-03 0. 0. Composition Misfit: 2.883349E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.762 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.133 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023277 0.014728 0.006969 0.016446 0.052845 0.000917 0.040252 0.030278 0.001748 0.108315 0.704225 Mica 0.019091 0.020174 0.000000 0.053418 0.003366 0.000000 0.005481 0.165192 0.000000 0.249029 0.484249 Gt 0.000000 0.024644 0.000000 0.000000 0.283793 0.044378 0.082439 0.000000 0.002462 0.136878 0.425406 Fsp 0.094770 0.058300 0.000000 0.001080 0.000000 0.000000 0.000000 0.000000 0.000000 0.154150 0.691700 Bio 0.000000 0.000000 0.011748 0.065968 0.178224 0.000912 0.165035 0.120187 0.003849 0.113551 0.340525 St 0.000000 0.000000 0.004403 0.000000 0.127269 0.002761 0.055456 0.088146 0.002298 0.389123 0.330546 Ilm 0.000000 0.000000 0.337534 0.000000 0.572235 0.011148 0.014097 0.000000 0.064986 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777785. -756396. -932342. -852899. -315223. -467443. -638019. -292750. -408688. -1636789. -887379. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 23 converged, 5 successes so far. Misfit function evaluations this try => 187 Misfit this try = 0.167143 Best Misfit so far = 0.121623 obtained on Try 20 Prior probability, PP = 7.377962E-07 Bayes score, PP * exp(-Misfit) = 6.242335E-07 Best Bayes score so far = 7.435228E-07 obtained on Try 20 P_bar T_K C_O2 C_H2O Initial coordinates: 6906.85 947.298 0.717044 0.931673 Final coordinates: 7803.13 928.245 0.320893 0.670070 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.165254 Extraneous predicted phases: 1.889265E-3 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.348 0.022240 0.022773 0.000000 0.065357 0.003861 0.000000 0.006302 0.298175 0.581292 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 6.3E-03 0. 0. 5.6E-03 1.4E-02 0. 8.3E-03 1.1E-03 6.0E-04 Composition Misfit: 5.846806E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.333 0.000000 0.021265 0.000000 0.000000 0.273966 0.057284 0.081427 0.138952 0.427107 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.1 0. 0. 3. -3. -3. 0.3 -0.3 Chi 0. 2.4E-05 0. 0. 8.4E-03 9.3E-03 8.7E-03 1.7E-04 1.4E-05 Composition Misfit: 2.657839E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.578 0.094635 0.058471 0.000000 0.001130 0.000000 0.000000 0.000000 0.154235 0.691529 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 9.4E-05 8.1E-04 0. 4.6E-05 0. 0. 0. 2.9E-04 1.3E-05 Composition Misfit: 1.248958E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.221 0.000000 0.000000 0.014192 0.075398 0.200896 0.001361 0.187214 0.130969 0.389970 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.9 -1. -1. 1.8E-02 -1. 0.7 1. Chi 0. 0. 3.6E-03 9.5E-04 1.3E-03 3.0E-06 1.7E-03 6.7E-04 1.7E-03 Composition Misfit: 9.990843E-03 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.126 0.000000 0.000000 0.005617 0.000000 0.136694 0.004010 0.060825 0.429058 0.363796 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.3 0. -0.4 -3.6E-02 -5. 1. 1. Chi 0. 0. 5.2E-04 0. 2.3E-04 7.3E-06 2.4E-02 8.9E-04 1.4E-03 Composition Misfit: 2.665443E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.600 0.000000 0.000000 0.434165 0.000000 0.529926 0.016744 0.019165 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -5. 0. 5. -1. -1. 0. 0. Chi 0. 0. 1.6E-02 0. 1.9E-02 2.7E-03 4.4E-03 0. 0. Composition Misfit: 4.231317E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.008 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.658 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.111 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000041 -.000041 0.000000 0.000000 ru 0.017 0.000000 0.000000 1.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023093 0.014612 0.006914 0.016316 0.052428 0.000910 0.039935 0.038611 0.001051 0.107460 0.698670 Mica 0.018565 0.019010 0.000000 0.054556 0.003223 0.000000 0.005260 0.165253 0.000000 0.248901 0.485232 Gt 0.000000 0.021229 0.000000 0.000000 0.273498 0.057187 0.081288 0.000000 0.001706 0.138715 0.426378 Fsp 0.094635 0.058471 0.000000 0.001130 0.000000 0.000000 0.000000 0.000000 0.000000 0.154235 0.691529 Bio 0.000000 0.000000 0.012449 0.066137 0.176220 0.001194 0.164219 0.119825 0.003003 0.114883 0.342071 St 0.000000 0.000000 0.005112 0.000000 0.124393 0.003649 0.055351 0.088282 0.001707 0.390448 0.331058 Ilm 0.000000 0.000000 0.420329 0.000000 0.513038 0.016211 0.018554 0.000000 0.031868 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -779562. -757717. -932135. -854828. -315790. -465916. -638502. -293345. -418348. -1637694. -888317. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 27 converged, 6 successes so far. Misfit function evaluations this try => 155 Misfit this try = 0.121190 Best Misfit so far = 0.121190 obtained on Try 27 Prior probability, PP = 8.334841E-07 Bayes score, PP * exp(-Misfit) = 7.383550E-07 Best Bayes score so far = 7.435228E-07 obtained on Try 20 P_bar T_K C_O2 C_H2O Initial coordinates: 6365.52 929.894 0.697280 0.466721 Final coordinates: 8263.70 930.210 0.536759 0.523221 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121190 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.324 0.022957 0.024393 0.000000 0.063774 0.004082 0.000000 0.006648 0.298247 0.579899 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.9E-03 0. 0. 6.7E-03 1.2E-02 0. 7.2E-03 1.1E-03 7.0E-04 Composition Misfit: 5.918702E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.982 0.000000 0.024779 0.000000 0.000000 0.285168 0.042949 0.083536 0.137140 0.426427 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 7.2E-04 0. 0. 4.7E-03 1.8E-03 9.9E-03 3.3E-04 7.3E-06 Composition Misfit: 1.744499E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.138 0.094816 0.058192 0.000000 0.001088 0.000000 0.000000 0.000000 0.154096 0.691808 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.5E-04 0. 6.7E-05 0. 0. 0. 3.0E-04 1.0E-05 Composition Misfit: 1.231046E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.872 0.000000 0.000000 0.013469 0.075299 0.202946 0.001015 0.188983 0.129490 0.388798 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.3E-04 1.7E-03 1.7E-04 2.0E-03 9.0E-04 1.9E-03 Composition Misfit: 1.221106E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.030 0.000000 0.000000 0.004862 0.000000 0.139603 0.002937 0.061433 0.427763 0.363403 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.2E-04 2.8E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.864494E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.826 0.000000 0.000000 0.357928 0.000000 0.615389 0.011553 0.015130 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.4 0. 0.7 -0.2 -0.8 0. 0. Chi 0. 0. 1.8E-04 0. 3.5E-04 2.1E-04 1.7E-03 0. 0. Composition Misfit: 2.470831E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.705 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.122 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023274 0.014726 0.006968 0.016444 0.052837 0.000917 0.040247 0.030385 0.001773 0.108300 0.704130 Mica 0.019165 0.020364 0.000000 0.053240 0.003408 0.000000 0.005550 0.165174 0.000000 0.248985 0.484115 Gt 0.000000 0.024717 0.000000 0.000000 0.284457 0.042842 0.083328 0.000000 0.002495 0.136798 0.425364 Fsp 0.094816 0.058192 0.000000 0.001088 0.000000 0.000000 0.000000 0.000000 0.000000 0.154096 0.691808 Bio 0.000000 0.000000 0.011799 0.065963 0.177784 0.000889 0.165552 0.120128 0.003858 0.113435 0.340593 St 0.000000 0.000000 0.004422 0.000000 0.126976 0.002672 0.055876 0.088142 0.002310 0.389071 0.330532 Ilm 0.000000 0.000000 0.334189 0.000000 0.574573 0.010787 0.014127 0.000000 0.066324 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777993. -756519. -932515. -853135. -315425. -467948. -638110. -292856. -408582. -1637014. -887474. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 30 converged, 7 successes so far. Misfit function evaluations this try => 293 Misfit this try = 0.132191 Best Misfit so far = 0.121190 obtained on Try 27 Prior probability, PP = 8.694199E-07 Bayes score, PP * exp(-Misfit) = 7.617630E-07 Best Bayes score so far = 7.617630E-07 obtained on Try 30 P_bar T_K C_O2 C_H2O Initial coordinates: 6716.70 842.863 0.933160 0.157192 Final coordinates: 8448.86 930.742 0.542442 0.641860 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.132191 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.795 0.024346 0.025607 0.000000 0.061784 0.003924 0.000000 0.006737 0.298944 0.578657 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 8.0E-03 0. 0. 8.3E-03 1.3E-02 0. 6.9E-03 1.1E-03 7.9E-04 Composition Misfit: 6.410072E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.839 0.000000 0.025496 0.000000 0.000000 0.282333 0.041629 0.087150 0.137012 0.426380 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -0.8 -3. 0.5 -0.2 Chi 0. 9.6E-04 0. 0. 5.5E-03 1.3E-03 1.2E-02 3.4E-04 7.0E-06 Composition Misfit: 2.017838E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.058 0.095282 0.057318 0.000000 0.001059 0.000000 0.000000 0.000000 0.153659 0.692682 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.4E-04 5.7E-04 0. 8.4E-05 0. 0. 0. 3.4E-04 4.8E-06 Composition Misfit: 1.139590E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.446 0.000000 0.000000 0.013618 0.075204 0.196499 0.000975 0.196084 0.128065 0.389553 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.8 0.1 -2. 0.9 1. Chi 0. 0. 4.4E-03 9.1E-04 7.4E-04 2.1E-04 3.6E-03 1.2E-03 1.8E-03 Composition Misfit: 1.281913E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.412 0.000000 0.000000 0.004976 0.000000 0.136644 0.002826 0.064494 0.427671 0.363389 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.4 0.2 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 2.3E-04 3.6E-04 2.7E-02 1.0E-03 1.4E-03 Composition Misfit: 3.096170E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.832 0.000000 0.000000 0.358293 0.000000 0.614402 0.011298 0.016007 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.5 0. 0.7 -0.2 -1. 0. 0. Chi 0. 0. 1.9E-04 0. 4.0E-04 1.5E-04 2.3E-03 0. 0. Composition Misfit: 2.991194E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.137 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.481 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023114 0.014625 0.006920 0.016331 0.052475 0.000911 0.039971 0.037018 0.001779 0.107557 0.699299 Mica 0.020325 0.021377 0.000000 0.051578 0.003276 0.000000 0.005624 0.165183 0.000000 0.249563 0.483073 Gt 0.000000 0.025431 0.000000 0.000000 0.281613 0.041523 0.086927 0.000000 0.002551 0.136663 0.425292 Fsp 0.095282 0.057318 0.000000 0.001059 0.000000 0.000000 0.000000 0.000000 0.000000 0.153659 0.692682 Bio 0.000000 0.000000 0.011933 0.065900 0.172187 0.000855 0.171823 0.119866 0.003861 0.112220 0.341355 St 0.000000 0.000000 0.004526 0.000000 0.124285 0.002570 0.058660 0.088139 0.002309 0.388989 0.330521 Ilm 0.000000 0.000000 0.334586 0.000000 0.573750 0.010550 0.014948 0.000000 0.066166 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777249. -756087. -932073. -852704. -315415. -468094. -637687. -292542. -407774. -1636698. -887108. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 34 converged, 8 successes so far. Misfit function evaluations this try => 226 Misfit this try = 0.180345 Best Misfit so far = 0.121190 obtained on Try 27 Prior probability, PP = 2.701533E-07 Bayes score, PP * exp(-Misfit) = 2.255731E-07 Best Bayes score so far = 7.617630E-07 obtained on Try 30 P_bar T_K C_O2 C_H2O Initial coordinates: 6884.72 845.172 0.325950 0.111934 Final coordinates: 7319.94 830.153 0.340010 0.537207 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.180345 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.531 0.026406 0.022592 0.000000 0.061623 0.002357 0.000000 0.004390 0.302525 0.580106 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 2. 1. 0. 1. -1. 3. Chi 9.8E-03 0. 0. 8.5E-03 3.3E-02 0. 1.9E-02 1.6E-03 6.8E-04 Composition Misfit: 9.504038E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.017 0.000000 0.034937 0.000000 0.000000 0.289743 0.048189 0.061436 0.138687 0.427008 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -2. -0.6 0.4 -0.3 Chi 0. 5.9E-03 0. 0. 3.6E-03 4.0E-03 7.2E-04 1.9E-04 1.3E-05 Composition Misfit: 1.445511E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.925 0.095400 0.058065 0.000000 0.000567 0.000000 0.000000 0.000000 0.154033 0.691935 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.5E-04 7.2E-04 0. 1.1E-03 0. 0. 0. 3.1E-04 9.5E-06 Composition Misfit: 2.285666E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.983 0.000000 0.000000 0.011431 0.074854 0.207086 0.000705 0.188935 0.122810 0.394178 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -2. 0.2 -1. 1. 1. Chi 0. 0. 8.6E-03 8.3E-04 2.5E-03 7.3E-04 2.0E-03 2.5E-03 1.2E-03 Composition Misfit: 1.836890E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.010 0.000000 0.000000 0.004187 0.000000 0.149851 0.002454 0.049760 0.429868 0.363881 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -3. 1. 1. Chi 0. 0. 2.4E-03 0. 2.4E-03 7.8E-04 1.4E-02 8.1E-04 1.4E-03 Composition Misfit: 2.216699E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.758 0.000000 0.000000 0.430278 0.000000 0.547041 0.010290 0.012392 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -4. 0. 4. -4.6E-02 -0.4 0. 0. Chi 0. 0. 1.5E-02 0. 1.3E-02 8.1E-06 4.6E-04 0. 0. Composition Misfit: 2.802842E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.913 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.863 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023270 0.014724 0.006967 0.016441 0.052829 0.000917 0.040240 0.031192 0.001123 0.108283 0.704015 Mica 0.022030 0.018848 0.000000 0.051411 0.001966 0.000000 0.003663 0.165729 0.000000 0.252388 0.483966 Gt 0.000000 0.034874 0.000000 0.000000 0.289215 0.048101 0.061324 0.000000 0.001821 0.138435 0.426230 Fsp 0.095400 0.058065 0.000000 0.000567 0.000000 0.000000 0.000000 0.000000 0.000000 0.154033 0.691935 Bio 0.000000 0.000000 0.010012 0.065560 0.181373 0.000617 0.165476 0.121107 0.003061 0.107561 0.345234 St 0.000000 0.000000 0.003810 0.000000 0.136348 0.002233 0.045276 0.088291 0.001819 0.391132 0.331091 Ilm 0.000000 0.000000 0.415783 0.000000 0.528613 0.009943 0.011974 0.000000 0.033687 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -760506. -745420. -921548. -834915. -304552. -455347. -631094. -285389. -411647. -1623605. -879105. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 39 converged, 9 successes so far. Misfit function evaluations this try => 153 Misfit this try = 0.121155 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 8.282433E-07 Bayes score, PP * exp(-Misfit) = 7.337383E-07 Best Bayes score so far = 7.617630E-07 obtained on Try 30 P_bar T_K C_O2 C_H2O Initial coordinates: 6118.90 928.832 0.721554 0.323346 Final coordinates: 8270.38 930.878 0.535352 0.523453 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121155 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.327 0.022933 0.024411 0.000000 0.063785 0.004096 0.000000 0.006665 0.298217 0.579893 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.9E-03 0. 0. 6.7E-03 1.2E-02 0. 7.1E-03 1.1E-03 7.0E-04 Composition Misfit: 5.903355E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.984 0.000000 0.024730 0.000000 0.000000 0.285163 0.042860 0.083684 0.137137 0.426426 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -0.9 -3. 0.5 -0.2 Chi 0. 7.1E-04 0. 0. 4.7E-03 1.7E-03 1.0E-02 3.3E-04 7.3E-06 Composition Misfit: 1.748332E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.138 0.094814 0.058189 0.000000 0.001092 0.000000 0.000000 0.000000 0.154094 0.691811 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.5E-04 0. 6.5E-05 0. 0. 0. 3.0E-04 1.0E-05 Composition Misfit: 1.228163E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.868 0.000000 0.000000 0.013488 0.075302 0.202943 0.001015 0.188945 0.129523 0.388785 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.3E-04 1.7E-03 1.7E-04 2.0E-03 9.0E-04 1.9E-03 Composition Misfit: 1.217063E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.048 0.000000 0.000000 0.004870 0.000000 0.139532 0.002936 0.061502 0.427757 0.363402 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 5.2E-04 2.8E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.868663E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.824 0.000000 0.000000 0.358380 0.000000 0.614874 0.011552 0.015194 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.5 0. 0.7 -0.2 -0.8 0. 0. Chi 0. 0. 2.0E-04 0. 3.7E-04 2.1E-04 1.8E-03 0. 0. Composition Misfit: 2.552213E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.688 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.124 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023274 0.014726 0.006968 0.016444 0.052837 0.000917 0.040246 0.030398 0.001768 0.108299 0.704124 Mica 0.019145 0.020379 0.000000 0.053250 0.003419 0.000000 0.005564 0.165169 0.000000 0.248960 0.484113 Gt 0.000000 0.024668 0.000000 0.000000 0.284451 0.042753 0.083475 0.000000 0.002496 0.136795 0.425362 Fsp 0.094814 0.058189 0.000000 0.001092 0.000000 0.000000 0.000000 0.000000 0.000000 0.154094 0.691811 Bio 0.000000 0.000000 0.011816 0.065966 0.177783 0.000889 0.165521 0.120116 0.003856 0.113466 0.340586 St 0.000000 0.000000 0.004430 0.000000 0.126911 0.002671 0.055939 0.088142 0.002309 0.389066 0.330532 Ilm 0.000000 0.000000 0.334682 0.000000 0.574214 0.010788 0.014190 0.000000 0.066127 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778112. -756593. -932584. -853255. -315497. -468052. -638161. -292909. -408636. -1637107. -887532. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Sp Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Sp Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 42 converged, 10 successes so far. Misfit function evaluations this try => 184 Misfit this try = 0.171068 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 1.844584E-07 Bayes score, PP * exp(-Misfit) = 1.554549E-07 Best Bayes score so far = 7.617630E-07 obtained on Try 30 P_bar T_K C_O2 C_H2O Initial coordinates: 5854.86 823.473 0.527823 0.148680 Final coordinates: 6927.99 823.289 0.514838 0.539401 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.171068 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.527 0.025251 0.021026 0.000000 0.063592 0.002201 0.000000 0.004244 0.302134 0.581552 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 8.8E-03 0. 0. 6.8E-03 3.6E-02 0. 2.0E-02 1.6E-03 5.9E-04 Composition Misfit: 9.560536E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.658 0.000000 0.033734 0.000000 0.000000 0.278623 0.063321 0.059540 0.138023 0.426759 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -3. -0.5 0.4 -0.2 Chi 0. 5.2E-03 0. 0. 6.7E-03 1.3E-02 3.8E-04 2.4E-04 1.0E-05 Composition Misfit: 2.586514E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.994 0.095105 0.058673 0.000000 0.000558 0.000000 0.000000 0.000000 0.154337 0.691327 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.3E-04 8.5E-04 0. 1.1E-03 0. 0. 0. 2.8E-04 1.5E-05 Composition Misfit: 2.419421E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.934 0.000000 0.000000 0.010706 0.074968 0.206378 0.000906 0.190972 0.124513 0.391558 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 1. 1. Chi 0. 0. 1.1E-02 8.6E-04 2.3E-03 3.0E-04 2.4E-03 2.0E-03 1.5E-03 Composition Misfit: 2.003239E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.028 0.000000 0.000000 0.003663 0.000000 0.150614 0.003279 0.049765 0.429051 0.363628 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -1. 0.1 -3. 1. 1. Chi 0. 0. 3.7E-03 0. 2.5E-03 9.6E-05 1.4E-02 8.9E-04 1.4E-03 Composition Misfit: 2.308670E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.891 0.000000 0.000000 0.376383 0.000000 0.600399 0.013139 0.010080 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 1. -0.5 -1.3E-02 0. 0. Chi 0. 0. 1.8E-03 0. 1.5E-03 7.5E-04 6.3E-07 0. 0. Composition Misfit: 4.059161E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.924 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.044 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023254 0.014713 0.006962 0.016430 0.052792 0.000916 0.040212 0.031297 0.001699 0.108206 0.703520 Mica 0.021065 0.017541 0.000000 0.053050 0.001836 0.000000 0.003541 0.165770 0.000000 0.252049 0.485148 Gt 0.000000 0.033663 0.000000 0.000000 0.278035 0.063188 0.059414 0.000000 0.002110 0.137732 0.425858 Fsp 0.095105 0.058673 0.000000 0.000558 0.000000 0.000000 0.000000 0.000000 0.000000 0.154337 0.691327 Bio 0.000000 0.000000 0.009362 0.065555 0.180466 0.000792 0.166995 0.121748 0.003805 0.108880 0.342397 St 0.000000 0.000000 0.003332 0.000000 0.136996 0.002983 0.045266 0.088201 0.002211 0.390260 0.330752 Ilm 0.000000 0.000000 0.354473 0.000000 0.565449 0.012374 0.009493 0.000000 0.058211 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -760799. -745703. -922051. -835228. -304423. -453022. -631023. -285379. -405318. -1623445. -879309. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Mica Bio ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Mica Bio ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 51 converged, 11 successes so far. Misfit function evaluations this try => 285 Misfit this try = 0.135774 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 8.732665E-07 Bayes score, PP * exp(-Misfit) = 7.623963E-07 Best Bayes score so far = 7.623963E-07 obtained on Try 51 P_bar T_K C_O2 C_H2O Initial coordinates: 13076.1 929.625 0.935667 0.147851 Final coordinates: 8450.85 930.421 0.566349 0.672799 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.135774 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.664 0.024689 0.025811 0.000000 0.061350 0.003844 0.000000 0.006715 0.299180 0.578412 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 8.3E-03 0. 0. 8.7E-03 1.4E-02 0. 6.9E-03 1.2E-03 8.1E-04 Composition Misfit: 6.566945E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.734 0.000000 0.025506 0.000000 0.000000 0.280366 0.042932 0.087879 0.136958 0.426359 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 9.6E-04 0. 0. 6.2E-03 1.8E-03 1.2E-02 3.5E-04 6.8E-06 Composition Misfit: 2.168675E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.781 0.095358 0.057178 0.000000 0.001053 0.000000 0.000000 0.000000 0.153589 0.692822 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.5 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.4E-04 5.5E-04 0. 8.8E-05 0. 0. 0. 3.5E-04 4.1E-06 Composition Misfit: 1.129345E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.854 0.000000 0.000000 0.013595 0.075192 0.194647 0.001005 0.198128 0.127882 0.389552 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.7 0.1 -2. 0.9 1. Chi 0. 0. 4.4E-03 9.0E-04 5.3E-04 1.8E-04 4.1E-03 1.2E-03 1.8E-03 Composition Misfit: 1.318358E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.529 0.000000 0.000000 0.004960 0.000000 0.135761 0.002921 0.065359 0.427623 0.363375 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.3 0.2 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 1.6E-04 2.9E-04 2.8E-02 1.0E-03 1.4E-03 Composition Misfit: 3.160409E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.853 0.000000 0.000000 0.350901 0.000000 0.621611 0.011651 0.015838 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -4.9E-02 0. 0.4 -0.3 -0.9 0. 0. Chi 0. 0. 2.3E-06 0. 1.1E-04 2.3E-04 2.2E-03 0. 0. Composition Misfit: 2.501112E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.983 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.602 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023071 0.014598 0.006907 0.016301 0.052377 0.000909 0.039896 0.038731 0.001854 0.107357 0.697998 Mica 0.020610 0.021547 0.000000 0.051215 0.003209 0.000000 0.005606 0.165198 0.000000 0.249756 0.482860 Gt 0.000000 0.025440 0.000000 0.000000 0.279644 0.042821 0.087653 0.000000 0.002574 0.136606 0.425262 Fsp 0.095358 0.057178 0.000000 0.001053 0.000000 0.000000 0.000000 0.000000 0.000000 0.153589 0.692822 Bio 0.000000 0.000000 0.011913 0.065886 0.170556 0.000880 0.173607 0.119860 0.003904 0.112055 0.341340 St 0.000000 0.000000 0.004511 0.000000 0.123480 0.002657 0.059446 0.088134 0.002329 0.388939 0.330503 Ilm 0.000000 0.000000 0.326557 0.000000 0.578485 0.010842 0.014739 0.000000 0.069377 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777159. -756051. -932041. -852704. -315436. -467807. -637593. -292484. -407216. -1636643. -887068. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 55 converged, 12 successes so far. Misfit function evaluations this try => 245 Misfit this try = 0.219949 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 7.678818E-07 Bayes score, PP * exp(-Misfit) = 6.162709E-07 Best Bayes score so far = 7.623963E-07 obtained on Try 51 P_bar T_K C_O2 C_H2O Initial coordinates: 6910.01 950.883 0.174231 0.890255 Final coordinates: 7913.22 928.046 0.460063 0.870108 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.151044 Extraneous predicted phases: 6.890536E-2 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.367 0.023132 0.023565 0.000000 0.064079 0.003701 0.000000 0.006367 0.298694 0.580462 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.1E-03 0. 0. 6.5E-03 1.5E-02 0. 8.1E-03 1.1E-03 6.6E-04 Composition Misfit: 6.198097E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.190 0.000000 0.022421 0.000000 0.000000 0.270218 0.058773 0.084055 0.137842 0.426691 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.2 0. 0. 3. -3. -3. 0.4 -0.2 Chi 0. 1.6E-04 0. 0. 9.9E-03 1.0E-02 1.0E-02 2.6E-04 9.7E-06 Composition Misfit: 3.073929E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.760 0.094858 0.058079 0.000000 0.001103 0.000000 0.000000 0.000000 0.154039 0.691921 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.2E-04 0. 5.9E-05 0. 0. 0. 3.1E-04 9.6E-06 Composition Misfit: 1.206100E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.640 0.000000 0.000000 0.013703 0.075351 0.196443 0.001388 0.194137 0.130263 0.388715 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.8 1.0E-02 -2. 0.7 1. Chi 0. 0. 4.3E-03 9.4E-04 7.3E-04 9.4E-07 3.1E-03 7.8E-04 1.9E-03 Composition Misfit: 1.176048E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.891 0.000000 0.000000 0.005124 0.000000 0.135570 0.004122 0.063572 0.428101 0.363511 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.3 -0.1 -5. 1. 1. Chi 0. 0. 9.5E-04 0. 1.5E-04 1.9E-05 2.6E-02 9.8E-04 1.4E-03 Composition Misfit: 2.951376E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.731 0.000000 0.000000 0.391565 0.000000 0.574101 0.016831 0.017502 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 3. -1. -1. 0. 0. Chi 0. 0. 4.4E-03 0. 5.4E-03 2.8E-03 3.2E-03 0. 0. Composition Misfit: 1.584318E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.000 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.563 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Melt 0.032 0.033299 0.010302 0.008364 0.013001 0.002492 0.000000 0.001647 0.380463 0.000254 0.058334 0.491842 F 0.826 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000024 -.000024 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022820 0.014439 0.006832 0.016123 0.051807 0.000899 0.039462 0.049544 0.001490 0.106188 0.690397 Mica 0.019309 0.019671 0.000000 0.053489 0.003089 0.000000 0.005315 0.165266 0.000000 0.249330 0.484531 Gt 0.000000 0.022372 0.000000 0.000000 0.269627 0.058645 0.083871 0.000000 0.002189 0.137540 0.425756 Fsp 0.094858 0.058079 0.000000 0.001103 0.000000 0.000000 0.000000 0.000000 0.000000 0.154039 0.691921 Bio 0.000000 0.000000 0.012007 0.066026 0.172132 0.001217 0.170111 0.120044 0.003715 0.114142 0.340608 St 0.000000 0.000000 0.004661 0.000000 0.123325 0.003749 0.057831 0.088181 0.002136 0.389436 0.330680 Ilm 0.000000 0.000000 0.371427 0.000000 0.544576 0.015965 0.016602 0.000000 0.051429 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -779014. -757371. -932422. -854497. -315848. -465602. -638176. -293092. -410229. -1637424. -888043. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 56 converged, 13 successes so far. Misfit function evaluations this try => 172 Misfit this try = 0.121176 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 8.222239E-07 Bayes score, PP * exp(-Misfit) = 7.283898E-07 Best Bayes score so far = 7.623963E-07 obtained on Try 51 P_bar T_K C_O2 C_H2O Initial coordinates: 12411.0 822.826 0.286763 0.664874 Final coordinates: 8244.03 930.873 0.550937 0.522688 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121176 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.292 0.022879 0.024315 0.000000 0.063890 0.004081 0.000000 0.006648 0.298210 0.579977 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.9E-03 0. 0. 6.6E-03 1.2E-02 0. 7.2E-03 1.1E-03 6.9E-04 Composition Misfit: 5.895880E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.945 0.000000 0.024600 0.000000 0.000000 0.284408 0.043848 0.083611 0.137115 0.426418 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 6.7E-04 0. 0. 4.9E-03 2.1E-03 9.9E-03 3.3E-04 7.3E-06 Composition Misfit: 1.798539E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.153 0.094782 0.058245 0.000000 0.001095 0.000000 0.000000 0.000000 0.154122 0.691755 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.6E-04 0. 6.3E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.234281E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.888 0.000000 0.000000 0.013452 0.075310 0.202824 0.001041 0.189073 0.129657 0.388643 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.7E-03 9.3E-04 1.7E-03 1.4E-04 2.0E-03 8.8E-04 1.9E-03 Composition Misfit: 1.220558E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.023 0.000000 0.000000 0.004837 0.000000 0.139493 0.003011 0.061534 0.427732 0.363393 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.1E-04 2.3E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.870621E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.837 0.000000 0.000000 0.353076 0.000000 0.620193 0.011794 0.014936 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.2 0. 0.5 -0.3 -0.8 0. 0. Chi 0. 0. 2.7E-05 0. 1.6E-04 2.7E-04 1.6E-03 0. 0. Composition Misfit: 2.086134E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.723 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.139 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023273 0.014726 0.006968 0.016444 0.052837 0.000917 0.040246 0.030353 0.001819 0.108299 0.704119 Mica 0.019100 0.020299 0.000000 0.053337 0.003407 0.000000 0.005550 0.165174 0.000000 0.248953 0.484180 Gt 0.000000 0.024539 0.000000 0.000000 0.283695 0.043738 0.083402 0.000000 0.002506 0.136771 0.425349 Fsp 0.094782 0.058245 0.000000 0.001095 0.000000 0.000000 0.000000 0.000000 0.000000 0.154122 0.691755 Bio 0.000000 0.000000 0.011784 0.065969 0.177666 0.000911 0.165621 0.120154 0.003886 0.113574 0.340435 St 0.000000 0.000000 0.004399 0.000000 0.126874 0.002738 0.055968 0.088138 0.002326 0.389038 0.330519 Ilm 0.000000 0.000000 0.328914 0.000000 0.577751 0.010987 0.013914 0.000000 0.068434 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778229. -756673. -932673. -853378. -315543. -467892. -638190. -292946. -408389. -1637163. -887592. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 60 converged, 14 successes so far. Misfit function evaluations this try => 152 Misfit this try = 0.149841 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 6.185301E-07 Bayes score, PP * exp(-Misfit) = 5.324585E-07 Best Bayes score so far = 7.623963E-07 obtained on Try 51 P_bar T_K C_O2 C_H2O Initial coordinates: 7239.91 828.723 0.690915 0.264764 Final coordinates: 7536.11 865.626 0.412552 0.531462 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.149841 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.169 0.024572 0.022625 0.000000 0.063308 0.002925 0.000000 0.005147 0.300819 0.580603 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 8.2E-03 0. 0. 7.1E-03 2.3E-02 0. 1.4E-02 1.4E-03 6.5E-04 Composition Misfit: 7.680379E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.856 0.000000 0.029786 0.000000 0.000000 0.285520 0.051209 0.068525 0.138152 0.426807 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -2. -1. 0.4 -0.3 Chi 0. 2.9E-03 0. 0. 4.6E-03 5.6E-03 2.8E-03 2.3E-04 1.1E-05 Composition Misfit: 1.611948E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.110 0.095046 0.058438 0.000000 0.000735 0.000000 0.000000 0.000000 0.154219 0.691562 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.2E-04 8.0E-04 0. 5.3E-04 0. 0. 0. 2.9E-04 1.2E-05 Composition Misfit: 1.751035E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.127 0.000000 0.000000 0.012111 0.075082 0.206464 0.000904 0.187785 0.126237 0.391415 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 1. 1. Chi 0. 0. 7.1E-03 8.8E-04 2.3E-03 3.0E-04 1.8E-03 1.6E-03 1.5E-03 Composition Misfit: 1.548184E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.171 0.000000 0.000000 0.004395 0.000000 0.146290 0.002958 0.053722 0.428966 0.363669 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 2.0E-03 0. 1.6E-03 2.6E-04 1.8E-02 8.9E-04 1.4E-03 Composition Misfit: 2.376816E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.772 0.000000 0.000000 0.406755 0.000000 0.567843 0.012025 0.013377 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -3. 0. 3. -0.3 -0.5 0. 0. Chi 0. 0. 7.9E-03 0. 6.8E-03 3.4E-04 8.5E-04 0. 0. Composition Misfit: 1.591659E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.771 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.024 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023272 0.014725 0.006967 0.016443 0.052834 0.000917 0.040244 0.030861 0.001362 0.108293 0.704082 Mica 0.020504 0.018880 0.000000 0.052828 0.002441 0.000000 0.004295 0.165544 0.000000 0.251020 0.484488 Gt 0.000000 0.029725 0.000000 0.000000 0.284934 0.051104 0.068384 0.000000 0.002054 0.137869 0.425930 Fsp 0.095046 0.058438 0.000000 0.000735 0.000000 0.000000 0.000000 0.000000 0.000000 0.154219 0.691562 Bio 0.000000 0.000000 0.010605 0.065746 0.180789 0.000792 0.164433 0.120886 0.003470 0.110539 0.342741 St 0.000000 0.000000 0.003999 0.000000 0.133084 0.002691 0.048872 0.088224 0.002050 0.390242 0.330839 Ilm 0.000000 0.000000 0.388636 0.000000 0.542548 0.011490 0.012781 0.000000 0.044546 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -767095. -749659. -925576. -841795. -308496. -459113. -633705. -288137. -409721. -1628458. -882250. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 64 converged, 15 successes so far. Misfit function evaluations this try => 224 Misfit this try = 0.127942 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 8.368046E-07 Bayes score, PP * exp(-Misfit) = 7.363082E-07 Best Bayes score so far = 7.623963E-07 obtained on Try 51 P_bar T_K C_O2 C_H2O Initial coordinates: 5600.00 833.254 0.444909 0.232517 Final coordinates: 8270.87 930.045 0.516731 0.595559 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.127942 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.175 0.023409 0.024657 0.000000 0.063201 0.003976 0.000000 0.006641 0.298526 0.579590 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.3E-03 0. 0. 7.2E-03 1.3E-02 0. 7.2E-03 1.1E-03 7.2E-04 Composition Misfit: 6.103806E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.784 0.000000 0.024623 0.000000 0.000000 0.281980 0.044923 0.084767 0.137241 0.426465 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 6.7E-04 0. 0. 5.7E-03 2.5E-03 1.1E-02 3.2E-04 7.7E-06 Composition Misfit: 1.979076E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.593 0.094966 0.057908 0.000000 0.001080 0.000000 0.000000 0.000000 0.153954 0.692092 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.2E-04 6.9E-04 0. 7.1E-05 0. 0. 0. 3.1E-04 8.4E-06 Composition Misfit: 1.196757E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.527 0.000000 0.000000 0.013579 0.075275 0.199868 0.001058 0.192016 0.129125 0.389080 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -2. 0.8 1. Chi 0. 0. 4.5E-03 9.2E-04 1.2E-03 1.3E-04 2.6E-03 9.7E-04 1.9E-03 Composition Misfit: 1.216324E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.956 0.000000 0.000000 0.004961 0.000000 0.138012 0.003077 0.062726 0.427803 0.363421 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.5 0.2 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 3.5E-04 1.9E-04 2.5E-02 1.0E-03 1.4E-03 Composition Misfit: 2.937221E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.804 0.000000 0.000000 0.366741 0.000000 0.605139 0.012210 0.015910 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.9 0. 1. -0.4 -0.9 0. 0. Chi 0. 0. 7.6E-04 0. 1.0E-03 4.0E-04 2.2E-03 0. 0. Composition Misfit: 4.380824E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.777 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.383 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023178 0.014665 0.006939 0.016376 0.052620 0.000913 0.040081 0.034443 0.001699 0.107854 0.701230 Mica 0.019542 0.020584 0.000000 0.052761 0.003319 0.000000 0.005544 0.165189 0.000000 0.249213 0.483848 Gt 0.000000 0.024563 0.000000 0.000000 0.281289 0.044813 0.084559 0.000000 0.002451 0.136905 0.425420 Fsp 0.094966 0.057908 0.000000 0.001080 0.000000 0.000000 0.000000 0.000000 0.000000 0.153954 0.692092 Bio 0.000000 0.000000 0.011897 0.065954 0.175118 0.000927 0.168238 0.120010 0.003820 0.113135 0.340900 St 0.000000 0.000000 0.004512 0.000000 0.125533 0.002798 0.057054 0.088149 0.002272 0.389121 0.330560 Ilm 0.000000 0.000000 0.343832 0.000000 0.567338 0.011447 0.014916 0.000000 0.062467 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777904. -756504. -932336. -853190. -315477. -467598. -637988. -292791. -408685. -1636972. -887440. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 65 converged, 16 successes so far. Misfit function evaluations this try => 617 Misfit this try = 3.23675 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 9.643359E-07 Bayes score, PP * exp(-Misfit) = 3.789020E-08 Best Bayes score so far = 7.623963E-07 obtained on Try 51 P_bar T_K C_O2 C_H2O Initial coordinates: 8697.66 920.532 0.907204 0.910744 Final coordinates: 8927.08 930.478 0.909473 0.911230 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.229598 Extraneous predicted phases: 3.00715 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 9.453 0.030382 0.030734 0.000000 0.053295 0.003219 0.000000 0.006340 0.302941 0.573089 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 3. 1. 0. 1. -1. 3. Chi 1.3E-02 0. 0. 1.8E-02 2.0E-02 0. 8.2E-03 1.7E-03 1.3E-03 Composition Misfit: 9.284113E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.940 0.000000 0.028332 0.000000 0.000000 0.275700 0.037096 0.096395 0.136347 0.426130 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 3. -0.3 -4. 0.5 -0.2 Chi 0. 2.1E-03 0. 0. 7.7E-03 2.2E-04 1.8E-02 4.1E-04 5.1E-06 Composition Misfit: 2.847477E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 22.967 0.096046 0.055986 0.000000 0.000961 0.000000 0.000000 0.000000 0.152993 0.694014 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.4 -0.4 0. 0.1 0. 0. 0. 0.5 2.2E-02 Chi 2.0E-04 3.4E-04 0. 1.6E-04 0. 0. 0. 4.1E-04 3.4E-07 Composition Misfit: 1.117664E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.572 0.000000 0.000000 0.013720 0.074967 0.180782 0.000842 0.214017 0.124509 0.391163 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. 0.2 0.2 -3. 1. 1. Chi 0. 0. 4.3E-03 8.6E-04 7.5E-05 4.0E-04 9.3E-03 2.0E-03 1.6E-03 Composition Misfit: 1.842846E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.237 0.000000 0.000000 0.005042 0.000000 0.129320 0.002453 0.072561 0.427319 0.363305 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. 0.1 0.3 -6. 1. 1. Chi 0. 0. 1.0E-03 0. 2.3E-05 7.8E-04 3.4E-02 1.1E-03 1.5E-03 Composition Misfit: 3.830741E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.156 0.000000 0.000000 0.253064 0.000000 0.726271 0.008669 0.011996 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. 0.2 -0.3 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 2.0E-04 3.3E-04 0. 0. Composition Misfit: 5.042855E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.355 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.028 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Melt 2.294 0.034933 0.010440 0.009937 0.011793 0.002868 0.000000 0.002127 0.398437 0.000305 0.058912 0.470247 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022734 0.014384 0.006806 0.016062 0.051611 0.000896 0.039313 0.051689 0.002934 0.105786 0.687786 Mica 0.025359 0.025653 0.000000 0.044483 0.002687 0.000000 0.005291 0.165337 0.000000 0.252853 0.478336 Gt 0.000000 0.028252 0.000000 0.000000 0.274917 0.036990 0.096121 0.000000 0.002840 0.135960 0.424920 Fsp 0.096046 0.055986 0.000000 0.000961 0.000000 0.000000 0.000000 0.000000 0.000000 0.152993 0.694014 Bio 0.000000 0.000000 0.012027 0.065717 0.158474 0.000738 0.187608 0.119406 0.003988 0.109145 0.342896 St 0.000000 0.000000 0.004585 0.000000 0.117614 0.002231 0.065993 0.088112 0.002404 0.388640 0.330420 Ilm 0.000000 0.000000 0.225253 0.000000 0.646455 0.007716 0.010677 0.000000 0.109899 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775030. -754633. -931045. -851248. -315203. -468516. -636485. -291608. -404300. -1635619. -885983. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 66 converged, 17 successes so far. Misfit function evaluations this try => 136 Misfit this try = 0.123750 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 8.507985E-07 Bayes score, PP * exp(-Misfit) = 7.517660E-07 Best Bayes score so far = 7.623963E-07 obtained on Try 51 P_bar T_K C_O2 C_H2O Initial coordinates: 12697.3 845.684 0.523110 0.603215 Final coordinates: 8383.04 931.143 0.519459 0.551897 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.123750 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.272 0.023413 0.024936 0.000000 0.063036 0.004090 0.000000 0.006735 0.298396 0.579394 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.3E-03 0. 0. 7.3E-03 1.2E-02 0. 6.9E-03 1.1E-03 7.3E-04 Composition Misfit: 6.040033E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.052 0.000000 0.025249 0.000000 0.000000 0.286171 0.040211 0.084871 0.137090 0.426409 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -0.7 -3. 0.5 -0.2 Chi 0. 8.8E-04 0. 0. 4.5E-03 8.8E-04 1.1E-02 3.3E-04 7.2E-06 Composition Misfit: 1.722277E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.842 0.095007 0.057828 0.000000 0.001079 0.000000 0.000000 0.000000 0.153914 0.692172 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.2E-04 6.7E-04 0. 7.2E-05 0. 0. 0. 3.2E-04 7.8E-06 Composition Misfit: 1.187159E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.208 0.000000 0.000000 0.013585 0.075255 0.201278 0.000949 0.190844 0.128830 0.389258 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.5E-03 9.2E-04 1.4E-03 2.4E-04 2.4E-03 1.0E-03 1.8E-03 Composition Misfit: 1.225409E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.048 0.000000 0.000000 0.004946 0.000000 0.138901 0.002732 0.062254 0.427759 0.363409 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 4.4E-04 4.5E-04 2.5E-02 1.0E-03 1.4E-03 Composition Misfit: 2.934004E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.813 0.000000 0.000000 0.364099 0.000000 0.609454 0.010778 0.015669 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.8 0. 0.9 -0.1 -0.9 0. 0. Chi 0. 0. 5.5E-04 0. 6.9E-04 5.6E-05 2.1E-03 0. 0. Composition Misfit: 3.345814E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.598 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.167 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023236 0.014702 0.006957 0.016417 0.052753 0.000915 0.040182 0.031998 0.001713 0.108126 0.702999 Mica 0.019546 0.020817 0.000000 0.052625 0.003414 0.000000 0.005623 0.165161 0.000000 0.249112 0.483701 Gt 0.000000 0.025185 0.000000 0.000000 0.285451 0.040110 0.084657 0.000000 0.002517 0.136745 0.425335 Fsp 0.095007 0.057828 0.000000 0.001079 0.000000 0.000000 0.000000 0.000000 0.000000 0.153914 0.692172 Bio 0.000000 0.000000 0.011903 0.065940 0.176363 0.000832 0.167220 0.119976 0.003811 0.112883 0.341072 St 0.000000 0.000000 0.004499 0.000000 0.126339 0.002485 0.056624 0.088145 0.002289 0.389075 0.330544 Ilm 0.000000 0.000000 0.340932 0.000000 0.570676 0.010092 0.014672 0.000000 0.063627 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777660. -756301. -932314. -852882. -315409. -468463. -637976. -292743. -408691. -1636906. -887302. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 68 converged, 18 successes so far. Misfit function evaluations this try => 194 Misfit this try = 0.121893 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 8.625892E-07 Bayes score, PP * exp(-Misfit) = 7.636014E-07 Best Bayes score so far = 7.636014E-07 obtained on Try 68 P_bar T_K C_O2 C_H2O Initial coordinates: 7891.16 916.888 0.832655 0.728486 Final coordinates: 8226.99 926.258 0.537160 0.523681 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121893 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.339 0.023104 0.024337 0.000000 0.063671 0.004002 0.000000 0.006556 0.298444 0.579886 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.0E-03 0. 0. 6.8E-03 1.3E-02 0. 7.5E-03 1.1E-03 7.0E-04 Composition Misfit: 6.017772E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.975 0.000000 0.025119 0.000000 0.000000 0.285201 0.043390 0.082701 0.137155 0.426433 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 8.3E-04 0. 0. 4.7E-03 1.9E-03 9.4E-03 3.3E-04 7.4E-06 Composition Misfit: 1.723521E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.128 0.094838 0.058200 0.000000 0.001062 0.000000 0.000000 0.000000 0.154100 0.691800 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.5E-04 0. 8.2E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.249286E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.873 0.000000 0.000000 0.013368 0.075285 0.203040 0.001008 0.189113 0.129278 0.388909 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.8E-03 9.2E-04 1.7E-03 1.7E-04 2.0E-03 9.4E-04 1.9E-03 Composition Misfit: 1.243393E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.012 0.000000 0.000000 0.004812 0.000000 0.139989 0.002939 0.061057 0.427796 0.363407 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.7 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.7E-04 2.8E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.842721E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.829 0.000000 0.000000 0.358226 0.000000 0.615301 0.011559 0.014914 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.5 0. 0.7 -0.2 -0.8 0. 0. Chi 0. 0. 1.9E-04 0. 3.5E-04 2.1E-04 1.6E-03 0. 0. Composition Misfit: 2.369313E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.727 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.117 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023273 0.014726 0.006968 0.016443 0.052836 0.000917 0.040246 0.030410 0.001774 0.108297 0.704110 Mica 0.019288 0.020317 0.000000 0.053153 0.003341 0.000000 0.005473 0.165198 0.000000 0.249141 0.484090 Gt 0.000000 0.025057 0.000000 0.000000 0.284492 0.043282 0.082495 0.000000 0.002489 0.136814 0.425372 Fsp 0.094838 0.058200 0.000000 0.001062 0.000000 0.000000 0.000000 0.000000 0.000000 0.154100 0.691800 Bio 0.000000 0.000000 0.011710 0.065947 0.177855 0.000883 0.165655 0.120184 0.003858 0.113242 0.340668 St 0.000000 0.000000 0.004377 0.000000 0.127326 0.002673 0.055534 0.088143 0.002312 0.389100 0.330535 Ilm 0.000000 0.000000 0.334514 0.000000 0.574571 0.010794 0.013927 0.000000 0.066194 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777277. -756069. -932091. -852405. -314990. -467392. -637819. -292545. -408397. -1636458. -887127. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 71 converged, 19 successes so far. Misfit function evaluations this try => 228 Misfit this try = 0.167467 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 2.289143E-07 Bayes score, PP * exp(-Misfit) = 1.936167E-07 Best Bayes score so far = 7.636014E-07 obtained on Try 68 P_bar T_K C_O2 C_H2O Initial coordinates: 8741.21 812.934 0.918267 0.234843 Final coordinates: 6973.91 829.879 0.482783 0.536205 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.167467 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.298 0.024858 0.020998 0.000000 0.063974 0.002315 0.000000 0.004383 0.301792 0.581681 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 8.5E-03 0. 0. 6.6E-03 3.4E-02 0. 1.9E-02 1.5E-03 5.8E-04 Composition Misfit: 9.101898E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.657 0.000000 0.032545 0.000000 0.000000 0.278924 0.062922 0.060668 0.138139 0.426802 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -3. -0.6 0.4 -0.3 Chi 0. 4.4E-03 0. 0. 6.6E-03 1.3E-02 5.7E-04 2.3E-04 1.1E-05 Composition Misfit: 2.493227E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.070 0.095052 0.058719 0.000000 0.000588 0.000000 0.000000 0.000000 0.154360 0.691281 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.2E-04 8.6E-04 0. 1.0E-03 0. 0. 0. 2.8E-04 1.5E-05 Composition Misfit: 2.285961E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.078 0.000000 0.000000 0.010933 0.075007 0.206966 0.000932 0.189651 0.125106 0.391404 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 1. 1. Chi 0. 0. 1.0E-02 8.7E-04 2.4E-03 2.6E-04 2.1E-03 1.8E-03 1.5E-03 Composition Misfit: 1.905466E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.062 0.000000 0.000000 0.003781 0.000000 0.150038 0.003323 0.050129 0.429083 0.363647 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -1. 0.1 -3. 1. 1. Chi 0. 0. 3.3E-03 0. 2.4E-03 8.0E-05 1.5E-02 8.8E-04 1.4E-03 Composition Misfit: 2.287589E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.856 0.000000 0.000000 0.386902 0.000000 0.588955 0.013418 0.010726 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. -0.5 -0.1 0. 0. Chi 0. 0. 3.5E-03 0. 2.9E-03 8.7E-04 4.9E-05 0. 0. Composition Misfit: 7.299674E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.928 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.051 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023260 0.014718 0.006964 0.016434 0.052807 0.000916 0.040224 0.031121 0.001593 0.108238 0.703725 Mica 0.020738 0.017518 0.000000 0.053371 0.001931 0.000000 0.003656 0.165735 0.000000 0.251774 0.485276 Gt 0.000000 0.032478 0.000000 0.000000 0.278349 0.062793 0.060544 0.000000 0.002060 0.137854 0.425923 Fsp 0.095052 0.058719 0.000000 0.000588 0.000000 0.000000 0.000000 0.000000 0.000000 0.154360 0.691281 Bio 0.000000 0.000000 0.009562 0.065603 0.181017 0.000815 0.165873 0.121644 0.003734 0.109421 0.342331 St 0.000000 0.000000 0.003439 0.000000 0.136478 0.003023 0.045598 0.088208 0.002171 0.390303 0.330781 Ilm 0.000000 0.000000 0.366194 0.000000 0.557433 0.012699 0.010152 0.000000 0.053522 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -761980. -746467. -922658. -836434. -305106. -453818. -631513. -285881. -406255. -1624314. -879868. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 72 converged, 20 successes so far. Misfit function evaluations this try => 201 Misfit this try = 2.09968 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 1.317276E-07 Bayes score, PP * exp(-Misfit) = 1.613609E-08 Best Bayes score so far = 7.636014E-07 obtained on Try 68 P_bar T_K C_O2 C_H2O Initial coordinates: 5922.21 871.059 0.936424 0.365649 Final coordinates: 6289.65 823.605 0.909505 0.693103 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.264737 Extraneous predicted phases: 1.83494 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.418 0.027715 0.021412 0.000000 0.061053 0.001594 0.000000 0.003664 0.303871 0.580691 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 2. 1. 0. 1. -1. 2. Chi 1.1E-02 0. 0. 9.0E-03 0.1 0. 2.7E-02 1.8E-03 6.4E-04 Composition Misfit: 0.127694 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.000000 0.027363 0.000000 0.000000 0.242082 0.101076 0.063857 0.138634 0.426988 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.9 0. 0. 4. -7. -0.9 0.4 -0.3 Chi 0. 1.7E-03 0. 0. 2.6E-02 4.4E-02 1.3E-03 2.0E-04 1.3E-05 Composition Misfit: 7.370662E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.489 0.094874 0.059131 0.000000 0.000561 0.000000 0.000000 0.000000 0.154565 0.690869 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.4 0.2 Chi 1.1E-04 9.6E-04 0. 1.1E-03 0. 0. 0. 2.6E-04 1.9E-05 Composition Misfit: 2.480721E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.500 0.000000 0.000000 0.010703 0.075070 0.186163 0.001466 0.210688 0.126056 0.389854 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.1 -1.2E-02 -3. 1. 1. Chi 0. 0. 1.1E-02 8.8E-04 1.5E-05 1.1E-06 8.0E-03 1.6E-03 1.7E-03 Composition Misfit: 2.292616E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.327 0.000000 0.000000 0.003752 0.000000 0.140195 0.005696 0.057742 0.428993 0.363621 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -0.7 -0.4 -4. 1. 1. Chi 0. 0. 3.4E-03 0. 6.0E-04 6.1E-04 2.1E-02 8.9E-04 1.4E-03 Composition Misfit: 2.791609E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.476 0.000000 0.000000 0.366361 0.000000 0.599065 0.023216 0.011358 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.9 0. 1. -2. -0.2 0. 0. Chi 0. 0. 7.3E-04 0. 1.6E-03 7.5E-03 1.6E-04 0. 0. Composition Misfit: 1.001409E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.138 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.847 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.767 0.000000 0.000000 0.189140 0.000000 0.666941 0.014747 0.004828 0.000000 0.124344 0.000000 0.000000 Mica 0.037 0.054810 0.037966 0.000000 0.009508 0.000117 0.000000 0.000270 0.166602 0.000000 0.268499 0.462228 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023018 0.014565 0.006891 0.016263 0.052258 0.000907 0.039805 0.039808 0.002971 0.107112 0.696402 Mica 0.023116 0.017859 0.000000 0.050922 0.001330 0.000000 0.003056 0.165936 0.000000 0.253448 0.484334 Gt 0.000000 0.027313 0.000000 0.000000 0.241635 0.100889 0.063739 0.000000 0.001844 0.138379 0.426200 Fsp 0.094874 0.059131 0.000000 0.000561 0.000000 0.000000 0.000000 0.000000 0.000000 0.154565 0.690869 Bio 0.000000 0.000000 0.009354 0.065608 0.162697 0.001281 0.184131 0.121862 0.004187 0.110167 0.340713 St 0.000000 0.000000 0.003413 0.000000 0.127521 0.005181 0.052522 0.088199 0.002206 0.390210 0.330748 Ilm 0.000000 0.000000 0.343414 0.000000 0.561543 0.021762 0.010646 0.000000 0.062634 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -763637. -747827. -922931. -839276. -305940. -450516. -631252. -286035. -403109. -1624873. -880801. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 79 converged, 21 successes so far. Misfit function evaluations this try => 267 Misfit this try = 0.126023 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 7.875074E-07 Bayes score, PP * exp(-Misfit) = 6.942622E-07 Best Bayes score so far = 7.636014E-07 obtained on Try 68 P_bar T_K C_O2 C_H2O Initial coordinates: 5888.94 816.643 0.435238 0.730301 Final coordinates: 8070.72 930.222 0.446552 0.512388 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.126023 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.463 0.022178 0.023441 0.000000 0.065041 0.004109 0.000000 0.006503 0.297925 0.580804 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 6.3E-03 0. 0. 5.8E-03 1.2E-02 0. 7.6E-03 1.0E-03 6.3E-04 Composition Misfit: 5.690642E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.851 0.000000 0.023459 0.000000 0.000000 0.283851 0.047049 0.081359 0.137660 0.426622 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.4 0. 0. 2. -1. -3. 0.4 -0.2 Chi 0. 3.6E-04 0. 0. 5.1E-03 3.5E-03 8.7E-03 2.8E-04 9.0E-06 Composition Misfit: 1.791005E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.401 0.094583 0.058597 0.000000 0.001119 0.000000 0.000000 0.000000 0.154298 0.691403 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 9.1E-05 8.4E-04 0. 5.1E-05 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 1.274490E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.462 0.000000 0.000000 0.013661 0.075370 0.205533 0.001124 0.185011 0.130543 0.388759 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.7 1. Chi 0. 