C:\jamie\Perple_X>build Perple_X version 6.8.6, source updated Jan 30, 2019. Copyright (C) 1986-2019 James A D Connolly . NO is the default (blank) answer to all Y/N prompts Enter a name for this project (the name will be used as the root for all output file names) [default = my_project]: kn7 The problem definition file will be named: kn7.dat Enter thermodynamic data file name [default = hp02ver.dat]: hp622ver.dat Enter the computational option file name [default = perplex_option.dat]: See: www.perplex.ethz.ch/perplex_options.html Reading Perple_X options from: perplex_option.dat The current data base components are: Na2O MgO Al2O3 SiO2 K2O CaO TiO2 MnO FeO NiO ZrO2 Cl2 O2 H2O CO2 CuO Cr2O3 S2 F2 N2 Transform them (Y/N)? Specify computational mode: 1 - Convex-Hull minimization 2 - Constrained minimization on a 2d grid [default] 3 - Constrained minimization on a 1d grid 4 - Output pseudocompound data 5 - 1-d Phase fractionation 6 - 0-d Infiltration-reaction-fractionation 7 - 2-d Phase fractionation (FRAC2D and TITRATE reactive transport models) Use Convex-Hull minimization for Schreinemakers projections or phase diagrams with > 2 independent variables. Use constrained minimization for phase diagrams or phase diagram sections with < 3 independent variables. Calculations with saturated components (Y/N)? Use chemical potentials, activities or fugacities as independent variables (Y/N)? y Specify a component whose chemical potential, activity or fugacity is to be independent, press to finish: Na2O MgO Al2O3 SiO2 K2O CaO TiO2 MnO FeO NiO ZrO2 Cl2 O2 H2O CO2 CuO Cr2O3 S2 F2 N2 O2 Component O2 is to be characterized by: 1 - chemical potential [default] 2 - log10(fugacity) 3 - log10(activity) 2 Phase O2 will be used to define O2 fugacity The log10(O2 fugacity) variable is named: f_O2 Specify a component whose chemical potential, activity or fugacity is to be independent, press to finish: In other words, if you only want one mobile component, then press Na2O MgO Al2O3 SiO2 K2O CaO TiO2 MnO FeO NiO ZrO2 Cl2 H2O CO2 CuO Cr2O3 S2 F2 N2 S2 Component S2 is to be characterized by: 1 - chemical potential [default] 2 - log10(fugacity) 3 - log10(activity) 2 Select the phase to be used to define S2 fugacity from the following: S S2 S2 **warning ver064** in general it is wise to exclude the unused phases from the above list from your calcultion. NOTE: you will not be prompted for these phases if you select the automatic phase exclusion prompt. to exclude unused reference phases eitherdo not select the prompt option or edit the problem definition after running BUILD The log10(S2 fugacity) variable is named: f_S2 Select thermodynamic components from the set: Na2O MgO Al2O3 SiO2 K2O CaO TiO2 MnO FeO NiO ZrO2 Cl2 H2O CO2 CuO Cr2O3 F2 N2 Enter names, 1 per line, press to finish: CuO FeO H2O The data base has P(bar) and T(K) as default independent potentials. Make one dependent on the other, e.g., as along a geothermal gradient (y/n)? Select x-axis variable: 1 - P(bar) 2 - T(K) 3 - f_O2 4 - f_S2 5 - Composition X_C1* (user defined) *X_C1 can not be selected as the y-axis variable 4 Enter minimum and maximum values, respectively, for: f_S2 -20 -10 Select y-axis variable: 2 - T(K) 3 - f_O2 4 - P(bar) 3 Enter minimum and maximum values, respectively, for: f_O2 -40 -20 Specify sectioning value for: T(K) 673 Specify sectioning value for: P(bar) 3500 For gridded minimization, grid resolution is determined by the number of levels (grid_levels) and the resolution at the lowest level in the X- and Y-directions (x_nodes and y_nodes) these parameters are currently set for the exploratory and autorefine cycles as follows: stage grid_levels xnodes ynodes effective resolution exploratory 1 40 40 40 x 40 nodes auto-refine 4 60 60 473 x 473 nodes To change these options edit or create the file perplex_option.dat See: www.perplex.ethz.ch/perplex_options.html#grid_parameters Specify component amounts by mass (Y/N)? The amounts you enter next need not be normalized; regardless of units, they define the molar amount of the system Enter the molar amounts of the components: CuO FeO H2O for the bulk composition of interest: 1 4 1 **warning ver110** in this mode Perple_X will not check whether conditions are supersaturated with respect to mobile components. To explicitly compute saturation surfaces: 1) use convex hull optimization and do not use activities or fugacities as independent variables 2) or compute the saturation surface with FLUIDS or FRENDLY. Output a print file (Y/N)? **warning ver051** cannot make tiL because of missing