0. 4.3E-03 9.4E-04 2.2E-03 8.1E-05 1.3E-03 7.3E-04 1.9E-03 Composition Misfit: 1.145690E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.045 0.000000 0.000000 0.005043 0.000000 0.140290 0.003249 0.059789 0.428120 0.363509 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.7 0.1 -5. 1. 1. Chi 0. 0. 1.0E-03 0. 6.1E-04 1.1E-04 2.3E-02 9.7E-04 1.4E-03 Composition Misfit: 2.688513E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.738 0.000000 0.000000 0.390455 0.000000 0.580247 0.012969 0.016329 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. -0.5 -1. 0. 0. Chi 0. 0. 4.2E-03 0. 4.3E-03 6.8E-04 2.5E-03 0. 0. Composition Misfit: 1.159011E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.887 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.154 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023295 0.014740 0.006974 0.016459 0.052886 0.000918 0.040284 0.029783 0.001476 0.108401 0.704783 Mica 0.018514 0.019569 0.000000 0.054297 0.003430 0.000000 0.005429 0.165190 0.000000 0.248710 0.484861 Gt 0.000000 0.023406 0.000000 0.000000 0.283207 0.046943 0.081175 0.000000 0.002269 0.137347 0.425654 Fsp 0.094583 0.058597 0.000000 0.001119 0.000000 0.000000 0.000000 0.000000 0.000000 0.154298 0.691403 Bio 0.000000 0.000000 0.011971 0.066043 0.180099 0.000985 0.162117 0.120115 0.003630 0.114389 0.340652 St 0.000000 0.000000 0.004588 0.000000 0.127618 0.002956 0.054388 0.088179 0.002151 0.389448 0.330673 Ilm 0.000000 0.000000 0.370179 0.000000 0.550116 0.012295 0.015481 0.000000 0.051928 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778858. -757108. -932619. -853889. -315599. -467420. -638473. -293184. -411288. -1637434. -887919. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 81 converged, 22 successes so far. Misfit function evaluations this try => 196 Misfit this try = 0.137112 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 7.406274E-07 Bayes score, PP * exp(-Misfit) = 6.457329E-07 Best Bayes score so far = 7.636014E-07 obtained on Try 68 P_bar T_K C_O2 C_H2O Initial coordinates: 13531.5 836.829 0.914639 7.632803E-02 Final coordinates: 7603.37 879.713 0.499096 0.526771 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.137112 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.098 0.024012 0.022720 0.000000 0.063774 0.003118 0.000000 0.005422 0.300258 0.580696 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 7.8E-03 0. 0. 6.7E-03 2.1E-02 0. 1.2E-02 1.3E-03 6.4E-04 Composition Misfit: 7.203352E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.767 0.000000 0.028131 0.000000 0.000000 0.282604 0.053382 0.071520 0.137718 0.426644 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -2. -2. 0.4 -0.2 Chi 0. 2.0E-03 0. 0. 5.5E-03 6.9E-03 3.9E-03 2.7E-04 9.3E-06 Composition Misfit: 1.856471E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.161 0.094904 0.058568 0.000000 0.000811 0.000000 0.000000 0.000000 0.154284 0.691432 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.1E-04 8.3E-04 0. 3.7E-04 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 1.606870E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.136 0.000000 0.000000 0.012224 0.075173 0.205517 0.001014 0.188493 0.127599 0.389979 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.9 1. Chi 0. 0. 6.8E-03 9.0E-04 2.2E-03 1.7E-04 1.9E-03 1.3E-03 1.7E-03 Composition Misfit: 1.496736E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.009 0.000000 0.000000 0.004338 0.000000 0.144933 0.003233 0.055523 0.428442 0.363531 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.1 -4. 1. 1. Chi 0. 0. 2.1E-03 0. 1.3E-03 1.1E-04 1.9E-02 9.4E-04 1.4E-03 Composition Misfit: 2.501596E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.828 0.000000 0.000000 0.376526 0.000000 0.597670 0.012879 0.012925 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 1. -0.5 -0.5 0. 0. Chi 0. 0. 1.9E-03 0. 1.7E-03 6.4E-04 6.6E-04 0. 0. Composition Misfit: 4.923266E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.902 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.098 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023272 0.014725 0.006967 0.016443 0.052833 0.000917 0.040244 0.030588 0.001648 0.108291 0.704072 Mica 0.020039 0.018960 0.000000 0.053221 0.002602 0.000000 0.004525 0.165479 0.000000 0.250572 0.484603 Gt 0.000000 0.028068 0.000000 0.000000 0.281970 0.053262 0.071359 0.000000 0.002243 0.137410 0.425687 Fsp 0.094904 0.058568 0.000000 0.000811 0.000000 0.000000 0.000000 0.000000 0.000000 0.154284 0.691432 Bio 0.000000 0.000000 0.010700 0.065801 0.179893 0.000887 0.164992 0.120901 0.003779 0.111690 0.341357 St 0.000000 0.000000 0.003946 0.000000 0.131830 0.002941 0.050503 0.088177 0.002230 0.389708 0.330665 Ilm 0.000000 0.000000 0.354632 0.000000 0.562917 0.012130 0.012174 0.000000 0.058147 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -769835. -751420. -927438. -844667. -310150. -460506. -634763. -289273. -407601. -1630474. -883571. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio F sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio F sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 86 converged, 23 successes so far. Misfit function evaluations this try => 249 Misfit this try = 0.190402 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 7.354429E-08 Bayes score, PP * exp(-Misfit) = 6.079367E-08 Best Bayes score so far = 7.636014E-07 obtained on Try 68 P_bar T_K C_O2 C_H2O Initial coordinates: 6091.29 811.511 0.269649 8.930930E-02 Final coordinates: 6610.38 801.708 0.477667 0.541784 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.190402 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.475 0.024966 0.019847 0.000000 0.064526 0.001948 0.000000 0.003890 0.302335 0.582488 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 8.5E-03 0. 0. 6.2E-03 4.4E-02 0. 2.4E-02 1.6E-03 5.3E-04 Composition Misfit: 0.104155 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.620 0.000000 0.035590 0.000000 0.000000 0.276616 0.067972 0.054640 0.138315 0.426868 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 3. -4. 1.5E-02 0.4 -0.3 Chi 0. 6.4E-03 0. 0. 7.4E-03 1.7E-02 4.4E-07 2.2E-04 1.1E-05 Composition Misfit: 3.074241E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.008 0.095135 0.058762 0.000000 0.000484 0.000000 0.000000 0.000000 0.154381 0.691238 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.3 0. 0. 0. 0.5 0.1 Chi 1.3E-04 8.7E-04 0. 1.6E-03 0. 0. 0. 2.7E-04 1.5E-05 Composition Misfit: 2.871415E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.986 0.000000 0.000000 0.010198 0.074899 0.207567 0.000867 0.190667 0.123478 0.392325 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -2. 0.2 -1. 1. 1. Chi 0. 0. 1.2E-02 8.4E-04 2.6E-03 3.6E-04 2.3E-03 2.3E-03 1.4E-03 Composition Misfit: 2.207182E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.085 0.000000 0.000000 0.003457 0.000000 0.153101 0.003300 0.046989 0.429443 0.363711 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. 0.1 -3. 1. 1. Chi 0. 0. 4.3E-03 0. 3.2E-03 8.8E-05 1.2E-02 8.5E-04 1.4E-03 Composition Misfit: 2.218645E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.876 0.000000 0.000000 0.390736 0.000000 0.586397 0.013389 0.009478 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. -0.5 0.1 0. 0. Chi 0. 0. 4.2E-03 0. 3.2E-03 8.6E-04 2.9E-05 0. 0. Composition Misfit: 8.375616E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.935 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.014 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023253 0.014713 0.006962 0.016429 0.052791 0.000916 0.040211 0.031435 0.001576 0.108205 0.703509 Mica 0.020826 0.016555 0.000000 0.053824 0.001625 0.000000 0.003245 0.165855 0.000000 0.252191 0.485879 Gt 0.000000 0.035520 0.000000 0.000000 0.276067 0.067837 0.054532 0.000000 0.001983 0.138040 0.426021 Fsp 0.095135 0.058762 0.000000 0.000484 0.000000 0.000000 0.000000 0.000000 0.000000 0.154381 0.691238 Bio 0.000000 0.000000 0.008915 0.065480 0.181464 0.000758 0.166690 0.122044 0.003710 0.107950 0.342988 St 0.000000 0.000000 0.003144 0.000000 0.139266 0.003001 0.042743 0.088225 0.002140 0.390637 0.330844 Ilm 0.000000 0.000000 0.370495 0.000000 0.556021 0.012695 0.008987 0.000000 0.051802 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -757707. -743753. -920087. -831895. -302338. -450268. -629746. -284063. -405485. -1621005. -877884. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 89 converged, 24 successes so far. Misfit function evaluations this try => 239 Misfit this try = 0.148470 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 7.743328E-07 Bayes score, PP * exp(-Misfit) = 6.674949E-07 Best Bayes score so far = 7.636014E-07 obtained on Try 68 P_bar T_K C_O2 C_H2O Initial coordinates: 5693.18 896.112 0.944492 0.356238 Final coordinates: 7938.02 928.034 0.514087 0.732587 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.147018 Extraneous predicted phases: 1.451580E-3 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.630 0.023325 0.023765 0.000000 0.063787 0.003669 0.000000 0.006384 0.298814 0.580256 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.2E-03 0. 0. 6.7E-03 1.5E-02 0. 8.0E-03 1.1E-03 6.7E-04 Composition Misfit: 6.278361E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.185 0.000000 0.022704 0.000000 0.000000 0.269509 0.058953 0.084644 0.137592 0.426597 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.3 0. 0. 3. -3. -3. 0.4 -0.2 Chi 0. 2.0E-04 0. 0. 1.0E-02 1.0E-02 1.1E-02 2.8E-04 8.8E-06 Composition Misfit: 3.156885E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.884 0.094901 0.058004 0.000000 0.001097 0.000000 0.000000 0.000000 0.154002 0.691996 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.1E-04 0. 6.2E-05 0. 0. 0. 3.1E-04 9.1E-06 Composition Misfit: 1.199262E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.632 0.000000 0.000000 0.013549 0.075343 0.195508 0.001391 0.195681 0.130139 0.388389 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.7 9.7E-03 -2. 0.7 1. Chi 0. 0. 4.5E-03 9.3E-04 6.2E-04 8.2E-07 3.5E-03 8.0E-04 2.0E-03 Composition Misfit: 1.232081E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.829 0.000000 0.000000 0.004985 0.000000 0.135339 0.004134 0.064205 0.427892 0.363446 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.3 -0.1 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 1.4E-04 2.1E-05 2.7E-02 1.0E-03 1.4E-03 Composition Misfit: 3.023459E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.784 0.000000 0.000000 0.372860 0.000000 0.593846 0.016664 0.016631 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 2. -1. -1. 0. 0. Chi 0. 0. 1.4E-03 0. 2.2E-03 2.7E-03 2.6E-03 0. 0. Composition Misfit: 8.911282E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.057 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.878 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.121 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000022 -.000022 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022996 0.014550 0.006885 0.016248 0.052207 0.000906 0.039766 0.042035 0.001677 0.107007 0.695723 Mica 0.019470 0.019838 0.000000 0.053245 0.003062 0.000000 0.005329 0.165268 0.000000 0.249430 0.484358 Gt 0.000000 0.022652 0.000000 0.000000 0.268890 0.058817 0.084450 0.000000 0.002298 0.137276 0.425617 Fsp 0.094901 0.058004 0.000000 0.001097 0.000000 0.000000 0.000000 0.000000 0.000000 0.154002 0.691996 Bio 0.000000 0.000000 0.011869 0.065999 0.171263 0.001218 0.171414 0.120129 0.003885 0.114000 0.340223 St 0.000000 0.000000 0.004534 0.000000 0.123105 0.003760 0.058401 0.088158 0.002238 0.389212 0.330592 Ilm 0.000000 0.000000 0.350574 0.000000 0.558351 0.015668 0.015637 0.000000 0.059771 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778899. -757295. -932550. -854426. -315862. -465552. -638106. -293040. -408576. -1637369. -887984. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 90 converged, 25 successes so far. Misfit function evaluations this try => 214 Misfit this try = 0.204319 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 8.532021E-07 Bayes score, PP * exp(-Misfit) = 6.955325E-07 Best Bayes score so far = 7.636014E-07 obtained on Try 68 P_bar T_K C_O2 C_H2O Initial coordinates: 6447.00 985.001 0.912906 0.591162 Final coordinates: 8271.14 928.391 0.978711 0.550150 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.204319 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.316 0.024781 0.025765 0.000000 0.061313 0.003636 0.000000 0.006600 0.299576 0.578329 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 8.4E-03 0. 0. 8.7E-03 1.6E-02 0. 7.3E-03 1.2E-03 8.1E-04 Composition Misfit: 6.778962E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.696 0.000000 0.025019 0.000000 0.000000 0.272428 0.051040 0.088411 0.136801 0.426300 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 3. -2. -3. 0.5 -0.2 Chi 0. 8.0E-04 0. 0. 9.0E-03 5.5E-03 1.3E-02 3.6E-04 6.3E-06 Composition Misfit: 2.846491E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.545 0.094987 0.057950 0.000000 0.001038 0.000000 0.000000 0.000000 0.153975 0.692050 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.2E-04 7.0E-04 0. 9.9E-05 0. 0. 0. 3.1E-04 8.7E-06 Composition Misfit: 1.232700E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.532 0.000000 0.000000 0.013182 0.075227 0.191138 0.001189 0.202135 0.128398 0.388732 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.4 0.1 -2. 0.9 1. Chi 0. 0. 5.1E-03 9.1E-04 2.3E-04 4.7E-05 5.3E-03 1.1E-03 1.9E-03 Composition Misfit: 1.454770E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.041 0.000000 0.000000 0.004646 0.000000 0.134095 0.003507 0.066886 0.427538 0.363327 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.2 0.1 -5. 1. 1. Chi 0. 0. 1.6E-03 0. 6.9E-05 3.1E-05 2.9E-02 1.0E-03 1.5E-03 Composition Misfit: 3.303014E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.254 0.000000 0.000000 0.245412 0.000000 0.733212 0.011310 0.010066 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. -0.2 -1.0E-02 0. 0. Chi 0. 0. 4.5E-02 0. 1.5E-02 1.5E-04 4.3E-07 0. 0. Composition Misfit: 5.925361E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.335 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.280 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023204 0.014682 0.006947 0.016394 0.052678 0.000914 0.040125 0.031852 0.003222 0.107974 0.702007 Mica 0.020686 0.021508 0.000000 0.051181 0.003035 0.000000 0.005510 0.165243 0.000000 0.250073 0.482765 Gt 0.000000 0.024953 0.000000 0.000000 0.271709 0.050905 0.088178 0.000000 0.002643 0.136439 0.425174 Fsp 0.094987 0.057950 0.000000 0.001038 0.000000 0.000000 0.000000 0.000000 0.000000 0.153975 0.692050 Bio 0.000000 0.000000 0.011543 0.065873 0.167371 0.001041 0.177001 0.120202 0.004140 0.112433 0.340396 St 0.000000 0.000000 0.004225 0.000000 0.121953 0.003190 0.060830 0.088114 0.002436 0.388824 0.330428 Ilm 0.000000 0.000000 0.217700 0.000000 0.650418 0.010033 0.008929 0.000000 0.112920 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777533. -756264. -932567. -853212. -315585. -466392. -637519. -292517. -405224. -1636705. -887259. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 92 converged, 26 successes so far. Misfit function evaluations this try => 152 Misfit this try = 0.121503 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 8.262532E-07 Bayes score, PP * exp(-Misfit) = 7.317201E-07 Best Bayes score so far = 7.636014E-07 obtained on Try 68 P_bar T_K C_O2 C_H2O Initial coordinates: 6171.30 872.801 0.483875 0.317306 Final coordinates: 8238.24 930.341 0.514953 0.523010 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121503 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.211 0.022826 0.024248 0.000000 0.063978 0.004093 0.000000 0.006632 0.298182 0.580042 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.8E-03 0. 0. 6.6E-03 1.2E-02 0. 7.2E-03 1.1E-03 6.9E-04 Composition Misfit: 5.874921E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.964 0.000000 0.024572 0.000000 0.000000 0.285114 0.043418 0.083206 0.137230 0.426461 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 6.6E-04 0. 0. 4.8E-03 1.9E-03 9.7E-03 3.2E-04 7.6E-06 Composition Misfit: 1.737366E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.173 0.094782 0.058250 0.000000 0.001093 0.000000 0.000000 0.000000 0.154125 0.691750 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.6E-04 0. 6.4E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.236394E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.946 0.000000 0.000000 0.013511 0.075310 0.203448 0.001027 0.188249 0.129647 0.388807 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.3E-04 1.8E-03 1.5E-04 1.9E-03 8.8E-04 1.9E-03 Composition Misfit: 1.205653E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.109 0.000000 0.000000 0.004900 0.000000 0.139700 0.002977 0.061183 0.427820 0.363420 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 5.4E-04 2.5E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.835751E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.804 0.000000 0.000000 0.365711 0.000000 0.607074 0.011758 0.015457 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.9 0. 1. -0.3 -0.9 0. 0. Chi 0. 0. 6.7E-04 0. 8.7E-04 2.6E-04 1.9E-03 0. 0. Composition Misfit: 3.729924E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.662 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.130 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023276 0.014727 0.006968 0.016445 0.052842 0.000917 0.040250 0.030375 0.001701 0.108309 0.704189 Mica 0.019056 0.020243 0.000000 0.053410 0.003417 0.000000 0.005536 0.165174 0.000000 0.248930 0.484234 Gt 0.000000 0.024511 0.000000 0.000000 0.284413 0.043311 0.083001 0.000000 0.002456 0.136893 0.425414 Fsp 0.094782 0.058250 0.000000 0.001093 0.000000 0.000000 0.000000 0.000000 0.000000 0.154125 0.691750 Bio 0.000000 0.000000 0.011837 0.065976 0.178234 0.000900 0.164919 0.120116 0.003817 0.113580 0.340620 St 0.000000 0.000000 0.004457 0.000000 0.127067 0.002707 0.055650 0.088148 0.002282 0.389132 0.330556 Ilm 0.000000 0.000000 0.342700 0.000000 0.568877 0.011018 0.014484 0.000000 0.062920 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778136. -756615. -932525. -853259. -315459. -467903. -638174. -292913. -409053. -1637090. -887547. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 95 converged, 27 successes so far. Misfit function evaluations this try => 259 Misfit this try = 3.47314 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 3.489608E-07 Bayes score, PP * exp(-Misfit) = 1.082458E-08 Best Bayes score so far = 7.636014E-07 obtained on Try 68 P_bar T_K C_O2 C_H2O Initial coordinates: 14336.9 828.756 0.894948 0.161937 Final coordinates: 6810.50 850.983 0.986851 0.705833 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.242148 Extraneous predicted phases: 3.23099 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.109 0.028525 0.023432 0.000000 0.059160 0.001860 0.000000 0.004136 0.303921 0.578967 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 2. 1. 0. 1. -1. 3. Chi 1.2E-02 0. 0. 1.1E-02 4.6E-02 0. 2.1E-02 1.8E-03 7.6E-04 Composition Misfit: 0.116250 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.000000 0.026612 0.000000 0.000000 0.245884 0.091159 0.071300 0.138215 0.426831 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.8 0. 0. 4. -6. -2. 0.4 -0.3 Chi 0. 1.4E-03 0. 0. 2.4E-02 3.6E-02 3.8E-03 2.3E-04 1.1E-05 Composition Misfit: 6.448529E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.221 0.094987 0.058710 0.000000 0.000658 0.000000 0.000000 0.000000 0.154355 0.691290 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.2E-04 8.6E-04 0. 7.4E-04 0. 0. 0. 2.8E-04 1.5E-05 Composition Misfit: 2.015476E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.134 0.000000 0.000000 0.011465 0.075092 0.183571 0.001510 0.212297 0.126383 0.389682 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. 0.1 -2.4E-02 -3. 1. 1. Chi 0. 0. 8.6E-03 8.8E-04 4.4E-06 4.8E-06 8.6E-03 1.5E-03 1.8E-03 Composition Misfit: 2.137245E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.588 0.000000 0.000000 0.004088 0.000000 0.136281 0.005471 0.062058 0.428562 0.363540 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -0.4 -0.3 -5. 1. 1. Chi 0. 0. 2.6E-03 0. 2.0E-04 4.9E-04 2.5E-02 9.3E-04 1.4E-03 Composition Misfit: 3.029531E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.275 0.000000 0.000000 0.353655 0.000000 0.611706 0.022114 0.012525 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.2 0. 0.8 -2. -0.4 0. 0. Chi 0. 0. 3.8E-05 0. 5.5E-04 6.6E-03 5.1E-04 0. 0. Composition Misfit: 7.729730E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.737 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.914 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 1.022 0.000000 0.000000 0.201193 0.000000 0.658042 0.015073 0.006169 0.000000 0.119523 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022996 0.014550 0.006885 0.016247 0.052206 0.000906 0.039766 0.040500 0.003220 0.107006 0.695718 Mica 0.023794 0.019546 0.000000 0.049349 0.001552 0.000000 0.003450 0.165833 0.000000 0.253521 0.482955 Gt 0.000000 0.026558 0.000000 0.000000 0.245386 0.090974 0.071155 0.000000 0.002027 0.137935 0.425966 Fsp 0.094987 0.058710 0.000000 0.000658 0.000000 0.000000 0.000000 0.000000 0.000000 0.154355 0.691290 Bio 0.000000 0.000000 0.010026 0.065668 0.160533 0.001321 0.185654 0.121310 0.004189 0.110522 0.340777 St 0.000000 0.000000 0.003718 0.000000 0.123957 0.004977 0.056446 0.088177 0.002256 0.389806 0.330664 Ilm 0.000000 0.000000 0.329542 0.000000 0.569998 0.020606 0.011671 0.000000 0.068183 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -767114. -749974. -925159. -843023. -308517. -453961. -632713. -287581. -403231. -1627811. -882396. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Mica Bio ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Mica Bio ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 113 converged, 28 successes so far. Misfit function evaluations this try => 196 Misfit this try = 0.124874 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 8.477670E-07 Bayes score, PP * exp(-Misfit) = 7.482461E-07 Best Bayes score so far = 7.636014E-07 obtained on Try 68 P_bar T_K C_O2 C_H2O Initial coordinates: 6182.12 841.652 0.948813 0.612671 Final coordinates: 8334.30 930.393 0.518536 0.565066 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.124874 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.513 0.023381 0.024798 0.000000 0.063146 0.004047 0.000000 0.006691 0.298440 0.579497 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.3E-03 0. 0. 7.2E-03 1.2E-02 0. 7.0E-03 1.1E-03 7.3E-04 Composition Misfit: 6.056222E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.951 0.000000 0.025025 0.000000 0.000000 0.284786 0.041957 0.084642 0.137157 0.426434 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -0.8 -3. 0.5 -0.2 Chi 0. 8.0E-04 0. 0. 4.8E-03 1.4E-03 1.1E-02 3.3E-04 7.4E-06 Composition Misfit: 1.791695E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.778 0.094978 0.057887 0.000000 0.001078 0.000000 0.000000 0.000000 0.153944 0.692113 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.2E-04 6.8E-04 0. 7.3E-05 0. 0. 0. 3.1E-04 8.2E-06 Composition Misfit: 1.195470E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.023 0.000000 0.000000 0.013566 0.075264 0.200959 0.000990 0.191087 0.128960 0.389174 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.5E-03 9.2E-04 1.4E-03 1.9E-04 2.4E-03 1.0E-03 1.8E-03 Composition Misfit: 1.222545E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.644 0.000000 0.000000 0.004940 0.000000 0.138702 0.002860 0.062308 0.427777 0.363413 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 4.2E-04 3.4E-04 2.5E-02 1.0E-03 1.4E-03 Composition Misfit: 2.925551E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.810 0.000000 0.000000 0.365116 0.000000 0.607727 0.011397 0.015760 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.8 0. 1. -0.2 -0.9 0. 0. Chi 0. 0. 6.3E-04 0. 8.2E-04 1.7E-04 2.1E-03 0. 0. Composition Misfit: 3.718324E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.042 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.239 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023219 0.014691 0.006951 0.016405 0.052713 0.000915 0.040152 0.032737 0.001708 0.108044 0.702465 Mica 0.019520 0.020702 0.000000 0.052716 0.003379 0.000000 0.005586 0.165173 0.000000 0.249146 0.483780 Gt 0.000000 0.024962 0.000000 0.000000 0.284077 0.041853 0.084431 0.000000 0.002488 0.136816 0.425373 Fsp 0.094978 0.057887 0.000000 0.001078 0.000000 0.000000 0.000000 0.000000 0.000000 0.153944 0.692113 Bio 0.000000 0.000000 0.011886 0.065945 0.176076 0.000867 0.167426 0.120003 0.003818 0.112992 0.340986 St 0.000000 0.000000 0.004494 0.000000 0.126159 0.002601 0.056673 0.088146 0.002285 0.389093 0.330549 Ilm 0.000000 0.000000 0.342047 0.000000 0.569331 0.010677 0.014764 0.000000 0.063181 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777708. -756348. -932299. -852944. -315397. -468083. -637966. -292741. -408680. -1636890. -887332. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 117 converged, 29 successes so far. Misfit function evaluations this try => 176 Misfit this try = 0.122912 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 8.124780E-07 Bayes score, PP * exp(-Misfit) = 7.185077E-07 Best Bayes score so far = 7.636014E-07 obtained on Try 68 P_bar T_K C_O2 C_H2O Initial coordinates: 6357.96 937.561 0.428359 0.436923 Final coordinates: 8180.16 930.355 0.529809 0.538491 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.122912 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.537 0.022777 0.024093 0.000000 0.064113 0.004044 0.000000 0.006595 0.298216 0.580163 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.8E-03 0. 0. 6.5E-03 1.3E-02 0. 7.3E-03 1.1E-03 6.8E-04 Composition Misfit: 5.888710E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.842 0.000000 0.024234 0.000000 0.000000 0.282878 0.045944 0.083244 0.137237 0.426464 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 5.6E-04 0. 0. 5.4E-03 3.0E-03 9.7E-03 3.2E-04 7.7E-06 Composition Misfit: 1.897460E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.089 0.094749 0.058306 0.000000 0.001098 0.000000 0.000000 0.000000 0.154153 0.691694 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.7E-04 0. 6.1E-05 0. 0. 0. 2.9E-04 1.1E-05 Composition Misfit: 1.241334E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.693 0.000000 0.000000 0.013476 0.075326 0.202740 0.001090 0.188902 0.129884 0.388582 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.3E-04 1.6E-03 1.0E-04 2.0E-03 8.4E-04 1.9E-03 Composition Misfit: 1.205608E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.785 0.000000 0.000000 0.004871 0.000000 0.139321 0.003165 0.061436 0.427795 0.363412 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.1 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 4.9E-04 1.4E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.846578E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.814 0.000000 0.000000 0.361308 0.000000 0.610898 0.012481 0.015313 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.6 0. 0.9 -0.4 -0.8 0. 0. Chi 0. 0. 3.5E-04 0. 6.0E-04 4.9E-04 1.8E-03 0. 0. Composition Misfit: 3.287451E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.019 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.221 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023254 0.014713 0.006962 0.016430 0.052792 0.000916 0.040212 0.031244 0.001748 0.108207 0.703522 Mica 0.019015 0.020113 0.000000 0.053522 0.003376 0.000000 0.005506 0.165186 0.000000 0.248954 0.484328 Gt 0.000000 0.024175 0.000000 0.000000 0.282184 0.045831 0.083039 0.000000 0.002453 0.136900 0.425418 Fsp 0.094749 0.058306 0.000000 0.001098 0.000000 0.000000 0.000000 0.000000 0.000000 0.154153 0.691694 Bio 0.000000 0.000000 0.011805 0.065984 0.177596 0.000955 0.165474 0.120162 0.003860 0.113776 0.340389 St 0.000000 0.000000 0.004430 0.000000 0.126720 0.002879 0.055880 0.088145 0.002297 0.389105 0.330544 Ilm 0.000000 0.000000 0.337878 0.000000 0.571282 0.011671 0.014320 0.000000 0.064849 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778393. -756802. -932662. -853551. -315572. -467525. -638229. -292992. -408751. -1637218. -887682. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 125 converged, 30 successes so far. Misfit function evaluations this try => 196 Misfit this try = 0.134372 Best Misfit so far = 0.121155 obtained on Try 39 Prior probability, PP = 8.448743E-07 Bayes score, PP * exp(-Misfit) = 7.386440E-07 Best Bayes score so far = 7.636014E-07 obtained on Try 68 P_bar T_K C_O2 C_H2O Initial coordinates: 6145.89 978.700 0.900321 0.606619 Final coordinates: 8301.60 929.947 0.537999 0.662227 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.134372 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.023 0.024016 0.025058 0.000000 0.062406 0.003855 0.000000 0.006640 0.298886 0.579139 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.8E-03 0. 0. 7.8E-03 1.4E-02 0. 7.2E-03 1.1E-03 7.5E-04 Composition Misfit: 6.351523E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.611 0.000000 0.024695 0.000000 0.000000 0.278711 0.046623 0.086379 0.137157 0.426434 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 7.0E-04 0. 0. 6.7E-03 3.3E-03 1.2E-02 3.3E-04 7.4E-06 Composition Misfit: 2.256132E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.026 0.095144 0.057574 0.000000 0.001069 0.000000 0.000000 0.000000 0.153787 0.692426 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.3E-04 6.2E-04 0. 7.8E-05 0. 0. 0. 3.3E-04 6.2E-06 Composition Misfit: 1.161972E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.227 0.000000 0.000000 0.013591 0.075245 0.196302 0.001096 0.195896 0.128669 0.389202 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.8 0.1 -2. 0.8 1. Chi 0. 0. 4.4E-03 9.1E-04 7.1E-04 9.8E-05 3.6E-03 1.1E-03 1.8E-03 Composition Misfit: 1.261997E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.463 0.000000 0.000000 0.004966 0.000000 0.136301 0.003201 0.064411 0.427721 0.363401 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.4 0.1 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 2.0E-04 1.3E-04 2.7E-02 1.0E-03 1.4E-03 Composition Misfit: 3.063258E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.821 0.000000 0.000000 0.361075 0.000000 0.610094 0.012756 0.016076 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.6 0. 0.9 -0.4 -1. 0. 0. Chi 0. 0. 3.4E-04 0. 6.5E-04 6.0E-04 2.3E-03 0. 0. Composition Misfit: 3.880758E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.206 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.623 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023087 0.014608 0.006912 0.016312 0.052414 0.000910 0.039924 0.038149 0.001762 0.107433 0.698488 Mica 0.020048 0.020919 0.000000 0.052096 0.003218 0.000000 0.005543 0.165207 0.000000 0.249508 0.483462 Gt 0.000000 0.024634 0.000000 0.000000 0.278018 0.046507 0.086164 0.000000 0.002487 0.136816 0.425373 Fsp 0.095144 0.057574 0.000000 0.001069 0.000000 0.000000 0.000000 0.000000 0.000000 0.153787 0.692426 Bio 0.000000 0.000000 0.011908 0.065928 0.171995 0.000960 0.171640 0.119947 0.003873 0.112737 0.341010 St 0.000000 0.000000 0.004516 0.000000 0.123974 0.002911 0.058586 0.088143 0.002296 0.389039 0.330535 Ilm 0.000000 0.000000 0.337623 0.000000 0.570468 0.011927 0.015031 0.000000 0.064951 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777725. -756427. -932225. -853194. -315542. -467250. -637808. -292684. -407902. -1636889. -887359. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 129 converged, 31 successes so far. Misfit function evaluations this try => 215 Misfit this try = 0.121013 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 8.155245E-07 Bayes score, PP * exp(-Misfit) = 7.225733E-07 Best Bayes score so far = 7.636014E-07 obtained on Try 68 P_bar T_K C_O2 C_H2O Initial coordinates: 7690.86 953.373 0.120754 0.268274 Final coordinates: 8216.55 930.906 0.534042 0.521329 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121013 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.161 0.022759 0.024193 0.000000 0.064073 0.004086 0.000000 0.006631 0.298164 0.580094 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.8E-03 0. 0. 6.5E-03 1.2E-02 0. 7.2E-03 1.0E-03 6.8E-04 Composition Misfit: 5.861092E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.928 0.000000 0.024392 0.000000 0.000000 0.284378 0.044353 0.083236 0.137194 0.426448 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 6.1E-04 0. 0. 5.0E-03 2.3E-03 9.7E-03 3.2E-04 7.5E-06 Composition Misfit: 1.791175E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.193 0.094748 0.058305 0.000000 0.001100 0.000000 0.000000 0.000000 0.154153 0.691695 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.7E-04 0. 6.1E-05 0. 0. 0. 2.9E-04 1.1E-05 Composition Misfit: 1.240405E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.977 0.000000 0.000000 0.013476 0.075321 0.203310 0.001054 0.188403 0.129820 0.388616 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.3E-04 1.7E-03 1.3E-04 1.9E-03 8.5E-04 1.9E-03 Composition Misfit: 1.209124E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.042 0.000000 0.000000 0.004864 0.000000 0.139670 0.003050 0.061230 0.427779 0.363407 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.3E-04 2.0E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.840011E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.820 0.000000 0.000000 0.359048 0.000000 0.613767 0.012011 0.015174 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.5 0. 0.7 -0.3 -0.8 0. 0. Chi 0. 0. 2.3E-04 0. 4.3E-04 3.4E-04 1.8E-03 0. 0. Composition Misfit: 2.758099E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.735 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.144 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023277 0.014728 0.006969 0.016446 0.052844 0.000917 0.040252 0.030278 0.001764 0.108313 0.704213 Mica 0.019000 0.020197 0.000000 0.053490 0.003411 0.000000 0.005536 0.165176 0.000000 0.248915 0.484276 Gt 0.000000 0.024332 0.000000 0.000000 0.283675 0.044243 0.083030 0.000000 0.002472 0.136854 0.425394 Fsp 0.094748 0.058305 0.000000 0.001100 0.000000 0.000000 0.000000 0.000000 0.000000 0.154153 0.691695 Bio 0.000000 0.000000 0.011805 0.065980 0.178096 0.000924 0.165038 0.120156 0.003860 0.113720 0.340421 St 0.000000 0.000000 0.004424 0.000000 0.127037 0.002774 0.055692 0.088143 0.002304 0.389088 0.330538 Ilm 0.000000 0.000000 0.335410 0.000000 0.573359 0.011220 0.014175 0.000000 0.065836 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778360. -756760. -932698. -853486. -315568. -467832. -638249. -292998. -408716. -1637228. -887659. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 132 converged, 32 successes so far. Misfit function evaluations this try => 157 Misfit this try = 0.213235 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 9.345217E-07 Bayes score, PP * exp(-Misfit) = 7.550618E-07 Best Bayes score so far = 7.636014E-07 obtained on Try 68 P_bar T_K C_O2 C_H2O Initial coordinates: 14413.3 913.598 0.148594 0.752221 Final coordinates: 8097.13 909.902 0.987817 0.555351 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.213235 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.529 0.025986 0.025832 0.000000 0.060170 0.003232 0.000000 0.006051 0.300849 0.577881 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 9.4E-03 0. 0. 9.8E-03 1.9E-02 0. 9.3E-03 1.4E-03 8.5E-04 Composition Misfit: 7.597564E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.664 0.000000 0.026612 0.000000 0.000000 0.272001 0.053613 0.084354 0.137033 0.426387 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.8 0. 0. 3. -2. -3. 0.5 -0.2 Chi 0. 1.4E-03 0. 0. 9.2E-03 7.0E-03 1.0E-02 3.4E-04 7.0E-06 Composition Misfit: 2.824139E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.431 0.095080 0.057996 0.000000 0.000922 0.000000 0.000000 0.000000 0.153998 0.692004 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.2E-04 7.1E-04 0. 2.1E-04 0. 0. 0. 3.1E-04 9.0E-06 Composition Misfit: 1.354747E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.475 0.000000 0.000000 0.012874 0.075149 0.190998 0.001149 0.203086 0.127238 0.389505 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.4 0.1 -2. 0.9 1. Chi 0. 0. 5.6E-03 8.9E-04 2.2E-04 6.6E-05 5.5E-03 1.3E-03 1.8E-03 Composition Misfit: 1.547455E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.019 0.000000 0.000000 0.004594 0.000000 0.135531 0.003525 0.065218 0.427754 0.363378 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.3 0.1 -5. 1. 1. Chi 0. 0. 1.6E-03 0. 1.5E-04 2.8E-05 2.7E-02 1.0E-03 1.4E-03 Composition Misfit: 3.168879E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.277 0.000000 0.000000 0.244581 0.000000 0.734360 0.011547 0.009512 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. -0.2 0.1 0. 0. Chi 0. 0. 4.5E-02 0. 1.5E-02 2.1E-04 2.5E-05 0. 0. Composition Misfit: 6.050012E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.342 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.264 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023196 0.014677 0.006944 0.016389 0.052661 0.000914 0.040112 0.032143 0.003251 0.107938 0.701775 Mica 0.021688 0.021560 0.000000 0.050219 0.002697 0.000000 0.005050 0.165375 0.000000 0.251096 0.482313 Gt 0.000000 0.026544 0.000000 0.000000 0.271309 0.053477 0.084140 0.000000 0.002542 0.136684 0.425303 Fsp 0.095080 0.057996 0.000000 0.000922 0.000000 0.000000 0.000000 0.000000 0.000000 0.153998 0.692004 Bio 0.000000 0.000000 0.011273 0.065801 0.167238 0.001006 0.177822 0.120328 0.004072 0.111410 0.341051 St 0.000000 0.000000 0.004178 0.000000 0.123264 0.003206 0.059315 0.088130 0.002381 0.389038 0.330488 Ilm 0.000000 0.000000 0.216883 0.000000 0.651196 0.010239 0.008435 0.000000 0.113247 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774216. -754170. -930324. -849871. -313556. -463831. -636167. -291061. -405088. -1634129. -885653. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 135 converged, 33 successes so far. Misfit function evaluations this try => 189 Misfit this try = 0.126336 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 8.832072E-07 Bayes score, PP * exp(-Misfit) = 7.783867E-07 Best Bayes score so far = 7.783867E-07 obtained on Try 135 P_bar T_K C_O2 C_H2O Initial coordinates: 13950.2 848.937 0.339176 0.349695 Final coordinates: 8324.70 926.573 0.539491 0.573334 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.126336 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.833 0.023750 0.024950 0.000000 0.062720 0.003941 0.000000 0.006610 0.298760 0.579270 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.6E-03 0. 0. 7.5E-03 1.3E-02 0. 7.3E-03 1.1E-03 7.4E-04 Composition Misfit: 6.238634E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.937 0.000000 0.025536 0.000000 0.000000 0.284357 0.042248 0.084358 0.137092 0.426409 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -0.9 -3. 0.5 -0.2 Chi 0. 9.7E-04 0. 0. 5.0E-03 1.5E-03 1.0E-02 3.3E-04 7.2E-06 Composition Misfit: 1.815073E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.671 0.095047 0.057811 0.000000 0.001048 0.000000 0.000000 0.000000 0.153906 0.692189 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.2E-04 6.7E-04 0. 9.2E-05 0. 0. 0. 3.2E-04 7.7E-06 Composition Misfit: 1.206765E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.818 0.000000 0.000000 0.013440 0.075238 0.200187 0.000977 0.192291 0.128572 0.389295 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -2. 0.8 1. Chi 0. 0. 4.7E-03 9.1E-04 1.2E-03 2.0E-04 2.7E-03 1.1E-03 1.8E-03 Composition Misfit: 1.262213E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.847 0.000000 0.000000 0.004870 0.000000 0.138707 0.002849 0.062415 0.427758 0.363402 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 4.2E-04 3.4E-04 2.5E-02 1.0E-03 1.4E-03 Composition Misfit: 2.944783E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.833 0.000000 0.000000 0.358245 0.000000 0.615183 0.011283 0.015290 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.5 0. 0.7 -0.2 -0.8 0. 0. Chi 0. 0. 1.9E-04 0. 3.6E-04 1.5E-04 1.8E-03 0. 0. Composition Misfit: 2.522557E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.805 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.256 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023206 0.014683 0.006948 0.016396 0.052684 0.000914 0.040130 0.033198 0.001776 0.107985 0.702080 Mica 0.019827 0.020828 0.000000 0.052359 0.003290 0.000000 0.005518 0.165199 0.000000 0.249405 0.483575 Gt 0.000000 0.025472 0.000000 0.000000 0.283642 0.042141 0.084146 0.000000 0.002516 0.136747 0.425336 Fsp 0.095047 0.057811 0.000000 0.001048 0.000000 0.000000 0.000000 0.000000 0.000000 0.153906 0.692189 Bio 0.000000 0.000000 0.011775 0.065915 0.175382 0.000856 0.168464 0.120056 0.003855 0.112640 0.341057 St 0.000000 0.000000 0.004429 0.000000 0.126161 0.002591 0.056769 0.088142 0.002309 0.389066 0.330532 Ilm 0.000000 0.000000 0.334534 0.000000 0.574466 0.010536 0.014278 0.000000 0.066186 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776898. -755836. -931874. -852163. -314970. -467549. -637617. -292389. -408053. -1636297. -886937. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 136 converged, 34 successes so far. Misfit function evaluations this try => 196 Misfit this try = 0.121257 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 8.298249E-07 Bayes score, PP * exp(-Misfit) = 7.350643E-07 Best Bayes score so far = 7.783867E-07 obtained on Try 135 P_bar T_K C_O2 C_H2O Initial coordinates: 8343.14 887.084 0.842205 0.820014 Final coordinates: 8268.30 930.676 0.516307 0.521904 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121257 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.242 0.022889 0.024366 0.000000 0.063852 0.004108 0.000000 0.006658 0.298188 0.579940 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.9E-03 0. 0. 6.7E-03 1.2E-02 0. 7.1E-03 1.1E-03 6.9E-04 Composition Misfit: 5.884287E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.001 0.000000 0.024708 0.000000 0.000000 0.285664 0.042534 0.083442 0.137202 0.426451 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -0.9 -3. 0.5 -0.2 Chi 0. 7.0E-04 0. 0. 4.6E-03 1.6E-03 9.8E-03 3.2E-04 7.5E-06 Composition Misfit: 1.707986E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.161 0.094810 0.058196 0.000000 0.001092 0.000000 0.000000 0.000000 0.154098 0.691804 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.5E-04 0. 6.5E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.229141E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.929 0.000000 0.000000 0.013524 0.075302 0.203332 0.001007 0.188436 0.129526 0.388875 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.5E-03 9.3E-04 1.7E-03 1.7E-04 1.9E-03 9.0E-04 1.9E-03 Composition Misfit: 1.208195E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.024 0.000000 0.000000 0.004903 0.000000 0.139682 0.002912 0.061282 0.427804 0.363417 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 5.3E-04 2.9E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.848364E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.807 0.000000 0.000000 0.364995 0.000000 0.608029 0.011513 0.015464 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.8 0. 1. -0.2 -0.9 0. 0. Chi 0. 0. 6.2E-04 0. 7.9E-04 2.0E-04 1.9E-03 0. 0. Composition Misfit: 3.539266E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.724 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.113 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023277 0.014728 0.006969 0.016446 0.052845 0.000917 0.040253 0.030312 0.001705 0.108316 0.704231 Mica 0.019108 0.020341 0.000000 0.053305 0.003429 0.000000 0.005558 0.165169 0.000000 0.248937 0.484152 Gt 0.000000 0.024647 0.000000 0.000000 0.284959 0.042429 0.083236 0.000000 0.002468 0.136863 0.425398 Fsp 0.094810 0.058196 0.000000 0.001092 0.000000 0.000000 0.000000 0.000000 0.000000 0.154098 0.691804 Bio 0.000000 0.000000 0.011848 0.065971 0.178137 0.000882 0.165087 0.120094 0.003816 0.113476 0.340689 St 0.000000 0.000000 0.004460 0.000000 0.127050 0.002649 0.055740 0.088147 0.002286 0.389116 0.330552 Ilm 0.000000 0.000000 0.341914 0.000000 0.569581 0.010785 0.014486 0.000000 0.063234 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778077. -756570. -932516. -853203. -315459. -468078. -638160. -292898. -408996. -1637079. -887515. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 144 converged, 35 successes so far. Misfit function evaluations this try => 237 Misfit this try = 0.153367 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 6.259595E-07 Bayes score, PP * exp(-Misfit) = 5.369573E-07 Best Bayes score so far = 7.783867E-07 obtained on Try 135 P_bar T_K C_O2 C_H2O Initial coordinates: 6553.30 918.614 9.155532E-02 0.932474 Final coordinates: 7229.47 878.095 0.405549 0.513801 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.153367 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.046 0.022600 0.020963 0.000000 0.066083 0.003094 0.000000 0.005251 0.299633 0.582375 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 6.6E-03 0. 0. 5.1E-03 2.1E-02 0. 1.3E-02 1.2E-03 5.3E-04 Composition Misfit: 6.856856E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.571 0.000000 0.025285 0.000000 0.000000 0.276863 0.063420 0.068941 0.138540 0.426952 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 3. -3. -1. 0.4 -0.3 Chi 0. 8.9E-04 0. 0. 7.3E-03 1.3E-02 2.9E-03 2.0E-04 1.2E-05 Composition Misfit: 2.475628E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.485 0.094622 0.059066 0.000000 0.000845 0.000000 0.000000 0.000000 0.154533 0.690934 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.4 0.2 Chi 9.3E-05 9.4E-04 0. 3.1E-04 0. 0. 0. 2.6E-04 1.8E-05 Composition Misfit: 1.629124E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.860 0.000000 0.000000 0.012370 0.075297 0.208236 0.001210 0.183767 0.129460 0.389659 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -2. 0.1 -1. 0.8 1. Chi 0. 0. 6.5E-03 9.3E-04 2.7E-03 3.8E-05 1.1E-03 9.1E-04 1.8E-03 Composition Misfit: 1.400914E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.004 0.000000 0.000000 0.004519 0.000000 0.144978 0.003921 0.053867 0.429021 0.363694 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. -1.7E-02 -4. 1. 1. Chi 0. 0. 1.8E-03 0. 1.3E-03 1.7E-06 1.8E-02 8.9E-04 1.4E-03 Composition Misfit: 2.315641E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.741 0.000000 0.000000 0.410772 0.000000 0.559333 0.015886 0.014010 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -3. 0. 3. -0.9 -0.6 0. 0. Chi 0. 0. 9.0E-03 0. 8.9E-03 2.2E-03 1.1E-03 0. 0. Composition Misfit: 2.124769E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.133 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.160 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023297 0.014741 0.006975 0.016460 0.052889 0.000918 0.040286 0.029867 0.001341 0.108407 0.704821 Mica 0.018860 0.017494 0.000000 0.055146 0.002582 0.000000 0.004382 0.165506 0.000000 0.250042 0.485988 Gt 0.000000 0.025237 0.000000 0.000000 0.276341 0.063300 0.068811 0.000000 0.001885 0.138279 0.426148 Fsp 0.094622 0.059066 0.000000 0.000845 0.000000 0.000000 0.000000 0.000000 0.000000 0.154533 0.690934 Bio 0.000000 0.000000 0.010830 0.065923 0.182310 0.001060 0.160888 0.121016 0.003485 0.113342 0.341146 St 0.000000 0.000000 0.004112 0.000000 0.131896 0.003567 0.049006 0.088234 0.002001 0.390309 0.330876 Ilm 0.000000 0.000000 0.393228 0.000000 0.535444 0.015208 0.013411 0.000000 0.042709 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771132. -752373. -927636. -845865. -310389. -459407. -635210. -289736. -411299. -1631034. -884257. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 148 converged, 36 successes so far. Misfit function evaluations this try => 232 Misfit this try = 0.148168 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 5.826347E-07 Bayes score, PP * exp(-Misfit) = 5.023978E-07 Best Bayes score so far = 7.783867E-07 obtained on Try 135 P_bar T_K C_O2 C_H2O Initial coordinates: 5662.80 935.646 0.522311 0.679573 Final coordinates: 7301.87 868.428 0.445655 0.521859 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.148168 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.602 0.023478 0.021514 0.000000 0.064958 0.002940 0.000000 0.005132 0.300263 0.581715 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 7.3E-03 0. 0. 5.9E-03 2.3E-02 0. 1.4E-02 1.3E-03 5.7E-04 Composition Misfit: 7.333349E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.651 0.000000 0.027571 0.000000 0.000000 0.279420 0.059933 0.068010 0.138229 0.426836 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.9 0. 0. 2. -3. -1. 0.4 -0.3 Chi 0. 1.8E-03 0. 0. 6.5E-03 1.1E-02 2.6E-03 2.3E-04 1.1E-05 Composition Misfit: 2.206837E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.311 0.094798 0.058854 0.000000 0.000775 0.000000 0.000000 0.000000 0.154427 0.691146 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.4 0.1 Chi 1.0E-04 9.0E-04 0. 4.4E-04 0. 0. 0. 2.7E-04 1.6E-05 Composition Misfit: 1.725787E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.492 0.000000 0.000000 0.012038 0.075197 0.207302 0.001085 0.186276 0.127960 0.390141 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -2. 0.1 -1. 0.9 1. Chi 0. 0. 7.2E-03 9.0E-04 2.5E-03 1.1E-04 1.5E-03 1.2E-03 1.7E-03 Composition Misfit: 1.516307E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.010 0.000000 0.000000 0.004295 0.000000 0.146295 0.003545 0.053405 0.428833 0.363627 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.1 -4. 1. 1. Chi 0. 0. 2.1E-03 0. 1.6E-03 2.4E-05 1.7E-02 9.1E-04 1.4E-03 Composition Misfit: 2.347572E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.787 0.000000 0.000000 0.396512 0.000000 0.576289 0.014258 0.012940 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -3. 0. 2. -0.7 -0.5 0. 0. Chi 0. 0. 5.5E-03 0. 5.0E-03 1.3E-03 6.7E-04 0. 0. Composition Misfit: 1.240171E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.035 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.112 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023283 0.014732 0.006970 0.016450 0.052858 0.000917 0.040262 0.030317 0.001472 0.108341 0.704397 Mica 0.019591 0.017952 0.000000 0.054205 0.002453 0.000000 0.004283 0.165544 0.000000 0.250557 0.485415 Gt 0.000000 0.027515 0.000000 0.000000 0.278855 0.059812 0.067873 0.000000 0.002021 0.137950 0.425974 Fsp 0.094798 0.058854 0.000000 0.000775 0.000000 0.000000 0.000000 0.000000 0.000000 0.154427 0.691146 Bio 0.000000 0.000000 0.010537 0.065818 0.181446 0.000950 0.163043 0.121100 0.003624 0.112001 0.341481 St 0.000000 0.000000 0.003907 0.000000 0.133081 0.003225 0.048581 0.088208 0.002118 0.390098 0.330782 Ilm 0.000000 0.000000 0.377004 0.000000 0.547937 0.013557 0.012304 0.000000 0.049198 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -768731. -750788. -926493. -843429. -309168. -458560. -634276. -288752. -408927. -1629393. -883079. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio F sill ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio F sill ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 152 converged, 37 successes so far. Misfit function evaluations this try => 190 Misfit this try = 0.121110 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 8.318917E-07 Bayes score, PP * exp(-Misfit) = 7.370030E-07 Best Bayes score so far = 7.783867E-07 obtained on Try 135 P_bar T_K C_O2 C_H2O Initial coordinates: 5716.35 853.155 0.939003 0.587055 Final coordinates: 8298.25 931.140 0.532284 0.524241 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121110 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.395 0.022996 0.024508 0.000000 0.063670 0.004109 0.000000 0.006686 0.298220 0.579810 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.9E-03 0. 0. 6.8E-03 1.2E-02 0. 7.0E-03 1.1E-03 7.0E-04 Composition Misfit: 5.912369E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.017 0.000000 0.024843 0.000000 0.000000 0.285711 0.042018 0.083883 0.137123 0.426421 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -0.9 -3. 0.5 -0.2 Chi 0. 7.4E-04 0. 0. 4.6E-03 1.4E-03 1.0E-02 3.3E-04 7.3E-06 Composition Misfit: 1.719146E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.115 0.094844 0.058130 0.000000 0.001091 0.000000 0.000000 0.000000 0.154065 0.691870 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.3E-04 0. 6.5E-05 0. 0. 0. 3.0E-04 1.0E-05 Composition Misfit: 1.220405E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.823 0.000000 0.000000 0.013510 0.075293 0.202810 0.000996 0.189117 0.129399 0.388875 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.2E-04 1.7E-03 1.8E-04 2.0E-03 9.2E-04 1.9E-03 Composition Misfit: 1.217451E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.049 0.000000 0.000000 0.004883 0.000000 0.139509 0.002875 0.061577 0.427754 0.363402 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 5.1E-04 3.2E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.877846E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.822 0.000000 0.000000 0.359272 0.000000 0.614136 0.011324 0.015268 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.5 0. 0.7 -0.2 -0.8 0. 0. Chi 0. 0. 2.4E-04 0. 4.1E-04 1.5E-04 1.8E-03 0. 0. Composition Misfit: 2.621673E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.666 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.113 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023273 0.014725 0.006967 0.016443 0.052835 0.000917 0.040245 0.030443 0.001758 0.108295 0.704098 Mica 0.019198 0.020460 0.000000 0.053154 0.003430 0.000000 0.005582 0.165165 0.000000 0.248965 0.484046 Gt 0.000000 0.024781 0.000000 0.000000 0.284996 0.041913 0.083674 0.000000 0.002502 0.136780 0.425354 Fsp 0.094844 0.058130 0.000000 0.001091 0.000000 0.000000 0.000000 0.000000 0.000000 0.154065 0.691870 Bio 0.000000 0.000000 0.011836 0.065962 0.177675 0.000872 0.165679 0.120088 0.003846 0.113362 0.340680 St 0.000000 0.000000 0.004441 0.000000 0.126890 0.002615 0.056008 0.088142 0.002307 0.389064 0.330533 Ilm 0.000000 0.000000 0.335654 0.000000 0.573764 0.010579 0.014265 0.000000 0.065739 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778046. -756546. -932552. -853196. -315492. -468203. -638141. -292890. -408663. -1637089. -887497. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio F sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio F sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 160 converged, 38 successes so far. Misfit function evaluations this try => 149 Misfit this try = 0.121226 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 8.304587E-07 Bayes score, PP * exp(-Misfit) = 7.356483E-07 Best Bayes score so far = 7.783867E-07 obtained on Try 135 P_bar T_K C_O2 C_H2O Initial coordinates: 7868.01 922.897 0.761137 0.656291 Final coordinates: 8255.03 930.311 0.537418 0.523150 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121226 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.303 0.022925 0.024358 0.000000 0.063823 0.004081 0.000000 0.006645 0.298235 0.579932 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.9E-03 0. 0. 6.7E-03 1.2E-02 0. 7.2E-03 1.1E-03 6.9E-04 Composition Misfit: 5.910225E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.970 0.000000 0.024716 0.000000 0.000000 0.284965 0.043241 0.083501 0.137148 0.426430 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 7.0E-04 0. 0. 4.8E-03 1.9E-03 9.9E-03 3.3E-04 7.4E-06 Composition Misfit: 1.756793E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.146 0.094804 0.058213 0.000000 0.001089 0.000000 0.000000 0.000000 0.154107 0.691787 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.5E-04 0. 6.6E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.233297E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.884 0.000000 0.000000 0.013469 0.075303 0.202985 0.001022 0.188911 0.129546 0.388764 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.3E-04 1.7E-03 1.6E-04 2.0E-03 8.9E-04 1.9E-03 Composition Misfit: 1.219317E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.042 0.000000 0.000000 0.004858 0.000000 0.139564 0.002964 0.061452 0.427760 0.363402 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.2E-04 2.6E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.864291E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.826 0.000000 0.000000 0.357707 0.000000 0.615497 0.011662 0.015134 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.4 0. 0.7 -0.3 -0.8 0. 0. Chi 0. 0. 1.7E-04 0. 3.4E-04 2.4E-04 1.7E-03 0. 0. Composition Misfit: 2.486451E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.701 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.128 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023274 0.014726 0.006968 0.016444 0.052838 0.000917 0.040247 0.030381 0.001775 0.108301 0.704131 Mica 0.019139 0.020335 0.000000 0.053281 0.003407 0.000000 0.005547 0.165174 0.000000 0.248975 0.484142 Gt 0.000000 0.024655 0.000000 0.000000 0.284255 0.043133 0.083293 0.000000 0.002492 0.136806 0.425368 Fsp 0.094804 0.058213 0.000000 0.001089 0.000000 0.000000 0.000000 0.000000 0.000000 0.154107 0.691787 Bio 0.000000 0.000000 0.011799 0.065966 0.177816 0.000895 0.165488 0.120133 0.003859 0.113483 0.340560 St 0.000000 0.000000 0.004419 0.000000 0.126940 0.002696 0.055894 0.088142 0.002312 0.389068 0.330531 Ilm 0.000000 0.000000 0.333948 0.000000 0.574615 0.010888 0.014129 0.000000 0.066421 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778054. -756560. -932547. -853196. -315451. -467915. -638131. -292879. -408577. -1637049. -887505. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 162 converged, 39 successes so far. Misfit function evaluations this try => 187 Misfit this try = 0.185226 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 7.702321E-07 Bayes score, PP * exp(-Misfit) = 6.399983E-07 Best Bayes score so far = 7.783867E-07 obtained on Try 135 P_bar T_K C_O2 C_H2O Initial coordinates: 6758.56 918.872 0.948310 0.742854 Final coordinates: 7902.28 927.440 0.895774 0.532749 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.185226 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.068 0.023283 0.023889 0.000000 0.063772 0.003632 0.000000 0.006380 0.298929 0.580116 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.2E-03 0. 0. 6.7E-03 1.6E-02 0. 8.0E-03 1.1E-03 6.8E-04 Composition Misfit: 6.323236E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.473 0.000000 0.022978 0.000000 0.000000 0.268163 0.060432 0.084691 0.137262 0.426473 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.3 0. 0. 3. -3. -3. 0.5 -0.2 Chi 0. 2.6E-04 0. 0. 1.1E-02 1.1E-02 1.1E-02 3.1E-04 7.7E-06 Composition Misfit: 3.325546E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.979 0.094611 0.058609 0.000000 0.001085 0.000000 0.000000 0.000000 0.154304 0.691391 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 9.3E-05 8.4E-04 0. 6.9E-05 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 1.296296E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.306 0.000000 0.000000 0.013257 0.075357 0.195206 0.001424 0.196632 0.130354 0.387771 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.7 2.1E-04 -2. 0.7 1. Chi 0. 0. 5.0E-03 9.4E-04 5.9E-04 3.7E-10 3.7E-03 7.6E-04 2.0E-03 Composition Misfit: 1.303909E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.032 0.000000 0.000000 0.004738 0.000000 0.135439 0.004251 0.064518 0.427682 0.363372 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.3 -0.1 -5. 1. 1. Chi 0. 0. 1.4E-03 0. 1.4E-04 4.0E-05 2.7E-02 1.0E-03 1.4E-03 Composition Misfit: 3.087857E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.159 0.000000 0.000000 0.259175 0.000000 0.715502 0.014550 0.010773 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. -0.7 -0.1 0. 0. Chi 0. 0. 3.2E-02 0. 1.0E-02 1.4E-03 5.5E-05 0. 0. Composition Misfit: 4.352452E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.634 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.349 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023233 0.014701 0.006956 0.016415 0.052746 0.000915 0.040177 0.030884 0.002953 0.108112 0.702907 Mica 0.019435 0.019941 0.000000 0.053232 0.003031 0.000000 0.005325 0.165274 0.000000 0.249524 0.484238 Gt 0.000000 0.022922 0.000000 0.000000 0.267508 0.060285 0.084485 0.000000 0.002442 0.136926 0.425432 Fsp 0.094611 0.058609 0.000000 0.001085 0.000000 0.000000 0.000000 0.000000 0.000000 0.154304 0.691391 Bio 0.000000 0.000000 0.011607 0.065978 0.170912 0.001247 0.172160 0.120350 0.004104 0.114131 0.339511 St 0.000000 0.000000 0.004310 0.000000 0.123182 0.003866 0.058679 0.088130 0.002367 0.388978 0.330487 Ilm 0.000000 0.000000 0.231321 0.000000 0.638606 0.012987 0.009615 0.000000 0.107472 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778960. -757265. -932892. -854476. -315882. -465325. -638080. -293033. -406590. -1637351. -888002. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Ilm Gt Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Ilm Gt Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Mica Bio ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Mica Bio ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 175 converged, 40 successes so far. Misfit function evaluations this try => 171 Misfit this try = 0.121147 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 8.295415E-07 Bayes score, PP * exp(-Misfit) = 7.348937E-07 Best Bayes score so far = 7.783867E-07 obtained on Try 135 P_bar T_K C_O2 C_H2O Initial coordinates: 5726.88 885.711 0.519637 0.608903 Final coordinates: 8270.59 930.755 0.544750 0.523402 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121147 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.352 0.022957 0.024429 0.000000 0.063754 0.004089 0.000000 0.006664 0.298236 0.579872 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.9E-03 0. 0. 6.7E-03 1.2E-02 0. 7.1E-03 1.1E-03 7.0E-04 Composition Misfit: 5.914649E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.980 0.000000 0.024762 0.000000 0.000000 0.285025 0.042953 0.083734 0.137110 0.426416 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 7.2E-04 0. 0. 4.8E-03 1.8E-03 1.0E-02 3.3E-04 7.3E-06 Composition Misfit: 1.759608E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.131 0.094817 0.058185 0.000000 0.001091 0.000000 0.000000 0.000000 0.154093 0.691815 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.5E-04 0. 6.5E-05 0. 0. 0. 3.0E-04 1.0E-05 Composition Misfit: 1.228435E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.851 0.000000 0.000000 0.013468 0.075300 0.202771 0.001017 0.189182 0.129504 0.388758 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.3E-04 1.7E-03 1.6E-04 2.0E-03 9.0E-04 1.9E-03 Composition Misfit: 1.222221E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.022 0.000000 0.000000 0.004852 0.000000 0.139502 0.002942 0.061569 0.427739 0.363396 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.1E-04 2.7E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.876172E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.833 0.000000 0.000000 0.355100 0.000000 0.618309 0.011548 0.015043 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.3 0. 0.5 -0.2 -0.8 0. 0. Chi 0. 0. 7.3E-05 0. 2.2E-04 2.1E-04 1.7E-03 0. 0. Composition Misfit: 2.192360E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.706 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.125 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023273 0.014726 0.006968 0.016443 0.052835 0.000917 0.040245 0.030394 0.001799 0.108296 0.704104 Mica 0.019165 0.020394 0.000000 0.053223 0.003413 0.000000 0.005563 0.165171 0.000000 0.248976 0.484094 Gt 0.000000 0.024700 0.000000 0.000000 0.284310 0.042845 0.083524 0.000000 0.002508 0.136766 0.425347 Fsp 0.094817 0.058185 0.000000 0.001091 0.000000 0.000000 0.000000 0.000000 0.000000 0.154093 0.691815 Bio 0.000000 0.000000 0.011798 0.065963 0.177627 0.000891 0.165723 0.120128 0.003872 0.113446 0.340552 St 0.000000 0.000000 0.004414 0.000000 0.126883 0.002676 0.055999 0.088139 0.002320 0.389046 0.330523 Ilm 0.000000 0.000000 0.331111 0.000000 0.576539 0.010767 0.014027 0.000000 0.067556 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778084. -756575. -932590. -853235. -315490. -468010. -638142. -292895. -408455. -1637087. -887518. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 176 converged, 41 successes so far. Misfit function evaluations this try => 293 Misfit this try = 0.980066 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 1.095275E-06 Bayes score, PP * exp(-Misfit) = 4.110415E-07 Best Bayes score so far = 7.783867E-07 obtained on Try 135 P_bar T_K C_O2 C_H2O Initial coordinates: 5783.38 935.066 0.563608 0.810323 Final coordinates: 8638.74 903.402 0.327015 0.930492 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.980066 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.001 0.063986 0.044591 0.000000 0.013584 0.000493 0.000000 0.000848 0.320552 0.555946 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -8. 0. 0. 6. 2. 0. 2. -2. 6. Chi 4.5E-02 0. 0. 0.4 0.2 0. 0.2 5.0E-03 3.5E-03 Composition Misfit: 0.888600 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.945 0.000000 0.028538 0.000000 0.000000 0.297298 0.027388 0.081711 0.138229 0.426836 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. 0.8 -3. 0.4 -0.3 Chi 0. 2.2E-03 0. 0. 2.0E-03 1.7E-03 8.9E-03 2.3E-04 1.1E-05 Composition Misfit: 1.509832E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.567 0.097608 0.052962 0.000000 0.000911 0.000000 0.000000 0.000000 0.151481 0.697038 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.5 -0.1 0. 0.1 0. 0. 0. 0.7 -0.1 Chi 3.6E-04 3.5E-05 0. 2.2E-04 0. 0. 0. 5.9E-04 9.2E-06 Composition Misfit: 1.212391E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.326 0.000000 0.000000 0.013686 0.074936 0.199345 0.000561 0.193706 0.124038 0.393727 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.2 -2. 1. 1. Chi 0. 0. 4.3E-03 8.5E-04 1.1E-03 1.3E-03 3.0E-03 2.1E-03 1.3E-03 Composition Misfit: 1.401335E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.634 0.000000 0.000000 0.005371 0.000000 0.140113 0.001662 0.060229 0.428892 0.363733 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.3 0. -0.7 0.5 -5. 1. 1. Chi 0. 0. 7.2E-04 0. 5.9E-04 2.9E-03 2.3E-02 9.0E-04 1.4E-03 Composition Misfit: 2.955765E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.704 0.000000 0.000000 0.428482 0.000000 0.546833 0.007038 0.017648 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -4. 0. 4. 0.5 -1. 0. 0. Chi 0. 0. 1.4E-02 0. 1.3E-02 1.2E-03 3.3E-03 0. 0. Composition Misfit: 3.158429E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.294 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 42.529 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022752 0.014396 0.006811 0.016075 0.051652 0.000896 0.039344 0.052823 0.001056 0.105870 0.688327 Mica 0.053334 0.037167 0.000000 0.011323 0.000411 0.000000 0.000707 0.166480 0.000000 0.267186 0.463392 Gt 0.000000 0.028480 0.000000 0.000000 0.296697 0.027333 0.081546 0.000000 0.002021 0.137950 0.425973 Fsp 0.097608 0.052962 0.000000 0.000911 0.000000 0.000000 0.000000 0.000000 0.000000 0.151481 0.697038 Bio 0.000000 0.000000 0.012010 0.065758 0.174929 0.000492 0.169981 0.119505 0.002977 0.108846 0.345503 St 0.000000 0.000000 0.004887 0.000000 0.127491 0.001512 0.054804 0.088258 0.001823 0.390257 0.330968 Ilm 0.000000 0.000000 0.413689 0.000000 0.527953 0.006795 0.017038 0.000000 0.034525 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -770149. -752002. -927545. -845555. -311591. -467495. -635222. -289744. -414540. -1631927. -883715. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 178 converged, 42 successes so far. Misfit function evaluations this try => 144 Misfit this try = 0.149176 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 1.024012E-06 Bayes score, PP * exp(-Misfit) = 8.821012E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 8348.49 920.424 0.336575 0.799579 Final coordinates: 8765.29 921.894 0.635197 0.609144 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.149176 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.279 0.027091 0.027765 0.000000 0.058009 0.003648 0.000000 0.006524 0.300659 0.576303 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 2. 1. 0. 1. -1. 3. Chi 1.0E-02 0. 0. 1.2E-02 1.5E-02 0. 7.6E-03 1.4E-03 9.7E-04 Composition Misfit: 7.550132E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.524 0.000000 0.028866 0.000000 0.000000 0.288730 0.031213 0.088469 0.136525 0.426197 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. 0.3 -3. 0.5 -0.2 Chi 0. 2.4E-03 0. 0. 3.8E-03 2.9E-04 1.3E-02 3.9E-04 5.6E-06 Composition Misfit: 1.972112E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.694 0.095979 0.056125 0.000000 0.000958 0.000000 0.000000 0.000000 0.153063 0.693875 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.4 -0.4 0. 0.1 0. 0. 0. 0.5 2.8E-02 Chi 2.0E-04 3.7E-04 0. 1.7E-04 0. 0. 0. 4.0E-04 5.7E-07 Composition Misfit: 1.129055E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.428 0.000000 0.000000 0.013390 0.075029 0.193408 0.000693 0.201150 0.125430 0.390900 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.6 0.2 -2. 1. 1. Chi 0. 0. 4.8E-03 8.7E-04 4.1E-04 7.7E-04 5.0E-03 1.8E-03 1.6E-03 Composition Misfit: 1.515412E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.801 0.000000 0.000000 0.004850 0.000000 0.136696 0.002017 0.065545 0.427546 0.363346 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.4 0.4 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 2.3E-04 1.6E-03 2.8E-02 1.0E-03 1.5E-03 Composition Misfit: 3.334327E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.954 0.000000 0.000000 0.326104 0.000000 0.651672 0.007907 0.014317 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 1. 0. -1. 0.3 -0.7 0. 0. Chi 0. 0. 1.8E-03 0. 7.2E-04 5.5E-04 1.3E-03 0. 0. Composition Misfit: 4.327473E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.186 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.133 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023151 0.014648 0.006931 0.016357 0.052558 0.000912 0.040034 0.035187 0.002087 0.107728 0.700407 Mica 0.022614 0.023177 0.000000 0.048423 0.003045 0.000000 0.005446 0.165252 0.000000 0.250975 0.481068 Gt 0.000000 0.028786 0.000000 0.000000 0.287933 0.031127 0.088225 0.000000 0.002763 0.136147 0.425019 Fsp 0.095979 0.056125 0.000000 0.000958 0.000000 0.000000 0.000000 0.000000 0.000000 0.153063 0.693875 Bio 0.000000 0.000000 0.011735 0.065751 0.169492 0.000607 0.176277 0.119768 0.003887 0.109920 0.342564 St 0.000000 0.000000 0.004411 0.000000 0.124324 0.001834 0.059613 0.088123 0.002381 0.388851 0.330462 Ilm 0.000000 0.000000 0.300018 0.000000 0.599543 0.007274 0.013172 0.000000 0.079993 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -773852. -753898. -930459. -849455. -313958. -468842. -636389. -291208. -405955. -1634591. -885419. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 179 converged, 43 successes so far. Misfit function evaluations this try => 168 Misfit this try = 0.183885 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 1.040697E-07 Bayes score, PP * exp(-Misfit) = 8.658924E-08 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 7172.84 810.340 0.774747 0.102868 Final coordinates: 6808.01 808.099 0.490970 0.542490 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.183885 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.658 0.025712 0.020789 0.000000 0.063296 0.002003 0.000000 0.003968 0.302631 0.581599 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 9.2E-03 0. 0. 7.1E-03 4.2E-02 0. 2.3E-02 1.6E-03 5.8E-04 Composition Misfit: 0.104163 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.694 0.000000 0.036184 0.000000 0.000000 0.279520 0.062986 0.056417 0.138104 0.426789 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -3. -0.2 0.4 -0.3 Chi 0. 6.8E-03 0. 0. 6.4E-03 1.3E-02 4.7E-05 2.4E-04 1.1E-05 Composition Misfit: 2.659587E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.933 0.095211 0.058583 0.000000 0.000497 0.000000 0.000000 0.000000 0.154292 0.691417 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.3E-04 8.3E-04 0. 1.5E-03 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 2.753100E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.876 0.000000 0.000000 0.010358 0.074880 0.206898 0.000826 0.191409 0.123195 0.392435 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.2 -1. 1. 1. Chi 0. 0. 1.2E-02 8.4E-04 2.4E-03 4.3E-04 2.5E-03 2.4E-03 1.4E-03 Composition Misfit: 2.169765E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.017 0.000000 0.000000 0.003523 0.000000 0.152465 0.003087 0.047965 0.429284 0.363676 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. 0.2 -3. 1. 1. Chi 0. 0. 4.1E-03 0. 3.0E-03 1.8E-04 1.3E-02 8.6E-04 1.4E-03 Composition Misfit: 2.265445E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.885 0.000000 0.000000 0.385030 0.000000 0.592855 0.012481 0.009634 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. -0.4 0.1 0. 0. Chi 0. 0. 3.2E-03 0. 2.3E-03 4.9E-04 1.4E-05 0. 0. Composition Misfit: 6.021193E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.943 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.994 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023251 0.014712 0.006961 0.016428 0.052786 0.000916 0.040208 0.031473 0.001620 0.108196 0.703449 Mica 0.021448 0.017342 0.000000 0.052799 0.001671 0.000000 0.003310 0.165836 0.000000 0.252444 0.485149 Gt 0.000000 0.036109 0.000000 0.000000 0.278940 0.062855 0.056300 0.000000 0.002075 0.137817 0.425903 Fsp 0.095211 0.058583 0.000000 0.000497 0.000000 0.000000 0.000000 0.000000 0.000000 0.154292 0.691417 Bio 0.000000 0.000000 0.009057 0.065473 0.180907 0.000722 0.167364 0.121890 0.003728 0.107719 0.343138 St 0.000000 0.000000 0.003204 0.000000 0.138684 0.002808 0.043630 0.088214 0.002173 0.390482 0.330804 Ilm 0.000000 0.000000 0.364099 0.000000 0.560628 0.011802 0.009111 0.000000 0.054360 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -758161. -743999. -920476. -832430. -302811. -451356. -629979. -284285. -405227. -1621497. -878065. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 180 converged, 44 successes so far. Misfit function evaluations this try => 157 Misfit this try = 0.160248 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 3.307543E-07 Bayes score, PP * exp(-Misfit) = 2.817802E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5682.82 810.784 0.950954 0.696663 Final coordinates: 7165.59 840.619 0.458507 0.532885 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.160248 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.211 0.024834 0.021561 0.000000 0.063675 0.002497 0.000000 0.004609 0.301543 0.581282 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 8.4E-03 0. 0. 6.8E-03 3.0E-02 0. 1.7E-02 1.5E-03 6.0E-04 Composition Misfit: 8.620958E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.728 0.000000 0.031884 0.000000 0.000000 0.281707 0.058504 0.063009 0.138106 0.426790 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -3. -0.8 0.4 -0.3 Chi 0. 4.0E-03 0. 0. 5.7E-03 1.0E-02 1.1E-03 2.4E-04 1.1E-05 Composition Misfit: 2.114734E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.092 0.095063 0.058616 0.000000 0.000629 0.000000 0.000000 0.000000 0.154308 0.691384 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.2E-04 8.4E-04 0. 8.5E-04 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 2.103942E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.133 0.000000 0.000000 0.011280 0.075025 0.207027 0.000915 0.188943 0.125371 0.391439 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 1. 1. Chi 0. 0. 9.0E-03 8.7E-04 2.5E-03 2.8E-04 2.0E-03 1.8E-03 1.5E-03 Composition Misfit: 1.794391E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.012 0.000000 0.000000 0.003958 0.000000 0.149014 0.003171 0.051174 0.429034 0.363649 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -1. 0.1 -4. 1. 1. Chi 0. 0. 2.9E-03 0. 2.2E-03 1.4E-04 1.6E-02 8.9E-04 1.4E-03 Composition Misfit: 2.307463E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.828 0.000000 0.000000 0.393993 0.000000 0.581631 0.012853 0.011523 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. -0.5 -0.2 0. 0. Chi 0. 0. 4.9E-03 0. 4.0E-03 6.3E-04 2.0E-04 0. 0. Composition Misfit: 9.769062E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.966 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.030 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023267 0.014722 0.006966 0.016439 0.052821 0.000917 0.040235 0.030936 0.001514 0.108268 0.703917 Mica 0.020720 0.017989 0.000000 0.053125 0.002083 0.000000 0.003845 0.165679 0.000000 0.251583 0.484976 Gt 0.000000 0.031818 0.000000 0.000000 0.281123 0.058382 0.062879 0.000000 0.002074 0.137819 0.425904 Fsp 0.095063 0.058616 0.000000 0.000629 0.000000 0.000000 0.000000 0.000000 0.000000 0.154308 0.691384 Bio 0.000000 0.000000 0.009870 0.065641 0.181134 0.000800 0.165312 0.121413 0.003659 0.109691 0.342481 St 0.000000 0.000000 0.003600 0.000000 0.135551 0.002885 0.046550 0.088211 0.002141 0.390270 0.330793 Ilm 0.000000 0.000000 0.374161 0.000000 0.552355 0.012206 0.010943 0.000000 0.050335 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -763401. -747344. -923485. -837920. -306078. -455450. -632142. -286517. -407232. -1625491. -880521. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 181 converged, 45 successes so far. Misfit function evaluations this try => 263 Misfit this try = 0.125486 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 8.244955E-07 Bayes score, PP * exp(-Misfit) = 7.272609E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 13317.9 812.370 7.872042E-02 0.918742 Final coordinates: 8242.03 930.603 0.480048 0.550725 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.125486 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.853 0.022920 0.024301 0.000000 0.063858 0.004078 0.000000 0.006634 0.298224 0.579984 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.9E-03 0. 0. 6.6E-03 1.2E-02 0. 7.2E-03 1.1E-03 6.9E-04 Composition Misfit: 5.906001E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.902 0.000000 0.024399 0.000000 0.000000 0.284432 0.043753 0.083509 0.137387 0.426520 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 6.1E-04 0. 0. 4.9E-03 2.1E-03 9.9E-03 3.0E-04 8.1E-06 Composition Misfit: 1.779766E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.987 0.094832 0.058149 0.000000 0.001094 0.000000 0.000000 0.000000 0.154075 0.691851 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.4E-04 0. 6.4E-05 0. 0. 0. 3.0E-04 1.0E-05 Composition Misfit: 1.221392E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.471 0.000000 0.000000 0.013634 0.075302 0.202666 0.001036 0.188763 0.129531 0.389068 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.4E-03 9.3E-04 1.6E-03 1.5E-04 2.0E-03 9.0E-04 1.9E-03 Composition Misfit: 1.181031E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.306 0.000000 0.000000 0.005006 0.000000 0.139203 0.002999 0.061417 0.427920 0.363455 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 4.8E-04 2.4E-04 2.4E-02 9.9E-04 1.4E-03 Composition Misfit: 2.834605E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.772 0.000000 0.000000 0.378825 0.000000 0.592912 0.012024 0.016239 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. -0.3 -1. 0. 0. Chi 0. 0. 2.2E-03 0. 2.3E-03 3.4E-04 2.4E-03 0. 0. Composition Misfit: 7.250988E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.485 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.224 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023241 0.014705 0.006958 0.016421 0.052763 0.000916 0.040190 0.031937 0.001583 0.108148 0.703138 Mica 0.019134 0.020287 0.000000 0.053310 0.003405 0.000000 0.005539 0.165176 0.000000 0.248964 0.484185 Gt 0.000000 0.024341 0.000000 0.000000 0.283753 0.043648 0.083309 0.000000 0.002388 0.137059 0.425502 Fsp 0.094832 0.058149 0.000000 0.001094 0.000000 0.000000 0.000000 0.000000 0.000000 0.154075 0.691851 Bio 0.000000 0.000000 0.011946 0.065983 0.177586 0.000908 0.165403 0.120020 0.003731 0.113502 0.340921 St 0.000000 0.000000 0.004554 0.000000 0.126621 0.002728 0.055866 0.088161 0.002223 0.389243 0.330604 Ilm 0.000000 0.000000 0.357184 0.000000 0.559041 0.011338 0.015311 0.000000 0.057127 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778171. -756651. -932406. -853333. -315496. -467876. -638169. -292922. -409835. -1637124. -887567. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 183 converged, 46 successes so far. Misfit function evaluations this try => 171 Misfit this try = 0.142318 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 6.747186E-07 Bayes score, PP * exp(-Misfit) = 5.852143E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 13823.5 815.435 0.363128 0.689714 Final coordinates: 7602.00 870.421 0.580441 0.537427 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.142318 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.766 0.025114 0.023251 0.000000 0.062452 0.002886 0.000000 0.005206 0.301106 0.579986 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 8.7E-03 0. 0. 7.8E-03 2.4E-02 0. 1.3E-02 1.4E-03 6.9E-04 Composition Misfit: 7.883935E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.781 0.000000 0.029971 0.000000 0.000000 0.282130 0.053117 0.070762 0.137470 0.426551 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -2. -2. 0.5 -0.2 Chi 0. 3.0E-03 0. 0. 5.6E-03 6.7E-03 3.6E-03 2.9E-04 8.4E-06 Composition Misfit: 1.918366E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.940 0.095056 0.058389 0.000000 0.000750 0.000000 0.000000 0.000000 0.154195 0.691611 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.2E-04 7.9E-04 0. 4.9E-04 0. 0. 0. 2.9E-04 1.2E-05 Composition Misfit: 1.709381E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.709 0.000000 0.000000 0.011881 0.075096 0.203426 0.000959 0.191894 0.126439 0.390305 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -2. 1. 1. Chi 0. 0. 7.6E-03 8.8E-04 1.8E-03 2.3E-04 2.6E-03 1.5E-03 1.7E-03 Composition Misfit: 1.626767E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.049 0.000000 0.000000 0.004148 0.000000 0.145125 0.003126 0.055770 0.428342 0.363489 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 2.4E-03 0. 1.4E-03 1.6E-04 1.9E-02 9.5E-04 1.4E-03 Composition Misfit: 2.569953E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.914 0.000000 0.000000 0.349383 0.000000 0.626879 0.012195 0.011544 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 3.4E-02 0. 0.1 -0.3 -0.2 0. 0. Chi 0. 0. 1.1E-06 0. 1.6E-05 3.9E-04 2.1E-04 0. 0. Composition Misfit: 6.179800E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.745 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.096 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023251 0.014712 0.006961 0.016428 0.052786 0.000916 0.040208 0.031179 0.001915 0.108195 0.703448 Mica 0.020956 0.019402 0.000000 0.052113 0.002408 0.000000 0.004344 0.165541 0.000000 0.251261 0.483974 Gt 0.000000 0.029900 0.000000 0.000000 0.281466 0.052992 0.070595 0.000000 0.002351 0.137146 0.425548 Fsp 0.095056 0.058389 0.000000 0.000750 0.000000 0.000000 0.000000 0.000000 0.000000 0.154195 0.691611 Bio 0.000000 0.000000 0.010397 0.065714 0.178011 0.000839 0.167920 0.121031 0.003906 0.110642 0.341541 St 0.000000 0.000000 0.003773 0.000000 0.131996 0.002843 0.050724 0.088161 0.002310 0.389589 0.330604 Ilm 0.000000 0.000000 0.324914 0.000000 0.582976 0.011341 0.010735 0.000000 0.070034 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -767832. -750126. -926452. -842717. -309110. -459387. -633911. -288414. -405802. -1629048. -882599. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 184 converged, 47 successes so far. Misfit function evaluations this try => 130 Misfit this try = 0.122359 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 8.772157E-07 Bayes score, PP * exp(-Misfit) = 7.761873E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 8024.82 925.548 0.247375 0.693790 Final coordinates: 8206.30 923.998 0.539983 0.524577 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.122359 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.374 0.023201 0.024327 0.000000 0.063589 0.003954 0.000000 0.006504 0.298568 0.579856 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.1E-03 0. 0. 6.9E-03 1.3E-02 0. 7.6E-03 1.1E-03 7.0E-04 Composition Misfit: 6.082476E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.968 0.000000 0.025320 0.000000 0.000000 0.285099 0.043703 0.082270 0.137170 0.426439 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 9.0E-04 0. 0. 4.8E-03 2.0E-03 9.2E-03 3.2E-04 7.4E-06 Composition Misfit: 1.720793E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.115 0.094854 0.058199 0.000000 0.001047 0.000000 0.000000 0.000000 0.154100 0.691801 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.5E-04 0. 9.2E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.260264E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.855 0.000000 0.000000 0.013310 0.075276 0.203000 0.001004 0.189288 0.129145 0.388977 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.9E-03 9.2E-04 1.7E-03 1.8E-04 2.1E-03 9.7E-04 1.9E-03 Composition Misfit: 1.256644E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.021 0.000000 0.000000 0.004791 0.000000 0.140154 0.002942 0.060882 0.427820 0.363411 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.7 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.9E-04 2.7E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.832097E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.834 0.000000 0.000000 0.357367 0.000000 0.616367 0.011530 0.014736 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.4 0. 0.6 -0.2 -0.8 0. 0. Chi 0. 0. 1.5E-04 0. 3.0E-04 2.0E-04 1.5E-03 0. 0. Composition Misfit: 2.178662E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.718 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.116 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023272 0.014725 0.006967 0.016442 0.052833 0.000917 0.040243 0.030461 0.001783 0.108291 0.704067 Mica 0.019368 0.020308 0.000000 0.053084 0.003300 0.000000 0.005430 0.165212 0.000000 0.249241 0.484057 Gt 0.000000 0.025257 0.000000 0.000000 0.284391 0.043595 0.082066 0.000000 0.002482 0.136829 0.425380 Fsp 0.094854 0.058199 0.000000 0.001047 0.000000 0.000000 0.000000 0.000000 0.000000 0.154100 0.691801 Bio 0.000000 0.000000 0.011659 0.065937 0.177813 0.000880 0.165802 0.120214 0.003860 0.113121 0.340715 St 0.000000 0.000000 0.004357 0.000000 0.127477 0.002676 0.055375 0.088144 0.002310 0.389122 0.330539 Ilm 0.000000 0.000000 0.333577 0.000000 0.575336 0.010763 0.013755 0.000000 0.066569 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776867. -755811. -931849. -851992. -314744. -467063. -637649. -292365. -408262. -1636140. -886929. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 192 converged, 48 successes so far. Misfit function evaluations this try => 184 Misfit this try = 0.121070 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 8.246501E-07 Bayes score, PP * exp(-Misfit) = 7.306170E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 7363.05 932.695 0.338340 0.830729 Final coordinates: 8252.25 930.821 0.534196 0.521978 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121070 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.250 0.022876 0.024336 0.000000 0.063882 0.004092 0.000000 0.006652 0.298200 0.579962 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.8E-03 0. 0. 6.6E-03 1.2E-02 0. 7.1E-03 1.1E-03 6.9E-04 Composition Misfit: 5.889656E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.968 0.000000 0.024632 0.000000 0.000000 0.284936 0.043329 0.083514 0.137156 0.426434 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 6.8E-04 0. 0. 4.8E-03 1.9E-03 9.9E-03 3.3E-04 7.4E-06 Composition Misfit: 1.758966E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.162 0.094791 0.058231 0.000000 0.001094 0.000000 0.000000 0.000000 0.154115 0.691769 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.6E-04 0. 6.4E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.232899E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.920 0.000000 0.000000 0.013484 0.075308 0.203115 0.001027 0.188712 0.129620 0.388735 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.3E-04 1.7E-03 1.5E-04 2.0E-03 8.8E-04 1.9E-03 Composition Misfit: 1.214192E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.016 0.000000 0.000000 0.004868 0.000000 0.139594 0.002971 0.061397 0.427766 0.363404 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 5.2E-04 2.5E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.858121E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.822 0.000000 0.000000 0.358809 0.000000 0.614326 0.011682 0.015183 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.5 0. 0.7 -0.3 -0.8 0. 0. Chi 0. 0. 2.2E-04 0. 4.0E-04 2.4E-04 1.8E-03 0. 0. Composition Misfit: 2.627489E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.734 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.127 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023276 0.014727 0.006968 0.016445 0.052842 0.000917 0.040250 0.030315 0.001764 0.108309 0.704187 Mica 0.019097 0.020316 0.000000 0.053330 0.003416 0.000000 0.005553 0.165172 0.000000 0.248946 0.484169 Gt 0.000000 0.024570 0.000000 0.000000 0.284227 0.043221 0.083306 0.000000 0.002488 0.136815 0.425373 Fsp 0.094791 0.058231 0.000000 0.001094 0.000000 0.000000 0.000000 0.000000 0.000000 0.154115 0.691769 Bio 0.000000 0.000000 0.011812 0.065971 0.177931 0.000899 0.165315 0.120129 0.003855 0.113549 0.340538 St 0.000000 0.000000 0.004428 0.000000 0.126968 0.002703 0.055844 0.088142 0.002307 0.389074 0.330534 Ilm 0.000000 0.000000 0.335149 0.000000 0.573817 0.010911 0.014182 0.000000 0.065940 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778181. -756640. -932609. -853318. -315513. -467969. -638184. -292933. -408683. -1637137. -887567. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 193 converged, 49 successes so far. Misfit function evaluations this try => 188 Misfit this try = 0.129436 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 8.308518E-07 Bayes score, PP * exp(-Misfit) = 7.299789E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5848.42 810.114 0.949155 0.749164 Final coordinates: 8250.55 930.168 0.530711 0.611590 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.129436 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.583 0.023466 0.024642 0.000000 0.063156 0.003939 0.000000 0.006629 0.298582 0.579586 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.3E-03 0. 0. 7.2E-03 1.3E-02 0. 7.2E-03 1.1E-03 7.2E-04 Composition Misfit: 6.140448E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.704 0.000000 0.024483 0.000000 0.000000 0.280482 0.046313 0.085056 0.137212 0.426455 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 6.3E-04 0. 0. 6.1E-03 3.1E-03 1.1E-02 3.2E-04 7.6E-06 Composition Misfit: 2.099122E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.476 0.094974 0.057889 0.000000 0.001082 0.000000 0.000000 0.000000 0.153945 0.692111 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.2E-04 6.8E-04 0. 7.0E-05 0. 0. 0. 3.1E-04 8.3E-06 Composition Misfit: 1.193230E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.227 0.000000 0.000000 0.013551 0.075279 0.199000 0.001093 0.192943 0.129178 0.388956 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -2. 0.8 1. Chi 0. 0. 4.5E-03 9.2E-04 1.1E-03 1.0E-04 2.8E-03 9.6E-04 1.9E-03 Composition Misfit: 1.226901E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.593 0.000000 0.000000 0.004937 0.000000 0.137549 0.003185 0.063156 0.427763 0.363409 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.5 0.1 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 3.1E-04 1.3E-04 2.6E-02 1.0E-03 1.4E-03 Composition Misfit: 2.968092E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.814 0.000000 0.000000 0.362621 0.000000 0.608853 0.012680 0.015846 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.7 0. 1. -0.4 -0.9 0. 0. Chi 0. 0. 4.4E-04 0. 7.3E-04 5.7E-04 2.2E-03 0. 0. Composition Misfit: 3.896953E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.144 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.458 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023155 0.014651 0.006932 0.016360 0.052569 0.000912 0.040042 0.035336 0.001744 0.107750 0.700549 Mica 0.019589 0.020571 0.000000 0.052723 0.003288 0.000000 0.005534 0.165196 0.000000 0.249258 0.483840 Gt 0.000000 0.024422 0.000000 0.000000 0.279791 0.046199 0.084846 0.000000 0.002464 0.136874 0.425404 Fsp 0.094974 0.057889 0.000000 0.001082 0.000000 0.000000 0.000000 0.000000 0.000000 0.153945 0.692111 Bio 0.000000 0.000000 0.011872 0.065952 0.174346 0.000957 0.169039 0.120032 0.003862 0.113173 0.340767 St 0.000000 0.000000 0.004490 0.000000 0.125110 0.002897 0.057445 0.088145 0.002290 0.389078 0.330544 Ilm 0.000000 0.000000 0.339314 0.000000 0.569719 0.011865 0.014828 0.000000 0.064274 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778017. -756591. -932406. -853353. -315558. -467376. -637990. -292818. -408325. -1637036. -887500. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio F sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio F sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 196 converged, 50 successes so far. Misfit function evaluations this try => 152 Misfit this try = 0.121296 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 8.184111E-07 Bayes score, PP * exp(-Misfit) = 7.249253E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6559.10 912.624 0.533315 0.561315 Final coordinates: 8221.96 930.744 0.550139 0.522377 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121296 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.240 0.022822 0.024231 0.000000 0.063992 0.004073 0.000000 0.006632 0.298199 0.580051 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.8E-03 0. 0. 6.5E-03 1.2E-02 0. 7.2E-03 1.1E-03 6.9E-04 Composition Misfit: 5.884761E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.922 0.000000 0.024489 0.000000 0.000000 0.283994 0.044499 0.083449 0.137141 0.426428 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 6.3E-04 0. 0. 5.1E-03 2.4E-03 9.8E-03 3.3E-04 7.3E-06 Composition Misfit: 1.823421E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.171 0.094759 0.058289 0.000000 0.001096 0.000000 0.000000 0.000000 0.154144 0.691711 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.7E-04 0. 6.2E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.240055E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.922 0.000000 0.000000 0.013443 0.075318 0.202963 0.001055 0.188878 0.129763 0.388580 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.7E-03 9.3E-04 1.7E-03 1.3E-04 2.0E-03 8.6E-04 1.9E-03 Composition Misfit: 1.218550E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.040 0.000000 0.000000 0.004836 0.000000 0.139495 0.003060 0.061471 0.427742 0.363395 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.1E-04 2.0E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.862229E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.835 0.000000 0.000000 0.353495 0.000000 0.619592 0.011978 0.014935 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.2 0. 0.5 -0.3 -0.8 0. 0. Chi 0. 0. 3.5E-05 0. 1.7E-04 3.3E-04 1.6E-03 0. 0. Composition Misfit: 2.166474E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.723 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.148 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023274 0.014726 0.006968 0.016444 0.052838 0.000917 0.040247 0.030336 0.001817 0.108301 0.704133 Mica 0.019052 0.020228 0.000000 0.053422 0.003400 0.000000 0.005536 0.165177 0.000000 0.248943 0.484240 Gt 0.000000 0.024428 0.000000 0.000000 0.283285 0.044388 0.083241 0.000000 0.002495 0.136799 0.425364 Fsp 0.094759 0.058289 0.000000 0.001096 0.000000 0.000000 0.000000 0.000000 0.000000 0.154144 0.691711 Bio 0.000000 0.000000 0.011775 0.065974 0.177783 0.000924 0.165446 0.120172 0.003889 0.113664 0.340373 St 0.000000 0.000000 0.004399 0.000000 0.126876 0.002783 0.055910 0.088139 0.002323 0.389048 0.330522 Ilm 0.000000 0.000000 0.329368 0.000000 0.577304 0.011160 0.013915 0.000000 0.068253 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778298. -756723. -932698. -853442. -315556. -467786. -638213. -292969. -408432. -1637190. -887629. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 198 converged, 51 successes so far. Misfit function evaluations this try => 264 Misfit this try = 2.02466 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 1.543740E-07 Bayes score, PP * exp(-Misfit) = 2.038329E-08 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 7197.59 815.529 0.169026 0.766387 Final coordinates: 6985.48 816.845 0.287090 0.681513 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.02466 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.108 0.066465 0.046564 0.000000 0.010204 0.000167 0.000000 0.000314 0.322657 0.553628 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -9. 0. 0. 6. 2. 0. 2. -2. 6. Chi 4.7E-02 0. 0. 0.5 0.7 0. 0.6 5.5E-03 3.9E-03 Composition Misfit: 1.92516 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.851 0.000000 0.033729 0.000000 0.000000 0.286243 0.055348 0.057920 0.139461 0.427298 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -2. -0.3 0.3 -0.3 Chi 0. 5.2E-03 0. 0. 4.4E-03 8.0E-03 1.7E-04 1.4E-04 1.6E-05 Composition Misfit: 1.796465E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 23.125 0.095687 0.057549 0.000000 0.000539 0.000000 0.000000 0.000000 0.153774 0.692451 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.7E-04 6.2E-04 0. 1.2E-03 0. 0. 0. 3.3E-04 6.1E-06 Composition Misfit: 2.367584E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.263 0.000000 0.000000 0.011222 0.074855 0.208630 0.000758 0.186751 0.122820 0.394965 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -2. 0.2 -1. 1. 1. Chi 0. 0. 9.2E-03 8.3E-04 2.8E-03 5.9E-04 1.6E-03 2.5E-03 1.1E-03 Composition Misfit: 1.858806E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.015 0.000000 0.000000 0.004171 0.000000 0.150832 0.002730 0.047557 0.430636 0.364074 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -1. 0.2 -3. 0.9 1. Chi 0. 0. 2.4E-03 0. 2.6E-03 4.5E-04 1.3E-02 7.4E-04 1.4E-03 Composition Misfit: 2.030082E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.729 0.000000 0.000000 0.446330 0.000000 0.529941 0.011577 0.012151 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -5. 0. 5. -0.3 -0.3 0. 0. Chi 0. 0. 2.1E-02 0. 1.9E-02 2.1E-04 3.8E-04 0. 0. Composition Misfit: 4.027861E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.328 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.581 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023081 0.014604 0.006910 0.016307 0.052399 0.000909 0.039913 0.039248 0.000940 0.107401 0.698288 Mica 0.055392 0.038807 0.000000 0.008504 0.000139 0.000000 0.000262 0.166600 0.000000 0.268902 0.461394 Gt 0.000000 0.033679 0.000000 0.000000 0.285819 0.055266 0.057834 0.000000 0.001484 0.139254 0.426664 Fsp 0.095687 0.057549 0.000000 0.000539 0.000000 0.000000 0.000000 0.000000 0.000000 0.153774 0.692451 Bio 0.000000 0.000000 0.009830 0.065571 0.182754 0.000664 0.163589 0.121312 0.002714 0.107587 0.345979 St 0.000000 0.000000 0.003795 0.000000 0.137267 0.002485 0.043280 0.088355 0.001580 0.391906 0.331331 Ilm 0.000000 0.000000 0.434666 0.000000 0.516092 0.011275 0.011834 0.000000 0.026134 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -759154. -744711. -920460. -833412. -303406. -453101. -630497. -284791. -415223. -1622380. -878531. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 199 converged, 52 successes so far. Misfit function evaluations this try => 149 Misfit this try = 0.201069 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 8.642596E-07 Bayes score, PP * exp(-Misfit) = 7.068396E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 13487.5 828.009 0.215906 0.949733 Final coordinates: 8334.10 928.760 0.964822 0.550669 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.201069 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.387 0.024970 0.026034 0.000000 0.060984 0.003657 0.000000 0.006633 0.299640 0.578082 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 8.6E-03 0. 0. 9.0E-03 1.5E-02 0. 7.2E-03 1.2E-03 8.3E-04 Composition Misfit: 6.826146E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.754 0.000000 0.025325 0.000000 0.000000 0.273772 0.049066 0.088748 0.136792 0.426297 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 3. -2. -3. 0.5 -0.2 Chi 0. 9.0E-04 0. 0. 8.5E-03 4.5E-03 1.3E-02 3.6E-04 6.3E-06 Composition Misfit: 2.720318E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.510 0.095044 0.057844 0.000000 0.001033 0.000000 0.000000 0.000000 0.153922 0.692156 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.2E-04 6.8E-04 0. 1.0E-04 0. 0. 0. 3.2E-04 7.9E-06 Composition Misfit: 1.222094E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.501 0.000000 0.000000 0.013257 0.075208 0.191208 0.001139 0.202112 0.128116 0.388960 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.4 0.1 -2. 0.9 1. Chi 0. 0. 5.0E-03 9.1E-04 2.4E-04 7.1E-05 5.3E-03 1.2E-03 1.9E-03 Composition Misfit: 1.446913E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.017 0.000000 0.000000 0.004700 0.000000 0.134154 0.003353 0.066936 0.427528 0.363329 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.2 0.1 -5. 1. 1. Chi 0. 0. 1.5E-03 0. 7.2E-05 7.0E-05 2.9E-02 1.0E-03 1.5E-03 Composition Misfit: 3.303818E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.242 0.000000 0.000000 0.247261 0.000000 0.731583 0.010907 0.010249 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. -0.1 -4.0E-02 0. 0. Chi 0. 0. 4.3E-02 0. 1.4E-02 7.5E-05 6.1E-06 0. 0. Composition Misfit: 5.687532E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.333 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.256 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023204 0.014682 0.006947 0.016395 0.052679 0.000914 0.040126 0.031883 0.003177 0.107976 0.702018 Mica 0.020844 0.021732 0.000000 0.050907 0.003052 0.000000 0.005537 0.165235 0.000000 0.250129 0.482563 Gt 0.000000 0.025258 0.000000 0.000000 0.273048 0.048937 0.088513 0.000000 0.002647 0.136430 0.425169 Fsp 0.095044 0.057844 0.000000 0.001033 0.000000 0.000000 0.000000 0.000000 0.000000 0.153922 0.692156 Bio 0.000000 0.000000 0.011610 0.065865 0.167455 0.000998 0.177005 0.120120 0.004107 0.112200 0.340641 St 0.000000 0.000000 0.004274 0.000000 0.122008 0.003049 0.060876 0.088115 0.002425 0.388819 0.330433 Ilm 0.000000 0.000000 0.219520 0.000000 0.649505 0.009683 0.009100 0.000000 0.112192 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777335. -756123. -932421. -853014. -315535. -466694. -637469. -292458. -405368. -1636628. -887154. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 205 converged, 53 successes so far. Misfit function evaluations this try => 204 Misfit this try = 0.305785 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 8.412918E-07 Bayes score, PP * exp(-Misfit) = 6.196493E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6985.09 949.346 0.931726 0.935506 Final coordinates: 8172.07 927.118 0.933560 0.922513 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.215978 Extraneous predicted phases: 8.980687E-2 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.901 0.026045 0.026103 0.000000 0.059937 0.003285 0.000000 0.006385 0.300480 0.577765 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 9.4E-03 0. 0. 1.0E-02 1.9E-02 0. 8.0E-03 1.3E-03 8.6E-04 Composition Misfit: 7.466068E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.143 0.000000 0.024073 0.000000 0.000000 0.261167 0.060499 0.090812 0.137053 0.426395 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 3. -3. -3. 0.5 -0.2 Chi 0. 5.2E-04 0. 0. 1.4E-02 1.1E-02 1.4E-02 3.4E-04 7.1E-06 Composition Misfit: 4.066734E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 24.780 0.095319 0.057309 0.000000 0.001027 0.000000 0.000000 0.000000 0.153654 0.692691 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.4E-04 5.7E-04 0. 1.1E-04 0. 0. 0. 3.4E-04 4.7E-06 Composition Misfit: 1.163513E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.173 0.000000 0.000000 0.013427 0.075200 0.183439 0.001399 0.209602 0.127999 0.388935 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. 0.1 7.4E-03 -3. 0.9 1. Chi 0. 0. 4.7E-03 9.0E-04 5.8E-06 4.7E-07 7.7E-03 1.2E-03 1.9E-03 Composition Misfit: 1.633597E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.224 0.000000 0.000000 0.004883 0.000000 0.129751 0.004203 0.070290 0.427529 0.363345 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. 0.1 -0.1 -6. 1. 1. Chi 0. 0. 1.2E-03 0. 1.3E-05 3.2E-05 3.2E-02 1.0E-03 1.5E-03 Composition Misfit: 3.567098E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.182 0.000000 0.000000 0.255470 0.000000 0.718563 0.014506 0.011461 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. -0.7 -0.2 0. 0. Chi 0. 0. 3.5E-02 0. 1.1E-02 1.4E-03 1.9E-04 0. 0. Composition Misfit: 4.747952E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.017 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.594 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Melt 0.057 0.033775 0.010359 0.008591 0.012320 0.002575 0.000000 0.001820 0.387868 0.000285 0.058177 0.484230 F 0.929 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000017 -.000017 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022717 0.014374 0.006801 0.016051 0.051574 0.000895 0.039284 0.052291 0.003009 0.105711 0.687292 Mica 0.021739 0.021787 0.000000 0.050028 0.002742 0.000000 0.005329 0.165321 0.000000 0.250805 0.482248 Gt 0.000000 0.024012 0.000000 0.000000 0.260506 0.060346 0.090582 0.000000 0.002533 0.136706 0.425315 Fsp 0.095319 0.057309 0.000000 0.001027 0.000000 0.000000 0.000000 0.000000 0.000000 0.153654 0.692691 Bio 0.000000 0.000000 0.011760 0.065866 0.160671 0.001225 0.183587 0.119973 0.004145 0.112112 0.340661 St 0.000000 0.000000 0.004441 0.000000 0.118008 0.003823 0.063928 0.088123 0.002378 0.388837 0.330462 Ilm 0.000000 0.000000 0.227638 0.000000 0.640280 0.012925 0.010212 0.000000 0.108945 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777629. -756482. -932121. -853721. -315833. -465034. -637298. -292437. -404769. -1636715. -887347. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio sill ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio sill ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 222 converged, 54 successes so far. Misfit function evaluations this try => 132 Misfit this try = 0.121166 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 8.174481E-07 Bayes score, PP * exp(-Misfit) = 7.241664E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 7559.24 901.734 0.713273 0.432223 Final coordinates: 8221.79 930.836 0.537909 0.522496 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121166 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.211 0.022788 0.024207 0.000000 0.064037 0.004083 0.000000 0.006632 0.298174 0.580079 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.8E-03 0. 0. 6.5E-03 1.2E-02 0. 7.2E-03 1.1E-03 6.8E-04 Composition Misfit: 5.869321E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.928 0.000000 0.024458 0.000000 0.000000 0.284256 0.044324 0.083351 0.137171 0.426439 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 6.3E-04 0. 0. 5.0E-03 2.3E-03 9.8E-03 3.2E-04 7.4E-06 Composition Misfit: 1.802120E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.178 0.094757 0.058290 0.000000 0.001098 0.000000 0.000000 0.000000 0.154145 0.691710 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.7E-04 0. 6.2E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.239374E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.941 0.000000 0.000000 0.013469 0.075319 0.203171 0.001052 0.188589 0.129779 0.388622 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.3E-04 1.7E-03 1.3E-04 1.9E-03 8.6E-04 1.9E-03 Composition Misfit: 1.212104E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.073 0.000000 0.000000 0.004858 0.000000 0.139559 0.003049 0.061365 0.427766 0.363403 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.2E-04 2.0E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.851321E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.824 0.000000 0.000000 0.357722 0.000000 0.615195 0.011966 0.015117 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.4 0. 0.7 -0.3 -0.8 0. 0. Chi 0. 0. 1.7E-04 0. 3.6E-04 3.2E-04 1.7E-03 0. 0. Composition Misfit: 2.578133E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.698 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.146 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023275 0.014727 0.006968 0.016444 0.052839 0.000917 0.040248 0.030344 0.001776 0.108304 0.704157 Mica 0.019024 0.020209 0.000000 0.053459 0.003409 0.000000 0.005536 0.165176 0.000000 0.248923 0.484264 Gt 0.000000 0.024398 0.000000 0.000000 0.283551 0.044214 0.083144 0.000000 0.002481 0.136831 0.425381 Fsp 0.094757 0.058290 0.000000 0.001098 0.000000 0.000000 0.000000 0.000000 0.000000 0.154145 0.691710 Bio 0.000000 0.000000 0.011798 0.065977 0.177973 0.000921 0.165199 0.120156 0.003867 0.113683 0.340424 St 0.000000 0.000000 0.004418 0.000000 0.126936 0.002773 0.055814 0.088142 0.002310 0.389074 0.330533 Ilm 0.000000 0.000000 0.333964 0.000000 0.574337 0.011171 0.014113 0.000000 0.066414 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778320. -756735. -932682. -853455. -315559. -467825. -638229. -292981. -408642. -1637206. -887639. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio F sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio F sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Mica Bio ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Mica Bio ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 230 converged, 55 successes so far. Misfit function evaluations this try => 193 Misfit this try = 0.185515 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 8.862159E-07 Bayes score, PP * exp(-Misfit) = 7.361589E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 13502.8 844.617 0.195310 0.909251 Final coordinates: 8500.87 930.213 0.901089 0.551880 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.185515 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.518 0.025270 0.026608 0.000000 0.060377 0.003759 0.000000 0.006737 0.299659 0.577591 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 8.8E-03 0. 0. 9.6E-03 1.5E-02 0. 6.9E-03 1.2E-03 8.7E-04 Composition Misfit: 6.854573E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.941 0.000000 0.026093 0.000000 0.000000 0.278423 0.043122 0.089320 0.136757 0.426284 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.7 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 1.2E-03 0. 0. 6.8E-03 1.8E-03 1.3E-02 3.7E-04 6.2E-06 Composition Misfit: 2.351774E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.436 0.095205 0.057533 0.000000 0.001029 0.000000 0.000000 0.000000 0.153766 0.692467 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.3E-04 6.1E-04 0. 1.1E-04 0. 0. 0. 3.3E-04 6.0E-06 Composition Misfit: 1.187364E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.447 0.000000 0.000000 0.013514 0.075163 0.191926 0.001003 0.201374 0.127440 0.389580 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.5 0.1 -2. 0.9 1. Chi 0. 0. 4.6E-03 9.0E-04 2.9E-04 1.8E-04 5.0E-03 1.3E-03 1.8E-03 Composition Misfit: 1.405368E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.010 0.000000 0.000000 0.004892 0.000000 0.134590 0.002923 0.066744 0.427510 0.363341 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.3 0.2 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 9.3E-05 2.9E-04 2.9E-02 1.0E-03 1.5E-03 Composition Misfit: 3.284869E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.185 0.000000 0.000000 0.257045 0.000000 0.721508 0.010211 0.011236 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. -3.4E-02 -0.2 0. 