data or an invalid definition in the thermodynamic data file. Exclude pure and/or endmember phases (Y/N)? | actually it is necessary to exclude tro and lot if you want the HP pyrrohtite model | to be stable. Include solution models (Y/N)? y Enter the solution model file name [default = solution_model.dat]: **warning ver025** 1 endmembers for Aq_solvent The solution will not be considered. **warning ver025** 1 endmembers for Aq_yuri The solution will not be considered. **warning ver025** 1 endmembers for Aq_solven0 The solution will not be considered. **warning ver025** 0 endmembers for Cpx(H) The solution will not be considered. **warning ver025** 0 endmembers for Augite(G) The solution will not be considered. **warning ver025** 0 endmembers for cAmph(G) The solution will not be considered. **warning ver114** the following endmembers are missing for melt(H) foHL faHL jdL silL kjL woL ekL tiL qHL **warning ver025** 1 endmembers for melt(G) The solution will not be considered. **warning ver025** 0 endmembers for Chl(W) The solution will not be considered. **warning ver025** 0 endmembers for Ep(HP11) The solution will not be considered. **warning ver025** 0 endmembers for Cpx(JH) The solution will not be considered. **warning ver025** 1 endmembers for Melt(JH) The solution will not be considered. **warning ver025** 0 endmembers for O(JH) The solution will not be considered. **warning ver025** 1 endmembers for Sp(JH) The solution will not be considered. **warning ver025** 0 endmembers for Pl(JH) The solution will not be considered. **warning ver025** 0 endmembers for Grt(JH) The solution will not be considered. **warning ver025** 0 endmembers for Opx(JH) The solution will not be considered. **warning ver025** 0 endmembers for Gt(W) The solution will not be considered. **warning ver025** 1 endmembers for melt(W) The solution will not be considered. **warning ver025** 0 endmembers for Mica(W) The solution will not be considered. **warning ver025** 0 endmembers for Ctd(W) The solution will not be considered. **warning ver025** 0 endmembers for St(W) The solution will not be considered. **warning ver025** 0 endmembers for Opx(W) The solution will not be considered. **warning ver025** 0 endmembers for Bi(W) The solution will not be considered. **warning ver025** 0 endmembers for Crd(W) The solution will not be considered. **warning ver025** 0 endmembers for Sa(WP) The solution will not be considered. **warning ver025** 0 endmembers for Opx(HP) The solution will not be considered. **warning ver025** 0 endmembers for Bio(TCC) The solution will not be considered. **warning ver025** 0 endmembers for Bio(WPH) The solution will not be considered. **warning ver025** 0 endmembers for CrOpx(HP) The solution will not be considered. **warning ver025** 0 endmembers for CrGt The solution will not be considered. **warning ver025** 0 endmembers for Gt(MPF) The solution will not be considered. **warning ver025** 0 endmembers for Pu The solution will not be considered. **warning ver025** 0 endmembers for O(SG) The solution will not be considered. **warning ver025** 1 endmembers for melt(HP) The solution will not be considered. **warning ver025** 1 endmembers for pMELTS(G) The solution will not be considered. **warning ver025** 1 endmembers for mMELTS(G) The solution will not be considered. **warning ver025** 0 endmembers for MELTS(GS) The solution will not be considered. **warning ver025** 0 endmembers for Ep(HP) The solution will not be considered. **warning ver025** 0 endmembers for Pheng(HP) The solution will not be considered. **warning ver025** 0 endmembers for Osm(HP) The solution will not be considered. **warning ver025** 0 endmembers for GaHcSp The solution will not be considered. **warning ver025** 1 endmembers for F The solution will not be considered. **warning ver025** 1 endmembers for F(salt) The solution will not be considered. **warning ver025** 0 endmembers for Scap The solution will not be considered. **warning ver025** 0 endmembers for St(HP) The solution will not be considered. **warning ver025** 0 endmembers for Ctd(HP) The solution will not be considered. **warning ver025** 0 endmembers for Carp The solution will not be considered. **warning ver025** 0 endmembers for hCrd The solution will not be considered. **warning ver025** 0 endmembers for Sud(Livi) The solution will not be considered. **warning ver025** 0 endmembers for Sud The solution will not be considered. **warning ver025** 0 endmembers for Cumm The solution will not be considered. **warning ver025** 0 endmembers for Anth The