0. Chi 0. 0. 3.4E-02 0. 1.2E-02 4.3E-06 1.4E-04 0. 0. Composition Misfit: 4.536146E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.281 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.183 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023207 0.014684 0.006948 0.016397 0.052686 0.000914 0.040132 0.031957 0.002967 0.107991 0.702116 Mica 0.021095 0.022212 0.000000 0.050402 0.003138 0.000000 0.005624 0.165206 0.000000 0.250153 0.482169 Gt 0.000000 0.026023 0.000000 0.000000 0.277682 0.043008 0.089082 0.000000 0.002662 0.136393 0.425149 Fsp 0.095205 0.057533 0.000000 0.001029 0.000000 0.000000 0.000000 0.000000 0.000000 0.153766 0.692467 Bio 0.000000 0.000000 0.011840 0.065853 0.168154 0.000879 0.176432 0.119866 0.003995 0.111655 0.341326 St 0.000000 0.000000 0.004449 0.000000 0.122409 0.002659 0.060703 0.088122 0.002382 0.388819 0.330457 Ilm 0.000000 0.000000 0.229202 0.000000 0.643355 0.009105 0.010019 0.000000 0.108319 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776918. -755819. -932012. -852563. -315433. -467710. -637408. -292356. -406104. -1636501. -886931. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 236 converged, 56 successes so far. Misfit function evaluations this try => 139 Misfit this try = 0.129187 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 8.483845E-07 Bayes score, PP * exp(-Misfit) = 7.455686E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 7597.24 857.757 0.156227 0.508957 Final coordinates: 7793.98 909.127 0.489292 0.517282 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.129187 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.599 0.022728 0.022823 0.000000 0.064895 0.003646 0.000000 0.006008 0.298862 0.581039 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 6.7E-03 0. 0. 5.9E-03 1.5E-02 0. 9.5E-03 1.1E-03 6.2E-04 Composition Misfit: 6.212979E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.724 0.000000 0.024783 0.000000 0.000000 0.281083 0.052822 0.077013 0.137672 0.426627 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -2. -2. 0.4 -0.2 Chi 0. 7.2E-04 0. 0. 5.9E-03 6.5E-03 6.4E-03 2.8E-04 9.1E-06 Composition Misfit: 1.988393E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.347 0.094647 0.058724 0.000000 0.000991 0.000000 0.000000 0.000000 0.154362 0.691276 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 9.5E-05 8.7E-04 0. 1.4E-04 0. 0. 0. 2.8E-04 1.5E-05 Composition Misfit: 1.387889E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.409 0.000000 0.000000 0.012969 0.075322 0.205670 0.001151 0.186270 0.129835 0.388783 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 5.4E-03 9.3E-04 2.2E-03 6.5E-05 1.5E-03 8.5E-04 1.9E-03 Composition Misfit: 1.286985E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.036 0.000000 0.000000 0.004678 0.000000 0.142041 0.003490 0.058110 0.428186 0.363495 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.8 0.1 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 8.5E-04 3.5E-05 2.1E-02 9.7E-04 1.4E-03 Composition Misfit: 2.609301E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.789 0.000000 0.000000 0.378127 0.000000 0.593491 0.013832 0.014550 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. -0.6 -0.7 0. 0. Chi 0. 0. 2.1E-03 0. 2.2E-03 1.1E-03 1.4E-03 0. 0. Composition Misfit: 6.822316E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.924 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.172 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023286 0.014734 0.006971 0.016452 0.052864 0.000917 0.040267 0.030055 0.001617 0.108355 0.704483 Mica 0.018971 0.019050 0.000000 0.054166 0.003043 0.000000 0.005014 0.165324 0.000000 0.249453 0.484979 Gt 0.000000 0.024727 0.000000 0.000000 0.280446 0.052703 0.076839 0.000000 0.002263 0.137360 0.425661 Fsp 0.094647 0.058724 0.000000 0.000991 0.000000 0.000000 0.000000 0.000000 0.000000 0.154362 0.691276 Bio 0.000000 0.000000 0.011357 0.065957 0.180097 0.001008 0.163109 0.120557 0.003782 0.113691 0.340442 St 0.000000 0.000000 0.004255 0.000000 0.129202 0.003174 0.052857 0.088170 0.002223 0.389481 0.330637 Ilm 0.000000 0.000000 0.356409 0.000000 0.559403 0.013037 0.013714 0.000000 0.057437 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775412. -754973. -930660. -850384. -313436. -464109. -637013. -291650. -409149. -1634663. -886265. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 237 converged, 57 successes so far. Misfit function evaluations this try => 261 Misfit this try = 0.264422 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 4.793451E-08 Bayes score, PP * exp(-Misfit) = 3.679689E-08 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5893.90 930.002 0.911440 6.553026E-02 Final coordinates: 5012.64 819.701 0.586035 0.529425 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.264422 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.029 0.020177 0.014497 0.000000 0.072039 0.001802 0.000000 0.003557 0.300283 0.587646 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 1. 0. 1. -1. 2. Chi 4.8E-03 0. 0. 2.1E-03 4.9E-02 0. 2.8E-02 1.3E-03 2.6E-04 Composition Misfit: 9.959102E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.052 0.000000 0.019126 0.000000 0.000000 0.232949 0.127212 0.053907 0.139495 0.427311 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. 0.2 0. 0. 5. -1.0E+01 0.1 0.3 -0.3 Chi 0. 1.1E-04 0. 0. 3.4E-02 0.1 1.5E-05 1.4E-04 1.6E-05 Composition Misfit: 0.102189 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.477 0.094448 0.059704 0.000000 0.000700 0.000000 0.000000 0.000000 0.154852 0.690296 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 0.2 0. 0. 0. 0.4 0.2 Chi 8.3E-05 1.1E-03 0. 6.2E-04 0. 0. 0. 2.4E-04 2.6E-05 Composition Misfit: 2.063982E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.869 0.000000 0.000000 0.010137 0.075669 0.206781 0.001922 0.185753 0.135030 0.384709 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. -0.1 -1. 0.4 2. Chi 0. 0. 1.2E-02 1.0E-03 2.4E-03 1.3E-04 1.4E-03 2.1E-04 2.5E-03 Composition Misfit: 2.014481E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.366 0.000000 0.000000 0.003385 0.000000 0.147277 0.007682 0.048563 0.429400 0.363694 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -1. -0.8 -3. 1. 1. Chi 0. 0. 4.6E-03 0. 1.8E-03 1.9E-03 1.4E-02 8.5E-04 1.4E-03 Composition Misfit: 2.410687E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.912 0.000000 0.000000 0.367933 0.000000 0.592876 0.029733 0.009458 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 2. -3. 0.1 0. 0. Chi 0. 0. 8.7E-04 0. 2.3E-03 1.3E-02 3.1E-05 0. 0. Composition Misfit: 1.632637E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.729 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.567 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023262 0.014718 0.006964 0.016435 0.052810 0.000916 0.040226 0.030729 0.001934 0.108244 0.703762 Mica 0.016829 0.012092 0.000000 0.060086 0.001503 0.000000 0.002966 0.165922 0.000000 0.250459 0.490143 Gt 0.000000 0.019098 0.000000 0.000000 0.232607 0.127025 0.053828 0.000000 0.001469 0.139290 0.426683 Fsp 0.094448 0.059704 0.000000 0.000700 0.000000 0.000000 0.000000 0.000000 0.000000 0.154852 0.690296 Bio 0.000000 0.000000 0.008844 0.066019 0.180410 0.001677 0.162064 0.123193 0.004337 0.117810 0.335647 St 0.000000 0.000000 0.003079 0.000000 0.133964 0.006988 0.044173 0.088218 0.002172 0.390586 0.330819 Ilm 0.000000 0.000000 0.345142 0.000000 0.556151 0.027892 0.008872 0.000000 0.061943 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -768389. -751455. -925336. -843232. -306804. -449697. -633202. -288016. -405698. -1627060. -883339. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 238 converged, 58 successes so far. Misfit function evaluations this try => 206 Misfit this try = 0.207366 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 8.460125E-07 Bayes score, PP * exp(-Misfit) = 6.875732E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 12407.6 976.868 0.936892 0.162128 Final coordinates: 8261.08 928.886 0.990465 0.550038 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.207366 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.324 0.024764 0.025740 0.000000 0.061343 0.003628 0.000000 0.006606 0.299565 0.578354 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 8.4E-03 0. 0. 8.7E-03 1.6E-02 0. 7.3E-03 1.2E-03 8.1E-04 Composition Misfit: 6.776281E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.681 0.000000 0.024888 0.000000 0.000000 0.271819 0.051634 0.088573 0.136789 0.426296 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 3. -2. -3. 0.5 -0.2 Chi 0. 7.6E-04 0. 0. 9.2E-03 5.9E-03 1.3E-02 3.6E-04 6.3E-06 Composition Misfit: 2.909671E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.546 0.094975 0.057967 0.000000 0.001041 0.000000 0.000000 0.000000 0.153984 0.692033 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.2E-04 7.0E-04 0. 9.6E-05 0. 0. 0. 3.1E-04 8.8E-06 Composition Misfit: 1.232242E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.523 0.000000 0.000000 0.013138 0.075233 0.190918 0.001206 0.202386 0.128502 0.388617 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.4 0.1 -2. 0.9 1. Chi 0. 0. 5.2E-03 9.1E-04 2.2E-04 4.0E-05 5.3E-03 1.1E-03 1.9E-03 Composition Misfit: 1.467140E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.023 0.000000 0.000000 0.004611 0.000000 0.133855 0.003565 0.067121 0.427527 0.363321 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.2 0.1 -5. 1. 1. Chi 0. 0. 1.6E-03 0. 5.9E-05 2.1E-05 2.9E-02 1.0E-03 1.5E-03 Composition Misfit: 3.327168E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.265 0.000000 0.000000 0.243849 0.000000 0.734862 0.011339 0.009950 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. -0.2 8.0E-03 0. 0. Chi 0. 0. 4.6E-02 0. 1.5E-02 1.6E-04 2.5E-07 0. 0. Composition Misfit: 6.133096E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.349 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.289 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023203 0.014681 0.006947 0.016394 0.052676 0.000914 0.040124 0.031845 0.003261 0.107970 0.701985 Mica 0.020672 0.021486 0.000000 0.051206 0.003029 0.000000 0.005515 0.165243 0.000000 0.250064 0.482786 Gt 0.000000 0.024822 0.000000 0.000000 0.271100 0.051498 0.088338 0.000000 0.002648 0.136427 0.425167 Fsp 0.094975 0.057967 0.000000 0.001041 0.000000 0.000000 0.000000 0.000000 0.000000 0.153984 0.692033 Bio 0.000000 0.000000 0.011503 0.065874 0.167166 0.001056 0.177207 0.120244 0.004166 0.112515 0.340269 St 0.000000 0.000000 0.004193 0.000000 0.121733 0.003242 0.061043 0.088112 0.002449 0.388810 0.330419 Ilm 0.000000 0.000000 0.216164 0.000000 0.651430 0.010052 0.008820 0.000000 0.113535 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777686. -756368. -932703. -853378. -315671. -466377. -637566. -292575. -405094. -1636806. -887336. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 240 converged, 59 successes so far. Misfit function evaluations this try => 147 Misfit this try = 0.167947 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 2.441329E-07 Bayes score, PP * exp(-Misfit) = 2.063897E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5482.14 918.995 0.311461 0.117823 Final coordinates: 6894.01 833.674 0.458587 0.530796 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.167947 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.933 0.024107 0.020443 0.000000 0.064988 0.002388 0.000000 0.004454 0.301327 0.582294 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 7.8E-03 0. 0. 5.8E-03 3.2E-02 0. 1.9E-02 1.4E-03 5.4E-04 Composition Misfit: 8.685366E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.600 0.000000 0.030851 0.000000 0.000000 0.276985 0.066079 0.060853 0.138350 0.426881 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 3. -4. -0.6 0.4 -0.3 Chi 0. 3.4E-03 0. 0. 7.3E-03 1.5E-02 6.0E-04 2.2E-04 1.2E-05 Composition Misfit: 2.689730E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.194 0.094943 0.058883 0.000000 0.000615 0.000000 0.000000 0.000000 0.154442 0.691117 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.4 0.2 Chi 1.1E-04 9.0E-04 0. 9.0E-04 0. 0. 0. 2.7E-04 1.7E-05 Composition Misfit: 2.199354E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.315 0.000000 0.000000 0.011063 0.075070 0.207772 0.001005 0.188014 0.126055 0.391020 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -2. 0.1 -1. 1. 1. Chi 0. 0. 9.6E-03 8.8E-04 2.6E-03 1.8E-04 1.8E-03 1.6E-03 1.6E-03 Composition Misfit: 1.828820E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.041 0.000000 0.000000 0.003861 0.000000 0.149595 0.003565 0.050116 0.429184 0.363679 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -1. 0.1 -3. 1. 1. Chi 0. 0. 3.1E-03 0. 2.3E-03 2.1E-05 1.5E-02 8.7E-04 1.4E-03 Composition Misfit: 2.247284E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.828 0.000000 0.000000 0.395628 0.000000 0.578850 0.014388 0.011134 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -3. 0. 2. -0.7 -0.2 0. 0. Chi 0. 0. 5.3E-03 0. 4.5E-03 1.3E-03 1.2E-04 0. 0. Composition Misfit: 1.123558E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.014 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.076 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023270 0.014723 0.006967 0.016441 0.052828 0.000917 0.040239 0.030819 0.001514 0.108281 0.704002 Mica 0.020112 0.017055 0.000000 0.054218 0.001992 0.000000 0.003716 0.165715 0.000000 0.251392 0.485799 Gt 0.000000 0.030791 0.000000 0.000000 0.276440 0.065949 0.060733 0.000000 0.001968 0.138077 0.426041 Fsp 0.094943 0.058883 0.000000 0.000615 0.000000 0.000000 0.000000 0.000000 0.000000 0.154442 0.691117 Bio 0.000000 0.000000 0.009676 0.065662 0.181733 0.000879 0.164451 0.121648 0.003681 0.110257 0.342014 St 0.000000 0.000000 0.003512 0.000000 0.136081 0.003243 0.045588 0.088220 0.002118 0.390412 0.330825 Ilm 0.000000 0.000000 0.376005 0.000000 0.550141 0.013674 0.010582 0.000000 0.049598 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -763129. -747246. -923186. -837583. -305639. -454012. -631950. -286342. -407238. -1625048. -880435. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 249 converged, 60 successes so far. Misfit function evaluations this try => 194 Misfit this try = 0.137289 Best Misfit so far = 0.121013 obtained on Try 129 Prior probability, PP = 9.218338E-07 Bayes score, PP * exp(-Misfit) = 8.035790E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6865.94 922.815 0.944981 0.230559 Final coordinates: 8468.10 926.002 0.554656 0.673870 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.137289 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.798 0.025157 0.026059 0.000000 0.060776 0.003757 0.000000 0.006611 0.299551 0.578088 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 8.7E-03 0. 0. 9.2E-03 1.5E-02 0. 7.3E-03 1.2E-03 8.3E-04 Composition Misfit: 6.788416E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.809 0.000000 0.026240 0.000000 0.000000 0.281634 0.041548 0.087254 0.136963 0.426361 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.7 0. 0. 2. -0.8 -3. 0.5 -0.2 Chi 0. 1.2E-03 0. 0. 5.8E-03 1.3E-03 1.2E-02 3.4E-04 6.8E-06 Composition Misfit: 2.070659E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.702 0.095459 0.057045 0.000000 0.001018 0.000000 0.000000 0.000000 0.153523 0.692955 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.5 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.5E-04 5.2E-04 0. 1.1E-04 0. 0. 0. 3.5E-04 3.5E-06 Composition Misfit: 1.143694E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.817 0.000000 0.000000 0.013520 0.075155 0.194571 0.000950 0.198563 0.127325 0.389916 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.7 0.1 -2. 0.9 1. Chi 0. 0. 4.6E-03 9.0E-04 5.2E-04 2.4E-04 4.2E-03 1.3E-03 1.7E-03 Composition Misfit: 1.352453E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.419 0.000000 0.000000 0.004939 0.000000 0.136199 0.002780 0.065026 0.427671 0.363386 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.4 0.2 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 1.9E-04 4.0E-04 2.7E-02 1.0E-03 1.4E-03 Composition Misfit: 3.147760E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.848 0.000000 0.000000 0.355013 0.000000 0.618043 0.011134 0.015810 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.3 0. 0.5 -0.2 -0.9 0. 0. Chi 0. 0. 7.1E-05 0. 2.3E-04 1.2E-04 2.1E-03 0. 0. Composition Misfit: 2.552906E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.039 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.569 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023071 0.014598 0.006907 0.016300 0.052376 0.000909 0.039895 0.038791 0.001816 0.107355 0.697982 Mica 0.021001 0.021754 0.000000 0.050734 0.003136 0.000000 0.005519 0.165224 0.000000 0.250058 0.482574 Gt 0.000000 0.026172 0.000000 0.000000 0.280910 0.041441 0.087029 0.000000 0.002572 0.136611 0.425264 Fsp 0.095459 0.057045 0.000000 0.001018 0.000000 0.000000 0.000000 0.000000 0.000000 0.153523 0.692955 Bio 0.000000 0.000000 0.011847 0.065855 0.170495 0.000833 0.173993 0.119864 0.003875 0.111570 0.341668 St 0.000000 0.000000 0.004492 0.000000 0.123879 0.002528 0.059144 0.088137 0.002319 0.388986 0.330515 Ilm 0.000000 0.000000 0.331017 0.000000 0.576267 0.010381 0.014742 0.000000 0.067593 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776098. -755370. -931418. -851640. -314862. -467477. -637185. -292046. -407156. -1635894. -886546. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 251 converged, 61 successes so far. Misfit function evaluations this try => 252 Misfit this try = 0.120895 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.229734E-07 Bayes score, PP * exp(-Misfit) = 7.292588E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5890.15 962.046 0.735378 0.226465 Final coordinates: 8251.31 930.965 0.538171 0.521753 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.120895 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.251 0.022853 0.024318 0.000000 0.063913 0.004097 0.000000 0.006654 0.298183 0.579982 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.8E-03 0. 0. 6.6E-03 1.2E-02 0. 7.1E-03 1.1E-03 6.9E-04 Composition Misfit: 5.880031E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.965 0.000000 0.024620 0.000000 0.000000 0.284917 0.043370 0.083523 0.137142 0.426428 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 6.7E-04 0. 0. 4.8E-03 1.9E-03 9.9E-03 3.3E-04 7.4E-06 Composition Misfit: 1.761320E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.163 0.094788 0.058234 0.000000 0.001095 0.000000 0.000000 0.000000 0.154117 0.691766 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.6E-04 0. 6.3E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.232607E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.919 0.000000 0.000000 0.013480 0.075309 0.203051 0.001030 0.188784 0.129637 0.388708 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.3E-04 1.7E-03 1.5E-04 2.0E-03 8.8E-04 1.9E-03 Composition Misfit: 1.214895E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.002 0.000000 0.000000 0.004863 0.000000 0.139540 0.002983 0.061456 0.427756 0.363401 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.2E-04 2.5E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.862567E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.825 0.000000 0.000000 0.357407 0.000000 0.615748 0.011714 0.015132 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.4 0. 0.7 -0.3 -0.8 0. 0. Chi 0. 0. 1.5E-04 0. 3.3E-04 2.5E-04 1.7E-03 0. 0. Composition Misfit: 2.474375E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.746 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.129 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023276 0.014727 0.006968 0.016445 0.052842 0.000917 0.040250 0.030302 0.001777 0.108309 0.704186 Mica 0.019079 0.020302 0.000000 0.053356 0.003420 0.000000 0.005555 0.165171 0.000000 0.248932 0.484186 Gt 0.000000 0.024559 0.000000 0.000000 0.284207 0.043262 0.083314 0.000000 0.002494 0.136799 0.425364 Fsp 0.094788 0.058234 0.000000 0.001095 0.000000 0.000000 0.000000 0.000000 0.000000 0.154117 0.691766 Bio 0.000000 0.000000 0.011808 0.065971 0.177874 0.000903 0.165375 0.120134 0.003862 0.113563 0.340510 St 0.000000 0.000000 0.004423 0.000000 0.126918 0.002713 0.055897 0.088141 0.002312 0.389065 0.330530 Ilm 0.000000 0.000000 0.333621 0.000000 0.574769 0.010934 0.014125 0.000000 0.066552 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778217. -756664. -932640. -853355. -315533. -467975. -638198. -292947. -408627. -1637162. -887585. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 253 converged, 62 successes so far. Misfit function evaluations this try => 226 Misfit this try = 0.122762 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.673457E-07 Bayes score, PP * exp(-Misfit) = 7.671447E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 12898.1 938.069 8.291757E-02 0.349111 Final coordinates: 8102.45 921.889 0.524537 0.520862 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.122762 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.076 0.022952 0.023876 0.000000 0.064078 0.003911 0.000000 0.006402 0.298532 0.580249 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.9E-03 0. 0. 6.5E-03 1.3E-02 0. 8.0E-03 1.1E-03 6.7E-04 Composition Misfit: 6.042820E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.889 0.000000 0.024957 0.000000 0.000000 0.284080 0.046111 0.081060 0.137303 0.426489 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 7.8E-04 0. 0. 5.0E-03 3.1E-03 8.5E-03 3.1E-04 7.9E-06 Composition Misfit: 1.770092E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.209 0.094764 0.058385 0.000000 0.001044 0.000000 0.000000 0.000000 0.154193 0.691615 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.9E-04 0. 9.4E-05 0. 0. 0. 2.9E-04 1.2E-05 Composition Misfit: 1.289828E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.059 0.000000 0.000000 0.013259 0.075300 0.203895 0.001056 0.188163 0.129506 0.388820 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 5.0E-03 9.3E-04 1.9E-03 1.3E-04 1.8E-03 9.0E-04 1.9E-03 Composition Misfit: 1.250570E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.002 0.000000 0.000000 0.004777 0.000000 0.140606 0.003107 0.060179 0.427900 0.363430 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.7 0.2 -5. 1. 1. Chi 0. 0. 1.4E-03 0. 6.5E-04 1.7E-04 2.3E-02 1.0E-03 1.4E-03 Composition Misfit: 2.768482E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.817 0.000000 0.000000 0.363419 0.000000 0.609531 0.012250 0.014800 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.7 0. 0.9 -0.4 -0.8 0. 0. Chi 0. 0. 5.0E-04 0. 6.9E-04 4.1E-04 1.6E-03 0. 0. Composition Misfit: 3.152781E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.811 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.136 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023278 0.014729 0.006969 0.016447 0.052847 0.000917 0.040254 0.030253 0.001733 0.108320 0.704255 Mica 0.019160 0.019931 0.000000 0.053491 0.003264 0.000000 0.005344 0.165232 0.000000 0.249205 0.484373 Gt 0.000000 0.024897 0.000000 0.000000 0.283392 0.046000 0.080863 0.000000 0.002424 0.136970 0.425455 Fsp 0.094764 0.058385 0.000000 0.001044 0.000000 0.000000 0.000000 0.000000 0.000000 0.154193 0.691615 Bio 0.000000 0.000000 0.011613 0.065953 0.178584 0.000925 0.164805 0.120292 0.003844 0.113429 0.340554 St 0.000000 0.000000 0.004345 0.000000 0.127890 0.002826 0.054737 0.088150 0.002288 0.389202 0.330562 Ilm 0.000000 0.000000 0.340187 0.000000 0.570567 0.011467 0.013854 0.000000 0.063925 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776863. -755827. -931755. -851942. -314606. -466478. -637640. -292338. -408602. -1636027. -886938. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 258 converged, 63 successes so far. Misfit function evaluations this try => 178 Misfit this try = 2.85565 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 2.332061E-08 Bayes score, PP * exp(-Misfit) = 1.341364E-09 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 11842.3 886.118 0.866203 0.734828 Final coordinates: 5000.02 800.000 1.00000 0.578387 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.316356 Extraneous predicted phases: 2.53929 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.046 0.022696 0.015739 0.000000 0.068963 0.001422 0.000000 0.003300 0.301731 0.586150 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 1. 0. 1. -1. 2. Chi 6.7E-03 0. 0. 3.5E-03 0.1 0. 3.2E-02 1.5E-03 3.3E-04 Composition Misfit: 0.126196 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.000000 0.021388 0.000000 0.000000 0.223006 0.134068 0.054611 0.139583 0.427344 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.1 0. 0. 6. -1.1E+01 1.8E-02 0.3 -0.3 Chi 0. 3.3E-05 0. 0. 4.4E-02 0.1 6.1E-07 1.3E-04 1.7E-05 Composition Misfit: 0.118374 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.736 0.094591 0.059707 0.000000 0.000556 0.000000 0.000000 0.000000 0.154854 0.690293 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 0.2 0. 0. 0. 0.4 0.2 Chi 9.1E-05 1.1E-03 0. 1.2E-03 0. 0. 0. 2.4E-04 2.6E-05 Composition Misfit: 2.611888E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.593 0.000000 0.000000 0.009825 0.075400 0.192135 0.001788 0.203137 0.131003 0.386712 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.5 -0.1 -2. 0.7 2. Chi 0. 0. 1.4E-02 9.5E-04 3.1E-04 7.4E-05 5.6E-03 6.6E-04 2.2E-03 Composition Misfit: 2.332525E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.342 0.000000 0.000000 0.003339 0.000000 0.143537 0.007648 0.052191 0.429556 0.363729 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -0.9 -0.8 -4. 1. 1. Chi 0. 0. 4.8E-03 0. 1.1E-03 1.9E-03 1.6E-02 8.4E-04 1.4E-03 Composition Misfit: 2.641217E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.432 0.000000 0.000000 0.375289 0.000000 0.583892 0.030850 0.009970 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 2. -3. 4.8E-03 0. 0. Chi 0. 0. 1.7E-03 0. 3.6E-03 1.4E-02 9.3E-08 0. 0. Composition Misfit: 1.943681E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.333 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.617 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.901 0.000000 0.000000 0.180963 0.000000 0.669420 0.018270 0.003733 0.000000 0.127615 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023164 0.014657 0.006935 0.016366 0.052589 0.000913 0.040057 0.033430 0.003287 0.107790 0.700813 Mica 0.018928 0.013126 0.000000 0.057514 0.001186 0.000000 0.002752 0.166010 0.000000 0.251641 0.488843 Gt 0.000000 0.021357 0.000000 0.000000 0.222687 0.133877 0.054533 0.000000 0.001430 0.139383 0.426732 Fsp 0.094591 0.059707 0.000000 0.000556 0.000000 0.000000 0.000000 0.000000 0.000000 0.154854 0.690293 Bio 0.000000 0.000000 0.008573 0.065793 0.167654 0.001560 0.177255 0.123013 0.004401 0.114311 0.337440 St 0.000000 0.000000 0.003037 0.000000 0.130566 0.006957 0.047475 0.088230 0.002135 0.390739 0.330861 Ilm 0.000000 0.000000 0.353261 0.000000 0.549620 0.029039 0.009384 0.000000 0.058696 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -764360. -748783. -922751. -839741. -304894. -447137. -631203. -286115. -403757. -1624242. -881404. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 259 converged, 64 successes so far. Misfit function evaluations this try => 185 Misfit this try = 0.183006 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.533124E-07 Bayes score, PP * exp(-Misfit) = 7.106073E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6432.71 976.770 0.863230 0.615561 Final coordinates: 8322.88 929.595 0.898673 0.545415 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.183006 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.011 0.024530 0.025727 0.000000 0.061566 0.003748 0.000000 0.006657 0.299337 0.578435 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 8.2E-03 0. 0. 8.5E-03 1.5E-02 0. 7.1E-03 1.2E-03 8.0E-04 Composition Misfit: 6.618916E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.770 0.000000 0.025139 0.000000 0.000000 0.275655 0.048126 0.087825 0.136913 0.426342 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 3. -2. -3. 0.5 -0.2 Chi 0. 8.4E-04 0. 0. 7.8E-03 4.0E-03 1.2E-02 3.5E-04 6.7E-06 Composition Misfit: 2.538502E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.636 0.094984 0.057939 0.000000 0.001046 0.000000 0.000000 0.000000 0.153970 0.692061 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.2E-04 6.9E-04 0. 9.3E-05 0. 0. 0. 3.1E-04 8.6E-06 Composition Misfit: 1.224831E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.736 0.000000 0.000000 0.013439 0.075223 0.193128 0.001127 0.199717 0.128340 0.389025 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.6 0.1 -2. 0.9 1. Chi 0. 0. 4.7E-03 9.1E-04 3.9E-04 7.9E-05 4.6E-03 1.1E-03 1.9E-03 Composition Misfit: 1.360140E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.051 0.000000 0.000000 0.004845 0.000000 0.134981 0.003301 0.065962 0.427562 0.363350 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.3 0.1 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 1.1E-04 8.8E-05 2.8E-02 1.0E-03 1.5E-03 Composition Misfit: 3.203631E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.175 0.000000 0.000000 0.257677 0.000000 0.719797 0.011447 0.011079 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. -0.2 -0.2 0. 0. Chi 0. 0. 3.3E-02 0. 1.1E-02 1.8E-04 1.1E-04 0. 0. Composition Misfit: 4.456914E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.384 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.237 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023216 0.014690 0.006951 0.016403 0.052707 0.000915 0.040147 0.031595 0.002960 0.108032 0.702385 Mica 0.020477 0.021477 0.000000 0.051394 0.003129 0.000000 0.005557 0.165219 0.000000 0.249881 0.482866 Gt 0.000000 0.025073 0.000000 0.000000 0.274940 0.048001 0.087598 0.000000 0.002594 0.136558 0.425237 Fsp 0.094984 0.057939 0.000000 0.001046 0.000000 0.000000 0.000000 0.000000 0.000000 0.153970 0.692061 Bio 0.000000 0.000000 0.011772 0.065892 0.169173 0.000987 0.174945 0.120012 0.004026 0.112421 0.340771 St 0.000000 0.000000 0.004406 0.000000 0.122765 0.003002 0.059992 0.088124 0.002378 0.388867 0.330466 Ilm 0.000000 0.000000 0.229830 0.000000 0.642010 0.010210 0.009882 0.000000 0.108068 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777577. -756268. -932306. -853163. -315584. -466946. -637634. -292579. -406290. -1636787. -887271. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 260 converged, 65 successes so far. Misfit function evaluations this try => 141 Misfit this try = 0.122634 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.727844E-07 Bayes score, PP * exp(-Misfit) = 7.720538E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 8515.45 956.803 0.784559 7.871881E-02 Final coordinates: 8153.57 922.900 0.519803 0.522477 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.122634 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.185 0.023050 0.024075 0.000000 0.063874 0.003939 0.000000 0.006451 0.298530 0.580081 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.0E-03 0. 0. 6.6E-03 1.3E-02 0. 7.8E-03 1.1E-03 6.8E-04 Composition Misfit: 6.049701E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.935 0.000000 0.025116 0.000000 0.000000 0.284850 0.044735 0.081549 0.137273 0.426477 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 8.3E-04 0. 0. 4.8E-03 2.5E-03 8.8E-03 3.1E-04 7.8E-06 Composition Misfit: 1.721290E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.173 0.094805 0.058298 0.000000 0.001047 0.000000 0.000000 0.000000 0.154149 0.691702 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.7E-04 0. 9.2E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.274653E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.984 0.000000 0.000000 0.013309 0.075289 0.203679 0.001026 0.188413 0.129331 0.388953 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.9E-03 9.2E-04 1.8E-03 1.5E-04 1.9E-03 9.3E-04 1.9E-03 Composition Misfit: 1.247029E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.032 0.000000 0.000000 0.004804 0.000000 0.140455 0.003012 0.060413 0.427887 0.363429 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.7 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 6.3E-04 2.3E-04 2.3E-02 1.0E-03 1.4E-03 Composition Misfit: 2.788468E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.814 0.000000 0.000000 0.364726 0.000000 0.608444 0.011879 0.014951 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.8 0. 1. -0.3 -0.8 0. 0. Chi 0. 0. 5.9E-04 0. 7.6E-04 3.0E-04 1.6E-03 0. 0. Composition Misfit: 3.294797E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.755 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.122 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023276 0.014728 0.006968 0.016445 0.052843 0.000917 0.040251 0.030344 0.001717 0.108311 0.704200 Mica 0.019242 0.020097 0.000000 0.053320 0.003288 0.000000 0.005385 0.165221 0.000000 0.249207 0.484239 Gt 0.000000 0.025055 0.000000 0.000000 0.284155 0.044626 0.081350 0.000000 0.002437 0.136938 0.425438 Fsp 0.094805 0.058298 0.000000 0.001047 0.000000 0.000000 0.000000 0.000000 0.000000 0.154149 0.691702 Bio 0.000000 0.000000 0.011658 0.065948 0.178410 0.000899 0.165038 0.120238 0.003827 0.113285 0.340698 St 0.000000 0.000000 0.004369 0.000000 0.127753 0.002740 0.054949 0.088150 0.002285 0.389191 0.330562 Ilm 0.000000 0.000000 0.341620 0.000000 0.569898 0.011126 0.014004 0.000000 0.063352 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776859. -755816. -931768. -851951. -314661. -466792. -637650. -292352. -408665. -1636078. -886930. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio F sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio F sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 286 converged, 66 successes so far. Misfit function evaluations this try => 205 Misfit this try = 0.151091 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 6.538750E-07 Bayes score, PP * exp(-Misfit) = 5.621817E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 14462.4 817.632 9.959182E-02 0.428674 Final coordinates: 7403.76 874.784 0.386383 0.517753 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.151091 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.387 0.023276 0.021728 0.000000 0.065022 0.003095 0.000000 0.005285 0.299970 0.581624 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 7.2E-03 0. 0. 5.8E-03 2.1E-02 0. 1.3E-02 1.3E-03 5.8E-04 Composition Misfit: 7.046115E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.713 0.000000 0.026978 0.000000 0.000000 0.281789 0.056730 0.069069 0.138498 0.426937 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.8 0. 0. 2. -2. -1. 0.4 -0.3 Chi 0. 1.5E-03 0. 0. 5.7E-03 8.9E-03 3.0E-03 2.1E-04 1.2E-05 Composition Misfit: 1.932596E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.373 0.094783 0.058819 0.000000 0.000807 0.000000 0.000000 0.000000 0.154410 0.691181 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.4 0.1 Chi 1.0E-04 8.9E-04 0. 3.8E-04 0. 0. 0. 2.7E-04 1.6E-05 Composition Misfit: 1.655031E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.638 0.000000 0.000000 0.012401 0.075204 0.207785 0.001059 0.184799 0.128064 0.390688 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -2. 0.1 -1. 0.9 1. Chi 0. 0. 6.5E-03 9.1E-04 2.6E-03 1.3E-04 1.3E-03 1.2E-03 1.6E-03 Composition Misfit: 1.420101E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.003 0.000000 0.000000 0.004555 0.000000 0.145490 0.003413 0.053721 0.429104 0.363717 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.1 -4. 1. 1. Chi 0. 0. 1.7E-03 0. 1.4E-03 5.3E-05 1.8E-02 8.8E-04 1.4E-03 Composition Misfit: 2.311644E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.737 0.000000 0.000000 0.415635 0.000000 0.556450 0.013855 0.014061 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -4. 0. 3. -0.6 -0.6 0. 0. Chi 0. 0. 1.0E-02 0. 9.7E-03 1.1E-03 1.2E-03 0. 0. Composition Misfit: 2.233157E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.071 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.078 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023293 0.014738 0.006973 0.016457 0.052880 0.000918 0.040280 0.030092 0.001277 0.108389 0.704703 Mica 0.019424 0.018132 0.000000 0.054261 0.002583 0.000000 0.004410 0.165501 0.000000 0.250325 0.485365 Gt 0.000000 0.026926 0.000000 0.000000 0.281252 0.056622 0.068938 0.000000 0.001904 0.138234 0.426124 Fsp 0.094783 0.058819 0.000000 0.000807 0.000000 0.000000 0.000000 0.000000 0.000000 0.154410 0.691181 Bio 0.000000 0.000000 0.010860 0.065862 0.181973 0.000927 0.161842 0.120864 0.003362 0.112155 0.342155 St 0.000000 0.000000 0.004144 0.000000 0.132366 0.003105 0.048875 0.088242 0.001965 0.390395 0.330907 Ilm 0.000000 0.000000 0.398812 0.000000 0.533927 0.013294 0.013492 0.000000 0.040475 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -769654. -751352. -926834. -844361. -309737. -459632. -634687. -289170. -411691. -1630147. -883510. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 288 converged, 67 successes so far. Misfit function evaluations this try => 199 Misfit this try = 0.123649 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.262327E-07 Bayes score, PP * exp(-Misfit) = 7.301333E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6779.87 948.243 0.524240 8.453021E-02 Final coordinates: 8250.98 930.636 0.480215 0.531128 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.123649 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.364 0.022830 0.024275 0.000000 0.063957 0.004111 0.000000 0.006642 0.298159 0.580026 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.8E-03 0. 0. 6.6E-03 1.2E-02 0. 7.2E-03 1.0E-03 6.9E-04 Composition Misfit: 5.864524E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.975 0.000000 0.024493 0.000000 0.000000 0.285617 0.042808 0.083200 0.137369 0.426513 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -0.9 -3. 0.5 -0.2 Chi 0. 6.4E-04 0. 0. 4.6E-03 1.7E-03 9.7E-03 3.0E-04 8.1E-06 Composition Misfit: 1.697167E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.127 0.094806 0.058200 0.000000 0.001095 0.000000 0.000000 0.000000 0.154100 0.691800 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.5E-04 0. 6.3E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.228062E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.832 0.000000 0.000000 0.013617 0.075305 0.203523 0.001014 0.187920 0.129573 0.389048 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.4E-03 9.3E-04 1.8E-03 1.7E-04 1.8E-03 8.9E-04 1.9E-03 Composition Misfit: 1.184083E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.499 0.000000 0.000000 0.004993 0.000000 0.139657 0.002929 0.061047 0.427920 0.363454 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 5.3E-04 2.8E-04 2.4E-02 9.9E-04 1.4E-03 Composition Misfit: 2.814354E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.773 0.000000 0.000000 0.378220 0.000000 0.594029 0.011677 0.016074 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. -0.3 -1. 0. 0. Chi 0. 0. 2.1E-03 0. 2.2E-03 2.4E-04 2.3E-03 0. 0. Composition Misfit: 6.819958E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.284 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.146 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023268 0.014722 0.006966 0.016439 0.052823 0.000917 0.040236 0.030835 0.001585 0.108271 0.703938 Mica 0.019059 0.020265 0.000000 0.053393 0.003432 0.000000 0.005545 0.165171 0.000000 0.248912 0.484223 Gt 0.000000 0.024435 0.000000 0.000000 0.284933 0.042706 0.083000 0.000000 0.002396 0.137039 0.425491 Fsp 0.094806 0.058200 0.000000 0.001095 0.000000 0.000000 0.000000 0.000000 0.000000 0.154100 0.691800 Bio 0.000000 0.000000 0.011932 0.065985 0.178334 0.000889 0.164662 0.120037 0.003730 0.113536 0.340896 St 0.000000 0.000000 0.004541 0.000000 0.127034 0.002665 0.055529 0.088161 0.002227 0.389242 0.330602 Ilm 0.000000 0.000000 0.356511 0.000000 0.559935 0.011007 0.015152 0.000000 0.057395 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778144. -756621. -932419. -853263. -315461. -468038. -638190. -292923. -409895. -1637110. -887550. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 294 converged, 68 successes so far. Misfit function evaluations this try => 336 Misfit this try = 1.41857 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 5.525074E-07 Bayes score, PP * exp(-Misfit) = 1.337399E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5863.88 817.817 0.456808 0.802873 Final coordinates: 7691.24 854.810 0.384896 0.779791 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.41857 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 9.940 0.065410 0.046144 0.000000 0.011441 0.000274 0.000000 0.000495 0.322073 0.554163 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -9. 0. 0. 6. 2. 0. 2. -2. 6. Chi 4.6E-02 0. 0. 0.5 0.4 0. 0.3 5.4E-03 3.8E-03 Composition Misfit: 1.34450 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.092 0.000000 0.032264 0.000000 0.000000 0.290988 0.044108 0.067626 0.138192 0.426822 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -1. -1. 0.4 -0.3 Chi 0. 4.3E-03 0. 0. 3.3E-03 2.2E-03 2.4E-03 2.3E-04 1.1E-05 Composition Misfit: 1.242331E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.526 0.096250 0.056139 0.000000 0.000681 0.000000 0.000000 0.000000 0.153069 0.693861 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.4 -0.4 0. 0.2 0. 0. 0. 0.5 2.9E-02 Chi 2.2E-04 3.7E-04 0. 6.7E-04 0. 0. 0. 4.0E-04 5.9E-07 Composition Misfit: 1.660394E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.595 0.000000 0.000000 0.011973 0.074929 0.205370 0.000729 0.190048 0.123937 0.393015 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.2 -1. 1. 1. Chi 0. 0. 7.4E-03 8.5E-04 2.1E-03 6.6E-04 2.2E-03 2.2E-03 1.3E-03 Composition Misfit: 1.673166E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.204 0.000000 0.000000 0.004381 0.000000 0.147171 0.002410 0.053134 0.429181 0.363723 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 2.0E-03 0. 1.8E-03 8.5E-04 1.7E-02 8.7E-04 1.4E-03 Composition Misfit: 2.404917E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.765 0.000000 0.000000 0.414849 0.000000 0.561894 0.009972 0.013285 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -4. 0. 3. 4.5E-03 -0.5 0. 0. Chi 0. 0. 1.0E-02 0. 8.3E-03 8.0E-08 8.1E-04 0. 0. Composition Misfit: 1.920479E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.825 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 42.053 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022944 0.014517 0.006869 0.016210 0.052088 0.000904 0.039676 0.044641 0.001253 0.106763 0.694136 Mica 0.054515 0.038458 0.000000 0.009536 0.000228 0.000000 0.000412 0.166560 0.000000 0.268429 0.461862 Gt 0.000000 0.032199 0.000000 0.000000 0.290395 0.044018 0.067488 0.000000 0.002037 0.137910 0.425953 Fsp 0.096250 0.056139 0.000000 0.000681 0.000000 0.000000 0.000000 0.000000 0.000000 0.153069 0.693861 Bio 0.000000 0.000000 0.010488 0.065632 0.179887 0.000638 0.166466 0.120776 0.003308 0.108559 0.344248 St 0.000000 0.000000 0.003986 0.000000 0.133892 0.002193 0.048340 0.088241 0.001985 0.390458 0.330905 Ilm 0.000000 0.000000 0.397908 0.000000 0.538948 0.009565 0.012743 0.000000 0.040837 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -763989. -747840. -923881. -838754. -306997. -458676. -632573. -286933. -410013. -1626481. -880774. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 303 converged, 69 successes so far. Misfit function evaluations this try => 260 Misfit this try = 0.127919 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.544885E-07 Bayes score, PP * exp(-Misfit) = 7.518854E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 7515.30 848.880 0.811683 0.888721 Final coordinates: 7834.43 910.872 0.496887 0.517120 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.127919 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.646 0.022761 0.022972 0.000000 0.064779 0.003679 0.000000 0.006060 0.298825 0.580924 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 6.8E-03 0. 0. 6.0E-03 1.5E-02 0. 9.2E-03 1.1E-03 6.3E-04 Composition Misfit: 6.190312E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.742 0.000000 0.024808 0.000000 0.000000 0.281433 0.051987 0.077557 0.137611 0.426604 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -2. -2. 0.4 -0.2 Chi 0. 7.3E-04 0. 0. 5.8E-03 6.1E-03 6.7E-03 2.8E-04 8.9E-06 Composition Misfit: 1.958074E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.334 0.094658 0.058688 0.000000 0.000998 0.000000 0.000000 0.000000 0.154344 0.691312 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 9.6E-05 8.6E-04 0. 1.3E-04 0. 0. 0. 2.8E-04 1.5E-05 Composition Misfit: 1.375326E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.373 0.000000 0.000000 0.013001 0.075320 0.205442 0.001140 0.186529 0.129803 0.388764 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 5.4E-03 9.3E-04 2.1E-03 7.1E-05 1.6E-03 8.5E-04 1.9E-03 Composition Misfit: 1.282869E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.005 0.000000 0.000000 0.004685 0.000000 0.141850 0.003445 0.058400 0.428137 0.363483 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.8 0.1 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 8.2E-04 4.5E-05 2.2E-02 9.7E-04 1.4E-03 Composition Misfit: 2.631698E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.795 0.000000 0.000000 0.375060 0.000000 0.596761 0.013638 0.014541 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 2. -0.6 -0.7 0. 0. Chi 0. 0. 1.7E-03 0. 1.9E-03 9.7E-04 1.4E-03 0. 0. Composition Misfit: 5.914270E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.937 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.167 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023285 0.014733 0.006971 0.016452 0.052863 0.000917 0.040266 0.030045 0.001642 0.108353 0.704472 Mica 0.018998 0.019174 0.000000 0.054070 0.003071 0.000000 0.005058 0.165312 0.000000 0.249426 0.484890 Gt 0.000000 0.024751 0.000000 0.000000 0.280788 0.051868 0.077380 0.000000 0.002290 0.137296 0.425627 Fsp 0.094658 0.058688 0.000000 0.000998 0.000000 0.000000 0.000000 0.000000 0.000000 0.154344 0.691312 Bio 0.000000 0.000000 0.011385 0.065956 0.179900 0.000999 0.163339 0.120527 0.003798 0.113665 0.340431 St 0.000000 0.000000 0.004261 0.000000 0.129027 0.003133 0.053121 0.088166 0.002237 0.389432 0.330623 Ilm 0.000000 0.000000 0.353007 0.000000 0.561673 0.012836 0.013686 0.000000 0.058797 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775618. -755093. -930825. -850603. -313598. -464417. -637102. -291746. -408986. -1634852. -886360. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 308 converged, 70 successes so far. Misfit function evaluations this try => 137 Misfit this try = 0.127202 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.667749E-07 Bayes score, PP * exp(-Misfit) = 7.632437E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 9711.71 885.902 0.826789 0.283929 Final coordinates: 8446.27 930.936 0.528897 0.586656 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.127202 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.334 0.023908 0.025365 0.000000 0.062331 0.004030 0.000000 0.006759 0.298657 0.578951 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.7E-03 0. 0. 7.9E-03 1.3E-02 0. 6.8E-03 1.1E-03 7.7E-04 Composition Misfit: 6.218690E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.020 0.000000 0.025567 0.000000 0.000000 0.285369 0.039626 0.086018 0.137033 0.426387 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -0.6 -3. 0.5 -0.2 Chi 0. 9.9E-04 0. 0. 4.7E-03 7.3E-04 1.1E-02 3.4E-04 7.0E-06 Composition Misfit: 1.807510E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.509 0.095164 0.057540 0.000000 0.001066 0.000000 0.000000 0.000000 0.153770 0.692460 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.3E-04 6.1E-04 0. 8.0E-05 0. 0. 0. 3.3E-04 6.0E-06 Composition Misfit: 1.159992E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.471 0.000000 0.000000 0.013606 0.075222 0.199217 0.000931 0.193205 0.128328 0.389493 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -2. 0.9 1. Chi 0. 0. 4.4E-03 9.1E-04 1.1E-03 2.6E-04 2.9E-03 1.1E-03 1.8E-03 Composition Misfit: 1.251221E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.291 0.000000 0.000000 0.004961 0.000000 0.137958 0.002687 0.063286 0.427710 0.363398 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.5 0.2 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 3.5E-04 4.9E-04 2.6E-02 1.0E-03 1.4E-03 Composition Misfit: 3.016959E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.823 0.000000 0.000000 0.361452 0.000000 0.611988 0.010713 0.015848 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.6 0. 0.8 -0.1 -0.9 0. 0. Chi 0. 0. 3.6E-04 0. 5.3E-04 4.7E-05 2.2E-03 0. 0. Composition Misfit: 3.098126E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.284 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.268 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023189 0.014672 0.006942 0.016384 0.052645 0.000914 0.040100 0.033944 0.001740 0.107906 0.701564 Mica 0.019959 0.021175 0.000000 0.052036 0.003364 0.000000 0.005642 0.165166 0.000000 0.249329 0.483328 Gt 0.000000 0.025502 0.000000 0.000000 0.284643 0.039526 0.085799 0.000000 0.002542 0.136685 0.425304 Fsp 0.095164 0.057540 0.000000 0.001066 0.000000 0.000000 0.000000 0.000000 0.000000 0.153770 0.692460 Bio 0.000000 0.000000 0.011922 0.065914 0.174567 0.000815 0.169299 0.119906 0.003826 0.112449 0.341300 St 0.000000 0.000000 0.004512 0.000000 0.125481 0.002444 0.057562 0.088142 0.002301 0.389027 0.330531 Ilm 0.000000 0.000000 0.338035 0.000000 0.572339 0.010019 0.014821 0.000000 0.064786 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777322. -756096. -932141. -852645. -315357. -468489. -637799. -292600. -408255. -1636736. -887135. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 312 converged, 71 successes so far. Misfit function evaluations this try => 182 Misfit this try = 0.130859 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.573346E-07 Bayes score, PP * exp(-Misfit) = 7.521754E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6124.05 897.406 0.539866 0.204685 Final coordinates: 8374.07 930.331 0.526588 0.630169 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.130859 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.304 0.023980 0.025218 0.000000 0.062348 0.003938 0.000000 0.006696 0.298784 0.579036 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.7E-03 0. 0. 7.8E-03 1.3E-02 0. 7.0E-03 1.1E-03 7.6E-04 Composition Misfit: 6.291306E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.796 0.000000 0.025122 0.000000 0.000000 0.282005 0.043136 0.086198 0.137120 0.426420 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 8.3E-04 0. 0. 5.6E-03 1.8E-03 1.1E-02 3.3E-04 7.3E-06 Composition Misfit: 2.009097E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.230 0.095162 0.057543 0.000000 0.001067 0.000000 0.000000 0.000000 0.153771 0.692457 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.3E-04 6.1E-04 0. 7.9E-05 0. 0. 0. 3.3E-04 6.0E-06 Composition Misfit: 1.159783E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.759 0.000000 0.000000 0.013617 0.075231 0.197641 0.001012 0.194635 0.128463 0.389401 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.9 0.1 -2. 0.9 1. Chi 0. 0. 4.4E-03 9.1E-04 8.8E-04 1.7E-04 3.2E-03 1.1E-03 1.8E-03 Composition Misfit: 1.251442E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.125 0.000000 0.000000 0.004981 0.000000 0.137105 0.002938 0.063836 0.427735 0.363406 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.4 0.2 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 2.7E-04 2.8E-04 2.6E-02 1.0E-03 1.4E-03 Composition Misfit: 3.032584E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.815 0.000000 0.000000 0.363749 0.000000 0.608405 0.011753 0.016093 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.8 0. 1. -0.3 -1. 0. 0. Chi 0. 0. 5.2E-04 0. 7.7E-04 2.6E-04 2.3E-03 0. 0. Composition Misfit: 3.854745E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.505 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.467 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023131 0.014636 0.006925 0.016343 0.052513 0.000911 0.040000 0.036371 0.001728 0.107635 0.699807 Mica 0.020019 0.021052 0.000000 0.052049 0.003288 0.000000 0.005590 0.165187 0.000000 0.249429 0.483386 Gt 0.000000 0.025059 0.000000 0.000000 0.281298 0.043028 0.085982 0.000000 0.002504 0.136776 0.425352 Fsp 0.095162 0.057543 0.000000 0.001067 0.000000 0.000000 0.000000 0.000000 0.000000 0.153771 0.692457 Bio 0.000000 0.000000 0.011932 0.065921 0.173184 0.000886 0.170550 0.119911 0.003834 0.112566 0.341215 St 0.000000 0.000000 0.004530 0.000000 0.124706 0.002672 0.058063 0.088144 0.002288 0.389054 0.330542 Ilm 0.000000 0.000000 0.340549 0.000000 0.569600 0.011003 0.015067 0.000000 0.063780 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777497. -756247. -932145. -852897. -315436. -467823. -637791. -292630. -408192. -1636794. -887234. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 315 converged, 72 successes so far. Misfit function evaluations this try => 173 Misfit this try = 0.194279 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 1.023594E-07 Bayes score, PP * exp(-Misfit) = 8.428563E-08 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6486.88 919.203 0.232458 5.377104E-02 Final coordinates: 6829.50 807.354 0.348443 0.535288 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.194279 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.173 0.025253 0.020514 0.000000 0.063878 0.002082 0.000000 0.004029 0.302313 0.581930 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 8.8E-03 0. 0. 6.6E-03 4.0E-02 0. 2.2E-02 1.6E-03 5.6E-04 Composition Misfit: 0.100082 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.783 0.000000 0.035612 0.000000 0.000000 0.283428 0.059113 0.055815 0.138932 0.427100 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -3. -0.1 0.4 -0.3 Chi 0. 6.4E-03 0. 0. 5.2E-03 1.0E-02 1.9E-05 1.7E-04 1.4E-05 Composition Misfit: 2.226464E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.069 0.095239 0.058527 0.000000 0.000497 0.000000 0.000000 0.000000 0.154264 0.691473 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.4E-04 8.2E-04 0. 1.5E-03 0. 0. 0. 2.9E-04 1.3E-05 Composition Misfit: 2.743753E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.220 0.000000 0.000000 0.010723 0.074847 0.208725 0.000770 0.188141 0.122709 0.394085 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -2. 0.2 -1. 1. 1. Chi 0. 0. 1.1E-02 8.3E-04 2.8E-03 5.6E-04 1.8E-03 2.5E-03 1.2E-03 Composition Misfit: 2.035740E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.009 0.000000 0.000000 0.003833 0.000000 0.152444 0.002850 0.046791 0.430158 0.363924 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. 0.2 -3. 0.9 1. Chi 0. 0. 3.2E-03 0. 3.0E-03 3.4E-04 1.2E-02 7.9E-04 1.4E-03 Composition Misfit: 2.087451E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.778 0.000000 0.000000 0.430091 0.000000 0.546911 0.011958 0.011040 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -4. 0. 4. -0.3 -0.2 0. 0. Chi 0. 0. 1.5E-02 0. 1.3E-02 3.2E-04 9.8E-05 0. 0. Composition Misfit: 2.795637E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.067 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.901 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023272 0.014725 0.006967 0.016443 0.052833 0.000917 0.040244 0.031083 0.001151 0.108292 0.704074 Mica 0.021066 0.017113 0.000000 0.053286 0.001737 0.000000 0.003361 0.165817 0.000000 0.252184 0.485436 Gt 0.000000 0.035551 0.000000 0.000000 0.282943 0.059012 0.055720 0.000000 0.001714 0.138694 0.426367 Fsp 0.095239 0.058527 0.000000 0.000497 0.000000 0.000000 0.000000 0.000000 0.000000 0.154264 0.691473 Bio 0.000000 0.000000 0.009385 0.065510 0.182685 0.000674 0.164669 0.121634 0.003123 0.107400 0.344920 St 0.000000 0.000000 0.003488 0.000000 0.138706 0.002593 0.042574 0.088301 0.001818 0.391393 0.331128 Ilm 0.000000 0.000000 0.415566 0.000000 0.528440 0.011554 0.010667 0.000000 0.033774 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -757913. -743828. -919914. -832058. -302581. -451666. -629945. -284226. -410597. -1621343. -877942. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 317 converged, 73 successes so far. Misfit function evaluations this try => 304 Misfit this try = 0.177457 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 2.026467E-07 Bayes score, PP * exp(-Misfit) = 1.696958E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 7052.07 926.432 8.845533E-02 0.148230 Final coordinates: 6966.50 825.781 0.519990 0.577642 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.177457 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.587 0.026018 0.021650 0.000000 0.062522 0.002142 0.000000 0.004209 0.302569 0.580890 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 9.4E-03 0. 0. 7.7E-03 3.8E-02 0. 2.1E-02 1.6E-03 6.3E-04 Composition Misfit: 9.966455E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.578 0.000000 0.033480 0.000000 0.000000 0.276125 0.064690 0.060942 0.138009 0.426754 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 3. -3. -0.6 0.4 -0.2 Chi 0. 5.0E-03 0. 0. 7.6E-03 1.4E-02 6.2E-04 2.5E-04 1.0E-05 Composition Misfit: 2.779286E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.670 0.095123 0.058632 0.000000 0.000561 0.000000 0.000000 0.000000 0.154316 0.691368 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.3E-04 8.4E-04 0. 1.1E-03 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 2.398172E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.183 0.000000 0.000000 0.010797 0.074955 0.203542 0.000935 0.193830 0.124329 0.391612 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -2. 1. 1. Chi 0. 0. 1.0E-02 8.5E-04 1.8E-03 2.6E-04 3.1E-03 2.1E-03 1.5E-03 Composition Misfit: 1.986552E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.521 0.000000 0.000000 0.003707 0.000000 0.149258 0.003377 0.051055 0.428988 0.363616 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -1. 0.1 -3. 1. 1. Chi 0. 0. 3.5E-03 0. 2.2E-03 6.3E-05 1.5E-02 8.9E-04 1.4E-03 Composition Misfit: 2.363505E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.891 0.000000 0.000000 0.375444 0.000000 0.600644 0.013547 0.010365 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 1. -0.6 -0.1 0. 0. Chi 0. 0. 1.7E-03 0. 1.4E-03 9.3E-04 1.3E-05 0. 0. Composition Misfit: 4.100491E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.376 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.193 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023202 0.014681 0.006946 0.016393 0.052674 0.000914 0.040122 0.033441 0.001712 0.107965 0.701950 Mica 0.021704 0.018061 0.000000 0.052157 0.001787 0.000000 0.003511 0.165784 0.000000 0.252408 0.484588 Gt 0.000000 0.033409 0.000000 0.000000 0.275540 0.064553 0.060814 0.000000 0.002116 0.137717 0.425850 Fsp 0.095123 0.058632 0.000000 0.000561 0.000000 0.000000 0.000000 0.000000 0.000000 0.154316 0.691368 Bio 0.000000 0.000000 0.009442 0.065550 0.178001 0.000817 0.169508 0.121658 0.003824 0.108728 0.342472 St 0.000000 0.000000 0.003372 0.000000 0.135763 0.003071 0.046438 0.088197 0.002220 0.390200 0.330739 Ilm 0.000000 0.000000 0.353433 0.000000 0.565431 0.012753 0.009757 0.000000 0.058627 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -761149. -745928. -922220. -835748. -304730. -453148. -631084. -285487. -405061. -1623727. -879471. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 318 converged, 74 successes so far. Misfit function evaluations this try => 263 Misfit this try = 0.121643 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.503944E-07 Bayes score, PP * exp(-Misfit) = 7.529938E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 13697.8 923.681 0.942031 4.859409E-02 Final coordinates: 8231.31 927.691 0.542017 0.523253 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121643 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.321 0.023036 0.024334 0.000000 0.063736 0.004025 0.000000 0.006585 0.298375 0.579909 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.0E-03 0. 0. 6.7E-03 1.3E-02 0. 7.4E-03 1.1E-03 7.0E-04 Composition Misfit: 5.981308E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.965 0.000000 0.024954 0.000000 0.000000 0.284920 0.043568 0.082983 0.137146 0.426430 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 7.8E-04 0. 0. 4.8E-03 2.0E-03 9.6E-03 3.3E-04 7.4E-06 Composition Misfit: 1.748550E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.137 0.094820 0.058216 0.000000 0.001072 0.000000 0.000000 0.000000 0.154108 0.691784 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.5E-04 0. 7.6E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.244800E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.880 0.000000 0.000000 0.013394 0.075293 0.202970 0.001018 0.189101 0.129400 0.388823 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.7E-03 9.2E-04 1.7E-03 1.6E-04 2.0E-03 9.2E-04 1.9E-03 Composition Misfit: 1.236085E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.011 0.000000 0.000000 0.004822 0.000000 0.139823 0.002964 0.061209 0.427779 0.363403 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.5E-04 2.6E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.850937E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.832 0.000000 0.000000 0.356384 0.000000 0.617076 0.011633 0.014907 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.3 0. 0.6 -0.3 -0.8 0. 0. Chi 0. 0. 1.1E-04 0. 2.7E-04 2.3E-04 1.6E-03 0. 0. Composition Misfit: 2.229625E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.731 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.123 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023273 0.014726 0.006968 0.016444 0.052836 0.000917 0.040246 0.030386 0.001790 0.108298 0.704116 Mica 0.019231 0.020315 0.000000 0.053207 0.003360 0.000000 0.005497 0.165191 0.000000 0.249086 0.484114 Gt 0.000000 0.024892 0.000000 0.000000 0.284209 0.043459 0.082776 0.000000 0.002492 0.136804 0.425367 Fsp 0.094820 0.058216 0.000000 0.001072 0.000000 0.000000 0.000000 0.000000 0.000000 0.154108 0.691784 Bio 0.000000 0.000000 0.011732 0.065954 0.177793 0.000892 0.165645 0.120175 0.003867 0.113349 0.340593 St 0.000000 0.000000 0.004386 0.000000 0.127175 0.002696 0.055672 0.088142 0.002315 0.389083 0.330531 Ilm 0.000000 0.000000 0.332507 0.000000 0.575734 0.010853 0.013909 0.000000 0.066997 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777577. -756259. -932273. -852712. -315163. -467542. -637935. -292671. -408397. -1636679. -887274. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 319 converged, 75 successes so far. Misfit function evaluations this try => 156 Misfit this try = 0.122835 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.280186E-07 Bayes score, PP * exp(-Misfit) = 7.323073E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6252.76 934.173 0.545952 0.352000 Final coordinates: 8266.50 930.812 0.561676 0.540062 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.122835 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.818 0.023082 0.024500 0.000000 0.063597 0.004050 0.000000 0.006663 0.298323 0.579785 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.0E-03 0. 0. 6.8E-03 1.2E-02 0. 7.1E-03 1.1E-03 7.0E-04 Composition Misfit: 5.970944E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.913 0.000000 0.024717 0.000000 0.000000 0.283713 0.043912 0.084173 0.137080 0.426405 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 7.0E-04 0. 0. 5.1E-03 2.1E-03 1.0E-02 3.3E-04 7.2E-06 Composition Misfit: 1.856936E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.998 0.094844 0.058133 0.000000 0.001089 0.000000 0.000000 0.000000 0.154066 0.691867 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.4E-04 0. 6.6E-05 0. 0. 0. 3.0E-04 1.0E-05 Composition Misfit: 1.221787E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.510 0.000000 0.000000 0.013455 0.075297 0.201701 0.001041 0.190341 0.129448 0.388719 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.7E-03 9.2E-04 1.5E-03 1.4E-04 2.3E-03 9.1E-04 1.9E-03 Composition Misfit: 1.229064E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.666 0.000000 0.000000 0.004840 0.000000 0.138998 0.003013 0.062055 0.427707 0.363387 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 4.5E-04 2.3E-04 2.5E-02 1.0E-03 1.4E-03 Composition Misfit: 2.909609E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.847 0.000000 0.000000 0.349756 0.000000 0.623561 0.011783 0.014900 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 1.3E-02 0. 0.3 -0.3 -0.8 0. 0. Chi 0. 0. 1.7E-07 0. 6.6E-05 2.7E-04 1.6E-03 0. 0. Composition Misfit: 1.948106E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.054 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.194 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023249 0.014711 0.006960 0.016426 0.052781 0.000916 0.040204 0.031329 0.001853 0.108186 0.703384 Mica 0.019270 0.020453 0.000000 0.053092 0.003381 0.000000 0.005562 0.165176 0.000000 0.249048 0.484019 Gt 0.000000 0.024655 0.000000 0.000000 0.282998 0.043801 0.083961 0.000000 0.002521 0.136734 0.425330 Fsp 0.094844 0.058133 0.000000 0.001089 0.000000 0.000000 0.000000 0.000000 0.000000 0.154066 0.691867 Bio 0.000000 0.000000 0.011786 0.065957 0.176683 0.000912 0.166733 0.120129 0.003902 0.113392 0.340506 St 0.000000 0.000000 0.004402 0.000000 0.126423 0.002740 0.056441 0.088136 0.002333 0.389013 0.330511 Ilm 0.000000 0.000000 0.325318 0.000000 0.579991 0.010960 0.013859 0.000000 0.069873 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778110. -756604. -932617. -853311. -315539. -467851. -638114. -292892. -408132. -1637105. -887534. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 322 converged, 76 successes so far. Misfit function evaluations this try => 156 Misfit this try = 0.178686 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 1.648718E-07 Bayes score, PP * exp(-Misfit) = 1.378936E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 9647.20 810.432 0.101586 0.768835 Final coordinates: 6872.75 820.572 0.410539 0.533170 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.178686 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.069 0.024708 0.020522 0.000000 0.064383 0.002234 0.000000 0.004245 0.301838 0.582070 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 8.3E-03 0. 0. 6.3E-03 3.6E-02 0. 2.0E-02 1.5E-03 5.5E-04 Composition Misfit: 9.318601E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.690 0.000000 0.033308 0.000000 0.000000 0.280299 0.062536 0.058371 0.138535 0.426951 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -3. -0.3 0.4 -0.3 Chi 0. 4.9E-03 0. 0. 6.2E-03 1.3E-02 2.2E-04 2.0E-04 1.2E-05 Composition Misfit: 2.429969E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.127 0.095090 0.058713 0.000000 0.000553 0.000000 0.000000 0.000000 0.154356 0.691287 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.2E-04 8.6E-04 0. 1.2E-03 0. 0. 0. 2.8E-04 1.5E-05 Composition Misfit: 2.449395E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.257 0.000000 0.000000 0.010863 0.074962 0.208307 0.000881 0.188189 0.124426 0.392372 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -2. 0.2 -1. 1. 1. Chi 0. 0. 1.0E-02 8.6E-04 2.7E-03 3.3E-04 1.9E-03 2.0E-03 1.4E-03 Composition Misfit: 1.937477E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.014 0.000000 0.000000 0.003821 0.000000 0.151179 0.003190 0.048478 0.429561 0.363772 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -1. 0.1 -3. 1. 1. Chi 0. 0. 3.2E-03 0. 2.7E-03 1.3E-04 1.3E-02 8.4E-04 1.4E-03 Composition Misfit: 2.174304E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.806 0.000000 0.000000 0.411414 0.000000 0.564412 0.013125 0.011050 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -3. 0. 3. -0.5 -0.2 0. 0. Chi 0. 0. 9.2E-03 0. 7.6E-03 7.4E-04 1.0E-04 0. 0. Composition Misfit: 1.763282E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.044 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.993 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023270 0.014724 0.006967 0.016441 0.052829 0.000917 0.040240 0.030957 0.001356 0.108283 0.704016 Mica 0.020612 0.017120 0.000000 0.053711 0.001864 0.000000 0.003542 0.165766 0.000000 0.251804 0.485582 Gt 0.000000 0.033245 0.000000 0.000000 0.279770 0.062418 0.058261 0.000000 0.001887 0.138273 0.426145 Fsp 0.095090 0.058713 0.000000 0.000553 0.000000 0.000000 0.000000 0.000000 0.000000 0.154356 0.691287 Bio 0.000000 0.000000 0.009504 0.065582 0.182242 0.000771 0.164641 0.121660 0.003471 0.108857 0.343274 St 0.000000 0.000000 0.003476 0.000000 0.137534 0.002902 0.044102 0.088250 0.002009 0.390789 0.330938 Ilm 0.000000 0.000000 0.393964 0.000000 0.540473 0.012568 0.010581 0.000000 0.042415 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -760475. -745504. -921557. -834777. -304100. -452835. -630935. -285266. -408283. -1623167. -879162. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 324 converged, 77 successes so far. Misfit function evaluations this try => 194 Misfit this try = 0.121072 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.322575E-07 Bayes score, PP * exp(-Misfit) = 7.373557E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6521.67 928.790 0.183198 0.573024 Final coordinates: 8287.47 930.867 0.540573 0.523540 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121072 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.381 0.022994 0.024482 0.000000 0.063687 0.004097 0.000000 0.006676 0.298237 0.579827 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.9E-03 0. 0. 6.8E-03 1.2E-02 0. 7.1E-03 1.1E-03 7.0E-04 Composition Misfit: 5.919482E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.003 0.000000 0.024835 0.000000 0.000000 0.285417 0.042398 0.083827 0.137108 0.426415 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -0.9 -3. 0.5 -0.2 Chi 0. 7.4E-04 0. 0. 4.7E-03 1.6E-03 1.0E-02 3.3E-04 7.2E-06 Composition Misfit: 1.736763E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.120 0.094836 0.058149 0.000000 0.001089 0.000000 0.000000 0.000000 0.154075 0.691851 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.4E-04 0. 6.6E-05 0. 0. 0. 3.0E-04 1.0E-05 Composition Misfit: 1.224192E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.833 0.000000 0.000000 0.013488 0.075295 0.202739 0.001002 0.189223 0.129422 0.388830 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.2E-04 1.6E-03 1.8E-04 2.1E-03 9.2E-04 1.9E-03 Composition Misfit: 1.221267E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.013 0.000000 0.000000 0.004864 0.000000 0.139507 0.002901 0.061589 0.427742 0.363397 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.1E-04 3.0E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.879413E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.830 0.000000 0.000000 0.356345 0.000000 0.617154 0.011391 0.015110 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.3 0. 0.6 -0.2 -0.8 0. 0. Chi 0. 0. 1.1E-04 0. 2.7E-04 1.7E-04 1.7E-03 0. 0. Composition Misfit: 2.278139E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.704 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.116 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023273 0.014726 0.006968 0.016443 0.052836 0.000917 0.040246 0.030402 0.001785 0.108297 0.704108 Mica 0.019196 0.020438 0.000000 0.053168 0.003420 0.000000 0.005573 0.165168 0.000000 0.248978 0.484058 Gt 0.000000 0.024772 0.000000 0.000000 0.284701 0.042292 0.083617 0.000000 0.002509 0.136764 0.425345 Fsp 0.094836 0.058149 0.000000 0.001089 0.000000 0.000000 0.000000 0.000000 0.000000 0.154075 0.691851 Bio 0.000000 0.000000 0.011816 0.065961 0.177606 0.000878 0.165766 0.120106 0.003859 0.113379 0.340629 St 0.000000 0.000000 0.004424 0.000000 0.126888 0.002639 0.056018 0.088140 0.002316 0.389050 0.330526 Ilm 0.000000 0.000000 0.332465 0.000000 0.575796 0.010627 0.014097 0.000000 0.067014 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778034. -756540. -932559. -853186. -315479. -468106. -638128. -292879. -408515. -1637068. -887492. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio F sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio F sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 328 converged, 78 successes so far. Misfit function evaluations this try => 153 Misfit this try = 0.127629 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 9.625857E-07 Bayes score, PP * exp(-Misfit) = 8.472483E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 7503.37 887.691 0.849776 0.371464 Final coordinates: 8268.04 914.093 0.587374 0.535659 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.127629 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.116 0.024376 0.025036 0.000000 0.062100 0.003722 0.000000 0.006333 0.299446 0.578986 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 8.1E-03 0. 0. 8.1E-03 1.5E-02 0. 8.2E-03 1.2E-03 7.6E-04 Composition Misfit: 6.617174E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.085 0.000000 0.027227 0.000000 0.000000 0.286615 0.041075 0.081724 0.136988 0.426371 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.9 0. 0. 2. -0.8 -3. 0.5 -0.2 Chi 0. 1.6E-03 0. 0. 4.3E-03 1.1E-03 8.9E-03 3.4E-04 6.9E-06 Composition Misfit: 1.634472E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.852 0.095123 0.057826 0.000000 0.000964 0.000000 0.000000 0.000000 0.153913 0.692174 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.3E-04 6.7E-04 0. 1.6E-04 0. 0. 0. 3.2E-04 7.8E-06 Composition Misfit: 1.283855E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.400 0.000000 0.000000 0.013045 0.075178 0.201044 0.000898 0.192488 0.127675 0.389672 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.2 -2. 0.9 1. Chi 0. 0. 5.3E-03 9.0E-04 1.4E-03 3.1E-04 2.7E-03 1.3E-03 1.8E-03 Composition Misfit: 1.364991E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.025 0.000000 0.000000 0.004658 0.000000 0.140419 0.002671 0.061054 0.427803 0.363395 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.7 0.2 -5. 1. 1. Chi 0. 0. 1.5E-03 0. 6.3E-04 5.1E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.893139E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.894 0.000000 0.000000 0.341702 0.000000 0.634199 0.010390 0.013709 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.5 0. -0.2 -0.1 -0.6 0. 0. Chi 0. 0. 2.0E-04 0. 2.8E-05 1.5E-05 1.0E-03 0. 0. Composition Misfit: 1.247668E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.561 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.069 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023253 0.014713 0.006962 0.016429 0.052790 0.000916 0.040211 0.031079 0.001938 0.108204 0.703504 Mica 0.020347 0.020898 0.000000 0.051837 0.003107 0.000000 0.005286 0.165268 0.000000 0.249957 0.483298 Gt 0.000000 0.027157 0.000000 0.000000 0.285881 0.040970 0.081514 0.000000 0.002561 0.136637 0.425279 Fsp 0.095123 0.057826 0.000000 0.000964 0.000000 0.000000 0.000000 0.000000 0.000000 0.153913 0.692174 Bio 0.000000 0.000000 0.011425 0.065844 0.176082 0.000786 0.168588 0.120263 0.003898 0.111823 0.341290 St 0.000000 0.000000 0.004236 0.000000 0.127713 0.002429 0.055530 0.088137 0.002350 0.389092 0.330513 Ilm 0.000000 0.000000 0.316640 0.000000 0.587684 0.009628 0.012704 0.000000 0.073344 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774394. -754223. -930545. -849575. -313498. -466204. -636644. -291331. -407013. -1634424. -885713. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 332 converged, 79 successes so far. Misfit function evaluations this try => 187 Misfit this try = 0.128458 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 9.100752E-07 Bayes score, PP * exp(-Misfit) = 8.003662E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 12765.7 860.055 0.897383 8.355265E-02 Final coordinates: 7952.12 901.194 0.508434 0.526891 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.128458 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.311 0.023847 0.023751 0.000000 0.063330 0.003520 0.000000 0.005951 0.299563 0.580038 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.6E-03 0. 0. 7.1E-03 1.7E-02 0. 9.7E-03 1.2E-03 6.9E-04 Composition Misfit: 6.658783E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.909 0.000000 0.027064 0.000000 0.000000 0.285175 0.046856 0.076928 0.137438 0.426539 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.8 0. 0. 2. -1. -2. 0.5 -0.2 Chi 0. 1.6E-03 0. 0. 4.7E-03 3.4E-03 6.4E-03 3.0E-04 8.3E-06 Composition Misfit: 1.637028E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.105 0.094931 0.058308 0.000000 0.000914 0.000000 0.000000 0.000000 0.154154 0.691692 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.7E-04 0. 2.1E-04 0. 0. 0. 2.9E-04 1.1E-05 Composition Misfit: 1.407435E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.956 0.000000 0.000000 0.012788 0.075206 0.204248 0.000976 0.189001 0.128085 0.389696 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.9 1. Chi 0. 0. 5.8E-03 9.1E-04 1.9E-03 2.1E-04 2.0E-03 1.2E-03 1.8E-03 Composition Misfit: 1.372918E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.028 0.000000 0.000000 0.004586 0.000000 0.142540 0.002985 0.058273 0.428140 0.363475 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.8 0.2 -4. 1. 1. Chi 0. 0. 1.6E-03 0. 9.3E-04 2.4E-04 2.1E-02 9.7E-04 1.4E-03 Composition Misfit: 2.666085E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.823 0.000000 0.000000 0.370647 0.000000 0.603591 0.011809 0.013952 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 1. -0.3 -0.6 0. 0. Chi 0. 0. 1.2E-03 0. 1.2E-03 2.8E-04 1.1E-03 0. 0. Composition Misfit: 3.702340E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.781 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.088 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023271 0.014724 0.006967 0.016442 0.052831 0.000917 0.040242 0.030594 0.001679 0.108287 0.704046 Mica 0.019904 0.019824 0.000000 0.052859 0.002938 0.000000 0.004967 0.165349 0.000000 0.250030 0.484129 Gt 0.000000 0.027000 0.000000 0.000000 0.284501 0.046745 0.076746 0.000000 0.002365 0.137113 0.425530 Fsp 0.094931 0.058308 0.000000 0.000914 0.000000 0.000000 0.000000 0.000000 0.000000 0.154154 0.691692 Bio 0.000000 0.000000 0.011198 0.065857 0.178859 0.000854 0.165507 0.120516 0.003791 0.112163 0.341254 St 0.000000 0.000000 0.004172 0.000000 0.129651 0.002715 0.053004 0.088162 0.002261 0.389426 0.330608 Ilm 0.000000 0.000000 0.348132 0.000000 0.566925 0.011091 0.013105 0.000000 0.060747 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772968. -753361. -929421. -847957. -312280. -463851. -636074. -290668. -408014. -1633068. -885051. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 334 converged, 80 successes so far. Misfit function evaluations this try => 170 Misfit this try = 0.131026 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.301320E-07 Bayes score, PP * exp(-Misfit) = 7.281876E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 7613.98 832.207 0.198621 0.460277 Final coordinates: 8297.35 931.290 0.406917 0.531974 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.131026 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.324 0.022815 0.024349 0.000000 0.063924 0.004183 0.000000 0.006675 0.298059 0.579994 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.8E-03 0. 0. 6.6E-03 1.2E-02 0. 7.1E-03 1.0E-03 6.9E-04 Composition Misfit: 5.816774E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.075 0.000000 0.024372 0.000000 0.000000 0.287616 0.040427 0.083147 0.137774 0.426665 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -0.7 -3. 0.4 -0.2 Chi 0. 6.0E-04 0. 0. 4.1E-03 9.4E-04 9.7E-03 2.7E-04 9.4E-06 Composition Misfit: 1.557964E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.130 0.094850 0.058108 0.000000 0.001096 0.000000 0.000000 0.000000 0.154054 0.691892 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.3E-04 0. 6.3E-05 0. 0. 0. 3.0E-04 9.8E-06 Composition Misfit: 1.214186E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.864 0.000000 0.000000 0.013903 0.075288 0.204023 0.000958 0.186689 0.129315 0.389825 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.9 -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.0E-03 9.2E-04 1.9E-03 2.3E-04 1.6E-03 9.4E-04 1.8E-03 Composition Misfit: 1.129751E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.635 0.000000 0.000000 0.005244 0.000000 0.139592 0.002751 0.060617 0.428240 0.363556 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 8.3E-04 0. 5.2E-04 4.3E-04 2.3E-02 9.6E-04 1.4E-03 Composition Misfit: 2.760564E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.714 0.000000 0.000000 0.403541 0.000000 0.567871 0.011215 0.017372 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -3. 0. 3. -0.2 -1. 0. 0. Chi 0. 0. 7.1E-03 0. 6.8E-03 1.3E-04 3.1E-03 0. 0. Composition Misfit: 1.716130E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.155 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.103 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023272 0.014725 0.006967 0.016443 0.052833 0.000917 0.040244 0.030890 0.001344 0.108292 0.704074 Mica 0.019047 0.020328 0.000000 0.053367 0.003492 0.000000 0.005573 0.165156 0.000000 0.248832 0.484205 Gt 0.000000 0.024318 0.000000 0.000000 0.286978 0.040337 0.082962 0.000000 0.002219 0.137468 0.425718 Fsp 0.094850 0.058108 0.000000 0.001096 0.000000 0.000000 0.000000 0.000000 0.000000 0.154054 0.691892 Bio 0.000000 0.000000 0.012189 0.066007 0.178872 0.000840 0.163675 0.119824 0.003452 0.113374 0.341769 St 0.000000 0.000000 0.004771 0.000000 0.126993 0.002502 0.055146 0.088198 0.002061 0.389588 0.330742 Ilm 0.000000 0.000000 0.384974 0.000000 0.541743 0.010699 0.016573 0.000000 0.046010 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778082. -756574. -932116. -853179. -315418. -468523. -638210. -292922. -412595. -1637115. -887515. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 339 converged, 81 successes so far. Misfit function evaluations this try => 236 Misfit this try = 0.126570 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 9.248365E-07 Bayes score, PP * exp(-Misfit) = 8.148845E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 11336.2 956.950 9.332980E-02 0.864884 Final coordinates: 8053.08 909.073 0.500457 0.526892 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.126570 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.324 0.023665 0.023864 0.000000 0.063423 0.003673 0.000000 0.006133 0.299184 0.580058 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.5E-03 0. 0. 7.0E-03 1.5E-02 0. 9.0E-03 1.2E-03 6.9E-04 Composition Misfit: 6.438246E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.948 0.000000 0.026485 0.000000 0.000000 0.285713 0.045155 0.078733 0.137392 0.426522 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.8 0. 0. 2. -1. -2. 0.5 -0.2 Chi 0. 1.3E-03 0. 0. 4.6E-03 2.6E-03 7.3E-03 3.0E-04 8.2E-06 Composition Misfit: 1.614272E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.108 0.094915 0.058255 0.000000 0.000958 0.000000 0.000000 0.000000 0.154128 0.691745 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.6E-04 0. 1.7E-04 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.348789E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.928 0.000000 0.000000 0.013012 0.075226 0.204050 0.000975 0.188770 0.128396 0.389572 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.9 1. Chi 0. 0. 5.4E-03 9.1E-04 1.9E-03 2.1E-04 2.0E-03 1.1E-03 1.8E-03 Composition Misfit: 1.321797E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.086 0.000000 0.000000 0.004696 0.000000 0.141806 0.002932 0.059024 0.428075 0.363468 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.8 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 8.2E-04 2.8E-04 2.2E-02 9.8E-04 1.4E-03 Composition Misfit: 2.706659E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.810 0.000000 0.000000 0.372690 0.000000 0.601135 0.011644 0.014530 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 1. -0.3 -0.7 0. 0. Chi 0. 0. 1.4E-03 0. 1.4E-03 2.3E-04 1.4E-03 0. 0. Composition Misfit: 4.411979E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.705 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.091 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023272 0.014725 0.006967 0.016442 0.052833 0.000917 0.040243 0.030595 0.001653 0.108290 0.704064 Mica 0.019753 0.019919 0.000000 0.052939 0.003066 0.000000 0.005119 0.165302 0.000000 0.249728 0.484173 Gt 0.000000 0.026422 0.000000 0.000000 0.285031 0.045047 0.078545 0.000000 0.002385 0.137065 0.425505 Fsp 0.094915 0.058255 0.000000 0.000958 0.000000 0.000000 0.000000 0.000000 0.000000 0.154128 0.691745 Bio 0.000000 0.000000 0.011397 0.065887 0.178717 0.000854 0.165334 0.120377 0.003774 0.112455 0.341206 St 0.000000 0.000000 0.004271 0.000000 0.128985 0.002667 0.053687 0.088161 0.002254 0.389370 0.330605 Ilm 0.000000 0.000000 0.350386 0.000000 0.565160 0.010947 0.013661 0.000000 0.059845 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774241. -754177. -930175. -849279. -313097. -465034. -636607. -291232. -408483. -1634093. -885665. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 341 converged, 82 successes so far. Misfit function evaluations this try => 214 Misfit this try = 0.198205 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.418092E-07 Bayes score, PP * exp(-Misfit) = 6.904531E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 13940.1 819.890 0.812452 0.553739 Final coordinates: 8157.63 926.666 0.953938 0.550333 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.198205 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.091 0.024408 0.025200 0.000000 0.061980 0.003611 0.000000 0.006508 0.299446 0.578847 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 8.1E-03 0. 0. 8.2E-03 1.6E-02 0. 7.6E-03 1.2E-03 7.7E-04 Composition Misfit: 6.678994E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.613 0.000000 0.024471 0.000000 0.000000 0.271305 0.053865 0.086992 0.136994 0.426373 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 3. -2. -3. 0.5 -0.2 Chi 0. 6.3E-04 0. 0. 9.4E-03 7.1E-03 1.2E-02 3.4E-04 6.9E-06 Composition Misfit: 2.948152E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.633 0.094888 0.058145 0.000000 0.001039 0.000000 0.000000 0.000000 0.154073 0.691855 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.4E-04 0. 9.8E-05 0. 0. 0. 3.0E-04 1.0E-05 Composition Misfit: 1.258235E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.657 0.000000 0.000000 0.013203 0.075254 0.192100 0.001253 0.200816 0.128814 0.388558 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.5 4.9E-02 -2. 0.8 1. Chi 0. 0. 5.0E-03 9.2E-04 3.0E-04 2.3E-05 4.9E-03 1.0E-03 1.9E-03 Composition Misfit: 1.412824E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.247 0.000000 0.000000 0.004709 0.000000 0.134604 0.003712 0.066027 0.427600 0.363348 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.3 2.7E-02 -5. 1. 1. Chi 0. 0. 1.5E-03 0. 9.4E-05 4.3E-06 2.8E-02 1.0E-03 1.5E-03 Composition Misfit: 3.217019E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.226 0.000000 0.000000 0.249268 0.000000 0.728234 0.012248 0.010250 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. -0.4 -4.0E-02 0. 0. Chi 0. 0. 4.1E-02 0. 1.3E-02 4.1E-04 6.1E-06 0. 0. Composition Misfit: 5.437712E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.217 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.315 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023205 0.014683 0.006947 0.016395 0.052682 0.000914 0.040128 0.031865 0.003141 0.107982 0.702057 Mica 0.020374 0.021036 0.000000 0.051737 0.003014 0.000000 0.005432 0.165259 0.000000 0.249960 0.483188 Gt 0.000000 0.024409 0.000000 0.000000 0.270611 0.053727 0.086769 0.000000 0.002559 0.136644 0.425282 Fsp 0.094888 0.058145 0.000000 0.001039 0.000000 0.000000 0.000000 0.000000 0.000000 0.154073 0.691855 Bio 0.000000 0.000000 0.011561 0.065896 0.168213 0.001097 0.175845 0.120232 0.004119 0.112796 0.340241 St 0.000000 0.000000 0.004283 0.000000 0.122419 0.003376 0.060050 0.088122 0.002400 0.388893 0.330457 Ilm 0.000000 0.000000 0.221499 0.000000 0.647109 0.010884 0.009108 0.000000 0.111400 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777654. -756368. -932418. -853289. -315504. -465864. -637563. -292539. -405687. -1636673. -887331. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 344 converged, 83 successes so far. Misfit function evaluations this try => 121 Misfit this try = 0.121071 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.266046E-07 Bayes score, PP * exp(-Misfit) = 7.323479E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6906.70 900.955 0.367492 0.551631 Final coordinates: 8263.65 930.887 0.535695 0.522163 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121071 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.280 0.022905 0.024373 0.000000 0.063833 0.004096 0.000000 0.006660 0.298204 0.579929 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.9E-03 0. 0. 6.7E-03 1.2E-02 0. 7.1E-03 1.1E-03 6.9E-04 Composition Misfit: 5.894603E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.979 0.000000 0.024692 0.000000 0.000000 0.285099 0.043028 0.083617 0.137138 0.426427 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 7.0E-04 0. 0. 4.8E-03 1.8E-03 9.9E-03 3.3E-04 7.3E-06 Composition Misfit: 1.751171E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.153 0.094803 0.058208 0.000000 0.001093 0.000000 0.000000 0.000000 0.154104 0.691792 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.5E-04 0. 6.4E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.230369E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.901 0.000000 0.000000 0.013482 0.075305 0.203039 0.001019 0.188835 0.129568 0.388753 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.3E-04 1.7E-03 1.6E-04 2.0E-03 8.9E-04 1.9E-03 Composition Misfit: 1.216824E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.005 0.000000 0.000000 0.004871 0.000000 0.139537 0.002951 0.061477 0.427761 0.363403 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 5.2E-04 2.7E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.865361E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.824 0.000000 0.000000 0.358330 0.000000 0.614873 0.011610 0.015187 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.5 0. 0.7 -0.3 -0.8 0. 0. Chi 0. 0. 1.9E-04 0. 3.7E-04 2.2E-04 1.8E-03 0. 0. Composition Misfit: 2.560871E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.736 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.123 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023275 0.014727 0.006968 0.016445 0.052841 0.000917 0.040249 0.030325 0.001769 0.108307 0.704175 Mica 0.019122 0.020347 0.000000 0.053290 0.003419 0.000000 0.005560 0.165170 0.000000 0.248949 0.484142 Gt 0.000000 0.024630 0.000000 0.000000 0.284388 0.042920 0.083408 0.000000 0.002496 0.136796 0.425362 Fsp 0.094803 0.058208 0.000000 0.001093 0.000000 0.000000 0.000000 0.000000 0.000000 0.154104 0.691792 Bio 0.000000 0.000000 0.011811 0.065968 0.177865 0.000893 0.165422 0.120125 0.003859 0.113503 0.340554 St 0.000000 0.000000 0.004430 0.000000 0.126916 0.002684 0.055916 0.088142 0.002308 0.389070 0.330533 Ilm 0.000000 0.000000 0.334626 0.000000 0.574199 0.010842 0.014183 0.000000 0.066149 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778145. -756615. -932599. -853285. -315507. -468023. -638172. -292921. -408644. -1637123. -887548. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 349 converged, 84 successes so far. Misfit function evaluations this try => 188 Misfit this try = 0.181046 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 1.151870E-07 Bayes score, PP * exp(-Misfit) = 9.611173E-08 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6349.22 818.494 0.629372 5.763447E-02 Final coordinates: 6768.57 811.473 0.495977 0.540265 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.181046 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.508 0.025238 0.020491 0.000000 0.063907 0.002053 0.000000 0.004039 0.302327 0.581945 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 8.8E-03 0. 0. 6.6E-03 4.0E-02 0. 2.2E-02 1.6E-03 5.6E-04 Composition Misfit: 0.100752 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.647 0.000000 0.034858 0.000000 0.000000 0.277781 0.065435 0.056914 0.138190 0.426821 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -3. -0.2 0.4 -0.3 Chi 0. 5.9E-03 0. 0. 7.0E-03 1.5E-02 7.9E-05 2.3E-04 1.1E-05 Composition Misfit: 2.807383E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.995 0.095133 0.058703 0.000000 0.000515 0.000000 0.000000 0.000000 0.154352 0.691297 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.3E-04 8.6E-04 0. 1.4E-03 0. 0. 0. 2.8E-04 1.5E-05 Composition Misfit: 2.658068E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.961 0.000000 0.000000 0.010432 0.074925 0.206996 0.000878 0.190872 0.123879 0.392017 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.2 -1. 1. 1. Chi 0. 0. 1.1E-02 8.5E-04 2.5E-03 3.4E-04 2.4E-03 2.2E-03 1.5E-03 Composition Misfit: 2.113475E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.024 0.000000 0.000000 0.003541 0.000000 0.152104 0.003259 0.048187 0.429242 0.363667 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. 0.1 -3. 1. 1. Chi 0. 0. 4.1E-03 0. 2.9E-03 1.0E-04 1.3E-02 8.7E-04 1.4E-03 Composition Misfit: 2.259667E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.885 0.000000 0.000000 0.383454 0.000000 0.593887 0.013023 0.009636 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. -0.5 0.1 0. 0. Chi 0. 0. 2.9E-03 0. 2.2E-03 7.0E-04 1.4E-05 0. 0. Composition Misfit: 5.830019E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.959 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.022 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023254 0.014714 0.006962 0.016430 0.052792 0.000916 0.040212 0.031348 0.001636 0.108208 0.703528 Mica 0.021053 0.017094 0.000000 0.053310 0.001713 0.000000 0.003369 0.165820 0.000000 0.252195 0.485447 Gt 0.000000 0.034787 0.000000 0.000000 0.277215 0.065302 0.056798 0.000000 0.002038 0.137908 0.425951 Fsp 0.095133 0.058703 0.000000 0.000515 0.000000 0.000000 0.000000 0.000000 0.000000 0.154352 0.691297 Bio 0.000000 0.000000 0.009121 0.065511 0.180987 0.000768 0.166889 0.121901 0.003751 0.108314 0.342760 St 0.000000 0.000000 0.003221 0.000000 0.138355 0.002964 0.043832 0.088212 0.002182 0.390441 0.330794 Ilm 0.000000 0.000000 0.362339 0.000000 0.561185 0.012306 0.009106 0.000000 0.055064 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -759036. -744586. -920948. -833342. -303261. -451529. -630297. -284629. -405300. -1622070. -878491. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 350 converged, 85 successes so far. Misfit function evaluations this try => 199 Misfit this try = 0.157797 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 6.957994E-07 Bayes score, PP * exp(-Misfit) = 5.942290E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 10325.9 904.936 0.112234 6.157853E-02 Final coordinates: 7449.41 879.528 0.329832 0.513626 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.157797 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.151 0.023074 0.021767 0.000000 0.065184 0.003206 0.000000 0.005386 0.299714 0.581670 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 7.0E-03 0. 0. 5.7E-03 2.0E-02 0. 1.2E-02 1.2E-03 5.8E-04 Composition Misfit: 6.835796E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.749 0.000000 0.026106 0.000000 0.000000 0.282915 0.055033 0.069856 0.138975 0.427116 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.7 0. 0. 2. -2. -1. 0.3 -0.3 Chi 0. 1.2E-03 0. 0. 5.4E-03 7.9E-03 3.2E-03 1.7E-04 1.4E-05 Composition Misfit: 1.784261E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.442 0.094748 0.058837 0.000000 0.000833 0.000000 0.000000 0.000000 0.154418 0.691163 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.4 0.1 Chi 1.0E-04 8.9E-04 0. 3.3E-04 0. 0. 0. 2.7E-04 1.6E-05 Composition Misfit: 1.610842E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.801 0.000000 0.000000 0.012752 0.075216 0.208078 0.001048 0.183318 0.128233 0.391355 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -2. 0.1 -0.9 0.9 1. Chi 0. 0. 5.8E-03 9.1E-04 2.7E-03 1.4E-04 1.0E-03 1.1E-03 1.5E-03 Composition Misfit: 1.326481E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.004 0.000000 0.000000 0.004839 0.000000 0.144666 0.003338 0.053778 0.429529 0.363850 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.1 -4. 1. 1. Chi 0. 0. 1.3E-03 0. 1.3E-03 7.5E-05 1.8E-02 8.4E-04 1.4E-03 Composition Misfit: 2.256808E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.693 0.000000 0.000000 0.432750 0.000000 0.538399 0.013764 0.015087 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -5. 0. 4. -0.6 -0.8 0. 0. Chi 0. 0. 1.6E-02 0. 1.6E-02 1.0E-03 1.7E-03 0. 0. Composition Misfit: 3.415228E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.108 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.052 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023303 0.014744 0.006976 0.016464 0.052903 0.000918 0.040297 0.029864 0.001091 0.108435 0.705004 Mica 0.019256 0.018165 0.000000 0.054397 0.002676 0.000000 0.004495 0.165472 0.000000 0.250120 0.485420 Gt 0.000000 0.026061 0.000000 0.000000 0.282436 0.054940 0.069737 0.000000 0.001696 0.138739 0.426391 Fsp 0.094748 0.058837 0.000000 0.000833 0.000000 0.000000 0.000000 0.000000 0.000000 0.154418 0.691163 Bio 0.000000 0.000000 0.011175 0.065913 0.182343 0.000918 0.160645 0.120650 0.003032 0.112373 0.342951 St 0.000000 0.000000 0.004403 0.000000 0.131639 0.003037 0.048936 0.088290 0.001758 0.390851 0.331086 Ilm 0.000000 0.000000 0.418672 0.000000 0.520885 0.013316 0.014596 0.000000 0.032531 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -770478. -751873. -927071. -845187. -310183. -460406. -635039. -289533. -415465. -1630779. -883904. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 352 converged, 86 successes so far. Misfit function evaluations this try => 211 Misfit this try = 0.124106 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.417524E-07 Bayes score, PP * exp(-Misfit) = 7.435081E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5993.11 814.149 0.903976 0.269148 Final coordinates: 8325.90 930.792 0.536324 0.558494 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.124106 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.358 0.023332 0.024759 0.000000 0.063215 0.004049 0.000000 0.006694 0.298412 0.579539 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.2E-03 0. 0. 7.1E-03 1.2E-02 0. 7.0E-03 1.1E-03 7.2E-04 Composition Misfit: 6.039583E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.945 0.000000 0.024975 0.000000 0.000000 0.284453 0.042364 0.084695 0.137101 0.426413 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -0.9 -3. 0.5 -0.2 Chi 0. 7.8E-04 0. 0. 4.9E-03 1.6E-03 1.1E-02 3.3E-04 7.2E-06 Composition Misfit: 1.816832E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.828 0.094949 0.057938 0.000000 0.001081 0.000000 0.000000 0.000000 0.153969 0.692062 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 6.9E-04 0. 7.1E-05 0. 0. 0. 3.1E-04 8.6E-06 Composition Misfit: 1.200037E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.132 0.000000 0.000000 0.013529 0.075271 0.201023 0.001000 0.191078 0.129069 0.389030 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.5E-03 9.2E-04 1.4E-03 1.8E-04 2.4E-03 9.8E-04 1.9E-03 Composition Misfit: 1.227992E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.366 0.000000 0.000000 0.004904 0.000000 0.138685 0.002895 0.062383 0.427734 0.363399 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 4.2E-04 3.1E-04 2.5E-02 1.0E-03 1.4E-03 Composition Misfit: 2.934226E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.826 0.000000 0.000000 0.358765 0.000000 0.614339 0.011442 0.015454 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.5 0. 0.7 -0.2 -0.9 0. 0. Chi 0. 0. 2.1E-04 0. 4.0E-04 1.8E-04 1.9E-03 0. 0. Composition Misfit: 2.719892E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.320 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.226 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023226 0.014696 0.006954 0.016410 0.052730 0.000915 0.040165 0.032367 0.001768 0.108079 0.702691 Mica 0.019478 0.020669 0.000000 0.052773 0.003381 0.000000 0.005589 0.165172 0.000000 0.249123 0.483815 Gt 0.000000 0.024912 0.000000 0.000000 0.283738 0.042257 0.084482 0.000000 0.002512 0.136756 0.425342 Fsp 0.094949 0.057938 0.000000 0.001081 0.000000 0.000000 0.000000 0.000000 0.000000 0.153969 0.692062 Bio 0.000000 0.000000 0.011853 0.065946 0.176117 0.000876 0.167405 0.120039 0.003855 0.113078 0.340832 St 0.000000 0.000000 0.004460 0.000000 0.126141 0.002633 0.056740 0.088141 0.002308 0.389046 0.330530 Ilm 0.000000 0.000000 0.335101 0.000000 0.573818 0.010687 0.014435 0.000000 0.065960 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777835. -756427. -932418. -853070. -315463. -468072. -638011. -292792. -408395. -1636973. -887395. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 354 converged, 87 successes so far. Misfit function evaluations this try => 232 Misfit this try = 7.07054 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 7.817889E-07 Bayes score, PP * exp(-Misfit) = 6.643434E-10 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5753.48 893.012 0.696834 0.943139 Final coordinates: 7988.63 928.643 0.405629 0.923737 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.153146 Extraneous predicted phases: 6.91739 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.581 0.023007 0.024253 0.000000 0.063836 0.003816 0.000000 0.006486 0.298734 0.579868 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.0E-03 0. 0. 6.7E-03 1.4E-02 0. 7.7E-03 1.1E-03 7.0E-04 Composition Misfit: 6.148423E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.288 0.000000 0.023030 0.000000 0.000000 0.273304 0.054819 0.084019 0.138056 0.426771 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.3 0. 0. 3. -2. -3. 0.4 -0.2 Chi 0. 2.7E-04 0. 0. 8.6E-03 7.7E-03 1.0E-02 2.4E-04 1.0E-05 Composition Misfit: 2.705282E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 24.677 0.094284 0.059279 0.000000 0.001077 0.000000 0.000000 0.000000 0.154639 0.690721 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.4 0.2 Chi 7.4E-05 1.0E-03 0. 7.3E-05 0. 0. 0. 2.5E-04 2.1E-05 Composition Misfit: 1.416802E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.581 0.000000 0.000000 0.013904 0.075327 0.197172 0.001294 0.193001 0.129911 0.389389 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.9 -1. -0.8 3.7E-02 -2. 0.7 1. Chi 0. 0. 4.0E-03 9.3E-04 8.2E-04 1.3E-05 2.9E-03 8.3E-04 1.8E-03 Composition Misfit: 1.127136E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.115 0.000000 0.000000 0.005304 0.000000 0.135802 0.003817 0.063164 0.428329 0.363584 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.4 4.7E-03 -5. 1. 1. Chi 0. 0. 7.8E-04 0. 1.7E-04 1.3E-07 2.6E-02 9.5E-04 1.4E-03 Composition Misfit: 2.894828E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.640 0.000000 0.000000 0.407072 0.000000 0.558815 0.015792 0.018321 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -3. 0. 3. -0.9 -1. 0. 0. Chi 0. 0. 8.0E-03 0. 9.1E-03 2.1E-03 3.8E-03 0. 0. Composition Misfit: 2.297274E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.000 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.657 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Melt 3.460 0.033266 0.010505 0.008619 0.013004 0.002489 0.000000 0.001678 0.381286 0.000242 0.058513 0.490399 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022754 0.014398 0.006812 0.016077 0.051658 0.000897 0.039349 0.052446 0.001310 0.105883 0.688416 Mica 0.019206 0.020245 0.000000 0.053289 0.003186 0.000000 0.005414 0.165233 0.000000 0.249373 0.484055 Gt 0.000000 0.022982 0.000000 0.000000 0.272731 0.054704 0.083843 0.000000 0.002096 0.137767 0.425877 Fsp 0.094284 0.059279 0.000000 0.001077 0.000000 0.000000 0.000000 0.000000 0.000000 0.154639 0.690721 Bio 0.000000 0.000000 0.012189 0.066033 0.172845 0.001135 0.169189 0.119878 0.003503 0.113883 0.341346 St 0.000000 0.000000 0.004825 0.000000 0.123549 0.003472 0.057465 0.088208 0.002018 0.389683 0.330779 Ilm 0.000000 0.000000 0.388997 0.000000 0.534003 0.015091 0.017508 0.000000 0.044401 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778899. -757084. -932168. -854265. -315753. -466139. -638152. -293050. -412253. -1637357. -887935. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 356 converged, 88 successes so far. Misfit function evaluations this try => 213 Misfit this try = 0.132138 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.615444E-07 Bayes score, PP * exp(-Misfit) = 7.549025E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 7649.65 907.086 0.115087 0.442073 Final coordinates: 8361.54 929.650 0.529875 0.641765 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.132138 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.598 0.024075 0.025234 0.000000 0.062251 0.003902 0.000000 0.006672 0.298871 0.578995 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.8E-03 0. 0. 7.9E-03 1.3E-02 0. 7.1E-03 1.1E-03 7.6E-04 Composition Misfit: 6.343398E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.749 0.000000 0.025125 0.000000 0.000000 0.281251 0.043837 0.086244 0.137123 0.426421 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 8.3E-04 0. 0. 5.9E-03 2.1E-03 1.1E-02 3.3E-04 7.3E-06 Composition Misfit: 2.061558E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.139 0.095180 0.057516 0.000000 0.001062 0.000000 0.000000 0.000000 0.153758 0.692484 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.3E-04 6.1E-04 0. 8.2E-05 0. 0. 0. 3.3E-04 5.9E-06 Composition Misfit: 1.159958E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.552 0.000000 0.000000 0.013595 0.075228 0.197113 0.001026 0.195227 0.128413 0.389397 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.8 0.1 -2. 0.9 1. Chi 0. 0. 4.4E-03 9.1E-04 8.1E-04 1.5E-04 3.4E-03 1.1E-03 1.8E-03 Composition Misfit: 1.261892E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.573 0.000000 0.000000 0.004974 0.000000 0.136867 0.002986 0.064036 0.427732 0.363404 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.4 0.2 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 2.5E-04 2.4E-04 2.6E-02 1.0E-03 1.4E-03 Composition Misfit: 3.045487E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.818 0.000000 0.000000 0.363139 0.000000 0.608783 0.011971 0.016107 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.7 0. 1. -0.3 -1. 0. 0. Chi 0. 0. 4.8E-04 0. 7.4E-04 3.2E-04 2.3E-03 0. 0. Composition Misfit: 3.854723E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.056 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.514 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023115 0.014626 0.006920 0.016332 0.052477 0.000911 0.039973 0.037015 0.001738 0.107562 0.699331 Mica 0.020098 0.021066 0.000000 0.051967 0.003257 0.000000 0.005570 0.165195 0.000000 0.249499 0.483348 Gt 0.000000 0.025062 0.000000 0.000000 0.280548 0.043727 0.086028 0.000000 0.002503 0.136780 0.425354 Fsp 0.095180 0.057516 0.000000 0.001062 0.000000 0.000000 0.000000 0.000000 0.000000 0.153758 0.692484 Bio 0.000000 0.000000 0.011913 0.065917 0.172717 0.000899 0.171064 0.119921 0.003848 0.112520 0.341202 St 0.000000 0.000000 0.004524 0.000000 0.124490 0.002716 0.058245 0.088144 0.002291 0.389050 0.330540 Ilm 0.000000 0.000000 0.339881 0.000000 0.569792 0.011204 0.015075 0.000000 0.064047 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777397. -756195. -932076. -852821. -315386. -467627. -637733. -292579. -408081. -1636712. -887189. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 357 converged, 89 successes so far. Misfit function evaluations this try => 266 Misfit this try = 0.124624 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 7.567100E-07 Bayes score, PP * exp(-Misfit) = 6.680455E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 11866.5 893.433 0.297666 0.148359 Final coordinates: 7928.21 929.745 0.511727 0.511868 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.124624 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.373 0.021979 0.022998 0.000000 0.065481 0.004005 0.000000 0.006402 0.297971 0.581164 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 6.1E-03 0. 0. 5.5E-03 1.3E-02 0. 8.0E-03 1.0E-03 6.1E-04 Composition Misfit: 5.702251E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.687 0.000000 0.022889 0.000000 0.000000 0.279588 0.052469 0.080987 0.137503 0.426564 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.3 0. 0. 2. -2. -3. 0.5 -0.2 Chi 0. 2.4E-04 0. 0. 6.4E-03 6.3E-03 8.5E-03 2.9E-04 8.5E-06 Composition Misfit: 2.174835E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.440 0.094472 0.058795 0.000000 0.001130 0.000000 0.000000 0.000000 0.154397 0.691205 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.4 0.1 Chi 8.4E-05 8.8E-04 0. 4.6E-05 0. 0. 0. 2.7E-04 1.6E-05 Composition Misfit: 1.300820E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.511 0.000000 0.000000 0.013414 0.075418 0.205216 0.001255 0.185572 0.131267 0.387858 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 4.8E-02 -1. 0.7 1. Chi 0. 0. 4.7E-03 9.5E-04 2.1E-03 2.3E-05 1.4E-03 6.2E-04 2.0E-03 Composition Misfit: 1.183384E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.028 0.000000 0.000000 0.004845 0.000000 0.140029 0.003676 0.060090 0.427920 0.363441 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.7 3.5E-02 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.8E-04 7.3E-06 2.3E-02 9.9E-04 1.4E-03 Composition Misfit: 2.727592E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.789 0.000000 0.000000 0.368542 0.000000 0.601750 0.014432 0.015276 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 1. -0.7 -0.8 0. 0. Chi 0. 0. 9.3E-04 0. 1.3E-03 1.4E-03 1.8E-03 0. 0. Composition Misfit: 5.442404E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.940 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.233 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023291 0.014737 0.006973 0.016456 0.052877 0.000918 0.040277 0.029747 0.001691 0.108381 0.704653 Mica 0.018348 0.019199 0.000000 0.054662 0.003343 0.000000 0.005344 0.165219 0.000000 0.248740 0.485145 Gt 0.000000 0.022836 0.000000 0.000000 0.278935 0.052347 0.080798 0.000000 0.002337 0.137181 0.425567 Fsp 0.094472 0.058795 0.000000 0.001130 0.000000 0.000000 0.000000 0.000000 0.000000 0.154397 0.691205 Bio 0.000000 0.000000 0.011748 0.066050 0.179727 0.001099 0.162523 0.120353 0.003853 0.114963 0.339684 St 0.000000 0.000000 0.004407 0.000000 0.127367 0.003343 0.054656 0.088154 0.002265 0.389228 0.330579 Ilm 0.000000 0.000000 0.345812 0.000000 0.564637 0.013542 0.014334 0.000000 0.061675 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -779380. -757486. -933061. -854442. -315791. -466662. -638602. -293347. -409512. -1637665. -888194. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio F sill ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio F sill ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 364 converged, 90 successes so far. Misfit function evaluations this try => 376 Misfit this try = 0.738092 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 9.780268E-07 Bayes score, PP * exp(-Misfit) = 4.675212E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5946.47 948.377 0.889285 0.187966 Final coordinates: 9129.94 931.876 0.756381 0.713597 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.182864 Extraneous predicted phases: 0.555228 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 9.158 0.030597 0.030472 0.000000 0.053191 0.003362 0.000000 0.006398 0.302548 0.573432 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 3. 1. 0. 1. -1. 3. Chi 1.3E-02 0. 0. 