solution will not be considered. **warning ver025** 0 endmembers for A The solution will not be considered. **warning ver025** 0 endmembers for Gl The solution will not be considered. **warning ver025** 0 endmembers for Tr The solution will not be considered. **warning ver025** 0 endmembers for feldspar The solution will not be considered. **warning ver025** 0 endmembers for feldspar_B The solution will not be considered. **warning ver025** 0 endmembers for Pl(h) The solution will not be considered. **warning ver025** 0 endmembers for Kf The solution will not be considered. **warning ver025** 0 endmembers for San The solution will not be considered. **warning ver025** 0 endmembers for San(TH) The solution will not be considered. **warning ver025** 1 endmembers for GCOHF The solution will not be considered. **warning ver025** 1 endmembers for COHF The solution will not be considered. **warning ver025** 0 endmembers for MaPa The solution will not be considered. **warning ver025** 0 endmembers for Mica(CF) The solution will not be considered. **warning ver025** 0 endmembers for Mica(CHA1) The solution will not be considered. **warning ver025** 0 endmembers for Mica(CHA) The solution will not be considered. **warning ver025** 0 endmembers for Mica+(CHA) The solution will not be considered. **warning ver025** 0 endmembers for O(HP) The solution will not be considered. **warning ver025** 0 endmembers for Stlp The solution will not be considered. **warning ver025** 0 endmembers for O(HPK) The solution will not be considered. **warning ver025** 0 endmembers for Cpx(l) The solution will not be considered. **warning ver025** 0 endmembers for Cpx(h) The solution will not be considered. **warning ver025** 0 endmembers for Do(HP) The solution will not be considered. **warning ver025** 0 endmembers for M(HP) The solution will not be considered. **warning ver025** 0 endmembers for Do(AE) The solution will not be considered. **warning ver025** 0 endmembers for Cc(AE) The solution will not be considered. **warning ver025** 1 endmembers for MF The solution will not be considered. **warning ver025** 0 endmembers for Sp(JR) The solution will not be considered. **warning ver025** 0 endmembers for Sp(GS) The solution will not be considered. **warning ver025** 0 endmembers for Sp(HP) The solution will not be considered. **warning ver025** 1 endmembers for Mt(W) The solution will not be considered. **warning ver025** 1 endmembers for IlHm(A) The solution will not be considered. **warning ver025** 0 endmembers for IlGkPy The solution will not be considered. **warning ver025** 1 endmembers for MtUl(A) The solution will not be considered. **warning ver025** 0 endmembers for Neph(FB) The solution will not be considered. **warning ver025** 0 endmembers for Gt(B) The solution will not be considered. **warning ver025** 0 endmembers for Gt(GCT) The solution will not be considered. **warning ver025** 0 endmembers for Gt(HP) The solution will not be considered. **warning ver025** 0 endmembers for Gt(EWHP) The solution will not be considered. **warning ver025** 0 endmembers for Gt(WPH) The solution will not be considered. **warning ver025** 0 endmembers for casmelt The solution will not be considered. **warning ver025** 0 endmembers for A-phase The solution will not be considered. **warning ver025** 0 endmembers for Chum The solution will not be considered. **warning ver025** 1 endmembers for B The solution will not be considered. **warning ver025** 0 endmembers for Pl(I1,HP) The solution will not be considered. **warning ver025** 0 endmembers for Fsp(C1) The solution will not be considered. **warning ver025** 0 endmembers for oCcM(HP) The solution will not be considered. **warning ver025** 0 endmembers for Tour(V) The solution will not be considered. **warning ver025** 0 endmembers for DoDo The solution will not be considered. **warning ver025** 0 endmembers for Wus(fab) The solution will not be considered. **warning ver025** 0 endmembers for Aki(fab) The solution will not be considered. **warning ver025** 0 endmembers for Pv(fab) The solution will not be considered. **warning ver025** 0 endmembers for Ppv(og) The solution will not be considered. **warning ver025** 0 endmembers for O(stx) The solution will not be considered. **warning ver025** 0 endmembers for Wad(stx) The solution will not be considered. **warning ver025** 0 endmembers for Ring(stx) The solution will not be considered. **warning ver025** 0 endmembers for Sp(stx) The solution will not be considered. **warning ver025** 0 endmembers for Gt(stx) The solution