1.8E-02 1.8E-02 0. 8.0E-03 1.6E-03 1.2E-03 Composition Misfit: 9.113305E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.627 0.000000 0.028935 0.000000 0.000000 0.284384 0.028155 0.096183 0.136249 0.426093 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. 0.7 -4. 0.5 -0.2 Chi 0. 2.4E-03 0. 0. 5.0E-03 1.3E-03 1.8E-02 4.2E-04 4.8E-06 Composition Misfit: 2.693995E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 24.072 0.096821 0.054396 0.000000 0.000981 0.000000 0.000000 0.000000 0.152198 0.695604 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.4 -0.3 0. 0.1 0. 0. 0. 0.6 -4.9E-02 Chi 2.8E-04 1.4E-04 0. 1.4E-04 0. 0. 0. 5.0E-04 1.8E-06 Composition Misfit: 1.064079E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.337 0.000000 0.000000 0.013822 0.074931 0.184183 0.000640 0.210789 0.123970 0.391664 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. 1.9E-02 0.2 -3. 1. 1. Chi 0. 0. 4.1E-03 8.5E-04 4.6E-07 9.6E-04 8.1E-03 2.2E-03 1.5E-03 Composition Misfit: 1.767227E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.241 0.000000 0.000000 0.005105 0.000000 0.131352 0.001837 0.071098 0.427302 0.363306 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -2.3E-02 0.4 -6. 1. 1. Chi 0. 0. 9.7E-04 0. 7.1E-07 2.2E-03 3.3E-02 1.1E-03 1.5E-03 Composition Misfit: 3.830385E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.644 0.000000 0.000000 0.317041 0.000000 0.660029 0.007347 0.015583 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 2. 0. -1. 0.4 -0.9 0. 0. Chi 0. 0. 3.4E-03 0. 1.4E-03 9.6E-04 2.0E-03 0. 0. Composition Misfit: 7.750599E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.048 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.445 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.428 0.000000 0.000000 0.227785 0.000000 0.646641 0.005897 0.010790 0.000000 0.108886 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023003 0.014555 0.006887 0.016252 0.052222 0.000906 0.039778 0.040958 0.002469 0.107039 0.695931 Mica 0.025539 0.025435 0.000000 0.044398 0.002807 0.000000 0.005340 0.165309 0.000000 0.252534 0.478638 Gt 0.000000 0.028852 0.000000 0.000000 0.283565 0.028074 0.095906 0.000000 0.002883 0.135856 0.424865 Fsp 0.096821 0.054396 0.000000 0.000981 0.000000 0.000000 0.000000 0.000000 0.000000 0.152198 0.695604 Bio 0.000000 0.000000 0.012119 0.065701 0.161496 0.000562 0.184825 0.119283 0.003895 0.108699 0.343420 St 0.000000 0.000000 0.004643 0.000000 0.119464 0.001670 0.064663 0.088113 0.002393 0.388629 0.330425 Ilm 0.000000 0.000000 0.290469 0.000000 0.604710 0.006731 0.014277 0.000000 0.083812 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774362. -754354. -930820. -850491. -314955. -470624. -636455. -291480. -404970. -1635405. -885671. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 367 converged, 91 successes so far. Misfit function evaluations this try => 331 Misfit this try = 0.121247 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.534567E-07 Bayes score, PP * exp(-Misfit) = 7.560052E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6105.21 840.693 0.931898 0.745037 Final coordinates: 8286.77 928.741 0.523524 0.523679 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121247 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.386 0.023110 0.024511 0.000000 0.063564 0.004068 0.000000 0.006635 0.298342 0.579770 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.0E-03 0. 0. 6.9E-03 1.2E-02 0. 7.2E-03 1.1E-03 7.1E-04 Composition Misfit: 5.974124E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.032 0.000000 0.025062 0.000000 0.000000 0.286092 0.041827 0.083377 0.137194 0.426448 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -0.8 -3. 0.5 -0.2 Chi 0. 8.1E-04 0. 0. 4.5E-03 1.4E-03 9.8E-03 3.2E-04 7.5E-06 Composition Misfit: 1.680048E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.112 0.094868 0.058116 0.000000 0.001074 0.000000 0.000000 0.000000 0.154058 0.691884 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.3E-04 0. 7.5E-05 0. 0. 0. 3.0E-04 9.9E-06 Composition Misfit: 1.229415E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.840 0.000000 0.000000 0.013498 0.075280 0.202933 0.000980 0.189034 0.129198 0.389076 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.2E-04 1.7E-03 2.0E-04 2.0E-03 9.6E-04 1.9E-03 Composition Misfit: 1.221882E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.011 0.000000 0.000000 0.004863 0.000000 0.140186 0.002797 0.060946 0.427796 0.363411 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.7 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 6.0E-04 3.9E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.840205E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.817 0.000000 0.000000 0.361692 0.000000 0.611843 0.011218 0.015247 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.6 0. 0.8 -0.2 -0.8 0. 0. Chi 0. 0. 3.8E-04 0. 5.4E-04 1.3E-04 1.8E-03 0. 0. Composition Misfit: 2.854581E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.705 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.098 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023274 0.014726 0.006968 0.016444 0.052838 0.000917 0.040247 0.030412 0.001729 0.108302 0.704142 Mica 0.019293 0.020462 0.000000 0.053065 0.003396 0.000000 0.005539 0.165178 0.000000 0.249063 0.484005 Gt 0.000000 0.025000 0.000000 0.000000 0.285385 0.041724 0.083171 0.000000 0.002471 0.136855 0.425394 Fsp 0.094868 0.058116 0.000000 0.001074 0.000000 0.000000 0.000000 0.000000 0.000000 0.154058 0.691884 Bio 0.000000 0.000000 0.011826 0.065954 0.177793 0.000859 0.165616 0.120082 0.003805 0.113192 0.340875 St 0.000000 0.000000 0.004423 0.000000 0.127507 0.002544 0.055434 0.088145 0.002299 0.389105 0.330543 Ilm 0.000000 0.000000 0.338297 0.000000 0.572268 0.010493 0.014260 0.000000 0.064681 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777565. -756237. -932267. -852684. -315196. -467986. -637966. -292690. -408706. -1636727. -887261. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 369 converged, 92 successes so far. Misfit function evaluations this try => 192 Misfit this try = 0.129852 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.367222E-07 Bayes score, PP * exp(-Misfit) = 7.348310E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6312.60 839.895 0.199905 0.699296 Final coordinates: 8283.67 930.345 0.510584 0.612591 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.129852 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.619 0.023544 0.024730 0.000000 0.063031 0.003956 0.000000 0.006648 0.298580 0.579511 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.4E-03 0. 0. 7.3E-03 1.3E-02 0. 7.2E-03 1.1E-03 7.2E-04 Composition Misfit: 6.148240E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.746 0.000000 0.024620 0.000000 0.000000 0.281411 0.045092 0.085173 0.137239 0.426465 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 6.7E-04 0. 0. 5.8E-03 2.6E-03 1.1E-02 3.2E-04 7.7E-06 Composition Misfit: 2.027277E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.458 0.095009 0.057827 0.000000 0.001078 0.000000 0.000000 0.000000 0.153914 0.692173 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.2E-04 6.7E-04 0. 7.3E-05 0. 0. 0. 3.2E-04 7.8E-06 Composition Misfit: 1.187710E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.211 0.000000 0.000000 0.013616 0.075268 0.199159 0.001064 0.192710 0.129022 0.389163 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -2. 0.8 1. Chi 0. 0. 4.4E-03 9.2E-04 1.1E-03 1.2E-04 2.8E-03 9.9E-04 1.8E-03 Composition Misfit: 1.216209E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.631 0.000000 0.000000 0.004987 0.000000 0.137633 0.003091 0.063058 0.427807 0.363424 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.5 0.2 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 3.2E-04 1.8E-04 2.6E-02 1.0E-03 1.4E-03 Composition Misfit: 2.958376E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.797 0.000000 0.000000 0.369347 0.000000 0.602031 0.012405 0.016218 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 1. -0.4 -1. 0. 0. Chi 0. 0. 1.0E-03 0. 1.3E-03 4.7E-04 2.4E-03 0. 0. Composition Misfit: 5.162872E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.095 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.442 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023156 0.014651 0.006932 0.016360 0.052569 0.000912 0.040042 0.035394 0.001678 0.107750 0.700554 Mica 0.019654 0.020645 0.000000 0.052619 0.003303 0.000000 0.005550 0.165191 0.000000 0.249257 0.483781 Gt 0.000000 0.024560 0.000000 0.000000 0.280721 0.044982 0.084965 0.000000 0.002452 0.136902 0.425419 Fsp 0.095009 0.057827 0.000000 0.001078 0.000000 0.000000 0.000000 0.000000 0.000000 0.153914 0.692173 Bio 0.000000 0.000000 0.011930 0.065951 0.174507 0.000932 0.168856 0.119972 0.003808 0.113051 0.340992 St 0.000000 0.000000 0.004536 0.000000 0.125189 0.002811 0.057356 0.088151 0.002264 0.389127 0.330566 Ilm 0.000000 0.000000 0.346698 0.000000 0.565114 0.011644 0.015223 0.000000 0.061321 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777908. -756518. -932305. -853239. -315521. -467578. -637967. -292787. -408734. -1636992. -887443. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 370 converged, 93 successes so far. Misfit function evaluations this try => 167 Misfit this try = 0.152919 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 6.525534E-07 Bayes score, PP * exp(-Misfit) = 5.600206E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5490.76 926.265 0.863552 0.122630 Final coordinates: 7330.37 877.833 0.386430 0.515123 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.152919 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.167 0.022883 0.021347 0.000000 0.065602 0.003123 0.000000 0.005297 0.299727 0.582021 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 6.9E-03 0. 0. 5.4E-03 2.1E-02 0. 1.3E-02 1.2E-03 5.6E-04 Composition Misfit: 6.891676E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.642 0.000000 0.025925 0.000000 0.000000 0.279500 0.059753 0.069268 0.138584 0.426969 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.7 0. 0. 2. -3. -1. 0.4 -0.3 Chi 0. 1.1E-03 0. 0. 6.4E-03 1.1E-02 3.0E-03 2.0E-04 1.3E-05 Composition Misfit: 2.167644E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.445 0.094689 0.058957 0.000000 0.000833 0.000000 0.000000 0.000000 0.154478 0.691043 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.2 0. 0. 0. 0.4 0.2 Chi 9.8E-05 9.2E-04 0. 3.3E-04 0. 0. 0. 2.7E-04 1.7E-05 Composition Misfit: 1.631493E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.782 0.000000 0.000000 0.012455 0.075256 0.208105 0.001134 0.183976 0.128836 0.390239 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -2. 0.1 -1. 0.8 1. Chi 0. 0. 6.4E-03 9.2E-04 2.7E-03 7.5E-05 1.1E-03 1.0E-03 1.7E-03 Composition Misfit: 1.390611E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.017 0.000000 0.000000 0.004591 0.000000 0.145011 0.003657 0.053896 0.429120 0.363725 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 3.9E-02 -4. 1. 1. Chi 0. 0. 1.6E-03 0. 1.3E-03 9.0E-06 1.8E-02 8.8E-04 1.4E-03 Composition Misfit: 2.306578E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.730 0.000000 0.000000 0.416296 0.000000 0.554527 0.014906 0.014271 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -4. 0. 3. -0.8 -0.7 0. 0. Chi 0. 0. 1.1E-02 0. 1.0E-02 1.6E-03 1.3E-03 0. 0. Composition Misfit: 2.372284E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.099 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.118 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023296 0.014740 0.006975 0.016460 0.052889 0.000918 0.040286 0.029943 0.001277 0.108405 0.704811 Mica 0.019096 0.017814 0.000000 0.054745 0.002606 0.000000 0.004420 0.165496 0.000000 0.250124 0.485699 Gt 0.000000 0.025877 0.000000 0.000000 0.278979 0.059642 0.069139 0.000000 0.001866 0.138326 0.426172 Fsp 0.094689 0.058957 0.000000 0.000833 0.000000 0.000000 0.000000 0.000000 0.000000 0.154478 0.691043 Bio 0.000000 0.000000 0.010907 0.065903 0.182242 0.000993 0.161112 0.120899 0.003378 0.112825 0.341741 St 0.000000 0.000000 0.004177 0.000000 0.131931 0.003327 0.049035 0.088245 0.001951 0.390415 0.330918 Ilm 0.000000 0.000000 0.399573 0.000000 0.532251 0.014307 0.013698 0.000000 0.040171 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -770634. -752014. -927335. -845354. -310200. -459714. -635052. -289558. -412087. -1630776. -883999. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 373 converged, 94 successes so far. Misfit function evaluations this try => 215 Misfit this try = 0.190543 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 7.100664E-08 Bayes score, PP * exp(-Misfit) = 5.868772E-08 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5847.02 812.312 0.792191 0.154456 Final coordinates: 6567.74 801.407 0.502022 0.540437 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.190543 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.460 0.024877 0.019697 0.000000 0.064693 0.001932 0.000000 0.003875 0.302300 0.582626 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 8.5E-03 0. 0. 6.0E-03 4.4E-02 0. 2.4E-02 1.6E-03 5.2E-04 Composition Misfit: 0.104474 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.592 0.000000 0.035231 0.000000 0.000000 0.275151 0.069863 0.054592 0.138301 0.426863 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 3. -4. 1.9E-02 0.4 -0.3 Chi 0. 6.1E-03 0. 0. 7.9E-03 1.8E-02 7.5E-07 2.2E-04 1.1E-05 Composition Misfit: 3.245940E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.019 0.095107 0.058818 0.000000 0.000484 0.000000 0.000000 0.000000 0.154409 0.691182 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.3 0. 0. 0. 0.4 0.1 Chi 1.3E-04 8.9E-04 0. 1.6E-03 0. 0. 0. 2.7E-04 1.6E-05 Composition Misfit: 2.879406E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.993 0.000000 0.000000 0.010129 0.074914 0.207400 0.000889 0.190927 0.123716 0.392024 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -2. 0.2 -1. 1. 1. Chi 0. 0. 1.2E-02 8.5E-04 2.5E-03 3.2E-04 2.4E-03 2.2E-03 1.5E-03 Composition Misfit: 2.226012E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.006 0.000000 0.000000 0.003413 0.000000 0.153067 0.003403 0.047061 0.429369 0.363688 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. 0.1 -3. 1. 1. Chi 0. 0. 4.5E-03 0. 3.2E-03 5.6E-05 1.2E-02 8.6E-04 1.4E-03 Composition Misfit: 2.236438E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.896 0.000000 0.000000 0.383044 0.000000 0.594004 0.013721 0.009231 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. -0.6 0.1 0. 0. Chi 0. 0. 2.9E-03 0. 2.2E-03 1.0E-03 6.4E-05 0. 0. Composition Misfit: 6.105167E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.006 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.028 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023253 0.014713 0.006962 0.016429 0.052791 0.000916 0.040211 0.031357 0.001656 0.108205 0.703507 Mica 0.020751 0.016430 0.000000 0.053963 0.001612 0.000000 0.003232 0.165859 0.000000 0.252160 0.485992 Gt 0.000000 0.035161 0.000000 0.000000 0.274603 0.069724 0.054483 0.000000 0.001989 0.138026 0.426014 Fsp 0.095107 0.058818 0.000000 0.000484 0.000000 0.000000 0.000000 0.000000 0.000000 0.154409 0.691182 Bio 0.000000 0.000000 0.008854 0.065483 0.181289 0.000777 0.166890 0.122112 0.003785 0.108140 0.342669 St 0.000000 0.000000 0.003105 0.000000 0.139231 0.003095 0.042807 0.088217 0.002175 0.390557 0.330814 Ilm 0.000000 0.000000 0.361882 0.000000 0.561187 0.012963 0.008721 0.000000 0.055247 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -757832. -743849. -920195. -832034. -302377. -450098. -629771. -284099. -404959. -1621055. -877952. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 374 converged, 95 successes so far. Misfit function evaluations this try => 155 Misfit this try = 0.182602 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 1.092964E-07 Bayes score, PP * exp(-Misfit) = 9.105484E-08 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5544.50 815.742 0.898286 7.782851E-02 Final coordinates: 6815.90 809.331 0.496421 0.542245 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.182602 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.654 0.025682 0.020797 0.000000 0.063320 0.002017 0.000000 0.003988 0.302591 0.581606 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 9.1E-03 0. 0. 7.1E-03 4.1E-02 0. 2.3E-02 1.6E-03 5.8E-04 Composition Misfit: 0.103502 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.688 0.000000 0.035962 0.000000 0.000000 0.279408 0.063105 0.056659 0.138085 0.426782 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -3. -0.2 0.4 -0.3 Chi 0. 6.6E-03 0. 0. 6.5E-03 1.3E-02 6.1E-05 2.4E-04 1.1E-05 Composition Misfit: 2.658250E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.937 0.095200 0.058595 0.000000 0.000502 0.000000 0.000000 0.000000 0.154297 0.691405 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.3E-04 8.4E-04 0. 1.5E-03 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 2.721906E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.875 0.000000 0.000000 0.010380 0.074888 0.206805 0.000834 0.191442 0.123316 0.392335 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.2 -1. 1. 1. Chi 0. 0. 1.2E-02 8.4E-04 2.4E-03 4.2E-04 2.5E-03 2.3E-03 1.4E-03 Composition Misfit: 2.157725E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.012 0.000000 0.000000 0.003530 0.000000 0.152334 0.003107 0.048103 0.429257 0.363670 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. 0.2 -3. 1. 1. Chi 0. 0. 4.1E-03 0. 3.0E-03 1.7E-04 1.3E-02 8.7E-04 1.4E-03 Composition Misfit: 2.269632E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.889 0.000000 0.000000 0.383166 0.000000 0.594601 0.012585 0.009648 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. -0.4 0.1 0. 0. Chi 0. 0. 2.9E-03 0. 2.1E-03 5.3E-04 1.3E-05 0. 0. Composition Misfit: 5.522200E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.945 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023251 0.014712 0.006961 0.016428 0.052786 0.000916 0.040208 0.031459 0.001638 0.108195 0.703446 Mica 0.021423 0.017348 0.000000 0.052819 0.001683 0.000000 0.003327 0.165832 0.000000 0.252412 0.485157 Gt 0.000000 0.035887 0.000000 0.000000 0.278825 0.062973 0.056541 0.000000 0.002083 0.137797 0.425893 Fsp 0.095200 0.058595 0.000000 0.000502 0.000000 0.000000 0.000000 0.000000 0.000000 0.154297 0.691405 Bio 0.000000 0.000000 0.009076 0.065480 0.180824 0.000730 0.167392 0.121884 0.003744 0.107824 0.343047 St 0.000000 0.000000 0.003211 0.000000 0.138564 0.002826 0.043755 0.088212 0.002180 0.390456 0.330797 Ilm 0.000000 0.000000 0.362018 0.000000 0.561783 0.011891 0.009115 0.000000 0.055193 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -758383. -744141. -920613. -832668. -302946. -451478. -630063. -284375. -405167. -1621657. -878169. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 378 converged, 96 successes so far. Misfit function evaluations this try => 319 Misfit this try = 6.48485 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 9.718898E-07 Bayes score, PP * exp(-Misfit) = 1.483484E-09 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6086.36 988.278 0.917096 9.185871E-02 Final coordinates: 9044.51 931.388 0.759767 0.748274 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.173247 Extraneous predicted phases: 6.31160 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.781 0.029525 0.029510 0.000000 0.054723 0.003457 0.000000 0.006513 0.301795 0.574478 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 2. 1. 0. 1. -1. 3. Chi 1.2E-02 0. 0. 1.6E-02 1.7E-02 0. 7.6E-03 1.5E-03 1.1E-03 Composition Misfit: 8.549320E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.462 0.000000 0.028397 0.000000 0.000000 0.283843 0.030207 0.095087 0.136339 0.426127 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. 0.4 -4. 0.5 -0.2 Chi 0. 2.2E-03 0. 0. 5.1E-03 5.4E-04 1.7E-02 4.1E-04 5.1E-06 Composition Misfit: 2.530794E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 23.122 0.096787 0.054442 0.000000 0.000992 0.000000 0.000000 0.000000 0.152221 0.695558 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.4 -0.3 0. 0.1 0. 0. 0. 0.6 -4.7E-02 Chi 2.7E-04 1.5E-04 0. 1.4E-04 0. 0. 0. 4.9E-04 1.6E-06 Composition Misfit: 1.052631E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.630 0.000000 0.000000 0.013770 0.074962 0.185499 0.000689 0.209255 0.124437 0.391388 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.1 0.2 -3. 1. 1. Chi 0. 0. 4.2E-03 8.6E-04 5.7E-06 7.9E-04 7.5E-03 2.0E-03 1.5E-03 Composition Misfit: 1.695424E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.137 0.000000 0.000000 0.005070 0.000000 0.131966 0.001979 0.070338 0.427335 0.363311 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.1 0.4 -6. 1. 1. Chi 0. 0. 1.0E-03 0. 6.4E-06 1.7E-03 3.2E-02 1.1E-03 1.5E-03 Composition Misfit: 3.722706E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.621 0.000000 0.000000 0.317037 0.000000 0.659716 0.007879 0.015368 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 2. 0. -1. 0.3 -0.9 0. 0. Chi 0. 0. 3.4E-03 0. 1.3E-03 5.7E-04 1.9E-03 0. 0. Composition Misfit: 7.212170E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.790 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.678 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.447 0.000000 0.000000 0.227837 0.000000 0.646337 0.006321 0.010639 0.000000 0.108865 0.000000 0.000000 Mica 2.333 0.051827 0.039082 0.000000 0.011835 0.000544 0.000000 0.001025 0.166405 0.000000 0.267579 0.461703 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022957 0.014526 0.006873 0.016220 0.052118 0.000904 0.039699 0.042862 0.002475 0.106825 0.694541 Mica 0.024645 0.024633 0.000000 0.045678 0.002886 0.000000 0.005436 0.165280 0.000000 0.251914 0.479528 Gt 0.000000 0.028316 0.000000 0.000000 0.283035 0.030121 0.094817 0.000000 0.002843 0.135952 0.424916 Fsp 0.096787 0.054442 0.000000 0.000992 0.000000 0.000000 0.000000 0.000000 0.000000 0.152221 0.695558 Bio 0.000000 0.000000 0.012072 0.065721 0.162631 0.000604 0.183459 0.119370 0.003907 0.109097 0.343138 St 0.000000 0.000000 0.004611 0.000000 0.120022 0.001800 0.063972 0.088115 0.002391 0.388659 0.330430 Ilm 0.000000 0.000000 0.290465 0.000000 0.604422 0.007218 0.014080 0.000000 0.083814 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774621. -754566. -930954. -850695. -314981. -470083. -636572. -291573. -405143. -1635511. -885813. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 380 converged, 97 successes so far. Misfit function evaluations this try => 267 Misfit this try = 0.133601 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 9.813392E-07 Bayes score, PP * exp(-Misfit) = 8.586118E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5902.69 906.331 8.086931E-02 0.107875 Final coordinates: 8378.84 915.835 0.638864 0.541906 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.133584 Extraneous predicted phases: 1.761726E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.625 0.024943 0.025692 0.000000 0.061201 0.003707 0.000000 0.006399 0.299708 0.578351 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 8.5E-03 0. 0. 8.8E-03 1.5E-02 0. 8.0E-03 1.2E-03 8.1E-04 Composition Misfit: 6.805442E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.164 0.000000 0.027682 0.000000 0.000000 0.286786 0.039061 0.083325 0.136834 0.426313 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.9 0. 0. 2. -0.5 -3. 0.5 -0.2 Chi 0. 1.8E-03 0. 0. 4.3E-03 5.9E-04 9.8E-03 3.6E-04 6.4E-06 Composition Misfit: 1.686920E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.677 0.095264 0.057552 0.000000 0.000960 0.000000 0.000000 0.000000 0.153776 0.692448 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.4E-04 6.2E-04 0. 1.6E-04 0. 0. 0. 3.3E-04 6.1E-06 Composition Misfit: 1.254072E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.075 0.000000 0.000000 0.013085 0.075144 0.199040 0.000857 0.194829 0.127161 0.389884 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.2 -2. 0.9 1. Chi 0. 0. 5.2E-03 8.9E-04 1.1E-03 3.8E-04 3.3E-03 1.4E-03 1.7E-03 Composition Misfit: 1.397080E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.002 0.000000 0.000000 0.004668 0.000000 0.139506 0.002537 0.062200 0.427715 0.363374 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.6 0.3 -5. 1. 1. Chi 0. 0. 1.5E-03 0. 5.1E-04 6.7E-04 2.5E-02 1.0E-03 1.4E-03 Composition Misfit: 2.995980E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.944 0.000000 0.000000 0.324979 0.000000 0.651998 0.009763 0.013259 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 1. 0. -1. 3.8E-02 -0.5 0. 0. Chi 0. 0. 1.9E-03 0. 7.4E-04 5.7E-06 8.0E-04 0. 0. Composition Misfit: 3.475369E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.455 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.057 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.002 0.000000 0.000000 0.221849 0.000000 0.650666 0.007615 0.008610 0.000000 0.111261 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023241 0.014705 0.006958 0.016421 0.052762 0.000916 0.040190 0.031425 0.002107 0.108146 0.703130 Mica 0.020821 0.021446 0.000000 0.051087 0.003094 0.000000 0.005341 0.165261 0.000000 0.250178 0.482772 Gt 0.000000 0.027610 0.000000 0.000000 0.286032 0.038958 0.083106 0.000000 0.002628 0.136474 0.425192 Fsp 0.095264 0.057552 0.000000 0.000960 0.000000 0.000000 0.000000 0.000000 0.000000 0.153776 0.692448 Bio 0.000000 0.000000 0.011461 0.065819 0.174339 0.000750 0.170650 0.120176 0.003925 0.111380 0.341499 St 0.000000 0.000000 0.004246 0.000000 0.126880 0.002307 0.056571 0.088130 0.002375 0.389005 0.330487 Ilm 0.000000 0.000000 0.298829 0.000000 0.599533 0.008978 0.012192 0.000000 0.080469 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774280. -754139. -930573. -849562. -313612. -466702. -636575. -291299. -406502. -1634461. -885648. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 382 converged, 98 successes so far. Misfit function evaluations this try => 172 Misfit this try = 0.146763 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 5.930873E-07 Bayes score, PP * exp(-Misfit) = 5.121301E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5780.07 954.199 0.240916 9.362533E-02 Final coordinates: 7509.58 863.408 0.460449 0.535307 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.146763 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.378 0.024762 0.022665 0.000000 0.063112 0.002856 0.000000 0.005087 0.301006 0.580512 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 8.4E-03 0. 0. 7.2E-03 2.4E-02 0. 1.4E-02 1.4E-03 6.5E-04 Composition Misfit: 7.850178E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.817 0.000000 0.030227 0.000000 0.000000 0.284240 0.052571 0.068350 0.137900 0.426713 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -2. -1. 0.4 -0.2 Chi 0. 3.1E-03 0. 0. 5.0E-03 6.4E-03 2.7E-03 2.6E-04 9.9E-06 Composition Misfit: 1.743411E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.049 0.095057 0.058440 0.000000 0.000723 0.000000 0.000000 0.000000 0.154220 0.691560 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.2E-04 8.0E-04 0. 5.6E-04 0. 0. 0. 2.9E-04 1.3E-05 Composition Misfit: 1.782551E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.985 0.000000 0.000000 0.011913 0.075078 0.205816 0.000918 0.189071 0.126166 0.391037 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 1. 1. Chi 0. 0. 7.5E-03 8.8E-04 2.2E-03 2.8E-04 2.0E-03 1.6E-03 1.6E-03 Composition Misfit: 1.607302E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.202 0.000000 0.000000 0.004243 0.000000 0.146562 0.003014 0.053836 0.428745 0.363600 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 2.3E-03 0. 1.6E-03 2.3E-04 1.8E-02 9.1E-04 1.4E-03 Composition Misfit: 2.419605E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.812 0.000000 0.000000 0.390780 0.000000 0.584361 0.012192 0.012666 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. -0.3 -0.4 0. 0. Chi 0. 0. 4.3E-03 0. 3.6E-03 3.9E-04 5.6E-04 0. 0. Composition Misfit: 8.775455E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.706 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.052 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023263 0.014720 0.006965 0.016436 0.052814 0.000917 0.040229 0.031073 0.001520 0.108252 0.703813 Mica 0.020662 0.018913 0.000000 0.052663 0.002383 0.000000 0.004245 0.165562 0.000000 0.251171 0.484401 Gt 0.000000 0.030161 0.000000 0.000000 0.283625 0.052457 0.068202 0.000000 0.002164 0.137602 0.425789 Fsp 0.095057 0.058440 0.000000 0.000723 0.000000 0.000000 0.000000 0.000000 0.000000 0.154220 0.691560 Bio 0.000000 0.000000 0.010428 0.065719 0.180159 0.000804 0.165502 0.121009 0.003650 0.110439 0.342290 St 0.000000 0.000000 0.003859 0.000000 0.133319 0.002742 0.048971 0.088199 0.002159 0.390005 0.330746 Ilm 0.000000 0.000000 0.370544 0.000000 0.554102 0.011561 0.012011 0.000000 0.051782 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -766735. -749433. -925531. -841456. -308310. -458684. -633534. -287971. -407863. -1628178. -882080. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 385 converged, 99 successes so far. Misfit function evaluations this try => 189 Misfit this try = 0.122484 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 7.817251E-07 Bayes score, PP * exp(-Misfit) = 6.916078E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 7722.63 875.906 0.168148 0.735687 Final coordinates: 8045.08 930.173 0.540161 0.516117 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.122484 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.739 0.022321 0.023507 0.000000 0.064873 0.004026 0.000000 0.006499 0.298071 0.580703 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 6.4E-03 0. 0. 5.9E-03 1.3E-02 0. 7.6E-03 1.0E-03 6.4E-04 Composition Misfit: 5.777727E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.764 0.000000 0.023547 0.000000 0.000000 0.281067 0.049508 0.082068 0.137315 0.426493 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.4 0. 0. 2. -2. -3. 0.5 -0.2 Chi 0. 3.8E-04 0. 0. 5.9E-03 4.7E-03 9.1E-03 3.1E-04 7.9E-06 Composition Misfit: 2.040522E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.331 0.094578 0.058613 0.000000 0.001116 0.000000 0.000000 0.000000 0.154306 0.691387 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 9.1E-05 8.4E-04 0. 5.3E-05 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 1.278743E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.258 0.000000 0.000000 0.013397 0.075378 0.204154 0.001179 0.187144 0.130668 0.388080 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.7 1. Chi 0. 0. 4.7E-03 9.4E-04 1.9E-03 5.1E-05 1.7E-03 7.1E-04 2.0E-03 Composition Misfit: 1.200687E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.021 0.000000 0.000000 0.004815 0.000000 0.139757 0.003444 0.060756 0.427815 0.363412 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.1 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.4E-04 4.5E-05 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.790390E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.819 0.000000 0.000000 0.357818 0.000000 0.613800 0.013450 0.014932 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.4 0. 0.7 -0.5 -0.8 0. 0. Chi 0. 0. 1.7E-04 0. 4.3E-04 8.9E-04 1.6E-03 0. 0. Composition Misfit: 3.112211E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.864 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.204 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023283 0.014732 0.006971 0.016450 0.052859 0.000917 0.040263 0.029984 0.001785 0.108344 0.704412 Mica 0.018634 0.019623 0.000000 0.054156 0.003361 0.000000 0.005425 0.165202 0.000000 0.248829 0.484770 Gt 0.000000 0.023490 0.000000 0.000000 0.280388 0.049388 0.081870 0.000000 0.002419 0.136983 0.425462 Fsp 0.094578 0.058613 0.000000 0.001116 0.000000 0.000000 0.000000 0.000000 0.000000 0.154306 0.691387 Bio 0.000000 0.000000 0.011733 0.066016 0.178799 0.001033 0.163901 0.120299 0.003896 0.114440 0.339882 St 0.000000 0.000000 0.004380 0.000000 0.127116 0.003133 0.055261 0.088144 0.002305 0.389120 0.330542 Ilm 0.000000 0.000000 0.334069 0.000000 0.573061 0.012557 0.013941 0.000000 0.066372 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778957. -757184. -932957. -854059. -315711. -467055. -638441. -293197. -408798. -1637481. -887972. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio F sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio F sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 393 converged, 100 successes so far. Misfit function evaluations this try => 216 Misfit this try = 2.84689 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 2.766020E-08 Bayes score, PP * exp(-Misfit) = 1.604965E-09 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5758.67 937.171 0.902547 0.911065 Final coordinates: 5145.01 801.419 0.996824 0.586535 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.308666 Extraneous predicted phases: 2.53823 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.325 0.023164 0.016258 0.000000 0.068229 0.001441 0.000000 0.003347 0.301905 0.585657 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 1. 0. 1. -1. 2. Chi 7.1E-03 0. 0. 3.9E-03 0.1 0. 3.1E-02 1.5E-03 3.5E-04 Composition Misfit: 0.125637 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.006 0.000000 0.022179 0.000000 0.000000 0.225368 0.130264 0.055389 0.139492 0.427309 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.2 0. 0. 5. -1.1E+01 -0.1 0.3 -0.3 Chi 0. 1.2E-04 0. 0. 4.1E-02 0.1 6.4E-06 1.4E-04 1.6E-05 Composition Misfit: 0.112415 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.648 0.094612 0.059675 0.000000 0.000550 0.000000 0.000000 0.000000 0.154838 0.690325 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 0.2 0. 0. 0. 0.4 0.2 Chi 9.3E-05 1.1E-03 0. 1.2E-03 0. 0. 0. 2.4E-04 2.5E-05 Composition Misfit: 2.633363E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.405 0.000000 0.000000 0.009895 0.075351 0.191551 0.001741 0.204017 0.130271 0.387174 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.5 -0.1 -2. 0.7 1. Chi 0. 0. 1.3E-02 9.4E-04 2.6E-04 5.8E-05 5.8E-03 7.7E-04 2.1E-03 Composition Misfit: 2.330383E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.627 0.000000 0.000000 0.003373 0.000000 0.143368 0.007384 0.052647 0.429508 0.363720 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -0.9 -0.8 -4. 1. 1. Chi 0. 0. 4.6E-03 0. 1.1E-03 1.7E-03 1.7E-02 8.4E-04 1.4E-03 Composition Misfit: 2.643351E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.431 0.000000 0.000000 0.374888 0.000000 0.585231 0.029811 0.010069 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 2. -3. -1.1E-02 0. 0. Chi 0. 0. 1.7E-03 0. 3.4E-03 1.3E-02 4.8E-07 0. 0. Composition Misfit: 1.824335E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.039 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.617 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.901 0.000000 0.000000 0.181247 0.000000 0.669718 0.017737 0.003797 0.000000 0.127501 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023154 0.014650 0.006932 0.016359 0.052564 0.000912 0.040039 0.033885 0.003275 0.107740 0.700490 Mica 0.019318 0.013559 0.000000 0.056903 0.001202 0.000000 0.002791 0.166001 0.000000 0.251788 0.488438 Gt 0.000000 0.022146 0.000000 0.000000 0.225037 0.130072 0.055307 0.000000 0.001470 0.139286 0.426681 Fsp 0.094612 0.059675 0.000000 0.000550 0.000000 0.000000 0.000000 0.000000 0.000000 0.154838 0.690325 Bio 0.000000 0.000000 0.008636 0.065762 0.167174 0.001519 0.178054 0.122889 0.004370 0.113693 0.337902 St 0.000000 0.000000 0.003068 0.000000 0.130412 0.006717 0.047889 0.088227 0.002141 0.390694 0.330851 Ilm 0.000000 0.000000 0.352818 0.000000 0.550777 0.028056 0.009476 0.000000 0.058873 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -764022. -748501. -922627. -839406. -304862. -447353. -631114. -286000. -403673. -1624132. -881212. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 394 converged, 101 successes so far. Misfit function evaluations this try => 190 Misfit this try = 0.121927 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.235800E-07 Bayes score, PP * exp(-Misfit) = 7.290437E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 14029.3 950.265 0.381264 9.671559E-02 Final coordinates: 8232.93 930.484 0.530666 0.532036 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121927 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.471 0.022882 0.024274 0.000000 0.063911 0.004071 0.000000 0.006632 0.298224 0.580007 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.9E-03 0. 0. 6.6E-03 1.2E-02 0. 7.2E-03 1.1E-03 6.9E-04 Composition Misfit: 5.902047E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.919 0.000000 0.024531 0.000000 0.000000 0.284246 0.044116 0.083472 0.137189 0.426446 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 6.5E-04 0. 0. 5.0E-03 2.2E-03 9.9E-03 3.2E-04 7.5E-06 Composition Misfit: 1.802932E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.101 0.094793 0.058229 0.000000 0.001093 0.000000 0.000000 0.000000 0.154115 0.691771 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.6E-04 0. 6.4E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.233609E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.754 0.000000 0.000000 0.013489 0.075310 0.202785 0.001046 0.188994 0.129644 0.388732 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.3E-04 1.7E-03 1.4E-04 2.0E-03 8.8E-04 1.9E-03 Composition Misfit: 1.211163E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.451 0.000000 0.000000 0.004876 0.000000 0.139450 0.003027 0.061458 0.427781 0.363408 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 5.1E-04 2.2E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.856859E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.818 0.000000 0.000000 0.360407 0.000000 0.612338 0.011963 0.015292 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.6 0. 0.8 -0.3 -0.8 0. 0. Chi 0. 0. 3.0E-04 0. 5.1E-04 3.2E-04 1.8E-03 0. 0. Composition Misfit: 2.963371E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.314 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.172 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023262 0.014719 0.006964 0.016436 0.052811 0.000917 0.040227 0.030881 0.001752 0.108247 0.703784 Mica 0.019102 0.020265 0.000000 0.053354 0.003398 0.000000 0.005536 0.165178 0.000000 0.248964 0.484203 Gt 0.000000 0.024471 0.000000 0.000000 0.283543 0.044007 0.083265 0.000000 0.002474 0.136850 0.425391 Fsp 0.094793 0.058229 0.000000 0.001093 0.000000 0.000000 0.000000 0.000000 0.000000 0.154115 0.691771 Bio 0.000000 0.000000 0.011817 0.065973 0.177644 0.000916 0.165563 0.120129 0.003850 0.113571 0.340538 St 0.000000 0.000000 0.004435 0.000000 0.126838 0.002753 0.055899 0.088144 0.002301 0.389091 0.330540 Ilm 0.000000 0.000000 0.336893 0.000000 0.572387 0.011182 0.014294 0.000000 0.065243 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778189. -756656. -932586. -853341. -315508. -467802. -638171. -292926. -408704. -1637125. -887575. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 395 converged, 102 successes so far. Misfit function evaluations this try => 174 Misfit this try = 0.188468 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.646901E-07 Bayes score, PP * exp(-Misfit) = 7.161599E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 13002.5 988.814 0.441205 0.925348 Final coordinates: 8370.65 929.544 0.917192 0.550234 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.188468 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.281 0.024836 0.026024 0.000000 0.061112 0.003725 0.000000 0.006671 0.299497 0.578135 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 8.4E-03 0. 0. 8.9E-03 1.5E-02 0. 7.1E-03 1.2E-03 8.3E-04 Composition Misfit: 6.732509E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.799 0.000000 0.025412 0.000000 0.000000 0.275769 0.047184 0.088470 0.136846 0.426317 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 3. -1. -3. 0.5 -0.2 Chi 0. 9.3E-04 0. 0. 7.7E-03 3.5E-03 1.3E-02 3.6E-04 6.5E-06 Composition Misfit: 2.538318E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.541 0.095055 0.057814 0.000000 0.001038 0.000000 0.000000 0.000000 0.153907 0.692186 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.2E-04 6.7E-04 0. 9.8E-05 0. 0. 0. 3.2E-04 7.7E-06 Composition Misfit: 1.214461E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.569 0.000000 0.000000 0.013421 0.075203 0.192230 0.001101 0.200842 0.128043 0.389160 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.5 0.1 -2. 0.9 1. Chi 0. 0. 4.7E-03 9.1E-04 3.1E-04 9.5E-05 4.9E-03 1.2E-03 1.8E-03 Composition Misfit: 1.392585E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.109 0.000000 0.000000 0.004825 0.000000 0.134609 0.003226 0.066458 0.427540 0.363343 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.3 0.1 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 9.4E-05 1.2E-04 2.9E-02 1.0E-03 1.5E-03 Composition Misfit: 3.251037E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.196 0.000000 0.000000 0.254500 0.000000 0.723605 0.011007 0.010888 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. -0.2 -0.1 0. 0. Chi 0. 0. 3.6E-02 0. 1.2E-02 9.2E-05 7.2E-05 0. 0. Composition Misfit: 4.810882E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.269 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.236 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023208 0.014685 0.006948 0.016398 0.052689 0.000914 0.040133 0.031863 0.003020 0.107995 0.702146 Mica 0.020733 0.021724 0.000000 0.051015 0.003110 0.000000 0.005569 0.165220 0.000000 0.250014 0.482615 Gt 0.000000 0.025346 0.000000 0.000000 0.275046 0.047061 0.088238 0.000000 0.002623 0.136487 0.425199 Fsp 0.095055 0.057814 0.000000 0.001038 0.000000 0.000000 0.000000 0.000000 0.000000 0.153907 0.692186 Bio 0.000000 0.000000 0.011756 0.065875 0.168387 0.000964 0.175932 0.119994 0.004037 0.112162 0.340892 St 0.000000 0.000000 0.004388 0.000000 0.122425 0.002934 0.060443 0.088122 0.002390 0.388842 0.330456 Ilm 0.000000 0.000000 0.226676 0.000000 0.644494 0.009803 0.009698 0.000000 0.109330 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777350. -756119. -932251. -852979. -315537. -467051. -637533. -292491. -406010. -1636675. -887156. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 398 converged, 103 successes so far. Misfit function evaluations this try => 260 Misfit this try = 0.175473 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 1.893111E-07 Bayes score, PP * exp(-Misfit) = 1.588434E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5808.47 841.801 0.846735 0.788715 Final coordinates: 6566.95 830.608 0.549526 0.530437 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.175473 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.887 0.023359 0.019286 0.000000 0.066341 0.002265 0.000000 0.004308 0.301098 0.583343 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 7.2E-03 0. 0. 4.9E-03 3.5E-02 0. 2.0E-02 1.4E-03 4.8E-04 Composition Misfit: 8.806477E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.427 0.000000 0.028768 0.000000 0.000000 0.267940 0.078244 0.059792 0.138368 0.426888 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 3. -5. -0.5 0.4 -0.3 Chi 0. 2.3E-03 0. 0. 1.1E-02 2.5E-02 4.2E-04 2.2E-04 1.2E-05 Composition Misfit: 3.860848E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.236 0.094795 0.059165 0.000000 0.000623 0.000000 0.000000 0.000000 0.154583 0.690835 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.4 0.2 Chi 1.0E-04 9.7E-04 0. 8.7E-04 0. 0. 0. 2.6E-04 1.9E-05 Composition Misfit: 2.218158E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.318 0.000000 0.000000 0.010754 0.075168 0.206860 0.001185 0.188929 0.127523 0.389581 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.9 1. Chi 0. 0. 1.0E-02 9.0E-04 2.4E-03 4.8E-05 2.0E-03 1.3E-03 1.8E-03 Composition Misfit: 1.890766E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.003 0.000000 0.000000 0.003657 0.000000 0.149270 0.004303 0.050164 0.428993 0.363613 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -1. -0.1 -3. 1. 1. Chi 0. 0. 3.7E-03 0. 2.2E-03 5.0E-05 1.5E-02 8.9E-04 1.4E-03 Composition Misfit: 2.306633E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.902 0.000000 0.000000 0.367414 0.000000 0.605709 0.016885 0.009991 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 1. -1. 1.4E-03 0. 0. Chi 0. 0. 8.3E-04 0. 9.7E-04 2.8E-03 7.3E-09 0. 0. Composition Misfit: 4.607205E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.043 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.184 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023263 0.014719 0.006965 0.016436 0.052813 0.000917 0.040228 0.030789 0.001814 0.108250 0.703805 Mica 0.019487 0.016089 0.000000 0.055345 0.001889 0.000000 0.003594 0.165753 0.000000 0.251190 0.486653 Gt 0.000000 0.028712 0.000000 0.000000 0.267415 0.078091 0.059675 0.000000 0.001960 0.138096 0.426051 Fsp 0.094795 0.059165 0.000000 0.000623 0.000000 0.000000 0.000000 0.000000 0.000000 0.154583 0.690835 Bio 0.000000 0.000000 0.009399 0.065700 0.180803 0.001036 0.165130 0.122000 0.003965 0.111460 0.340507 St 0.000000 0.000000 0.003326 0.000000 0.135772 0.003914 0.045628 0.088195 0.002231 0.390201 0.330733 Ilm 0.000000 0.000000 0.344572 0.000000 0.568051 0.015836 0.009370 0.000000 0.062171 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -763915. -747875. -923654. -838447. -305806. -452795. -632093. -286559. -405444. -1625303. -880873. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 401 converged, 104 successes so far. Misfit function evaluations this try => 185 Misfit this try = 0.123147 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.395583E-07 Bayes score, PP * exp(-Misfit) = 7.422816E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6959.42 927.295 0.267527 0.948645 Final coordinates: 8330.73 931.107 0.582442 0.534558 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.123147 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.857 0.023279 0.024779 0.000000 0.063254 0.004064 0.000000 0.006710 0.298383 0.579530 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.2E-03 0. 0. 7.1E-03 1.2E-02 0. 7.0E-03 1.1E-03 7.2E-04 Composition Misfit: 6.019815E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.994 0.000000 0.025080 0.000000 0.000000 0.284720 0.042126 0.084721 0.136984 0.426369 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -0.9 -3. 0.5 -0.2 Chi 0. 8.2E-04 0. 0. 4.9E-03 1.5E-03 1.1E-02 3.4E-04 6.9E-06 Composition Misfit: 1.807321E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.977 0.094909 0.058016 0.000000 0.001083 0.000000 0.000000 0.000000 0.154008 0.691984 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.1E-04 0. 7.0E-05 0. 0. 0. 3.1E-04 9.2E-06 Composition Misfit: 1.209728E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.500 0.000000 0.000000 0.013451 0.075276 0.201213 0.000997 0.191072 0.129137 0.388854 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.7E-03 9.2E-04 1.4E-03 1.8E-04 2.4E-03 9.7E-04 1.9E-03 Composition Misfit: 1.244269E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.308 0.000000 0.000000 0.004828 0.000000 0.138898 0.002880 0.062359 0.427662 0.363374 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 4.4E-04 3.2E-04 2.5E-02 1.0E-03 1.4E-03 Composition Misfit: 2.946341E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.870 0.000000 0.000000 0.342097 0.000000 0.632131 0.011178 0.014594 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.4 0. -0.1 -0.2 -0.7 0. 0. Chi 0. 0. 1.8E-04 0. 7.2E-06 1.2E-04 1.4E-03 0. 0. Composition Misfit: 1.760040E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.348 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.146 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023255 0.014714 0.006962 0.016431 0.052795 0.000916 0.040214 0.031018 0.001922 0.108213 0.703560 Mica 0.019434 0.020687 0.000000 0.052806 0.003393 0.000000 0.005602 0.165168 0.000000 0.249100 0.483811 Gt 0.000000 0.025016 0.000000 0.000000 0.283990 0.042018 0.084504 0.000000 0.002563 0.136633 0.425276 Fsp 0.094909 0.058016 0.000000 0.001083 0.000000 0.000000 0.000000 0.000000 0.000000 0.154008 0.691984 Bio 0.000000 0.000000 0.011783 0.065941 0.176260 0.000874 0.167376 0.120098 0.003916 0.113122 0.340631 St 0.000000 0.000000 0.004391 0.000000 0.126331 0.002619 0.056716 0.088132 0.002350 0.388966 0.330495 Ilm 0.000000 0.000000 0.317064 0.000000 0.585875 0.010360 0.013526 0.000000 0.073174 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777890. -756449. -932568. -853110. -315497. -468146. -638036. -292817. -407823. -1637013. -887419. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio F sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio F sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 412 converged, 105 successes so far. Misfit function evaluations this try => 217 Misfit this try = 0.130578 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.724303E-07 Bayes score, PP * exp(-Misfit) = 7.656342E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6166.41 820.207 0.635261 0.336342 Final coordinates: 8447.85 930.439 0.497438 0.615134 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.130578 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.010 0.024054 0.025395 0.000000 0.062175 0.003998 0.000000 0.006739 0.298739 0.578900 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.8E-03 0. 0. 8.0E-03 1.3E-02 0. 6.9E-03 1.1E-03 7.7E-04 Composition Misfit: 6.275226E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.959 0.000000 0.025514 0.000000 0.000000 0.284753 0.039954 0.086202 0.137147 0.426430 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -0.6 -3. 0.5 -0.2 Chi 0. 9.7E-04 0. 0. 4.9E-03 8.2E-04 1.1E-02 3.3E-04 7.4E-06 Composition Misfit: 1.840928E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.301 0.095227 0.057418 0.000000 0.001064 0.000000 0.000000 0.000000 0.153709 0.692582 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.3E-04 5.9E-04 0. 8.1E-05 0. 0. 0. 3.4E-04 5.3E-06 Composition Misfit: 1.147369E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.989 0.000000 0.000000 0.013693 0.075210 0.198410 0.000936 0.193856 0.128149 0.389746 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.9 0.1 -2. 0.9 1. Chi 0. 0. 4.3E-03 9.1E-04 9.8E-04 2.6E-04 3.1E-03 1.2E-03 1.8E-03 Composition Misfit: 1.241548E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.469 0.000000 0.000000 0.005045 0.000000 0.137556 0.002701 0.063477 0.427794 0.363426 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.5 0.2 -5. 1. 1. Chi 0. 0. 1.0E-03 0. 3.1E-04 4.8E-04 2.6E-02 1.0E-03 1.4E-03 Composition Misfit: 3.017446E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.794 0.000000 0.000000 0.373240 0.000000 0.599305 0.010920 0.016535 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 1. -0.1 -1. 0. 0. Chi 0. 0. 1.4E-03 0. 1.6E-03 7.8E-05 2.6E-03 0. 0. Composition Misfit: 5.679459E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.114 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.363 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023153 0.014650 0.006932 0.016359 0.052564 0.000912 0.040038 0.035537 0.001634 0.107739 0.700482 Mica 0.020081 0.021200 0.000000 0.051906 0.003338 0.000000 0.005626 0.165173 0.000000 0.249395 0.483282 Gt 0.000000 0.025450 0.000000 0.000000 0.284043 0.039855 0.085987 0.000000 0.002492 0.136805 0.425367 Fsp 0.095227 0.057418 0.000000 0.001064 0.000000 0.000000 0.000000 0.000000 0.000000 0.153709 0.692582 Bio 0.000000 0.000000 0.012001 0.065915 0.173889 0.000820 0.169898 0.119829 0.003758 0.112312 0.341578 St 0.000000 0.000000 0.004589 0.000000 0.125120 0.002457 0.057739 0.088152 0.002253 0.389119 0.330571 Ilm 0.000000 0.000000 0.350994 0.000000 0.563585 0.010269 0.015549 0.000000 0.059602 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777195. -756034. -931962. -852547. -315300. -468391. -637738. -292544. -408804. -1636652. -887077. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio F ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio F ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 416 converged, 106 successes so far. Misfit function evaluations this try => 310 Misfit this try = 0.124311 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 9.095050E-07 Bayes score, PP * exp(-Misfit) = 8.031886E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5778.72 813.093 0.850832 0.838752 Final coordinates: 8086.06 914.725 0.531515 0.525740 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.124311 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.328 0.023413 0.024015 0.000000 0.063576 0.003770 0.000000 0.006267 0.298959 0.580000 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.3E-03 0. 0. 6.9E-03 1.4E-02 0. 8.5E-03 1.1E-03 6.9E-04 Composition Misfit: 6.290924E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.920 0.000000 0.025910 0.000000 0.000000 0.284794 0.045559 0.079988 0.137273 0.426477 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.7 0. 0. 2. -1. -2. 0.5 -0.2 Chi 0. 1.1E-03 0. 0. 4.8E-03 2.8E-03 7.9E-03 3.1E-04 7.8E-06 Composition Misfit: 1.701415E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.119 0.094867 0.058282 0.000000 0.000992 0.000000 0.000000 0.000000 0.154141 0.691718 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.7E-04 0. 1.3E-04 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.318442E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.908 0.000000 0.000000 0.013083 0.075254 0.203516 0.001009 0.189141 0.128816 0.389180 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 5.2E-03 9.2E-04 1.8E-03 1.7E-04 2.0E-03 1.0E-03 1.8E-03 Composition Misfit: 1.302009E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.049 0.000000 0.000000 0.004700 0.000000 0.141146 0.003006 0.059765 0.427947 0.363436 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.7 0.2 -5. 1. 1. Chi 0. 0. 1.5E-03 0. 7.2E-04 2.3E-04 2.3E-02 9.9E-04 1.4E-03 Composition Misfit: 2.756372E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.832 0.000000 0.000000 0.361446 0.000000 0.612345 0.011844 0.014366 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.6 0. 0.8 -0.3 -0.7 0. 0. Chi 0. 0. 3.6E-04 0. 5.1E-04 2.9E-04 1.3E-03 0. 0. Composition Misfit: 2.485313E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.729 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.116 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023271 0.014724 0.006967 0.016442 0.052831 0.000917 0.040242 0.030527 0.001755 0.108286 0.704039 Mica 0.019543 0.020046 0.000000 0.053069 0.003147 0.000000 0.005232 0.165270 0.000000 0.249550 0.484143 Gt 0.000000 0.025847 0.000000 0.000000 0.284100 0.045448 0.079793 0.000000 0.002437 0.136938 0.425438 Fsp 0.094867 0.058282 0.000000 0.000992 0.000000 0.000000 0.000000 0.000000 0.000000 0.154141 0.691718 Bio 0.000000 0.000000 0.011458 0.065908 0.178239 0.000884 0.165649 0.120357 0.003847 0.112817 0.340842 St 0.000000 0.000000 0.004275 0.000000 0.128380 0.002734 0.054360 0.088151 0.002293 0.389241 0.330565 Ilm 0.000000 0.000000 0.338028 0.000000 0.572672 0.011077 0.013435 0.000000 0.064789 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775350. -754861. -930896. -850421. -313762. -465666. -637030. -291696. -408123. -1634919. -886199. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 417 converged, 107 successes so far. Misfit function evaluations this try => 301 Misfit this try = 0.135012 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.123090E-07 Bayes score, PP * exp(-Misfit) = 7.097191E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6027.58 860.812 0.645423 4.878963E-02 Final coordinates: 8071.67 927.564 0.380371 0.509457 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.135012 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.296 0.022248 0.023450 0.000000 0.064970 0.004106 0.000000 0.006462 0.297987 0.580777 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 6.4E-03 0. 0. 5.8E-03 1.2E-02 0. 