will not be considered. **warning ver025** 0 endmembers for C2/c(stx) The solution will not be considered. **warning ver025** 0 endmembers for Opx(stx) The solution will not be considered. **warning ver025** 0 endmembers for Cpx(stx) The solution will not be considered. **warning ver025** 0 endmembers for Cpx(stx7) The solution will not be considered. **warning ver025** 0 endmembers for Omph(HP) The solution will not be considered. **warning ver025** 0 endmembers for Cpx(HP) The solution will not be considered. **warning ver025** 1 endmembers for CrSp The solution will not be considered. **warning ver025** 1 endmembers for Eskol(C) The solution will not be considered. **warning ver025** 0 endmembers for Wus(stx7) The solution will not be considered. **warning ver025** 0 endmembers for Aki(stx7) The solution will not be considered. **warning ver025** 0 endmembers for Pv(stx7) The solution will not be considered. **warning ver025** 0 endmembers for O(stx7) The solution will not be considered. **warning ver025** 0 endmembers for Wad(stx7) The solution will not be considered. **warning ver025** 0 endmembers for Ring(stx7) The solution will not be considered. **warning ver025** 0 endmembers for Sp(stx7) The solution will not be considered. **warning ver025** 1 endmembers for Sp(WPC) The solution will not be considered. **warning ver025** 0 endmembers for Cpx(m) The solution will not be considered. **warning ver025** 0 endmembers for Ol(m) The solution will not be considered. **warning ver025** 0 endmembers for Pl(stx8) The solution will not be considered. **warning ver025** 0 endmembers for Sp(stx8) The solution will not be considered. **warning ver025** 0 endmembers for O(stx8) The solution will not be considered. **warning ver025** 0 endmembers for Wad(stx8) The solution will not be considered. **warning ver025** 0 endmembers for Ring(stx8) The solution will not be considered. **warning ver025** 0 endmembers for Opx(stx8) The solution will not be considered. **warning ver025** 0 endmembers for Cpx(stx8) The solution will not be considered. **warning ver025** 0 endmembers for Aki(stx8) The solution will not be considered. **warning ver025** 0 endmembers for Gt(stx8) The solution will not be considered. **warning ver025** 0 endmembers for Ppv(stx8) The solution will not be considered. **warning ver025** 0 endmembers for CF(stx8) The solution will not be considered. **warning ver025** 0 endmembers for Pu(M) The solution will not be considered. **warning ver025** 0 endmembers for Act(M) The solution will not be considered. **warning ver025** 0 endmembers for Stlp(M) The solution will not be considered. **warning ver025** 0 endmembers for Mica(M) The solution will not be considered. **warning ver025** 0 endmembers for Carp(M) The solution will not be considered. **warning ver025** 0 endmembers for Sud(M) The solution will not be considered. **warning ver025** 0 endmembers for Carb(M) The solution will not be considered. **warning ver025** 0 endmembers for Bio(HP) The solution will not be considered. **warning ver025** 0 endmembers for Mica(SGH) The solution will not be considered. **warning ver025** 0 endmembers for Ctd(SGH) The solution will not be considered. **warning ver025** 0 endmembers for Carp(SGH) The solution will not be considered. **warning ver025** 0 endmembers for Gt(WPPH) The solution will not be considered. **warning ver025** 0 endmembers for cAmph(DP) The solution will not be considered. **warning ver025** 0 endmembers for oAmph(DP) The solution will not be considered. **warning ver025** 0 endmembers for Omph(GHP) The solution will not be considered. **warning ver025** 1 endmembers for FeSi(BCC) The solution will not be considered. **warning ver025** 0 endmembers for FeSi(fcc) The solution will not be considered. **warning ver025** 0 endmembers for oFeSi(bcc) The solution will not be considered. **warning ver025** 0 endmembers for FeSi_liq The solution will not be considered. **warning ver025** 0 endmembers for ZrRu The solution will not be considered. **warning ver025** 0 endmembers for ZrGt(KP) The solution will not be considered. **warning ver025** 0 endmembers for Si-Fluid The solution will not be considered. **warning ver114** the following endmembers are missing for COH-Fluid CO2 CH4 SO2 CO O2 NH3 **warning ver114** the following endmembers are missing for COH-Fluid+ CO2 CH4 SO2 CO **warning ver025** 1 endmembers for C-H-Fluid The solution will not be considered. **warning ver114** the following endmembers are missing for HOS-Fluid SO2 **warning ver025** 0 endmembers for Maj The solution will not be considered. **warning ver025** 0 endmembers for Wad The solution will not be considered. **warning ver025** 0 endmembers for Ring The solution will not be considered. **warning ver025** 1 endmembers for Wus The solution will not be considered. **warning ver025** 0 endmembers for Aki The solution will not be considered. **warning ver025** 0 endmembers for Pv The solution will not be considered. **warning ver025** 0 endmembers for FeSiC_liq The solution will not be considered. **warning ver025** 0 endmembers for Sapp(TP) The solution will not be considered. **warning ver025** 0 endmembers for oCcM(EF) The solution will not be considered. **warning ver025** 0 endmembers for LIQ(NK) The solution will not be considered. **warning ver025** 0 endmembers for LIQ(EF) The solution will not be considered. **warning ver025** 0 endmembers for dis(EF) The solution will not be considered. **warning ver025** 0 endmembers for Si-vapor The solution will not be considered. **warning ver025** 0 endmembers for CCO-vapor The solution will not be considered. **warning ver025** 0 endmembers for ideal_gas The solution will not be considered. **warning ver025** 0 endmembers for FeSiC-BCC The solution will not be considered. **warning ver025** 0 endmembers for FeSiC-FCC The solution will not be considered. **warning ver025** 0 endmembers for FeCr(liq) The solution will not be considered. **warning ver025** 0 endmembers for FeCr-FCC The solution will not be considered. **warning ver025** 0 endmembers for FeCr-BCC The solution will not be considered. **warning ver025** 0 endmembers for FeCr-s The solution will not be considered. **warning ver025** 0 endmembers for FeCliq The solution will not be considered. **warning ver025** 0 endmembers for FeCfcc The solution will not be considered. **warning ver025** 0 endmembers for FeCbcc The solution will not be considered. **warning ver025** 1 endmembers for Ilm(WPH) The solution will not be considered. **warning ver025** 0 endmembers for Gt(H) The solution will not be considered. **warning ver025** 1 endmembers for Fper(H) The solution will not be considered. **warning ver025** 0 endmembers for Mpv(H) The solution will not be considered. **warning ver025** 0 endmembers for Cpv(H) The solution will not be considered. **warning ver025** 0 endmembers for Cor(H) The solution will not be considered. **warning ver025** 0 endmembers for CFer(H) The solution will not be considered. **warning ver025** 0 endmembers for NAl(H) The solution will not be considered. **warning ver025** 0 endmembers for Aki(H) The solution will not be considered. **warning ver025** 0 endmembers for Wad(H) The solution will not be considered. **warning ver025** 0 endmembers for Ring(H) The solution will not be considered. **warning ver025** 0 endmembers for Hpx(H) The solution will not be considered. **warning ver025** 0 endmembers for Po(SE) The solution will not be considered. **warning ver025** 0 endmembers for FeS_liq The solution will not be considered. **warning ver025** 0 endmembers for cAmph(G)_I The solution will not be considered. **warning ver025** 0 endmembers for T The solution will not be considered. **warning ver025** 0 endmembers for Atg(PN) The solution will not be considered. **warning ver025** 0 endmembers for GlTrTsMr The solution will not be considered. **warning ver025** 0 endmembers for Ca-Amph(D) The solution will not be considered. **warning ver025** 0 endmembers for Na-Amph(D) The solution will not be considered. **warning ver025** 0 endmembers for o-Amph The solution will not be considered. **warning ver025** 0 endmembers for GlTrTsPg The solution will not be considered. **warning ver025** 0 endmembers for Amph(DHP) The solution will not be considered. **warning ver025** 0 endmembers for Amph(DPW) The solution will not be considered. **warning ver025** 0 endmembers for Sapp(HP) The solution will not be considered. **warning ver025** 0 endmembers for Sapp(KWP) The solution will not be considered. **warning ver025** 0 endmembers for Chl(HP) The solution will not be considered. **warning ver025** 0 endmembers for Chl(LWV) The solution will not be considered. Select models from the following list, enter 1 per line, press to finish liquid models: melt(H) pyrrhotite models: Po(HP) fluid models: COH-Fluid COH-Fluid+ WADDAH HOS-Fluid For details on these models see: www.perplex.ethz.ch/perplex_solution_model_glossary.html or read the commentary in the solution model file. COH-Fluid Po(HP) Enter calculation title: kn7 fo2 vs fs2 with a GFSM H-O-S fluid