7.8E-03 1.0E-03 6.4E-04 Composition Misfit: 5.718745E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.919 0.000000 0.023490 0.000000 0.000000 0.285462 0.045480 0.080611 0.138150 0.426806 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.4 0. 0. 2. -1. -2. 0.4 -0.3 Chi 0. 3.7E-04 0. 0. 4.7E-03 2.8E-03 8.3E-03 2.3E-04 1.1E-05 Composition Misfit: 1.631190E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.440 0.094611 0.058580 0.000000 0.001099 0.000000 0.000000 0.000000 0.154290 0.691420 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 9.3E-05 8.3E-04 0. 6.1E-05 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 1.283085E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.595 0.000000 0.000000 0.013850 0.075347 0.206213 0.001069 0.183702 0.130199 0.389621 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.7 1. Chi 0. 0. 4.1E-03 9.4E-04 2.3E-03 1.2E-04 1.1E-03 7.9E-04 1.8E-03 Composition Misfit: 1.108716E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.016 0.000000 0.000000 0.005261 0.000000 0.140381 0.003105 0.059105 0.428519 0.363629 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.7 0.2 -4. 1. 1. Chi 0. 0. 8.2E-04 0. 6.2E-04 1.7E-04 2.2E-02 9.4E-04 1.4E-03 Composition Misfit: 2.610365E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.689 0.000000 0.000000 0.413348 0.000000 0.556647 0.012679 0.017326 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -3. 0. 3. -0.4 -1. 0. 0. Chi 0. 0. 9.7E-03 0. 9.7E-03 5.7E-04 3.1E-03 0. 0. Composition Misfit: 2.303836E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.944 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.102 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023305 0.014746 0.006977 0.016466 0.052907 0.000918 0.040300 0.029624 0.001258 0.108443 0.705057 Mica 0.018573 0.019576 0.000000 0.054237 0.003427 0.000000 0.005394 0.165196 0.000000 0.248761 0.484835 Gt 0.000000 0.023442 0.000000 0.000000 0.284875 0.045387 0.080446 0.000000 0.002055 0.137866 0.425929 Fsp 0.094611 0.058580 0.000000 0.001099 0.000000 0.000000 0.000000 0.000000 0.000000 0.154290 0.691420 Bio 0.000000 0.000000 0.012142 0.066056 0.180786 0.000937 0.161051 0.119970 0.003334 0.114145 0.341579 St 0.000000 0.000000 0.004787 0.000000 0.127719 0.002825 0.053775 0.088222 0.001969 0.389871 0.330833 Ilm 0.000000 0.000000 0.396183 0.000000 0.533531 0.012153 0.016606 0.000000 0.041527 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778264. -756724. -931992. -853259. -315210. -467343. -638266. -292944. -414209. -1637004. -887626. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 420 converged, 108 successes so far. Misfit function evaluations this try => 250 Misfit this try = 0.121040 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.130226E-07 Bayes score, PP * exp(-Misfit) = 7.203371E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6427.42 889.507 0.546576 0.178796 Final coordinates: 8203.43 930.850 0.522122 0.519479 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121040 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.059 0.022683 0.024092 0.000000 0.064200 0.004095 0.000000 0.006617 0.298121 0.580192 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.7E-03 0. 0. 6.4E-03 1.2E-02 0. 7.3E-03 1.0E-03 6.8E-04 Composition Misfit: 5.833360E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.926 0.000000 0.024325 0.000000 0.000000 0.284402 0.044535 0.083037 0.137237 0.426464 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 5.9E-04 0. 0. 4.9E-03 2.4E-03 9.6E-03 3.2E-04 7.7E-06 Composition Misfit: 1.784297E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.223 0.094730 0.058338 0.000000 0.001101 0.000000 0.000000 0.000000 0.154169 0.691662 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.8E-04 0. 6.0E-05 0. 0. 0. 2.9E-04 1.2E-05 Composition Misfit: 1.244376E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.048 0.000000 0.000000 0.013497 0.075326 0.203651 0.001059 0.187941 0.129895 0.388631 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.3E-04 1.8E-03 1.3E-04 1.8E-03 8.4E-04 1.9E-03 Composition Misfit: 1.201621E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.010 0.000000 0.000000 0.004881 0.000000 0.139756 0.003064 0.061074 0.427809 0.363416 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 5.4E-04 2.0E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.824213E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.809 0.000000 0.000000 0.363193 0.000000 0.609453 0.012045 0.015309 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.7 0. 0.9 -0.3 -0.8 0. 0. Chi 0. 0. 4.8E-04 0. 6.9E-04 3.5E-04 1.8E-03 0. 0. Composition Misfit: 3.360422E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.785 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.140 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023280 0.014730 0.006970 0.016448 0.052851 0.000917 0.040257 0.030175 0.001725 0.108329 0.704317 Mica 0.018936 0.020113 0.000000 0.053596 0.003418 0.000000 0.005524 0.165176 0.000000 0.248878 0.484358 Gt 0.000000 0.024265 0.000000 0.000000 0.283704 0.044426 0.082834 0.000000 0.002453 0.136901 0.425418 Fsp 0.094730 0.058338 0.000000 0.001101 0.000000 0.000000 0.000000 0.000000 0.000000 0.154169 0.691662 Bio 0.000000 0.000000 0.011824 0.065987 0.178401 0.000927 0.164639 0.120150 0.003836 0.113790 0.340446 St 0.000000 0.000000 0.004440 0.000000 0.127117 0.002787 0.055551 0.088147 0.002290 0.389119 0.330550 Ilm 0.000000 0.000000 0.339940 0.000000 0.570433 0.011274 0.014329 0.000000 0.064024 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778405. -756793. -932684. -853520. -315569. -467804. -638273. -293016. -408983. -1637248. -887683. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 422 converged, 109 successes so far. Misfit function evaluations this try => 249 Misfit this try = 0.121166 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.291123E-07 Bayes score, PP * exp(-Misfit) = 7.344996E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5684.27 883.513 0.706626 0.585211 Final coordinates: 8216.84 929.546 0.531641 0.520987 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121166 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.174 0.022830 0.024204 0.000000 0.064000 0.004066 0.000000 0.006607 0.298227 0.580065 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.8E-03 0. 0. 6.5E-03 1.2E-02 0. 7.3E-03 1.1E-03 6.9E-04 Composition Misfit: 5.895037E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.944 0.000000 0.024599 0.000000 0.000000 0.284689 0.044057 0.083016 0.137192 0.426447 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 6.7E-04 0. 0. 4.9E-03 2.2E-03 9.6E-03 3.2E-04 7.5E-06 Composition Misfit: 1.764320E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.186 0.094769 0.058283 0.000000 0.001089 0.000000 0.000000 0.000000 0.154141 0.691717 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.7E-04 0. 6.6E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.243445E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.974 0.000000 0.000000 0.013449 0.075312 0.203346 0.001041 0.188467 0.129683 0.388703 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.7E-03 9.3E-04 1.8E-03 1.4E-04 1.9E-03 8.7E-04 1.9E-03 Composition Misfit: 1.217112E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.002 0.000000 0.000000 0.004854 0.000000 0.139750 0.003023 0.061174 0.427790 0.363409 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.4E-04 2.2E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.838922E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.820 0.000000 0.000000 0.359971 0.000000 0.613055 0.011853 0.015121 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.5 0. 0.8 -0.3 -0.8 0. 0. Chi 0. 0. 2.8E-04 0. 4.7E-04 2.9E-04 1.7E-03 0. 0. Composition Misfit: 2.768799E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.768 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.132 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023277 0.014728 0.006969 0.016446 0.052845 0.000917 0.040253 0.030259 0.001756 0.108316 0.704233 Mica 0.019059 0.020206 0.000000 0.053428 0.003394 0.000000 0.005516 0.165182 0.000000 0.248966 0.484249 Gt 0.000000 0.024539 0.000000 0.000000 0.283985 0.043948 0.082810 0.000000 0.002472 0.136853 0.425393 Fsp 0.094769 0.058283 0.000000 0.001089 0.000000 0.000000 0.000000 0.000000 0.000000 0.154141 0.691717 Bio 0.000000 0.000000 0.011781 0.065972 0.178127 0.000912 0.165094 0.120163 0.003854 0.113600 0.340497 St 0.000000 0.000000 0.004415 0.000000 0.127110 0.002750 0.055641 0.088144 0.002303 0.389098 0.330540 Ilm 0.000000 0.000000 0.336417 0.000000 0.572941 0.011077 0.014132 0.000000 0.065433 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778054. -756567. -932513. -853177. -315399. -467703. -638131. -292870. -408719. -1637008. -887509. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 424 converged, 110 successes so far. Misfit function evaluations this try => 229 Misfit this try = 0.150450 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.033977E-07 Bayes score, PP * exp(-Misfit) = 6.911795E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 7844.72 872.692 0.179061 0.297591 Final coordinates: 8150.80 930.570 0.284458 0.504875 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.149851 Extraneous predicted phases: 5.996731E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.095 0.022176 0.023642 0.000000 0.064922 0.004252 0.000000 0.006563 0.297761 0.580684 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 6.3E-03 0. 0. 5.9E-03 1.1E-02 0. 7.4E-03 1.0E-03 6.4E-04 Composition Misfit: 5.610290E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.080 0.000000 0.022888 0.000000 0.000000 0.288447 0.041533 0.080984 0.139017 0.427131 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.3 0. 0. 2. -0.8 -3. 0.3 -0.3 Chi 0. 2.4E-04 0. 0. 3.9E-03 1.3E-03 8.5E-03 1.7E-04 1.4E-05 Composition Misfit: 1.405236E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.491 0.094641 0.058490 0.000000 0.001114 0.000000 0.000000 0.000000 0.154245 0.691510 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 9.5E-05 8.1E-04 0. 5.3E-05 0. 0. 0. 2.9E-04 1.3E-05 Composition Misfit: 1.260319E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.742 0.000000 0.000000 0.014383 0.075327 0.206496 0.000986 0.181767 0.129902 0.391139 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.9 -1. -1. 0.1 -0.8 0.8 1. Chi 0. 0. 3.4E-03 9.3E-04 2.3E-03 2.0E-04 8.3E-04 8.3E-04 1.6E-03 Composition Misfit: 1.010182E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.004 0.000000 0.000000 0.005756 0.000000 0.139583 0.002829 0.058721 0.429254 0.363857 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.3 0. -0.6 0.2 -4. 1. 1. Chi 0. 0. 4.3E-04 0. 5.2E-04 3.6E-04 2.2E-02 8.7E-04 1.4E-03 Composition Misfit: 2.538442E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.595 0.000000 0.000000 0.441157 0.000000 0.528149 0.011777 0.018917 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -5. 0. 5. -0.3 -1. 0. 0. Chi 0. 0. 1.9E-02 0. 2.0E-02 2.7E-04 4.2E-03 0. 0. Composition Misfit: 4.294884E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.963 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.013 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 ru 0.017 0.000000 0.000000 1.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023318 0.014754 0.006981 0.016475 0.052938 0.000919 0.040323 0.029375 0.000941 0.108506 0.705469 Mica 0.018513 0.019737 0.000000 0.054199 0.003550 0.000000 0.005479 0.165162 0.000000 0.248582 0.484777 Gt 0.000000 0.022850 0.000000 0.000000 0.287963 0.041464 0.080848 0.000000 0.001677 0.138784 0.426415 Fsp 0.094641 0.058490 0.000000 0.001114 0.000000 0.000000 0.000000 0.000000 0.000000 0.154245 0.691510 Bio 0.000000 0.000000 0.012623 0.066111 0.181233 0.000865 0.159530 0.119600 0.002741 0.114010 0.343287 St 0.000000 0.000000 0.005238 0.000000 0.127032 0.002574 0.053441 0.088304 0.001610 0.390658 0.331142 Ilm 0.000000 0.000000 0.428548 0.000000 0.513054 0.011441 0.018376 0.000000 0.028581 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778583. -756907. -931759. -853563. -315366. -468348. -638438. -293113. -421178. -1637316. -887773. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 428 converged, 111 successes so far. Misfit function evaluations this try => 501 Misfit this try = 0.971047 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 9.708926E-07 Bayes score, PP * exp(-Misfit) = 3.676639E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6310.88 969.594 0.297632 0.918744 Final coordinates: 8216.94 890.846 0.294078 0.956360 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.944972 Extraneous predicted phases: 2.607492E-2 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 14.988 0.062586 0.044331 0.000000 0.015121 0.000469 0.000000 0.000806 0.320508 0.556179 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -8. 0. 0. 6. 2. 0. 2. -2. 6. Chi 4.4E-02 0. 0. 0.3 0.2 0. 0.2 5.0E-03 3.5E-03 Composition Misfit: 0.859035 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.175 0.000000 0.028243 0.000000 0.000000 0.291542 0.038284 0.076328 0.138620 0.426983 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -0.4 -2. 0.4 -0.3 Chi 0. 2.1E-03 0. 0. 3.2E-03 4.3E-04 6.1E-03 2.0E-04 1.3E-05 Composition Misfit: 1.197100E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.470 0.096840 0.054588 0.000000 0.000866 0.000000 0.000000 0.000000 0.152294 0.695412 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.4 -0.3 0. 0.1 0. 0. 0. 0.6 -4.1E-02 Chi 2.8E-04 1.6E-04 0. 2.8E-04 0. 0. 0. 4.9E-04 1.2E-06 Composition Misfit: 1.208714E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.167 0.000000 0.000000 0.013291 0.075007 0.202215 0.000752 0.190362 0.125107 0.393265 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.2 -1. 1. 1. Chi 0. 0. 4.9E-03 8.7E-04 1.6E-03 6.0E-04 2.3E-03 1.8E-03 1.3E-03 Composition Misfit: 1.337097E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.848 0.000000 0.000000 0.005201 0.000000 0.141906 0.002299 0.057544 0.429243 0.363808 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.8 0.3 -4. 1. 1. Chi 0. 0. 8.7E-04 0. 8.3E-04 1.0E-03 2.1E-02 8.7E-04 1.4E-03 Composition Misfit: 2.581927E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.471 0.000000 0.000000 0.433370 0.000000 0.540339 0.009667 0.016624 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -5. 0. 4. 0.1 -1. 0. 0. Chi 0. 0. 1.6E-02 0. 1.5E-02 1.1E-05 2.6E-03 0. 0. Composition Misfit: 3.356685E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.000 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 42.771 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 ru 0.108 0.000000 0.000000 1.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022721 0.014376 0.006802 0.016053 0.051581 0.000895 0.039290 0.054218 0.000948 0.105726 0.687390 Mica 0.052166 0.036951 0.000000 0.012604 0.000391 0.000000 0.000672 0.166489 0.000000 0.267147 0.463581 Gt 0.000000 0.028190 0.000000 0.000000 0.291002 0.038214 0.076187 0.000000 0.001850 0.138364 0.426193 Fsp 0.096840 0.054588 0.000000 0.000866 0.000000 0.000000 0.000000 0.000000 0.000000 0.152294 0.695412 Bio 0.000000 0.000000 0.011658 0.065792 0.177372 0.000660 0.166975 0.119926 0.002928 0.109737 0.344951 St 0.000000 0.000000 0.004733 0.000000 0.129129 0.002092 0.052363 0.088280 0.001756 0.390595 0.331052 Ilm 0.000000 0.000000 0.419398 0.000000 0.522918 0.009356 0.016088 0.000000 0.032241 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -769346. -751401. -926792. -844447. -310626. -463769. -634841. -289221. -415251. -1630873. -883342. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio F sill ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio F sill ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 434 converged, 112 successes so far. Misfit function evaluations this try => 215 Misfit this try = 0.136938 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 9.011396E-07 Bayes score, PP * exp(-Misfit) = 7.858153E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5794.07 917.775 0.824137 0.264425 Final coordinates: 8414.62 926.887 0.374227 0.523203 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.136938 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.440 0.023427 0.024908 0.000000 0.063037 0.004152 0.000000 0.006667 0.298389 0.579420 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 7.3E-03 0. 0. 7.3E-03 1.2E-02 0. 7.1E-03 1.1E-03 7.3E-04 Composition Misfit: 6.019654E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.362 0.000000 0.025477 0.000000 0.000000 0.291516 0.035379 0.082995 0.137915 0.426718 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -0.1 -3. 0.4 -0.2 Chi 0. 9.5E-04 0. 0. 3.2E-03 3.6E-05 9.6E-03 2.5E-04 1.0E-05 Composition Misfit: 1.400639E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.060 0.095085 0.057728 0.000000 0.001051 0.000000 0.000000 0.000000 0.153864 0.692272 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.2E-04 6.5E-04 0. 9.0E-05 0. 0. 0. 3.2E-04 7.2E-06 Composition Misfit: 1.193939E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.835 0.000000 0.000000 0.013961 0.075212 0.203759 0.000819 0.187240 0.128179 0.390830 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.9 -1. -1. 0.2 -1. 0.9 1. Chi 0. 0. 3.9E-03 9.1E-04 1.8E-03 4.5E-04 1.7E-03 1.1E-03 1.6E-03 Composition Misfit: 1.155135E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.022 0.000000 0.000000 0.005341 0.000000 0.139901 0.002349 0.060359 0.428436 0.363614 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.3 0. -0.7 0.3 -5. 1. 1. Chi 0. 0. 7.4E-04 0. 5.6E-04 9.4E-04 2.3E-02 9.4E-04 1.4E-03 Composition Misfit: 2.782049E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.702 0.000000 0.000000 0.413627 0.000000 0.558991 0.009679 0.017702 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -3. 0. 3. 0.1 -1. 0. 0. Chi 0. 0. 9.8E-03 0. 9.0E-03 1.1E-05 3.4E-03 0. 0. Composition Misfit: 2.216975E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.627 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.951 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023286 0.014734 0.006972 0.016453 0.052866 0.000917 0.040268 0.030400 0.001236 0.108359 0.704509 Mica 0.019558 0.020794 0.000000 0.052626 0.003466 0.000000 0.005566 0.165161 0.000000 0.249107 0.483722 Gt 0.000000 0.025422 0.000000 0.000000 0.290887 0.035303 0.082816 0.000000 0.002157 0.137618 0.425798 Fsp 0.095085 0.057728 0.000000 0.001051 0.000000 0.000000 0.000000 0.000000 0.000000 0.153864 0.692272 Bio 0.000000 0.000000 0.012245 0.065964 0.178705 0.000718 0.164217 0.119683 0.003278 0.112418 0.342773 St 0.000000 0.000000 0.004859 0.000000 0.127283 0.002137 0.054915 0.088218 0.001975 0.389794 0.330819 Ilm 0.000000 0.000000 0.396503 0.000000 0.535850 0.009279 0.016970 0.000000 0.041399 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776576. -755595. -931190. -851673. -314688. -468859. -637662. -292333. -413808. -1636152. -886765. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 435 converged, 113 successes so far. Misfit function evaluations this try => 207 Misfit this try = 0.209572 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.522176E-07 Bayes score, PP * exp(-Misfit) = 6.910901E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 10338.7 979.312 0.947814 0.944463 Final coordinates: 8260.29 928.227 0.997869 0.550625 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.209572 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.371 0.024843 0.025788 0.000000 0.061243 0.003610 0.000000 0.006590 0.299633 0.578292 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 8.4E-03 0. 0. 8.8E-03 1.6E-02 0. 7.3E-03 1.2E-03 8.1E-04 Composition Misfit: 6.818556E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.681 0.000000 0.024970 0.000000 0.000000 0.271568 0.051782 0.088609 0.136779 0.426292 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 3. -2. -3. 0.5 -0.2 Chi 0. 7.8E-04 0. 0. 9.3E-03 5.9E-03 1.3E-02 3.6E-04 6.3E-06 Composition Misfit: 2.933078E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.528 0.094987 0.057954 0.000000 0.001036 0.000000 0.000000 0.000000 0.153977 0.692046 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.2E-04 7.0E-04 0. 1.0E-04 0. 0. 0. 3.1E-04 8.7E-06 Composition Misfit: 1.234668E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.497 0.000000 0.000000 0.013100 0.075229 0.190717 0.001203 0.202686 0.128433 0.388633 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.4 0.1 -2. 0.9 1. Chi 0. 0. 5.2E-03 9.1E-04 2.0E-04 4.1E-05 5.4E-03 1.1E-03 1.9E-03 Composition Misfit: 1.482243E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.009 0.000000 0.000000 0.004586 0.000000 0.133829 0.003562 0.067175 0.427529 0.363320 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.2 0.1 -5. 1. 1. Chi 0. 0. 1.6E-03 0. 5.8E-05 2.2E-05 2.9E-02 1.0E-03 1.5E-03 Composition Misfit: 3.335661E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.273 0.000000 0.000000 0.242888 0.000000 0.735979 0.011270 0.009864 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. -0.2 2.2E-02 0. 0. Chi 0. 0. 4.7E-02 0. 1.5E-02 1.4E-04 1.9E-06 0. 0. Composition Misfit: 6.264161E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.352 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.289 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023202 0.014680 0.006946 0.016393 0.052673 0.000914 0.040122 0.031877 0.003285 0.107964 0.701944 Mica 0.020738 0.021527 0.000000 0.051123 0.003014 0.000000 0.005501 0.165248 0.000000 0.250120 0.482731 Gt 0.000000 0.024904 0.000000 0.000000 0.270848 0.051644 0.088374 0.000000 0.002652 0.136416 0.425162 Fsp 0.094987 0.057954 0.000000 0.001036 0.000000 0.000000 0.000000 0.000000 0.000000 0.153977 0.692046 Bio 0.000000 0.000000 0.011470 0.065867 0.166984 0.001053 0.177464 0.120265 0.004175 0.112450 0.340271 St 0.000000 0.000000 0.004171 0.000000 0.121708 0.003239 0.061091 0.088111 0.002454 0.388809 0.330416 Ilm 0.000000 0.000000 0.215220 0.000000 0.652142 0.009986 0.008740 0.000000 0.113912 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777543. -756277. -932641. -853250. -315602. -466271. -637497. -292510. -404967. -1636702. -887266. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 444 converged, 114 successes so far. Misfit function evaluations this try => 185 Misfit this try = 0.162046 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 2.982446E-07 Bayes score, PP * exp(-Misfit) = 2.536279E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5743.34 824.549 0.508561 0.358573 Final coordinates: 7171.61 836.305 0.477461 0.536510 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.162046 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.444 0.025358 0.021826 0.000000 0.063038 0.002406 0.000000 0.004507 0.301926 0.580940 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 8.9E-03 0. 0. 7.3E-03 3.2E-02 0. 1.8E-02 1.5E-03 6.3E-04 Composition Misfit: 9.007451E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.753 0.000000 0.033019 0.000000 0.000000 0.282220 0.057597 0.062439 0.137982 0.426743 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -3. -0.7 0.4 -0.2 Chi 0. 4.7E-03 0. 0. 5.6E-03 9.5E-03 9.4E-04 2.5E-04 1.0E-05 Composition Misfit: 2.095477E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.010 0.095134 0.058522 0.000000 0.000605 0.000000 0.000000 0.000000 0.154261 0.691478 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.3E-04 8.2E-04 0. 9.4E-04 0. 0. 0. 2.9E-04 1.3E-05 Composition Misfit: 2.182844E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.988 0.000000 0.000000 0.011141 0.074985 0.206507 0.000878 0.190046 0.124782 0.391661 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.2 -1. 1. 1. Chi 0. 0. 9.4E-03 8.6E-04 2.4E-03 3.4E-04 2.2E-03 1.9E-03 1.5E-03 Composition Misfit: 1.859739E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.014 0.000000 0.000000 0.003879 0.000000 0.149447 0.003067 0.050979 0.428995 0.363633 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -1. 0.2 -3. 1. 1. Chi 0. 0. 3.1E-03 0. 2.3E-03 1.9E-04 1.5E-02 8.9E-04 1.4E-03 Composition Misfit: 2.327360E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.849 0.000000 0.000000 0.387257 0.000000 0.589278 0.012381 0.011084 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. -0.4 -0.2 0. 0. Chi 0. 0. 3.6E-03 0. 2.8E-03 4.6E-04 1.1E-04 0. 0. Composition Misfit: 6.962451E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.923 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.019 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023260 0.014718 0.006964 0.016434 0.052807 0.000916 0.040224 0.031138 0.001576 0.108238 0.703724 Mica 0.021156 0.018209 0.000000 0.052592 0.002007 0.000000 0.003760 0.165705 0.000000 0.251895 0.484675 Gt 0.000000 0.032948 0.000000 0.000000 0.281620 0.057474 0.062306 0.000000 0.002128 0.137688 0.425835 Fsp 0.095134 0.058522 0.000000 0.000605 0.000000 0.000000 0.000000 0.000000 0.000000 0.154261 0.691478 Bio 0.000000 0.000000 0.009746 0.065601 0.180662 0.000768 0.166261 0.121455 0.003699 0.109165 0.342643 St 0.000000 0.000000 0.003529 0.000000 0.135940 0.002790 0.046372 0.088205 0.002173 0.390223 0.330768 Ilm 0.000000 0.000000 0.366592 0.000000 0.557832 0.011720 0.010493 0.000000 0.053363 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -762462. -746728. -923016. -836974. -305582. -455022. -631765. -286127. -406485. -1624837. -880067. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 445 converged, 115 successes so far. Misfit function evaluations this try => 178 Misfit this try = 0.156861 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 3.776029E-07 Bayes score, PP * exp(-Misfit) = 3.227837E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 13907.8 835.630 0.463085 6.570065E-02 Final coordinates: 7234.05 845.071 0.468082 0.532795 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.156861 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.251 0.024908 0.021843 0.000000 0.063447 0.002553 0.000000 0.004692 0.301503 0.581055 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 8.5E-03 0. 0. 7.0E-03 2.9E-02 0. 1.7E-02 1.5E-03 6.2E-04 Composition Misfit: 8.508545E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.743 0.000000 0.031639 0.000000 0.000000 0.282075 0.057419 0.064083 0.138025 0.426759 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -3. -0.9 0.4 -0.2 Chi 0. 3.9E-03 0. 0. 5.6E-03 9.4E-03 1.3E-03 2.4E-04 1.0E-05 Composition Misfit: 2.046861E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.081 0.095063 0.058582 0.000000 0.000646 0.000000 0.000000 0.000000 0.154291 0.691418 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.2E-04 8.3E-04 0. 7.9E-04 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 2.037539E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.101 0.000000 0.000000 0.011386 0.075035 0.206693 0.000917 0.189134 0.125532 0.391302 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 1. 1. Chi 0. 0. 8.8E-03 8.7E-04 2.4E-03 2.8E-04 2.0E-03 1.7E-03 1.6E-03 Composition Misfit: 1.761992E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.005 0.000000 0.000000 0.003997 0.000000 0.148495 0.003151 0.051785 0.428942 0.363629 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -1. 0.1 -4. 1. 1. Chi 0. 0. 2.8E-03 0. 2.1E-03 1.5E-04 1.6E-02 9.0E-04 1.4E-03 Composition Misfit: 2.337377E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.832 0.000000 0.000000 0.390037 0.000000 0.585633 0.012717 0.011613 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. -0.4 -0.3 0. 0. Chi 0. 0. 4.1E-03 0. 3.4E-03 5.8E-04 2.2E-04 0. 0. Composition Misfit: 8.275527E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.953 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.035 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023266 0.014721 0.006965 0.016438 0.052820 0.000917 0.040234 0.030930 0.001545 0.108265 0.703898 Mica 0.020781 0.018224 0.000000 0.052936 0.002130 0.000000 0.003915 0.165659 0.000000 0.251557 0.484798 Gt 0.000000 0.031572 0.000000 0.000000 0.281480 0.057298 0.063948 0.000000 0.002110 0.137734 0.425859 Fsp 0.095063 0.058582 0.000000 0.000646 0.000000 0.000000 0.000000 0.000000 0.000000 0.154291 0.691418 Bio 0.000000 0.000000 0.009962 0.065654 0.180851 0.000803 0.165487 0.121346 0.003681 0.109837 0.342379 St 0.000000 0.000000 0.003636 0.000000 0.135077 0.002867 0.047105 0.088205 0.002159 0.390181 0.330770 Ilm 0.000000 0.000000 0.369709 0.000000 0.555112 0.012054 0.011008 0.000000 0.052116 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -764042. -747746. -923907. -838610. -306517. -456052. -632406. -286794. -407075. -1626007. -880819. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 448 converged, 116 successes so far. Misfit function evaluations this try => 182 Misfit this try = 0.121601 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.360875E-07 Bayes score, PP * exp(-Misfit) = 7.403570E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 11852.7 831.506 0.203469 7.944381E-02 Final coordinates: 8234.12 929.251 0.553307 0.523391 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121601 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.327 0.022969 0.024334 0.000000 0.063798 0.004045 0.000000 0.006615 0.298308 0.579930 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.9E-03 0. 0. 6.7E-03 1.2E-02 0. 7.3E-03 1.1E-03 6.9E-04 Composition Misfit: 5.946920E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.945 0.000000 0.024771 0.000000 0.000000 0.284381 0.043958 0.083354 0.137117 0.426419 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 7.2E-04 0. 0. 5.0E-03 2.1E-03 9.8E-03 3.3E-04 7.3E-06 Composition Misfit: 1.794179E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.140 0.094799 0.058236 0.000000 0.001083 0.000000 0.000000 0.000000 0.154118 0.691764 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.6E-04 0. 7.0E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.240610E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.869 0.000000 0.000000 0.013409 0.075303 0.202779 0.001034 0.189237 0.129539 0.388699 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.7E-03 9.3E-04 1.7E-03 1.5E-04 2.1E-03 9.0E-04 1.9E-03 Composition Misfit: 1.231192E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.024 0.000000 0.000000 0.004823 0.000000 0.139595 0.003004 0.061436 0.427747 0.363395 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.2E-04 2.3E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.865414E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.841 0.000000 0.000000 0.352413 0.000000 0.620995 0.011767 0.014826 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.1 0. 0.4 -0.3 -0.8 0. 0. Chi 0. 0. 1.7E-05 0. 1.3E-04 2.7E-04 1.6E-03 0. 0. Composition Misfit: 1.983069E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.719 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.136 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023272 0.014725 0.006967 0.016443 0.052834 0.000917 0.040244 0.030393 0.001827 0.108293 0.704084 Mica 0.019175 0.020315 0.000000 0.053260 0.003377 0.000000 0.005523 0.165183 0.000000 0.249033 0.484135 Gt 0.000000 0.024709 0.000000 0.000000 0.283668 0.043848 0.083145 0.000000 0.002505 0.136774 0.425351 Fsp 0.094799 0.058236 0.000000 0.001083 0.000000 0.000000 0.000000 0.000000 0.000000 0.154118 0.691764 Bio 0.000000 0.000000 0.011746 0.065960 0.177621 0.000906 0.165760 0.120175 0.003889 0.113468 0.340476 St 0.000000 0.000000 0.004386 0.000000 0.126966 0.002732 0.055878 0.088139 0.002325 0.389052 0.330521 Ilm 0.000000 0.000000 0.328194 0.000000 0.578319 0.010958 0.013807 0.000000 0.068722 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777911. -756473. -932487. -853059. -315360. -467676. -638059. -292809. -408296. -1636923. -887437. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 457 converged, 117 successes so far. Misfit function evaluations this try => 240 Misfit this try = 0.124152 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 7.652379E-07 Bayes score, PP * exp(-Misfit) = 6.758927E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 7133.75 926.160 0.608801 5.989374E-02 Final coordinates: 7959.74 929.675 0.508982 0.511936 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.124152 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.417 0.022050 0.023118 0.000000 0.065347 0.004017 0.000000 0.006424 0.297985 0.581058 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 6.2E-03 0. 0. 5.6E-03 1.3E-02 0. 7.9E-03 1.0E-03 6.2E-04 Composition Misfit: 5.713392E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.715 0.000000 0.023078 0.000000 0.000000 0.280219 0.051491 0.081173 0.137483 0.426556 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.3 0. 0. 2. -2. -3. 0.5 -0.2 Chi 0. 2.8E-04 0. 0. 6.2E-03 5.8E-03 8.6E-03 2.9E-04 8.5E-06 Composition Misfit: 2.113123E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.425 0.094498 0.058753 0.000000 0.001126 0.000000 0.000000 0.000000 0.154376 0.691247 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 8.6E-05 8.7E-04 0. 4.8E-05 0. 0. 0. 2.8E-04 1.5E-05 Composition Misfit: 1.296249E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.483 0.000000 0.000000 0.013428 0.075406 0.205164 0.001227 0.185700 0.131096 0.387978 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.7 1. Chi 0. 0. 4.7E-03 9.5E-04 2.1E-03 3.2E-05 1.4E-03 6.5E-04 2.0E-03 Composition Misfit: 1.183638E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.003 0.000000 0.000000 0.004856 0.000000 0.140052 0.003593 0.060137 0.427920 0.363442 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.7 0.1 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.8E-04 1.7E-05 2.3E-02 9.9E-04 1.4E-03 Composition Misfit: 2.731531E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.788 0.000000 0.000000 0.369276 0.000000 0.601264 0.014132 0.015328 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 1. -0.7 -0.8 0. 0. Chi 0. 0. 1.0E-03 0. 1.4E-03 1.2E-03 1.9E-03 0. 0. Composition Misfit: 5.439386E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.950 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.218 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023291 0.014737 0.006973 0.016456 0.052877 0.000918 0.040277 0.029752 0.001682 0.108381 0.704656 Mica 0.018407 0.019299 0.000000 0.054551 0.003354 0.000000 0.005363 0.165214 0.000000 0.248754 0.485059 Gt 0.000000 0.023024 0.000000 0.000000 0.279562 0.051370 0.080982 0.000000 0.002345 0.137161 0.425556 Fsp 0.094498 0.058753 0.000000 0.001126 0.000000 0.000000 0.000000 0.000000 0.000000 0.154376 0.691247 Bio 0.000000 0.000000 0.011761 0.066043 0.179689 0.001075 0.162642 0.120326 0.003841 0.114818 0.339804 St 0.000000 0.000000 0.004417 0.000000 0.127389 0.003268 0.054700 0.088155 0.002262 0.389229 0.330581 Ilm 0.000000 0.000000 0.346621 0.000000 0.564376 0.013265 0.014387 0.000000 0.061352 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -779225. -757378. -932983. -854286. -315737. -466776. -638552. -293293. -409536. -1637586. -888114. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 458 converged, 118 successes so far. Misfit function evaluations this try => 149 Misfit this try = 0.121187 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.198948E-07 Bayes score, PP * exp(-Misfit) = 7.263190E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 6433.78 953.503 0.593768 0.379441 Final coordinates: 8236.81 930.938 0.514114 0.520796 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121187 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.136 0.022765 0.024211 0.000000 0.064055 0.004108 0.000000 0.006640 0.298132 0.580089 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.8E-03 0. 0. 6.5E-03 1.2E-02 0. 7.2E-03 1.0E-03 6.8E-04 Composition Misfit: 5.847155E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.964 0.000000 0.024482 0.000000 0.000000 0.285151 0.043448 0.083220 0.137235 0.426463 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 6.3E-04 0. 0. 4.7E-03 1.9E-03 9.7E-03 3.2E-04 7.6E-06 Composition Misfit: 1.735611E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.197 0.094766 0.058271 0.000000 0.001098 0.000000 0.000000 0.000000 0.154136 0.691729 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.6E-04 0. 6.2E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.236502E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.998 0.000000 0.000000 0.013523 0.075315 0.203582 0.001034 0.188054 0.129729 0.388762 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.3E-04 1.8E-03 1.5E-04 1.8E-03 8.6E-04 1.9E-03 Composition Misfit: 1.201358E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.036 0.000000 0.000000 0.004903 0.000000 0.139753 0.002982 0.061124 0.427817 0.363420 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 5.4E-04 2.5E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.830642E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.803 0.000000 0.000000 0.365985 0.000000 0.606743 0.011789 0.015483 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.9 0. 1. -0.3 -0.9 0. 0. Chi 0. 0. 7.0E-04 0. 8.9E-04 2.7E-04 1.9E-03 0. 0. Composition Misfit: 3.802587E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.740 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.127 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023279 0.014729 0.006969 0.016447 0.052849 0.000917 0.040255 0.030250 0.001698 0.108324 0.704282 Mica 0.019005 0.020212 0.000000 0.053475 0.003430 0.000000 0.005543 0.165171 0.000000 0.248890 0.484275 Gt 0.000000 0.024422 0.000000 0.000000 0.284451 0.043342 0.083016 0.000000 0.002454 0.136898 0.425417 Fsp 0.094766 0.058271 0.000000 0.001098 0.000000 0.000000 0.000000 0.000000 0.000000 0.154136 0.691729 Bio 0.000000 0.000000 0.011847 0.065981 0.178352 0.000906 0.164748 0.120116 0.003818 0.113651 0.340581 St 0.000000 0.000000 0.004460 0.000000 0.127115 0.002712 0.055596 0.088148 0.002282 0.389130 0.330556 Ilm 0.000000 0.000000 0.343002 0.000000 0.568640 0.011048 0.014510 0.000000 0.062799 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778276. -756704. -932604. -853393. -315530. -467974. -638234. -292973. -409118. -1637190. -887616. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 462 converged, 119 successes so far. Misfit function evaluations this try => 169 Misfit this try = 0.141913 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 7.376130E-07 Bayes score, PP * exp(-Misfit) = 6.400241E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 11939.6 880.290 0.197277 8.365569E-02 Final coordinates: 7668.16 876.452 0.437677 0.527131 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.141913 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.122 0.024357 0.022984 0.000000 0.063302 0.003106 0.000000 0.005386 0.300452 0.580413 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 8.0E-03 0. 0. 7.1E-03 2.1E-02 0. 1.2E-02 1.3E-03 6.6E-04 Composition Misfit: 7.331324E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.883 0.000000 0.028964 0.000000 0.000000 0.285785 0.049613 0.070984 0.137931 0.426724 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -2. -2. 0.4 -0.2 Chi 0. 2.4E-03 0. 0. 4.6E-03 4.8E-03 3.7E-03 2.5E-04 1.0E-05 Composition Misfit: 1.572835E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.133 0.095010 0.058405 0.000000 0.000787 0.000000 0.000000 0.000000 0.154202 0.691595 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.2E-04 7.9E-04 0. 4.1E-04 0. 0. 0. 2.9E-04 1.2E-05 Composition Misfit: 1.628889E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.142 0.000000 0.000000 0.012320 0.075122 0.206078 0.000922 0.187868 0.126832 0.390859 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 1. 1. Chi 0. 0. 6.6E-03 8.9E-04 2.3E-03 2.7E-04 1.8E-03 1.4E-03 1.6E-03 Composition Misfit: 1.490944E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.017 0.000000 0.000000 0.004458 0.000000 0.145297 0.002950 0.054987 0.428701 0.363607 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.9E-03 0. 1.4E-03 2.7E-04 1.9E-02 9.2E-04 1.4E-03 Composition Misfit: 2.454733E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.783 0.000000 0.000000 0.397391 0.000000 0.577052 0.011938 0.013619 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -3. 0. 2. -0.3 -0.6 0. 0. Chi 0. 0. 5.7E-03 0. 4.9E-03 3.1E-04 9.6E-04 0. 0. Composition Misfit: 1.178623E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.889 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.032 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023276 0.014728 0.006968 0.016446 0.052843 0.000917 0.040251 0.030615 0.001446 0.108311 0.704200 Mica 0.020326 0.019181 0.000000 0.052827 0.002592 0.000000 0.004495 0.165486 0.000000 0.250732 0.484363 Gt 0.000000 0.028901 0.000000 0.000000 0.285170 0.049506 0.070832 0.000000 0.002151 0.137634 0.425806 Fsp 0.095010 0.058405 0.000000 0.000787 0.000000 0.000000 0.000000 0.000000 0.000000 0.154202 0.691595 Bio 0.000000 0.000000 0.010788 0.065781 0.180452 0.000808 0.164507 0.120774 0.003575 0.111061 0.342256 St 0.000000 0.000000 0.004055 0.000000 0.132174 0.002684 0.050020 0.088204 0.002117 0.389980 0.330765 Ilm 0.000000 0.000000 0.377997 0.000000 0.548891 0.011356 0.012954 0.000000 0.048801 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -768844. -750759. -926722. -843626. -309625. -460573. -634422. -288892. -409138. -1629831. -883079. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 466 converged, 120 successes so far. Misfit function evaluations this try => 156 Misfit this try = 0.204213 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.609714E-07 Bayes score, PP * exp(-Misfit) = 7.019404E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 14136.5 989.932 0.630766 0.112606 Final coordinates: 8341.07 929.248 0.977178 0.552945 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.204213 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.486 0.025006 0.026087 0.000000 0.060920 0.003654 0.000000 0.006648 0.299651 0.578034 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 8.6E-03 0. 0. 9.1E-03 1.5E-02 0. 7.2E-03 1.2E-03 8.3E-04 Composition Misfit: 6.838359E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.747 0.000000 0.025309 0.000000 0.000000 0.273415 0.049173 0.089071 0.136750 0.426281 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 3. -2. -3. 0.5 -0.2 Chi 0. 9.0E-04 0. 0. 8.6E-03 4.5E-03 1.3E-02 3.7E-04 6.2E-06 Composition Misfit: 2.759429E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.479 0.095055 0.057820 0.000000 0.001035 0.000000 0.000000 0.000000 0.153910 0.692180 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.2E-04 6.7E-04 0. 1.0E-04 0. 0. 0. 3.2E-04 7.8E-06 Composition Misfit: 1.217517E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.433 0.000000 0.000000 0.013217 0.075208 0.190796 0.001145 0.202610 0.128121 0.388903 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.4 0.1 -2. 0.9 1. Chi 0. 0. 5.0E-03 9.1E-04 2.1E-04 6.8E-05 5.4E-03 1.2E-03 1.9E-03 Composition Misfit: 1.465767E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.067 0.000000 0.000000 0.004666 0.000000 0.133888 0.003371 0.067239 0.427513 0.363322 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.2 0.1 -6. 1. 1. Chi 0. 0. 1.5E-03 0. 6.0E-05 6.5E-05 2.9E-02 1.0E-03 1.5E-03 Composition Misfit: 3.333951E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.254 0.000000 0.000000 0.245599 0.000000 0.733352 0.010889 0.010160 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. -0.1 -2.6E-02 0. 0. Chi 0. 0. 4.4E-02 0. 1.5E-02 7.3E-05 2.5E-06 0. 0. Composition Misfit: 5.902021E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.267 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.266 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023200 0.014679 0.006946 0.016392 0.052670 0.000914 0.040119 0.032009 0.003217 0.107957 0.701897 Mica 0.020874 0.021776 0.000000 0.050854 0.003050 0.000000 0.005550 0.165233 0.000000 0.250138 0.482524 Gt 0.000000 0.025241 0.000000 0.000000 0.272687 0.049042 0.088834 0.000000 0.002665 0.136386 0.425145 Fsp 0.095055 0.057820 0.000000 0.001035 0.000000 0.000000 0.000000 0.000000 0.000000 0.153910 0.692180 Bio 0.000000 0.000000 0.011575 0.065861 0.167084 0.001002 0.177430 0.120148 0.004130 0.112199 0.340571 St 0.000000 0.000000 0.004244 0.000000 0.121765 0.003066 0.061151 0.088113 0.002439 0.388801 0.330423 Ilm 0.000000 0.000000 0.217884 0.000000 0.650596 0.009660 0.009014 0.000000 0.112846 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777412. -756173. -932525. -853111. -315601. -466726. -637485. -292488. -405193. -1636691. -887192. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio sill ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio sill ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 476 converged, 121 successes so far. Misfit function evaluations this try => 216 Misfit this try = 0.121073 Best Misfit so far = 0.120895 obtained on Try 251 Prior probability, PP = 8.127036E-07 Bayes score, PP * exp(-Misfit) = 7.200306E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5701.17 921.669 0.778966 0.441282 Final coordinates: 8193.81 930.657 0.534345 0.520076 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121073 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.090 0.022690 0.024085 0.000000 0.064198 0.004082 0.000000 0.006610 0.298144 0.580191 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.7E-03 0. 0. 6.4E-03 1.2E-02 0. 7.3E-03 1.0E-03 6.8E-04 Composition Misfit: 5.844560E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.909 0.000000 0.024311 0.000000 0.000000 0.284008 0.044956 0.083039 0.137226 0.426460 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 5.8E-04 0. 0. 5.1E-03 2.6E-03 9.6E-03 3.2E-04 7.6E-06 Composition Misfit: 1.812652E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.216 0.094726 0.058348 0.000000 0.001100 0.000000 0.000000 0.000000 0.154174 0.691652 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.8E-04 0. 6.0E-05 0. 0. 0. 2.9E-04 1.2E-05 Composition Misfit: 1.246548E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.025 0.000000 0.000000 0.013451 0.075329 0.203484 0.001069 0.188210 0.129928 0.388529 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.7 1. Chi 0. 0. 4.7E-03 9.3E-04 1.8E-03 1.2E-04 1.9E-03 8.3E-04 1.9E-03 Composition Misfit: 1.210826E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.014 0.000000 0.000000 0.004864 0.000000 0.139589 0.003108 0.061241 0.427789 0.363409 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.2E-04 1.7E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.836712E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.819 0.000000 0.000000 0.359365 0.000000 0.613427 0.012118 0.015090 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.5 0. 0.8 -0.3 -0.8 0. 0. Chi 0. 0. 2.4E-04 0. 4.5E-04 3.7E-04 1.7E-03 0. 0. Composition Misfit: 2.778813E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.777 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.149 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023278 0.014729 0.006969 0.016447 0.052848 0.000917 0.040254 0.030208 0.001765 0.108321 0.704264 Mica 0.018942 0.020107 0.000000 0.053594 0.003407 0.000000 0.005518 0.165179 0.000000 0.248897 0.484356 Gt 0.000000 0.024251 0.000000 0.000000 0.283310 0.044845 0.082835 0.000000 0.002457 0.136889 0.425412 Fsp 0.094726 0.058348 0.000000 0.001100 0.000000 0.000000 0.000000 0.000000 0.000000 0.154174 0.691652 Bio 0.000000 0.000000 0.011782 0.065983 0.178240 0.000937 0.164861 0.120185 0.003873 0.113809 0.340329 St 0.000000 0.000000 0.004424 0.000000 0.126964 0.002827 0.055702 0.088144 0.002301 0.389098 0.330541 Ilm 0.000000 0.000000 0.335756 0.000000 0.573126 0.011322 0.014098 0.000000 0.065698 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778405. -756795. -932709. -853526. -315567. -467712. -638263. -293010. -408748. -1637237. -887684. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 478 converged, 122 successes so far. Misfit function evaluations this try => 273 Misfit this try = 0.120787 Best Misfit so far = 0.120787 obtained on Try 478 Prior probability, PP = 8.184916E-07 Bayes score, PP * exp(-Misfit) = 7.253658E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 9738.56 867.752 0.377614 0.302207 Final coordinates: 8222.21 930.742 0.531466 0.521348 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.120787 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.174 0.022755 0.024204 0.000000 0.064070 0.004092 0.000000 0.006632 0.298160 0.580086 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.8E-03 0. 0. 6.5E-03 1.2E-02 0. 7.2E-03 1.0E-03 6.8E-04 Composition Misfit: 5.857776E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.940 0.000000 0.024454 0.000000 0.000000 0.284617 0.044078 0.083212 0.137192 0.426447 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 6.2E-04 0. 0. 4.9E-03 2.2E-03 9.7E-03 3.2E-04 7.5E-06 Composition Misfit: 1.773915E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.188 0.094760 0.058287 0.000000 0.001097 0.000000 0.000000 0.000000 0.154144 0.691713 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.7E-04 0. 6.2E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.239664E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.969 0.000000 0.000000 0.013482 0.075318 0.203294 0.001048 0.188427 0.129770 0.388661 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.3E-04 1.7E-03 1.4E-04 1.9E-03 8.6E-04 1.9E-03 Composition Misfit: 1.209025E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.034 0.000000 0.000000 0.004866 0.000000 0.139718 0.003028 0.061197 0.427783 0.363408 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.4E-04 2.2E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.838827E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.818 0.000000 0.000000 0.359853 0.000000 0.613187 0.011835 0.015125 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.5 0. 0.8 -0.3 -0.8 0. 0. Chi 0. 0. 2.7E-04 0. 4.6E-04 2.8E-04 1.7E-03 0. 0. Composition Misfit: 2.752011E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.738 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.138 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023277 0.014728 0.006969 0.016446 0.052844 0.000917 0.040252 0.030280 0.001755 0.108314 0.704219 Mica 0.018997 0.020206 0.000000 0.053487 0.003416 0.000000 0.005537 0.165174 0.000000 0.248912 0.484270 Gt 0.000000 0.024394 0.000000 0.000000 0.283913 0.043969 0.083006 0.000000 0.002472 0.136853 0.425393 Fsp 0.094760 0.058287 0.000000 0.001097 0.000000 0.000000 0.000000 0.000000 0.000000 0.154144 0.691713 Bio 0.000000 0.000000 0.011811 0.065979 0.178086 0.000918 0.165062 0.120147 0.003852 0.113679 0.340467 St 0.000000 0.000000 0.004426 0.000000 0.127081 0.002754 0.055662 0.088144 0.002302 0.389092 0.330539 Ilm 0.000000 0.000000 0.336288 0.000000 0.573032 0.011060 0.014135 0.000000 0.065485 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778298. -756720. -932661. -853423. -315539. -467847. -638228. -292974. -408742. -1637189. -887628. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 479 converged, 123 successes so far. Misfit function evaluations this try => 199 Misfit this try = 0.121709 Best Misfit so far = 0.120787 obtained on Try 478 Prior probability, PP = 8.042824E-07 Bayes score, PP * exp(-Misfit) = 7.121164E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5576.11 822.905 0.716383 0.384083 Final coordinates: 8129.93 929.966 0.542392 0.518988 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121709 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.972 0.022576 0.023863 0.000000 0.064433 0.004044 0.000000 0.006557 0.298151 0.580377 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.6E-03 0. 0. 6.2E-03 1.3E-02 0. 7.5E-03 1.0E-03 6.6E-04 Composition Misfit: 5.836957E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.841 0.000000 0.024065 0.000000 0.000000 0.282634 0.046975 0.082628 0.137234 0.426463 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -1. -3. 0.5 -0.2 Chi 0. 5.1E-04 0. 0. 5.5E-03 3.4E-03 9.4E-03 3.2E-04 7.6E-06 Composition Misfit: 1.912419E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.256 0.094667 0.058460 0.000000 0.001102 0.000000 0.000000 0.000000 0.154230 0.691540 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 9.6E-05 8.1E-04 0. 5.9E-05 0. 0. 0. 2.9E-04 1.3E-05 Composition Misfit: 1.262247E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.103 0.000000 0.000000 0.013412 0.075346 0.203656 0.001114 0.187929 0.130189 0.388355 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.7 1. Chi 0. 0. 4.7E-03 9.4E-04 1.8E-03 8.7E-05 1.8E-03 7.9E-04 2.0E-03 Composition Misfit: 1.210085E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.026 0.000000 0.000000 0.004825 0.000000 0.139699 0.003244 0.061036 0.427789 0.363406 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.1 -5. 1. 1. Chi 0. 0. 1.3E-03 0. 5.4E-04 1.1E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.819134E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.825 0.000000 0.000000 0.356649 0.000000 0.615717 0.012689 0.014944 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.4 0. 0.7 -0.4 -0.8 0. 0. Chi 0. 0. 1.2E-04 0. 3.3E-04 5.7E-04 1.6E-03 0. 0. Composition Misfit: 2.660862E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.803 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.174 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023279 0.014729 0.006969 0.016448 0.052849 0.000917 0.040256 0.030146 0.001792 0.108325 0.704290 Mica 0.018847 0.019921 0.000000 0.053789 0.003376 0.000000 0.005473 0.165192 0.000000 0.248899 0.484504 Gt 0.000000 0.024006 0.000000 0.000000 0.281941 0.046860 0.082426 0.000000 0.002454 0.136898 0.425416 Fsp 0.094667 0.058460 0.000000 0.001102 0.000000 0.000000 0.000000 0.000000 0.000000 0.154230 0.691540 Bio 0.000000 0.000000 0.011747 0.065993 0.178376 0.000975 0.164602 0.120240 0.003888 0.114029 0.340149 St 0.000000 0.000000 0.004389 0.000000 0.127063 0.002951 0.055515 0.088143 0.002311 0.389094 0.330535 Ilm 0.000000 0.000000 0.332796 0.000000 0.574537 0.011841 0.013945 0.000000 0.066882 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778535. -756893. -932765. -853652. -315575. -467353. -638292. -293043. -408648. -1637264. -887755. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 480 converged, 124 successes so far. Misfit function evaluations this try => 127 Misfit this try = 0.212754 Best Misfit so far = 0.120787 obtained on Try 478 Prior probability, PP = 8.954795E-07 Bayes score, PP * exp(-Misfit) = 7.238654E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 12390.6 862.507 0.896522 0.248406 Final coordinates: 8044.96 915.196 0.993394 0.551694 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.212754 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.279 0.025222 0.025305 0.000000 0.061174 0.003333 0.000000 0.006180 0.300285 0.578501 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 8.8E-03 0. 0. 8.9E-03 1.8E-02 0. 8.8E-03 1.3E-03 8.0E-04 Composition Misfit: 7.217312E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.592 0.000000 0.025481 0.000000 0.000000 0.269835 0.056248 0.084993 0.137049 0.426394 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 3. -2. -3. 0.5 -0.2 Chi 0. 9.6E-04 0. 0. 1.0E-02 8.6E-03 1.1E-02 3.4E-04 7.1E-06 Composition Misfit: 3.068700E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.547 0.094955 0.058160 0.000000 0.000965 0.000000 0.000000 0.000000 0.154080 0.691840 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.2E-04 7.4E-04 0. 1.6E-04 0. 0. 0. 3.0E-04 1.0E-05 Composition Misfit: 1.327357E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.586 0.000000 0.000000 0.012909 0.075207 0.191278 0.001240 0.202338 0.128111 0.388917 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -0.5 0.1 -2. 0.9 1. Chi 0. 0. 5.5E-03 9.1E-04 2.4E-04 2.7E-05 5.3E-03 1.2E-03 1.9E-03 Composition Misfit: 1.508456E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.064 0.000000 0.000000 0.004562 0.000000 0.135079 0.003771 0.065513 0.427710 0.363364 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.3 1.4E-02 -5. 1. 1. Chi 0. 0. 1.7E-03 0. 1.2E-04 1.2E-06 2.8E-02 1.0E-03 1.4E-03 Composition Misfit: 3.194855E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.274 0.000000 0.000000 0.243807 0.000000 0.734526 0.012151 0.009516 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. -0.3 0.1 0. 0. Chi 0. 0. 4.6E-02 0. 1.5E-02 3.8E-04 2.5E-05 0. 0. Composition Misfit: 6.153329E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.356 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.301 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023200 0.014680 0.006946 0.016392 0.052671 0.000914 0.040120 0.031937 0.003270 0.107959 0.701911 Mica 0.021052 0.021121 0.000000 0.051059 0.002782 0.000000 0.005158 0.165343 0.000000 0.250635 0.482849 Gt 0.000000 0.025417 0.000000 0.000000 0.269151 0.056106 0.084778 0.000000 0.002534 0.136702 0.425313 Fsp 0.094955 0.058160 0.000000 0.000965 0.000000 0.000000 0.000000 0.000000 0.000000 0.154080 0.691840 Bio 0.000000 0.000000 0.011302 0.065843 0.167462 0.001085 0.177145 0.120385 0.004125 0.112160 0.340493 St 0.000000 0.000000 0.004149 0.000000 0.122851 0.003430 0.059582 0.088125 0.002403 0.388990 0.330469 Ilm 0.000000 0.000000 0.216123 0.000000 0.651120 0.010771 0.008435 0.000000 0.113551 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775612. -755085. -931214. -851271. -314282. -464192. -636694. -291630. -405082. -1635083. -886344. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 491 converged, 125 successes so far. Misfit function evaluations this try => 245 Misfit this try = 0.134753 Best Misfit so far = 0.120787 obtained on Try 478 Prior probability, PP = 8.295395E-07 Bayes score, PP * exp(-Misfit) = 7.249609E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 5895.63 919.141 0.175714 7.467364E-02 Final coordinates: 8267.73 930.691 0.372731 0.515183 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.134753 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.779 0.022632 0.024178 0.000000 0.064193 0.004213 0.000000 0.006645 0.297974 0.580165 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.7E-03 0. 0. 6.4E-03 1.1E-02 0. 7.2E-03 1.0E-03 6.8E-04 Composition Misfit: 5.754874E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.120 0.000000 0.024101 0.000000 0.000000 0.288582 0.040107 0.082364 0.138070 0.426776 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.5 0. 0. 2. -0.6 -3. 0.4 -0.2 Chi 0. 5.2E-04 0. 0. 3.9E-03 8.6E-04 9.2E-03 2.4E-04 1.1E-05 Composition Misfit: 1.471039E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.288 0.094791 0.058221 0.000000 0.001098 0.000000 0.000000 0.000000 0.154111 0.691779 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 7.5E-04 0. 6.1E-05 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.229144E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.261 0.000000 0.000000 0.014015 0.075295 0.205102 0.000950 0.185057 0.129420 0.390162 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.9 -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 3.9E-03 9.2E-04 2.1E-03 2.4E-04 1.3E-03 9.2E-04 1.7E-03 Composition Misfit: 1.102076E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.057 0.000000 0.000000 0.005361 0.000000 0.139894 0.002723 0.059918 0.428478 0.363627 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.3 0. -0.7 0.2 -5. 1. 1. Chi 0. 0. 7.3E-04 0. 5.6E-04 4.6E-04 2.3E-02 9.4E-04 1.4E-03 Composition Misfit: 2.693192E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.688 0.000000 0.000000 0.414667 0.000000 0.556435 0.011149 0.017748 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -4. 0. 3. -0.2 -1. 0. 0. Chi 0. 0. 1.0E-02 0. 9.7E-03 1.2E-04 3.4E-03 0. 0. Composition Misfit: 2.331201E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.771 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.037 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023297 0.014741 0.006975 0.016460 0.052891 0.000918 0.040287 0.029948 0.001232 0.108410 0.704841 Mica 0.018895 0.020185 0.000000 0.053591 0.003517 0.000000 0.005548 0.165156 0.000000 0.248762 0.484348 Gt 0.000000 0.024051 0.000000 0.000000 0.287979 0.040023 0.082191 0.000000 0.002090 0.137781 0.425884 Fsp 0.094791 0.058221 0.000000 0.001098 0.000000 0.000000 0.000000 0.000000 0.000000 0.154111 0.691779 Bio 0.000000 0.000000 0.012291 0.066030 0.179864 0.000833 0.162286 0.119769 0.003280 0.113495 0.342153 St 0.000000 0.000000 0.004878 0.000000 0.127279 0.002477 0.054514 0.088223 0.001956 0.389838 0.330835 Ilm 0.000000 0.000000 0.397699 0.000000 0.533665 0.010693 0.017022 0.000000 0.040920 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778087. -756570. -931959. -853131. -315332. -468530. -638238. -292926. -414461. -1637083. -887518. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 492 converged, 126 successes so far. Misfit function evaluations this try => 191 Misfit this try = 0.169984 Best Misfit so far = 0.120787 obtained on Try 478 Prior probability, PP = 5.283321E-07 Bayes score, PP * exp(-Misfit) = 4.457421E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 7522.46 878.415 0.946508 0.580865 Final coordinates: 6791.63 916.749 0.616210 0.534653 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.169726 Extraneous predicted phases: 2.582102E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.006 0.020725 0.019487 0.000000 0.068663 0.003263 0.000000 0.005428 0.298445 0.583989 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 1. 0. 1. -1. 2. Chi 5.2E-03 0. 0. 3.6E-03 1.9E-02 0. 1.2E-02 1.1E-03 4.4E-04 Composition Misfit: 6.105602E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.096 0.000000 0.018401 0.000000 0.000000 0.253879 0.088109 0.074678 0.138133 0.426800 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. 0.3 0. 0. 4. -6. -2. 0.4 -0.3 Chi 0. 2.5E-04 0. 0. 1.8E-02 3.3E-02 5.3E-03 2.4E-04 1.1E-05 Composition Misfit: 5.695159E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.546 0.094101 0.059443 0.000000 0.001178 0.000000 0.000000 0.000000 0.154721 0.690557 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 0.1 0. 0. 0. 0.4 0.2 Chi 6.4E-05 1.0E-03 0. 2.7E-05 0. 0. 0. 2.5E-04 2.3E-05 Composition Misfit: 1.396163E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.694 0.000000 0.000000 0.012691 0.075709 0.204216 0.002068 0.184967 0.135642 0.384707 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. -0.2 -1. 0.3 2. Chi 0. 0. 5.9E-03 1.0E-03 1.9E-03 2.0E-04 1.3E-03 1.6E-04 2.5E-03 Composition Misfit: 1.304427E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.874 0.000000 0.000000 0.004448 0.000000 0.138731 0.006494 0.058761 0.428110 0.363456 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.6 -0.6 -4. 1. 1. Chi 0. 0. 1.9E-03 0. 4.3E-04 1.1E-03 2.2E-02 9.8E-04 1.4E-03 Composition Misfit: 2.764430E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.867 0.000000 0.000000 0.341041 0.000000 0.621375 0.024428 0.013156 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.5 0. 0.4 -2. -0.5 0. 0. Chi 0. 0. 2.4E-04 0. 1.2E-04 8.5E-03 7.6E-04 0. 0. Composition Misfit: 9.633865E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.271 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.593 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.053 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000020 -.000020 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023252 0.014713 0.006961 0.016429 0.052789 0.000916 0.040210 0.031020 0.002033 0.108200 0.703478 Mica 0.017295 0.016263 0.000000 0.057302 0.002723 0.000000 0.004530 0.165458 0.000000 0.249065 0.487364 Gt 0.000000 0.018363 0.000000 0.000000 0.253355 0.087927 0.074524 0.000000 0.002062 0.137849 0.425920 Fsp 0.094101 0.059443 0.000000 0.001178 0.000000 0.000000 0.000000 0.000000 0.000000 0.154721 0.690557 Bio 0.000000 0.000000 0.011098 0.066206 0.178583 0.001808 0.161750 0.121315 0.004205 0.118616 0.336419 St 0.000000 0.000000 0.004046 0.000000 0.126182 0.005906 0.053445 0.088154 0.002306 0.389383 0.330578 Ilm 0.000000 0.000000 0.315931 0.000000 0.575625 0.022630 0.012187 0.000000 0.073628 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -781456. -759284. -933786. -856718. -315935. -462166. -638950. -293846. -408044. -1638041. -889393. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 495 converged, 127 successes so far. Misfit function evaluations this try => 264 Misfit this try = 0.191432 Best Misfit so far = 0.120787 obtained on Try 478 Prior probability, PP = 6.682054E-08 Bayes score, PP * exp(-Misfit) = 5.517880E-08 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 12387.6 817.948 0.941993 0.540054 Final coordinates: 6548.45 800.144 0.510374 0.541200 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.191432 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.501 0.024846 0.019616 0.000000 0.064768 0.001918 0.000000 0.003856 0.302302 0.582693 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 2. Chi 8.4E-03 0. 0. 6.0E-03 4.4E-02 0. 2.4E-02 1.6E-03 5.1E-04 Composition Misfit: 0.104982 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.585 0.000000 0.035436 0.000000 0.000000 0.274712 0.070368 0.054368 0.138266 0.426850 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 3. -4. 4.1E-02 0.4 -0.3 Chi 0. 6.3E-03 0. 0. 8.1E-03 1.9E-02 3.3E-06 2.2E-04 1.1E-05 Composition Misfit: 3.314732E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.008 0.095109 0.058824 0.000000 0.000479 0.000000 0.000000 0.000000 0.154412 0.691176 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.3 0. 0. 0. 0.4 0.1 Chi 1.3E-04 8.9E-04 0. 1.6E-03 0. 0. 0. 2.7E-04 1.6E-05 Composition Misfit: 2.915696E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.964 0.000000 0.000000 0.010078 0.074911 0.207274 0.000889 0.191191 0.123658 0.392000 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -2. 0.2 -1. 1. 1. Chi 0. 0. 1.3E-02 8.5E-04 2.5E-03 3.2E-04 2.5E-03 2.2E-03 1.5E-03 Composition Misfit: 2.248666E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.013 0.000000 0.000000 0.003389 0.000000 0.153180 0.003410 0.046976 0.429361 0.363684 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. 0.1 -3. 1. 1. Chi 0. 0. 4.6E-03 0. 3.2E-03 5.4E-05 1.2E-02 8.6E-04 1.4E-03 Composition Misfit: 2.241744E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.904 0.000000 0.000000 0.380536 0.000000 0.596480 0.013845 0.009139 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. -0.6 0.1 0. 0. Chi 0. 0. 2.5E-03 0. 1.9E-03 1.1E-03 8.1E-05 0. 0. Composition Misfit: 5.482806E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.994 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.032 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023252 0.014712 0.006961 0.016428 0.052787 0.000916 0.040208 0.031399 0.001684 0.108197 0.703457 Mica 0.020725 0.016363 0.000000 0.054026 0.001600 0.000000 0.003216 0.165864 0.000000 0.252161 0.486045 Gt 0.000000 0.035365 0.000000 0.000000 0.274161 0.070227 0.054259 0.000000 0.002004 0.137989 0.425994 Fsp 0.095109 0.058824 0.000000 0.000479 0.000000 0.000000 0.000000 0.000000 0.000000 0.154412 0.691176 Bio 0.000000 0.000000 0.008809 0.065475 0.181168 0.000777 0.167110 0.122142 0.003809 0.108083 0.342627 St 0.000000 0.000000 0.003082 0.000000 0.139333 0.003102 0.042729 0.088215 0.002183 0.390548 0.330808 Ilm 0.000000 0.000000 0.359087 0.000000 0.562859 0.013064 0.008624 0.000000 0.056365 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -757656. -743738. -920100. -831853. -302263. -449924. -629693. -284022. -404799. -1620915. -877871. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 497 converged, 128 successes so far. Misfit function evaluations this try => 268 Misfit this try = 0.121021 Best Misfit so far = 0.120787 obtained on Try 478 Prior probability, PP = 8.317569E-07 Bayes score, PP * exp(-Misfit) = 7.369496E-07 Best Bayes score so far = 8.821012E-07 obtained on Try 178 P_bar T_K C_O2 C_H2O Initial coordinates: 9835.31 840.830 0.260478 0.154542 Final coordinates: 8298.80 931.165 0.534837 0.523401 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.121021 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.380 0.022996 0.024509 0.000000 0.063670 0.004109 0.000000 0.006687 0.298219 0.579810 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 2. 1. 0. 1. -1. 3. Chi 6.9E-03 0. 0. 6.8E-03 1.2E-02 0. 7.0E-03 1.1E-03 7.0E-04 Composition Misfit: 5.912116E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.018 0.000000 0.024848 0.000000 0.000000 0.285710 0.042014 0.083895 0.137115 0.426418 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 2. -0.9 -3. 0.5 -0.2 Chi 0. 7.4E-04 0. 0. 4.6E-03 1.4E-03 1.0E-02 3.3E-04 7.3E-06 Composition Misfit: 1.719933E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.119 0.094843 0.058132 0.000000 0.001091 0.000000 0.000000 0.000000 0.154066 0.691868 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 7.3E-04 0. 6.5E-05 0. 0. 0. 3.0E-04 1.0E-05 Composition Misfit: 1.220578E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.834 0.000000 0.000000 0.013505 0.075293 0.202802 0.000996 0.189140 0.129401 0.388864 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1. -1. -1. 0.1 -1. 0.8 1. Chi 0. 0. 4.6E-03 9.2E-04 1.7E-03 1.8E-04 2.0E-03 9.2E-04 1.9E-03 Composition Misfit: 1.218614E-02 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.010 0.000000 0.000000 0.004878 0.000000 0.139513 0.002874 0.061586 0.427748 0.363400 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.2 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 5.1E-04 3.2E-04 2.4E-02 1.0E-03 1.4E-03 Composition Misfit: 2.879323E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.824 0.000000 0.000000 0.358348 0.000000 0.615113 0.011314 0.015224 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.5 0. 0.7 -0.2 -0.8 0. 0. Chi 0. 0. 1.9E-04 0. 3.6E-04 1.5E-04 1.8E-03 0. 0. Composition Misfit: 2.500255E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.704 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.110 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023274 0.014726 0.006968 0.016444 0.052837 0.000917 0.040247 0.030395 0.001766 0.108300 0.704127 Mica 0.019198 0.020461 0.000000 0.053154 0.003430 0.000000 0.005583 0.165165 0.000000 0.248964 0.484046 Gt 0.000000 0.024785 0.000000 0.000000 0.284994 0.041909 0.083685 0.000000 0.002506 0.136771 0.425350 Fsp 0.094843 0.058132 0.000000 0.001091 0.000000 0.000000 0.000000 0.000000 0.000000 0.154066 0.691868 Bio 0.000000 0.000000 0.011831 0.065961 0.177666 0.000872 0.165697 0.120091 0.003850 0.113362 0.340667 St 0.000000 0.000000 0.004437 0.000000 0.126893 0.002614 0.056015 0.088141 0.002310 0.389058 0.330530 Ilm 0.000000 0.000000 0.334646 0.000000 0.574429 0.010566 0.014217 0.000000 0.066141 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778049. -756549. -932562. -853199. -315495. -468207. -638142. -292891. -408621. -1637092. -887498. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Sp Gt fak ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Sp Gt fak ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 2 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 10367.2 800.000 0.999997 0.762478 70.7408 Mean perturbed parameters: 9294.70 865.371 0.765732 0.641913 35.4308 Parameter standard deviation: 2144.99 130.742 0.468531 0.241130 70.6200 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio fak ky cen di mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio fak ky cen di mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 3 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 9427.67 971.968 0.985691 0.559144 0.269381 Mean perturbed parameters: 9339.03 900.903 0.839051 0.614323 23.7103 Parameter standard deviation: 1739.85 96.9355 0.461433 0.172587 49.9360 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 4 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 8275.74 925.524 0.580948 0.661830 0.251436 Mean perturbed parameters: 9073.20 907.058 0.774525 0.626200 17.8456 Parameter standard deviation: 1420.91 79.2048 0.377840 0.162591 40.7726 -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Sp Gt Bio ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Sp Gt Bio ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky cen di mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky cen di mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Sp Gt Mica Bio ky abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Sp Gt Mica Bio ky abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 5 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 8912.16 800.222 0.994338 0.802113 1.67943 Mean perturbed parameters: 9040.99 885.691 0.818488 0.661382 14.6124 Parameter standard deviation: 1277.99 94.6780 0.400793 0.198832 35.3187 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky abh fscf ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky abh fscf ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx ky mstp abh ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx ky mstp abh ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica fak ky minm abh ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica fak ky minm abh ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Mica Bio fanth q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Mica Bio fanth q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio fak ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio fak ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 6 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 6278.13 944.418 0.690298 0.599193 44.1814 Mean perturbed parameters: 8580.52 895.479 0.797123 0.651017 19.5405 Parameter standard deviation: 1436.14 84.9031 0.365450 0.181216 37.2317 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky minm mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky minm mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica fak ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica fak ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Opx ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Opx ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Mica ky minm abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Mica ky minm abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky cen mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky cen mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Sp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Sp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 7 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 9183.38 918.582 0.415684 0.601776 0.632424 Mean perturbed parameters: 8666.64 898.779 0.742632 0.643983 16.8394 Parameter standard deviation: 1368.47 77.6644 0.336941 0.168654 33.9884 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 8 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 6923.28 973.223 0.461142 0.855047 0.736349 Mean perturbed parameters: 8448.72 908.085 0.707446 0.670366 14.8265 Parameter standard deviation: 1358.76 73.6742 0.313077 0.200720 31.4680 -------------------------------------------------------------------------------- Although Fsp St Ilm Mica Bio ky fscf q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Mica Bio ky fscf q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 9 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 9631.54 978.605 0.933744 0.801666 0.590515 Mean perturbed parameters: 8580.14 915.920 0.732590 0.684955 13.2447 Parameter standard deviation: 1365.18 70.9631 0.325566 0.212308 29.4361 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Sp Gt Mica minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Sp Gt Mica minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky minm abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky minm abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Sp Gt Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Sp Gt Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio fak ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio fak ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky abh fscf q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky abh fscf q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Mica Bio ky fanth minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Mica Bio ky fanth minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Mica Bio ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Mica Bio ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Chl Ilm Gt Mica Bio F fak ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Chl Ilm Gt Mica Bio F fak ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio fak ky minm cacf ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio fak ky minm cacf ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Chl Ilm Ilm Gt Mica Bio ky abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Chl Ilm Ilm Gt Mica Bio ky abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica fak ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica fak ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Mica Bio F minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Mica Bio F minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx ky mstp abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx ky mstp abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Mica Bio fak ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Mica Bio fak ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ep Ilm Gt fak ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ep Ilm Gt fak ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio fak ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio fak ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 10 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 8335.75 1000.00 0.999981 0.561926 0.605706 Mean perturbed parameters: 8555.70 924.328 0.759329 0.672652 11.9808 Parameter standard deviation: 1287.66 70.7757 0.344392 0.200623 27.7531 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx Bio fak ky cen mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx Bio fak ky cen mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio fanth q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio fanth q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp abh ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp abh ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky cen di mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky cen di mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 11 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 10579.5 872.527 0.631144 0.625237 0.485060 Mean perturbed parameters: 8739.69 919.619 0.747676 0.668341 10.9358 Parameter standard deviation: 1431.06 69.6216 0.328236 0.193142 26.3291 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Sp Gt Mica Bio ky fscf q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Sp Gt Mica Bio ky fscf q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 12 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 9304.41 965.253 0.407824 0.500969 7.01021 Mean perturbed parameters: 8786.75 923.422 0.719355 0.654394 10.6086 Parameter standard deviation: 1402.94 67.1922 0.315173 0.184256 25.1896 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp abh ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp abh ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Opx ky jd ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Opx ky jd ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Sp Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Sp Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx Opx fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx Opx fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 13 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 15000.0 985.269 0.999213 0.776558 0.335728 Mean perturbed parameters: 9264.69 928.179 0.740882 0.663791 9.81840 Parameter standard deviation: 2373.27 66.2294 0.330588 0.191177 24.1173 -------------------------------------------------------------------------------- After 14 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 7714.40 937.423 0.686121 0.596845 0.122626 Mean perturbed parameters: 9153.95 928.840 0.736971 0.659009 9.12585 Parameter standard deviation: 2284.51 63.6581 0.320502 0.184867 23.1712 -------------------------------------------------------------------------------- Although Fsp Ep St Ilm Mica ky fanth minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ep St Ilm Mica ky fanth minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky mstp abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky mstp abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Mica Bio ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Mica Bio ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky cen mstp fscf ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky cen mstp fscf ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Sp Gt Mica Bio fstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Sp Gt Mica Bio fstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Ilm Gt Mica ky minm abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Ilm Gt Mica ky minm abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 15 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 8336.10 902.950 0.602664 0.753424 0.276881 Mean perturbed parameters: 9099.43 927.114 0.728017 0.665303 8.53592 Parameter standard deviation: 2201.62 61.7905 0.309429 0.188631 22.3283 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 16 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 8412.77 873.598 0.728217 0.720610 0.384680 Mean perturbed parameters: 9056.51 923.769 0.728030 0.668760 8.02646 Parameter standard deviation: 2127.54 61.4917 0.303223 0.189359 21.5713 -------------------------------------------------------------------------------- After 17 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 8963.06 943.049 0.579831 0.374489 0.108991 Mean perturbed parameters: 9051.02 924.903 0.719312 0.651450 7.56073 Parameter standard deviation: 2068.29 59.6185 0.293843 0.186986 20.8863 -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 18 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 5626.50 842.389 0.671626 0.497442 0.202240 Mean perturbed parameters: 8860.77 920.319 0.716663 0.642894 7.15193 Parameter standard deviation: 2102.98 61.6804 0.287089 0.181495 20.2627 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 19 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 10044.8 865.078 0.392514 0.446096 0.867875 Mean perturbed parameters: 8923.08 917.412 0.699602 0.632536 6.82119 Parameter standard deviation: 2088.39 61.9084 0.280917 0.177271 19.6926 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp lc ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp lc ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ep Ilm Gt Mica Bio fak ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ep Ilm Gt Mica Bio fak ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 20 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 7097.49 948.684 0.558527 0.557445 11.2937 Mean perturbed parameters: 8831.80 918.975 0.692549 0.628782 7.04481 Parameter standard deviation: 2049.00 60.3977 0.273495 0.172742 19.3380 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 21 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 7028.14 800.000 0.999892 0.465629 14.1966 Mean perturbed parameters: 8745.92 913.310 0.707184 0.621013 7.38537 Parameter standard deviation: 2014.89 65.7279 0.286410 0.168828 19.1094 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 22 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 7732.94 927.557 0.600339 0.462266 157.334 Mean perturbed parameters: 8699.87 913.957 0.702327 0.613797 14.2012 Parameter standard deviation: 1969.23 64.1476 0.279911 0.165263 39.0478 -------------------------------------------------------------------------------- After 23 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 8273.42 880.383 0.651504 0.531785 0.154403 Mean perturbed parameters: 8681.33 912.498 0.700118 0.610231 13.5905 Parameter standard deviation: 1923.98 63.5857 0.274670 0.161479 38.1501 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 24 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 9907.62 858.212 0.880843 0.518222 5.36596 Mean perturbed parameters: 8732.43 910.236 0.707648 0.606397 13.2478 Parameter standard deviation: 1914.23 64.0006 0.278336 0.157931 37.3275 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Mica Bio ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Mica Bio ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt fak ky jd ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt fak ky jd ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Fsp Ilm Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Fsp Ilm Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 25 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 10430.1 854.562 0.553203 0.816982 6.15778 Mean perturbed parameters: 8800.33 908.009 0.701470 0.614821 12.9642 Parameter standard deviation: 1927.36 64.5540 0.272511 0.165965 36.5624 -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd minm cacf ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd minm cacf ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Sp Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Sp Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 26 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 9477.16 864.902 0.694489 0.711362 61.1998 Mean perturbed parameters: 8826.37 906.351 0.701202 0.618534 14.8194 Parameter standard deviation: 1905.02 64.6059 0.268989 0.166994 37.8492 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky cen mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky cen mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky di mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky di mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 27 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 7039.38 899.093 0.700266 0.632861 0.281018 Mean perturbed parameters: 8760.18 906.082 0.701167 0.619064 14.2810 Parameter standard deviation: 1882.38 63.6546 0.265835 0.165205 37.1142 -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio abh ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio abh ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky di mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky di mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 28 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 13279.8 967.418 0.816660 0.584135 0.614950 Mean perturbed parameters: 8921.60 908.273 0.705292 0.617817 13.7929 Parameter standard deviation: 2087.94 62.8623 0.266577 0.162566 36.4205 -------------------------------------------------------------------------------- After 29 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 9346.07 968.955 1.00000 0.858510 29.3950 Mean perturbed parameters: 8936.23 910.365 0.715454 0.626117 14.3309 Parameter standard deviation: 2061.29 62.1505 0.276343 0.171883 36.1896 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky abh ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky abh ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 30 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 9196.24 954.217 0.386883 0.722215 1.19276 Mean perturbed parameters: 8944.90 911.827 0.704502 0.629320 13.8930 Parameter standard deviation: 2033.50 61.2249 0.272860 0.172964 35.5607 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F ky fscf ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F ky fscf ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Mica Bio minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Mica Bio minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky lc ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky lc ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Sp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Sp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 31 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 8964.67 960.733 0.164345 0.368555 0.175165 Mean perturbed parameters: 8945.54 913.404 0.687077 0.620908 13.4504 Parameter standard deviation: 2003.91 60.4444 0.276521 0.172329 34.9630 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio fak ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio fak ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 32 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 7945.43 889.321 0.776057 0.457859 4.26744 Mean perturbed parameters: 8914.29 912.652 0.689858 0.615813 13.1635 Parameter standard deviation: 1971.95 59.9251 0.275548 0.169910 34.4025 -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 33 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 11839.2 900.192 0.266393 0.590672 15.5223 Mean perturbed parameters: 9002.92 912.274 0.677026 0.615051 13.2350 Parameter standard deviation: 2043.50 59.2280 0.275227 0.167683 33.9700 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Mica fak ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Mica fak ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica fak ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica fak ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp St Ilm Gt Mica Bio fak q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp St Ilm Gt Mica Bio fak q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 34 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 7444.31 933.696 0.973789 0.912017 68.0628 Mean perturbed parameters: 8957.08 912.904 0.685754 0.623785 14.8475 Parameter standard deviation: 2016.85 58.3260 0.281750 0.178579 35.4806 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky mstp abh ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky mstp abh ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky cen di mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky cen di mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 35 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 8958.26 925.738 0.729184 0.670294 0.166509 Mean perturbed parameters: 8957.11 913.271 0.686995 0.625114 14.4281 Parameter standard deviation: 1990.98 57.4683 0.279640 0.177778 34.9550 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 36 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 5922.88 886.866 0.880023 0.783230 0.374991 Mean perturbed parameters: 8872.83 912.537 0.692357 0.629506 14.0377 Parameter standard deviation: 2000.45 57.1248 0.281843 0.180725 34.4520 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 37 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 8551.21 952.219 0.751029 0.531589 35.8624 Mean perturbed parameters: 8864.13 913.610 0.693942 0.626860 14.6276 Parameter standard deviation: 1973.23 56.4395 0.280299 0.178205 34.4885 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp fscf ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp fscf ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky jd ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky jd ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 38 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 7522.82 937.532 0.986150 0.904545 79.0946 Mean perturbed parameters: 8828.84 914.239 0.701632 0.634167 16.3241 Parameter standard deviation: 1949.77 55.6827 0.286412 0.186728 36.4125 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky minm fscf q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky minm fscf q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Gt Bio ky acm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Gt Bio ky acm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 39 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 9171.76 919.732 0.941745 0.624108 5.83652 Mean perturbed parameters: 8837.63 914.380 0.707789 0.633909 16.0552 Parameter standard deviation: 1930.10 54.9742 0.290349 0.185007 35.9422 -------------------------------------------------------------------------------- Although Melt Fsp St Ilm Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp St Ilm Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 40 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 7559.71 946.955 0.616884 0.543127 0.294136 Mean perturbed parameters: 8805.68 915.195 0.705516 0.631640 15.6611 Parameter standard deviation: 1908.15 54.3269 0.286929 0.182653 35.4784 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 41 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 7299.47 964.572 0.437992 0.416571 0.276086 Mean perturbed parameters: 8768.94 916.399 0.698991 0.626394 15.2859 Parameter standard deviation: 1889.79 53.9095 0.283705 0.181115 35.0321 -------------------------------------------------------------------------------- Although Fsp Ilm Mica fak ky fanth minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Mica fak ky fanth minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky cen di mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky cen di mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Mica Bio F fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Mica Bio F fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio fak ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio fak ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky fscf ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky fscf ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Opx ky jd ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Opx ky jd ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica F ky mstp abh lc q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica F ky mstp abh lc q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky cen di mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky cen di mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ep Ilm Gt fak ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ep Ilm Gt fak ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx ky mstp abh fscf ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx ky mstp abh fscf ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Sp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Sp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 42 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 8907.45 912.220 0.587428 0.399721 3.29013 Mean perturbed parameters: 8772.24 916.299 0.696335 0.620997 15.0003 Parameter standard deviation: 1869.66 53.3266 0.280360 0.179898 34.6058 -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp abh ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp abh ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx Opx fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx Opx fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp fscf ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp fscf ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Mica Bio ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Mica Bio ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 43 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 10955.8 925.121 0.399848 0.584489 0.278188 Mean perturbed parameters: 8823.02 916.505 0.689440 0.620148 14.6579 Parameter standard deviation: 1894.82 52.6950 0.277746 0.178011 34.1914 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ep Ilm Gt Mica ky minm fscf ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ep Ilm Gt Mica ky minm fscf ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp St Ilm Mica Bio fak ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp St Ilm Mica Bio fak ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Sp Gt ky mstp abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Sp Gt ky mstp abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Chl St Ilm Sp Gt Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Chl St Ilm Sp Gt Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 44 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 7517.58 947.479 0.639410 0.591701 1.91072 Mean perturbed parameters: 8793.35 917.209 0.688303 0.619502 14.3682 Parameter standard deviation: 1875.74 52.1412 0.274990 0.176255 33.7926 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Sp Gt ky mstp abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Sp Gt ky mstp abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky minm mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky minm mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Sp Gt Mica Bio fak ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Sp Gt Mica Bio fak ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 45 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 8579.83 998.312 0.375905 0.759278 27.8456 Mean perturbed parameters: 8788.61 919.011 0.681361 0.622608 14.6677 Parameter standard deviation: 1855.08 52.5422 0.272857 0.177895 33.6668 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Opx Opx fak ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Opx Opx fak ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 46 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 7700.21 965.053 0.351770 0.594581 0.335696 Mean perturbed parameters: 8764.95 920.012 0.674196 0.621999 14.3561 Parameter standard deviation: 1836.00 52.2063 0.271135 0.176245 33.2906 -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp abh ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp abh ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky cen di mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky cen di mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio fak ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio fak ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 47 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 6593.37 800.000 0.735462 0.857033 32.2634 Mean perturbed parameters: 8718.74 917.458 0.675499 0.626999 14.7371 Parameter standard deviation: 1831.75 55.1166 0.269853 0.181209 33.2661 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky mstp abh ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky mstp abh ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 48 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 9222.31 999.522 0.999478 0.430733 83.4150 Mean perturbed parameters: 8729.24 919.168 0.682249 0.622910 16.1679 Parameter standard deviation: 1818.02 55.4424 0.275557 0.179758 35.0814 -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Sp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Sp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 49 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 7233.42 942.516 0.483901 0.509763 0.864322 Mean perturbed parameters: 8698.71 919.644 0.678201 0.620601 15.8556 Parameter standard deviation: 1804.64 54.8881 0.272758 0.177883 34.7142 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 50 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 5810.07 924.072 0.144340 0.961205 2.05531 Mean perturbed parameters: 8640.94 919.733 0.667524 0.627413 15.5796 Parameter standard deviation: 1819.06 54.3335 0.275567 0.186936 34.3593 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky minm mstp fscf ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky minm mstp fscf ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 51 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 10331.7 807.739 0.455029 0.743121 4.01339 Mean perturbed parameters: 8674.09 917.537 0.663357 0.629682 15.3528 Parameter standard deviation: 1825.32 56.5304 0.273011 0.187696 34.0184 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Sp Gt Bio ky fanth q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Sp Gt Bio ky fanth q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky minm mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky minm mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 52 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 8549.44 980.020 0.646681 0.490212 11.3856 Mean perturbed parameters: 8671.69 918.739 0.663036 0.627000 15.2765 Parameter standard deviation: 1807.92 56.3971 0.270803 0.185898 33.7201 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 53 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 10754.1 984.108 0.854551 0.500826 0.169401 Mean perturbed parameters: 8710.98 919.972 0.666650 0.624619 14.9915 Parameter standard deviation: 1824.55 56.3404 0.271903 0.184124 33.3943 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Opx fak ky cen mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Opx fak ky cen mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Sp Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Sp Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky fanth q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky fanth q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx ky mstp abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx ky mstp abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky minm abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky minm abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica fak ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica fak ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky mstp abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky mstp abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio fak ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio fak ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Sp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Sp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 54 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 5493.02 800.288 0.568882 0.673021 1.43534 Mean perturbed parameters: 8651.39 917.756 0.664839 0.625516 14.7404 Parameter standard deviation: 1845.73 58.6127 0.269374 0.183565 33.0783 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky fanth ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky fanth ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Sp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Sp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Gt Mica Bio ky abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Gt Mica Bio ky abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ep Ilm Gt Mica ky minm fscf ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ep Ilm Gt Mica ky minm fscf ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio fak ky jd ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio fak ky jd ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky abh ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky abh ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Mica Bio fak ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Mica Bio fak ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp fscf ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp fscf ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky mstp abh ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky mstp abh ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 55 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 10758.4 923.404 0.355621 0.769946 2.06221 Mean perturbed parameters: 8689.70 917.858 0.659217 0.628142 14.5099 Parameter standard deviation: 1860.85 58.0760 0.267939 0.184977 32.7716 -------------------------------------------------------------------------------- After 56 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 5856.56 884.077 0.851191 0.648474 10.7692 Mean perturbed parameters: 8639.11 917.255 0.662645 0.628505 14.4431 Parameter standard deviation: 1871.24 57.8886 0.268970 0.184088 32.5041 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Mica Bio F fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Mica Bio F fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp abh cacf ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp abh cacf ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd nyb ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd nyb ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 57 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 9987.14 983.690 0.693581 0.469980 0.243016 Mean perturbed parameters: 8662.76 918.421 0.663188 0.625724 14.1940 Parameter standard deviation: 1869.40 57.8041 0.267436 0.182566 32.2126 -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky di mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky di mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Mica Bio minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Mica Bio minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 58 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 9140.24 974.514 0.996262 0.549789 76.8630 Mean perturbed parameters: 8670.99 919.388 0.668931 0.624414 15.2745 Parameter standard deviation: 1856.91 57.5874 0.272135 0.180996 33.5077 -------------------------------------------------------------------------------- After 59 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 7416.83 960.492 0.551090 0.574580 0.424533 Mean perturbed parameters: 8649.73 920.084 0.666933 0.623570 15.0228 Parameter standard deviation: 1843.87 57.2223 0.269791 0.179565 33.2176 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Sp Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Sp Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 60 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 6584.01 969.597 0.682997 0.430129 0.646282 Mean perturbed parameters: 8615.30 920.910 0.667201 0.620346 14.7832 Parameter standard deviation: 1840.58 56.9603 0.268222 0.178433 32.9350 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 61 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 7032.43 939.505 0.913609 0.495532 73.2053 Mean perturbed parameters: 8589.36 921.215 0.671241 0.618300 15.7409 Parameter standard deviation: 1831.62 56.4950 0.270514 0.176971 33.9950 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky abh ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky abh ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 62 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 10559.8 984.083 0.647045 0.676621 0.210178 Mean perturbed parameters: 8621.14 922.229 0.670850 0.619240 15.4904 Parameter standard deviation: 1841.04 56.4447 0.268695 0.176637 33.7152 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Sp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Sp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 63 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 6881.70 917.887 3.480904E-02 0.609732 71.6379 Mean perturbed parameters: 8593.53 922.160 0.660754 0.619089 16.3817 Parameter standard deviation: 1834.05 56.0115 0.273882 0.175566 34.6536 -------------------------------------------------------------------------------- Although Melt Fsp Fsp St Ilm Gt Mica Bio abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Fsp St Ilm Gt Mica Bio abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Mica Bio minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Mica Bio minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Mica Bio minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Mica Bio minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 64 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 9630.52 917.525 0.253283 0.664249 0.721962 Mean perturbed parameters: 8609.73 922.087 0.654388 0.619795 16.1370 Parameter standard deviation: 1828.07 55.5901 0.273950 0.175095 34.3776 -------------------------------------------------------------------------------- After 65 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 10559.0 978.132 0.338736 0.451719 0.493026 Mean perturbed parameters: 8639.72 922.949 0.649532 0.617209 15.8963 Parameter standard deviation: 1837.10 55.4713 0.272867 0.173939 34.1080 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Ilm Gt Bio ky abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Ilm Gt Bio ky abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 66 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 8476.16 940.938 0.337413 0.676295 2.49611 Mean perturbed parameters: 8637.24 923.222 0.644802 0.618104 15.6933 Parameter standard deviation: 1823.19 55.0575 0.271828 0.173663 33.8459 -------------------------------------------------------------------------------- Although Melt Fsp St Ilm Gt Mica Bio minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp St Ilm Gt Mica Bio minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky minm cacf ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky minm cacf ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp abh ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp abh ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 67 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 7543.23 933.940 0.888779 0.521420 0.336249 Mean perturbed parameters: 8620.91 923.382 0.648444 0.616661 15.4641 Parameter standard deviation: 1811.25 54.6402 0.273323 0.172342 33.5885 -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt ky fanth minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt ky fanth minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Opx ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Opx ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 68 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 11040.1 922.504 0.270190 0.503371 2.01573 Mean perturbed parameters: 8656.49 923.369 0.642881 0.614995 15.2663 Parameter standard deviation: 1830.35 54.2402 0.273147 0.171065 33.3377 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Ilm Gt Opx fak ky mstp abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Ilm Gt Opx fak ky mstp abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 69 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 9813.94 832.163 0.971304 0.771343 16.3567 Mean perturbed parameters: 8673.26 922.047 0.647641 0.617261 15.2821 Parameter standard deviation: 1827.07 55.1511 0.276328 0.172488 33.1502 -------------------------------------------------------------------------------- After 70 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 8034.65 983.516 0.815130 0.615082 0.264652 Mean perturbed parameters: 8664.14 922.925 0.650034 0.617230 15.0676 Parameter standard deviation: 1813.92 55.1174 0.276435 0.171605 32.9091 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 71 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 8381.52 930.971 0.597412 0.500722 0.392009 Mean perturbed parameters: 8660.16 923.039 0.649293 0.615589 14.8609 Parameter standard deviation: 1801.02 54.7223 0.274567 0.170393 32.6732 -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Mica Bio ky fscf q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Mica Bio ky fscf q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Fsp Ilm Gt Mica minm fscf ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Fsp Ilm Gt Mica minm fscf ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 72 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 11752.0 969.770 0.140071 0.538603 0.198004 Mean perturbed parameters: 8703.10 923.688 0.642220 0.614520 14.6572 Parameter standard deviation: 1836.70 54.5326 0.276555 0.169201 32.4423 -------------------------------------------------------------------------------- Although Melt Fsp Fsp St Ilm Gt Bio F minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Fsp St Ilm Gt Bio F minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 73 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8222.21 930.742 0.531466 0.521348 0.120787 Perturbed central model parameter: 6837.37 972.967 0.547368 0.652741 9.845783E-02 Mean perturbed parameters: 8677.54 924.363 0.640921 0.615044 14.4578 Parameter standard deviation: 1831.19 54.3808 0.274634 0.168734 32.2162 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky cen mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky cen mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Mica fak ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Mica fak ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Mica Bio fak ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Mica Bio fak ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Ilm Sp Gt Opx ky mstp abh q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Ilm Sp Gt Opx ky mstp abh q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky q --------------------------------------------------------------------------------